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真空低温烹饪温度对肌原纤维蛋白凝胶特性和结构的影响

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食品与发酵工业 2024年第18期50卷 240-246页

作者：李甜甜谭青玲卢家维吴淼叶柯夏杨毅西南大学食品科学学院重庆400715 重庆市特色食品工程技术研究中心重庆400715

以鸭肉为原料提取肌原纤维蛋白(myofibrillar protein,MP),在真空且较低温度(60~80℃)条件下制备凝胶,以高温(100℃)、非真空MP凝胶为对照,探究真空低温烹饪(sous-vide cooking,SVC)温度对肌原纤维蛋白凝胶特性和结构的影响。结果表明,... 详细信息

以鸭肉为原料提取肌原纤维蛋白(myofibrillar protein,MP),在真空且较低温度(60~80℃)条件下制备凝胶,以高温(100℃)、非真空MP凝胶为对照,探究真空低温烹饪(sous-vide cooking,SVC)温度对肌原纤维蛋白凝胶特性和结构的影响。结果表明,SVC条件制备的MP凝胶的白度值、持水性、弹性和化学作用力显著高于对照组(P<0.05),蒸煮损失率和硬度显著低于对照组(P<0.05);随着SVC的温度升高,MP凝胶的持水性、硬度、咀嚼性、胶黏性先增加后降低(P<0.05),70℃条件的MP凝胶持水性(84%)、硬度(99.392 g)、弹性(0.9488)达到最大值;SVC下凝胶的α-螺旋和β-转角含量降低(P<0.05)、β-折叠含量增加(P<0.05),且70℃条件的MP凝胶具有清晰且规则的网状结构,孔径最小。因此,SVC技术能显著提高MP凝胶特性,在低温肉制品加工中潜力巨大。

关键词：真空低温烹饪肌原纤维蛋白凝胶特性结构

基于二段油炒的猪肉预制熟度及其复热品质特性变化

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食品研究与开发 2024年第16期45卷 19-26页

作者：叶柯卢家维吴淼李甜甜夏杨毅谭青玲西南大学食品科学学院重庆400715 川渝共建特色食品重庆市重点实验室重庆400715

熟度是肉制品的熟化程度,肉制品常采用油炒烹饪至食用熟度,预制菜肴根据中心温度(40~85℃)进行不同熟度预制,食用前复热至安全食用熟度。本试验以猪里脊肉为原料,用1段油炒预制低、中、高3个熟度,然后2段油炒复热至食用熟度,分析不同熟... 详细信息

熟度是肉制品的熟化程度,肉制品常采用油炒烹饪至食用熟度,预制菜肴根据中心温度(40~85℃)进行不同熟度预制,食用前复热至安全食用熟度。本试验以猪里脊肉为原料,用1段油炒预制低、中、高3个熟度,然后2段油炒复热至食用熟度,分析不同熟度的猪肉品质特性变化。结果表明:随着1段油炒预制熟度增加,2段油炒复热后的猪肉出品率及水分含量均显著降低(P<0.05),低熟度1段油炒预制经2段油炒复热后猪肉出品率与水分含量均最高,分别达到84.18%和57.21%,L^(*)值逐渐减小、a^(*)值和b^(*)值逐渐增加,猪肉颜色发生褐变,剪切力值、硬度、咀嚼性总体增加,低熟度经2段油炒复热后硬度、咀嚼性最低(4 808.35 g、3 634.82)。表明低熟度1段油炒预制的猪肉经过2段油炒复热后有利于保留肉品多汁性、柔嫩口感和色泽等。电子鼻能有效区分猪肉熟度,1段油炒预制熟度越高脂肪氧化程度越深;微观结构发现高熟度1段油炒预制后再经2段油炒复热猪肉的肌纤维收缩空隙变大,组织结构破坏程度加大。因此,猪肉油炒预制宜采用低熟度油炒预制。

关键词：油炒熟度 1段油炒预制 2段油炒复热品质特性

Adaptive Sensor-Fault Tolerant Control of Unmanned Underwater Vehicles With Input Saturation

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IEEE/CAA Journal of Automatica Sinica 2024年第4期11卷 907-918页

