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Extension of pilot tests of cyanide elimination by ozone from blast furnace gas washing water through Aspen Plus based model

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Frontiers of Chemical Science and Engineering 2018年第4期12卷 718-730页

作者： Ismael Matino Valentina CoHa teresa a.branca Scuola Superiore Sant' Anna TeCIP Institute-ICT-COISP56124 PisaItaly

For improving wastewater quality, one of the dare of steelworks is reducing cyanide in wastewater of gas washing treatment of blast furnaces. Costs of existing treatments, stringent environmental regulations and changeable composition of water from gas treatment, have led to study how available treatments can be modified and to examine new ones. Ozonation is one of cyanide treatments, tested within a European project. A process model was set up with Aspen Plus®, to assess operating conditions and wastewater distinctive characteristics and to demonstrate treatment robustness. Process was modeled by theoretical reactors, taking into account all more affecting reactions. A genetic algorithm was exploited to find kinetic parameters of these reactions. After validation, the model was used to analyse scenarios, by considering also real contexts. Pilot tests were extended, process knowledge was enhanced and suggestions were obtained. To promote cyanide removal with ozone, temperature and pH values were 30°C and 10, respectively. With an ozone (mg/h)/water (L/h) ratio of 100 mg/L, batch mode ensure reaching cyanide regulation limit (0.2 mg/L) after maximum 4.5 h, if initial amount was less than 20 mg/L. Higher removal was obtained than in continuous mode due to constraints related to this last run. Higher wastewater contamination needed further time and more ozone.

关键词： blast furnace cyanide removal gas washing water modeling and simulation ozonation

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Recovery of Scenic Beauty of a Lake in Urban Park from Environmental Diagnosis and Implantation of Mitigating Measures

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Journal of Water Resource and Protection 2019年第5期11卷 595-605页

作者： Joã o Alexandre Saviolo Osti Clovis Ferreira Do Carmo Marcos Cerqueira Maria teresa Duarte Giamas Ana Carolina Peixoto Cacilda Thais Janson Cacilda Thais Janson Pesquisador Associado ao Instituto de Pesca S&#227 o Paulo Brasil Professor Colaborador à Universidade Brasil Fernand&#243 polis Brasil Centro de Pesquisa em Recursos Hí dricos Instituto de Pesca APTA-SAA S&#227 o Paulo Brasil Pesquisador Cientí fico do Instituto de Pesca S&#227 o Paulo Brasil Aluna PIBIC de Iniciaç o Cientí fica do Instituto de Pesca S&#227 o Paulo Brasil

The city of S?o Paulo, state of S?o Paulo/Brazil, with about 12 million inhabitants is considered the largest city in Latin America. Just as in other large metropolises it is devoid of green areas, in this way it is of great socio-environmental importance of the preservation and maintenance of parks and green areas of the municipality. The Fernando Costa Park, known as the Parque da água.branca, is an urban park located in the central region of the Municipality of S?o Paulo, and has more than 79 thousand m2 of green area, in a total area of 137 thousand m2. Two lakes, populated predominantly with carp, are inserted in the Park, and are important components of the urban landscape and the patrimony of the city, present landscape function (scenic beauty) and are used to contemplate the environment and leisure of the population. The lakes due to the intense eutrophication process with uncontrolled growth of the phytoplankton presented blue-green coloration, with formations of lumps and foams, low transparency, bad smell and unpleasant visual aspect impairing the visitation of this place. In the first stage of the present research, an environmental diagnosis was carried out and the second stage involved elaboration and implementation of mitigating measures aiming at its restoration. The recovery proposal included the implementation of Artificial Floating Islands (IFAs) aiming at pollution control. After 60 days, it was possible to observe the efficiency of the Eichhornia crassipes populated islands showing that the methodology of phytoremediation was efficient in controlling the eutrophication of urban lakes, guaranteeing the recovery and conservation of the scenic beauty of these places.

关键词： Water Quality Eutrophication Pollution Landscape Ecology

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