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Ni–Co bimetallic coordination effect for long lifetime rechargeable Zn–air battery

Journal of Energy Chemistry 2020年第8期29卷 146-154,I0005页

作者： Mengfei Qiao Ying Wang thomas wagberg Xamxikamar Mamat Xun Hu Guoan Zou Guangzhi Hu Key Laboratory of Xinjiang Indigenous Medicinal Plants Resource Utilization and Key Laboratory of Plant Resources and Chemistry in Arid RegionsXinjiang Technical Institute of Physics and ChemistryChinese Academy of SciencesUrumqi 830011XinjiangChina Department of Physics Umea UniversityS-90187 UmeaSweden School of Material Science and Engineering University of JinanJinan 250022ShandongChina University of Chinese Academy of Sciences Beijing 100049China

The development of bifunctional oxygen electrocatalysts with high efficiency, high stability, and low cost is of great significance to the industrialization of rechargeable Zn–air batteries. A widely accepted view is that the oxygen reduction reaction(ORR) and the oxygen evolution reaction(OER) follow different catalytic mechanisms, and accordingly they need different active sites for catalysis. Transition metal elements have admirable electronic acceptance ability for coordinating with reactants, and this can weaken the bond energy between reactants, thus promoting the ORR or OER reactions. Herein, the ORR and OER activities of different transition metal supported nitrogen-doped carbon nanotubes were systematically studied and compared. The optimal catalyst for synchronous ORR and OER was obtained by pyrolyzing melamine, cobalt nitrate, and nickel nitrate on carbon nanotubes, called cobalt–nickel supported nitrogenmixed carbon nanotubes(CoNi–NCNT), which were equipped with two types of high-performance active sites—the Co/Ni–N–C structure for the ORR and Co Ni alloy particles for the OER—simultaneously. Remarkably, the optimized Co Ni–NCNT exhibited a satisfactory bifunctional catalytic activity for both the ORR and OER. The value of the oxygen electrode activity parameter,△E, of CoNi–NCNT was 0.81 V, which surpasses that of catalysts Pt/C and Ir/C, and most of the non-precious metal-based bifunctional electrocatalysts reported in previous literatures. Furthermore, a specially assembled rechargeable Zn–air cell with Co Ni–NCNT loaded carbon paper as an air cathode was used to evaluate the practicability. As a result, a superior specific capacity of 744.3 mAh/gZn, a peak power density of 88 mW/cm2, and an excellent rechargeable cycling stability were observed, and these endow the Co Ni–NCNT with promising prospects for practical application.

关键词： Bifunctional catalysis Oxygen reduction reaction Oxygen evolution reaction Carbon nanotubes Zn–air battery

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NiCo_(2)O_(4) hollow microsphere-mediated ultrafast peroxymonosulfate activation for dye degradation

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Chinese Chemical Letters 2021年第8期32卷 2495-2498页

作者： Pengjia Ding Jianrui Niu Fengqin Chang Zhuang He thomas wagberg Zaixing Li Guangzhi Hu College of Environmental Science and Engineering Hebei University of Science and TechnologyShijiazhuang 050018China Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan UniversityKunming 650504China Department of Physics Umea UniversityUmeå90187Sweden

Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of an NH_(3) *** physical structure and chemical properties were characterized using techniques such as scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),N2 adsorption and X-ray photoelectron spectroscopy(XPS).The test results confirm that the inner and outer surfaces of open-type NiCo_(2)O_(4) hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst,which can minimize the diffusion resistance of the reactants and *** optimized conditions,the total orga nic carbon(TOC) removal efficiency of rhodamine B(RhB) can reach up to 80% in 40 min,which is almost 50% shorter than the reported *** reactive radicals were identified and the proposed reaction mechanism was well ***,the disturbances of HCO_(3)^(-),NO_(3)^(-),Cl^(-)and H_(2) PO_(4)^(-)were further *** a result,HCO_(3)-and NO_(3)-suppressed the reaction while Cl-and H_(2) PO4-had a double effect on reaction.