作者： Xuerao Wang qingling Wang Yanxu Su Yuncheng Ouyang Changyin Sun the School of Artificial Intelligence the Engineering Research Center of Autonomous Unmanned System Technologyand the Anhui Provincial Engineering Research Center for Unmanned System and Intelligent TechnologyMinistry of EducationAnhui UniversityHefei 230601China the School of Automation Southeast UniversityNanjing 210096China

This paper investigates the tracking control problem for unmanned underwater vehicles(UUVs)systems with sensor faults,input saturation,and external disturbance caused by waves and ocean *** active sensor fault-tolerant control scheme is ***,the developed method only requires the inertia matrix of the UUV,without other dynamic information,and can handle both additive and multiplicative sensor ***,an adaptive fault-tolerant controller is designed to achieve asymptotic tracking control of the UUV by employing robust integral of the sign of error feedback *** is shown that the effect of sensor faults is online estimated and compensated by an adaptive *** the proposed controller,the tracking error and estimation error can asymptotically converge to ***,simulation results are performed to demonstrate the effectiveness of the proposed method.

关键词： Asymptotic stability fault-tolerant control input saturation robust integral of the sign of error unmanned underwater vehicle

WNT7A promotes tumorigenesis of head and neck squamous cell carcinoma via activating FZD7/JAK1/STAT3 signaling

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International Journal of Oral Science 2024年第1期16卷 85-96页

作者： qingling Huang Yi Xiao Ting Lan Youguang Lu Li Huang Dali Zheng Department of Biochemistry and Molecular Biology School of Basic Medical SciencesFujian Medical UniversityFuzhouChina Fujian Key Laboratory of Oral Diseases School and Hospital of StomatologyFujian Medical UniversityFuzhouChina Department of Preventive Dentistry School and Hospital of StomatologyFujian Medical UniversityFuzhouChina Department of Dentistry The First Affiliated Hospital of Fujian Medical UniversityFuzhouChina

Wnt signaling are critical pathway involved in organ development, tumorigenesis, and cancer progression. WNT7A, a member of the Wnt family, remains poorly understood in terms of its role and the underlying molecular mechanisms it entails in head and neck squamous cell carcinoma (HNSCC). According to the Cancer Genome Atlas (TCGA), transcriptome sequencing data of HNSCC, the expression level of WNT7A in tumors was found to be higher than in adjacent normal tissues, which was validated using Real-time RT-PCR and immunohistochemistry. Unexpectedly, overexpression of WNT7A did not activate the canonical Wnt-β-catenin pathway in HNSCC. Instead, our findings suggested that WNT7A potentially activated the FZD7/JAK1/STAT3 signaling pathway, leading to enhanced cell proliferation, self-renewal, and resistance to apoptosis. Furthermore, in a patient-derived xenograft (PDX) tumor model, high expression of WNT7A and phosphorylated STAT3 was observed, which positively correlated with tumor *** findings underscore the significance of WNT7A in HNSCC progression and propose the targeting of key molecules within the FZD7/JAK1/STAT3 pathway as a promising strategy for precise treatment of HNSCC.

关键词： WNT squamous tumorigenesis

Insight into the Alkali Resistance Mechanism of CoMnHPMo Catalyst for NH_(3) Selective Catalytic Reduction of NO

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Transactions of Tianjin University 2024年第4期30卷 324-336页

作者： Kaixin Wang Yunchong Wang Zongxiang Yang Xinyue Wang Caixia Liu qingling Liu Tianjin Key Laboratory of Indoor Air Environmental Quality Control School of Environmental Science and EngineeringTianjin UniversityTianjin 300350China State Key Laboratory of Engines Tianjin UniversityTianjin 300350China

The existence of alkali metals in fl ue gases originating from stationary sources can result in catalyst deactivation in the low-temperature selective catalytic reduction(SCR)of nitrogen oxides(NO_(x)).It is widely accepted that alkali metal poisoning causes damage to the acidic sites of ***,in this study,a series of CoMn catalysts doped with heteropolyacids(HPAs)were prepared using the coprecipitation *** these,CoMnHPMo exhibited superior catalytic performance for SCR and over 95%NO_(x) conversion at 150-300􁕑.Moreover,it exhibited excellent catalytic activity and stability after alkali poisoning,demonstrating outstanding alkali metal *** characterization indicated that HPMo increased the specifi c surface area of the catalyst,which provided abundant adsorption sites for NO_(x) and NH_(3).Comparing catalysts before and after poisoning,CoMnHPMo enhanced its alkali metal resistance by sacrifi cing Brønsted acid sites to protect its Lewis acid *** situ DRIFTS was used to study the reaction pathways of the *** results showed that CoMnHPMo maintained high NH_(3) adsorption capacity after K poisoning and then reacted rapidly with NO intermediates to ensure that the active sites were not ***,SCR performance was ensured even after alkali metal *** sum-mary,this research proposed a simple method for the design of an alkali-resistant NH_(3)-SCR catalyst with high activity at low temperatures.

