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Evaluation of Corrosion Stability of Water Soluble Epoxy-Ester Primer through Electrochemical Studies

Materials Sciences and Applications 2012年第6期3卷 333-347页

作者： Duraisamy Ramesh thiagarajan vasudevan Department of Industrial Chemistry Alagappa University Karaikudi India

The corrosion behavior of water borne epoxy-ester primer coatings (10% - 50% PVCs) was evaluated through electrochemical techniques such as polarization and impedance spectroscopic (EIS) measurements. Studies were carried out for a longer duration of exposure extending up to 60 days in aqueous solution of NaCl (5%). Corrosion current (icorr), Corrosion potential (Ecorr), Coating resistance (Rc), Charge transfer resistance (Rct), Coating capacitance (Cc), Double layer capacitance (Cdl), break point frequency (fb), Water uptake (∮), diffusion coefficient (Dw) etc., indicated that 10% - 30% PVC coatings performed well in comparison to higher PVCs. Changes in the electrochemical characteristics were found to occur as a function of exposure time in all cases. The corrosion stability of the coatings were found to be greatly affected by the percentage of PVCs. Studies further indicated that when lower concentration of pigments were available, they remained completely surrounded by the binder;Thus leaving no space for the entry of corrosive agents. From these studies, it was concluded that the water borne paints could replace the conventional coatings, containing organic solvents. Therefore, water soluble epoxy-ester primers have to be employed in paints for developing eco- friendly coatings.

关键词： Epoxy-Ester Water Borne Paint Polarization and Electrochemical Impedance (EIS) Measurements

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