关键词： Open-type sphere Hollow NiCo_(2)O_(4) Vesicle Inner and outer surface Ultra peroxymonosulfate activation

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Photocatalytic reduction of CO2 with H2O over modified TiO2 nanofibers： Understanding the reduction pathway

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Nano Research 2016年第7期9卷 1956-1968页

作者： Anjana Sarkar Eduardo Gracia-Espino thomas wagberg Andrey Shchukarev Melinda Mohl Anne-Riikka Rautio Olli Pitkanen Tiva Sharifi Krisztian Kordas Jyri-Pekka Mikkola Technical Chemistry Department of Chemistry Chemical-Biological Centre Umea University SE-901 87 Umea Sweden Department of Physics Umea University SE-901 87 Umea Sweden Microelectronics and Materials Physics Laboratories Department of Electrical Engineering University of Oulu P.O. Box 4500 Oulu FI-90014 Finland Laboratory of Industrial Chemistry and Reaction Engineering Johan Gadofin Process Chemistry Centre Abo Akademi University Biskopsgatan 8 Abo-Turku FI-20500 Finland

Nanosized metal （Pt or Pd）-decorated TiO2 nanofibers （NFs） were synthesized by a wet impregnation method. CdSe quantum dots （QDs） were then anchored onto the metal-decorated TiO2 NFs. The photocatalytic performance of these catalysts was tested for activation and reduction of CO2 under UV-B light. Gas chromatographic analysis indicated the formation of methanol, formic acid, and methyl formate as the primary products. In the absence of CdSe QDs, Pd-decorated TiO2 NFs were found to exhibit enhanced performance compared to Pt-decorated TiO2 NFs for methanol production. However, in the presence of CdSe, Pt-decorated TiO2 NFs exhibited higher selectivity for methanol, typically producing -90 ppmg^-1.h^-1 methanol. The CO2 photoreduction mechanism is proposed to take place via a hydrogenation pathway from first principles calculations, which complement the experimental observations.

关键词： TiO2 photocatalysis CdSe quantum dots CO2 photoreduction

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Spontaneous twisting of a collapsed carbon nanotube

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Nano Research 2017年第6期10卷 1942-1949页

作者： Hamid Reza Barzegar Aiming Yan Sinisa Coh Eduardo Gracia-Espino Claudia Ojeda-Aristizabal Gabriel Dunn Marvin L. Cohen Steven G. Louie thomas wagberg Alex Zettl Department of Physics University of California Berkeley CA 94720 USA Department of Physics Umea University 90187 Umea Sweden Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

We study the collapsing and subsequent spontaneous twisting of a carbon nanotube by in situ transmission electron microscopy （TEM）. A custom-sized nanotube is first created in the microscope by selectively extracting shells from a parent multi-walled tube. The few-walled, large-diameter daughter nanotube is driven to collapse via mechanical stimulation, after which the ribbon-like collapsed tube spontaneously twists along its long axis. In situ diffraction experiments fully characterize the uncollapsed and collapsed tubes. The experimental observations and associated theoretical analysis indicate that the origin of the twisting is compressive strain.

关键词： multi-walled carbonnanotube collapsed carbon nanotube in situ TEM electron diffraction twisting graphene nanoribbons

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One-pot synthesis of Pd-Au-alloy-nanoparticle-decorated graphene oxide functionalized with dodecahydrododecaborate cluster for rapid and complete reduction of 4-nitrophenol at room temperature

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Rare Metals 2023年第11期42卷 3622-3629页

作者： Yu-Bo Ma Yu-Wen Wang Da-Feng Zhang Xiu-Xiu Jia Yin Wang Shu-Xing Zhou thomas wagberg Guang-Zhi Hu School of Chemical Engineering Chongqing Chemical Industry Vocational CollegeChongqing401220China School of Materials and Energy Institute for Ecological Research and Pollution Control of Plateau LakesYunnan UniversityKunming650504China School of Materials Science and Engineering Liaocheng UniversityLiaocheng252000China Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang441053China Department of Physics UmeåUniversity90187UmeåSweden

The treatment of nitroaromatics in wastewater is a significant issue that must be addressed because of their high *** catalytic reduction of 4-nitrophenol(4-NP)to the widely used 4-aminophenol(4-AP)is an excellent method for 4-NP ***,performing this reaction is *** this study,two-dimensional(2D)graphene oxide(GO)with oxygen-containing surface groups was used as a substrate for the in situ anchoring ofPdAu alloy nanocrystals.