关键词： NH3-SCR Alkali resistance Phosphomolybdic acid CoMn

B and Fe co-doped Co_(2)P hollow nanocubes for nitrate electroreduction to ammonia

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Chinese Chemical Letters 2024年第2期35卷 278-282页

作者： Jing Miao qingling Hong Liping Liang Guomin Li Zhihong Liu Shibin Yin Yu Chen School of Materials Science and Engineering Taiyuan University of Science and TechnologyTaiyuan 030024China School of Materials Science and Engineering Shaanxi Normal UniversityXi'an 710062China School of Chemistry and Chemical Engineering Shaanxi Normal UniversityXi'an 710062China Guangxi Key Laboratory of Electrochemical Energy Materials School of Chemistry and Chemical EngineeringGuangxi UniversityNanning 530004China

Nitrate(NO_(3)^(−))electroreduction reaction(NO_(3)^(−)RR)provides an attractive and sustainable route for NO_(3)^(−)pollution mitigation or energy-saved ammonia(NH3)*** this work,high-quality B and Fe co-doped Co_(2) P hollow nanocubes(B/Fe-Co_(2) P HNCs)are successfully synthesized though simultaneous boronation-phosphorization treatment,which reveal outstanding selectivity,activity,stability for the NO_(3)^(−)to NH_(3) conversion in neutral electrolyte because of big surface area,fast mass transport,superhydrophilic surface,and optimized electronic structure.B/Fe-Co_(2) P HNCs can achieve the high NH3 yield rate(22.67 mg h^(−1) mg_(cat)^(−1))as well as Faradaic efficiency(97.54%)for NO_(3)^(−)RR,greatly outperforming most of non-precious metal based NO_(3)^(−)RR electrocatalysts.

关键词： Nitrate electroreduction reaction Ammonia synthesis Transition metal phosphides Hollow nanocubes

Mesoporous amorphous FeOOH-encapsulated BiO_(2–x) photocatalyst with harnessing broad spectrum toward activation of persulfate for tetracycline degradation

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Chinese Journal of Chemical Engineering 2024年第7期71卷 235-248页

作者： Pengfei Wu Zhaolong Liu Li Wu Yingkun Zhang Bing Wang Zhanghao Cheng Wenquan Cui Xiangyang Lv qingling Liu Tianjin Key Laboratory of Indoor Air Environmental Quality Control School of Environmental Science and EngineeringTianjin UniversityTianjin 300350China Hebei Pollution Control Technology Innovation Center of Steel and Coking Industry Department of Environmental and Chemical EngineeringHebei College of Industry and TechnologyShijiazhuang 050091China Hebei Key Laboratory of Environmental Photocatalytic and Electrocatalytic Materials College of Chemical EngineeringNorth China University of Science and TechnologyTangshan 063210China Hebei Academy of Product Quality Supervision&Inspection Shijiazhuang 050227China