关键词： alloy rapid cluster

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Fe-substituted cobalt-phosphate polyoxometalates as enhanced oxygen evolution catalysts in acidic media

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Chinese Journal of Catalysis 2020年第5期41卷 853-857页

作者： Xin-Bao Han Dong-Xue Wang Eduardo Gracia-Espino Yu-Hui Luo Yuan-Zhi Tan Dong-Fei Lu Yang-Guang Li thomas wagberg En-Bo Wang Lan-Sun Zheng State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005FujianChina Key Laboratory of Polyoxometalate Science of the Ministry of Education Faculty of ChemistryNortheast Normal UniversityChangchun 130024JilinChina Department of Physics Ume?UniversityUme?90187Sweden Department of Chemical Engineering Huaihai Institute of TechnologyLianyungang 222000JiangsuChina

All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable ***,their atomically precise structures remain undefined,complicating their optimization and limiting the understanding of their enhanced ***,the underlying structure-property correlation is explored by using a well-defined cobalt-phosphate polyoxometalate cluster [{(Co4)(OH)3(PO4)}4(SiW9 O34)4]^32-(1),which may serve as a molecular model of multimetal hydr(oxy)*** catalytic activity is enhanced upon replacing Co by Fe in 1,resulting in a reduced overpotential(385 mV) for oxygen evolution(by 66 mV) compared to that of the parent 1 at 10 mA cm^-2 in an acidic medium;this overpotential is comparable to that for the IrO2 catalyst These abundant-metal-based polyoxometalates exhibit high stability,with no evidence of degradation even after 24 h of operation.

关键词： Colbalt-phosphate Polyoxometalate Oxygen evolution reaction Isostructural substitution

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A4C60的高压拉曼光谱研究（A=Li,Na,Rb）

A4C60的高压拉曼光谱研究（A=Li,Na,Rb）

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第十六届全国光散射学术会议

作者：姚明光刘冰冰 thomas wagberg Bertil Sundqvist 吉林大学物理学院超硬材料国家重点实验室 Umea university department of physics

＜正＞碱金属掺杂富勒烯（AxC60,A代表碱金属）具有丰富的结构和电子特性,其特性与掺杂的碱金属种类和浓度密切相关,如电学上可以呈现半导体性、金属性甚至超导特性。从富勒烯带结构理论来看,每个C60分子可以接受六个电子,而非饱和掺杂...

＜正＞碱金属掺杂富勒烯（AxC60,A代表碱金属）具有丰富的结构和电子特性,其特性与掺杂的碱金属种类和浓度密切相关,如电学上可以呈现半导体性、金属性甚至超导特性。从富勒烯带结构理论来看,每个C60分子可以接受六个电子,而非饱和掺杂的富勒烯都可呈现金属特性,因此A3C60具有金属性而A6C60是绝缘体。但实验上却发现A4C60出现反常,主要呈现出半导体性质,因为根据带结构理论,4个碱金属离子掺杂的C60分子应具有金属特性。因此,很多研究致力于理解A4C60的这一

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Tuning beneficial calcineurin phosphatase activation to counterα-synuclein toxicity in a yeast model of Parkinson’s disease

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Neural Regeneration Research 2025年第1期20卷 199-200页

作者： Srishti Chawla Mikael Molin thomas Nystrom Institute for Biomedicine Sahlgrenska AcademyCentre for Ageing and Health-AgeCapUniversity of GothenburgGothenburgSweden Department of Life Sciences Chalmers University of TechnologyGothenburgSweden

Calcineurin(CN)is a calcium-and calmodulindependent serine/threonine that has been studied in many model organisms including yeast,filamentous fungi,plants,and *** biological functions range from ion homeostasis and virulence in lower eukaryotes to T-cell activation in humans by human nuclear factors of activated *** is a heterodimeric protein consisting of a catalytic subunit,calcineurin A(Cna1p),which contains an active site with a dinuclear metal center,and a regulatory Ca^(2+) binding subunit called calcineurin B(Cnb1p)required to activate *** calcineurin B subunit has been highly conserved through evolution:For example,the mammalian calcineurin B shows 54%identity with calcineurin B from Saccharomyces cerevisiae.

关键词： activation dinuclear conserved

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Microglia:a promising therapeutic target in spinal cord injury

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Neural Regeneration Research 2025年第2期20卷 454-463页

作者： Xiaowei Zha Guoli Zheng thomas Skutella Karl Kiening Andreas Unterberg Alexander Younsi Department of Neurosurgery Heidelberg University HospitalHeidelbergGermany Department of Neuroanatomy Institute for Anatomy and Cell BiologyHeidelberg UniversityHeidelbergGermany

Microglia are present throughout the central nervous system and are vital in neural repair,nutrition,phagocytosis,immunological regulation,and maintaining neuronal *** a healthy spinal cord,microglia are accountable for immune surveillance,however,when a spinal cord injury occurs,the microenvironment drastically changes,leading to glial scars and failed axonal *** this context,microglia vary their gene and protein expression during activation,and proliferation in reaction to the injury,influencing injury responses both favorably and unfavorably.A dynamic and multifaceted injury response is mediated by microglia,which interact directly with neurons,astrocytes,oligodendrocytes,and neural stem/progenitor *** a clear understanding of their essential nature and origin,the mechanisms of action and new functions of microglia in spinal cord injury require extensive *** review summarizes current studies on microglial genesis,physiological function,and pathological state,highlights their crucial roles in spinal cord injury,and proposes microglia as a therapeutic target.

关键词： astrocytes cytokines functional recovery immune regulation M1/M2 activation macrophages microglia neuroinflammation spinal cord injury therapy

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Sleep as a window to understand and regulate Alzheimer's disease:emerging roles of thalamic reticular nucleus

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Neural Regeneration Research 2025年第6期20卷 1711-1712页

作者： Haoqi Sun Shiqian Shen Robert J.thomas M.Brandon Westover Can Zhang Department of Neurology Beth Israel Deaconess Medical CenterHarvard Medical SchoolBostonMAUSA Center for Translational Pain Research Department of AnesthesiaCritical Care and Pain MedicineMassachusetis General HospitalHarvard Medical SchoolBostonMAUSA Division of Pulmonary Critical Care and Sleep MedicineDepartment of MedicineBeth Israel Deaconess Medical CenterHarvard Medical SchoolBostonMAUSA Genetics and Aging Research Unit McCance Center for Brain HealthMass General Institute for Neurodegenerative DiseaseDepartment of NeurologyMassachusetts General HospitalHarvard Medical SchoolBostonMAUSA

Introduction:Alzheimer 's disease(AD) is a common neurodegenerative disorder and the primary cause of dementia. Considerable evidence supports the “amyloid hypothesis,” stating that the pathogenesis of AD is primarily caused by the deposition of amyloid-β(Aβ), which drives tau phosphorylation, neuroinflammation, and neurodegeneration in the brain. The amyloid hypothesis is strengthened by the significant and moderate benefit of lecanemab, a humanized antibody through an anti-amyloid mechanism,showing slowed clinical decline(van Dyck et al.,2023). The recent positive results of anti-amyloid trials have brought back focus on the amyloid hypothesis through biochemical, genetic, and pharmacological approaches(Zhang, 2023).

关键词： Alzheimer inflammation hypothesis

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