With the growing concern about the water environment,the advanced oxidation process of persulfate activation assisted by photocatalysis has attracted considerable attention to decompose dissolved organic *** this work,to overcome the drawbacks of the photocatalytic activity reduction caused by the photo-corrosion of non-stoichiometric BiO_(2–x),a novel material with amorphous FeOOH in situ grown on layered BiO_(2–x) to form a core-shell structure similar to popcorn chicken-like morphology was produced in two simple and environmentally beneficial *** a series of degradation activity tests of hybrid materials under different conditions,the as-prepared materials exhibited remarkable degradation activity and stability toward tetracycline in the FeOOH@BiO_(2–x)/Vis/PS system due to the synergism of photocatalysis and persulfate *** results of XRD,SEM,TEM,XPS,FTIR,and BET show that the loading of FeOOH increases the specific surface area and active sites appreciably;the heterogeneous structure formed by FeOOH and BiO_(2–x) is more favorable to the effective separation of photogenerated *** optimal degradation conditions were at a catalyst addition of 0.7 g·L^(–1),a persulfate concentration of 1.0 g·L^(–1),and an initial pH of 4.5,at which the degradation rate could reach 94.7%after 90 *** influence of typical inorganic anions on degradation was also *** studies and radical quenching experiments revealed that·OH,SO_(4)^(-)·,and·O_(2)^(-)were the principal active species generated during the degradation of *** results of the 1,10-phenanthroline approach proved that the effect of dissolved iron ions on the tetracycline degradation was limited,and the interfacial reaction that occurs on the active sites on the material's surface was a critical *** work provides a novel method for producing efficient broad-spectrum Bismuth-based composite photocatalysts and photocatalytic-activated persulfate synerg

关键词： Amorphous FeOOH BiO_(2–x) Activated persulfate Photocatalytic Tetracycline degradation

Adrenal pheochromocytoma impacts three main pathways: cysteine-methionine, pyrimidine, and tyrosine metabolism

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2024年第5期25卷 410-421页

作者： Chong LAI qingling YANG Yunuo ZHANG Renjie GONG Majie WANG Jiankang LI Maode LAI Qingrong SUN Department of Urology the First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003China School of Basic Medical Sciences and Clinical Pharmacy China Pharmaceutical UniversityNanjing 210009China Department of Laboratory Medicine the First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003China Laboratory of Behavioral Neuroscience Ningbo Kangning HospitalNingbo Institute of Microcirculation and HenbaneSchool of MedicineNingbo UniversityNingbo 315201China Xi'an Key Laboratory of Stem Celland Regenerative Medicine Institute of Medical ResearchNorthwestern Polytechnical UniversityXi'an 710072China Department of Pathology Research Unit of Intelligence Classification of Tumor Pathology and Precision TherapyChinese Academy of Medical Sciences Key Laboratory of Disease Proteomics of Zhejiang ProvinceZhejiang University School of MedicineHangzhou 310058China

Pheochromocytomas and paragangliomas(PPGLs)cause symptoms by altering the circulation levels of catecholamines and peptide ***,the diagnosis of PPGLs relies on diagnostic imaging and the detection of *** this study,we used ultra-performance liquid chromatography(UPLC)/quadrupole time-of-flight mass spectrometry(Q-TOF MS)analysis to identify and measure the perioperative differential metabolites in the plasma of adrenal pheochromocytoma *** identified differentially expressed genes by comparing the transcriptomic data of pheochromocytoma with the normal adrenal *** conducting two steps of metabolomics analysis,we identified 111 differential metabolites between the healthy group and the patient group,among which 53 metabolites were *** integrating the information of differential metabolites and differentially expressed genes,we inferred that the cysteine-methionine,pyrimidine,and tyrosine metabolism pathways were the three main metabolic pathways altered by the *** analysis of transcription levels revealed that the tyrosine and cysteine-methionine metabolism pathways were downregulated in pheochromocytoma,whereas the pyrimidine pathway showed no significant ***,we developed an optimized diagnostic model of two metabolites,L-dihydroorotic acid and *** results for these metabolites suggest that they may serve as potential clinical biomarkers and can be used to supplement and improve the diagnosis of pheochromocytoma.

关键词： Pheochromocytoma and paraganglioma(PPGL) Metabolomics Gene set variation analysis L-Dihydroorotic acid Vanylglycol

Organic interfacial engineering of gold nanowires for selective glycerol electrooxidation

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Chinese Chemical Letters 2024年第3期35卷 502-507页

作者： Zhe Wang qingling Hong Boqiang Miao Tianjiao Wang Yu Ding Pujun Jin Pei Chen Yu Chen Key Laboratory of Macromolecular Science of Shaanxi Province Key Laboratory of Applied Surface and Colloid Chemistry(Ministry of Education)Shaanxi Key Laboratory for Advanced Energy DevicesSchool of Materials Science and EngineeringShaanxi Normal UniversityXi'an 710062China

The selective electrochemical conversion of glycerol into value-added products is a green and sustainable strategy for the biomass *** this work,Au nanowires(Au-NW)modified with polyethyleneimine(PEI)molecule(Au-NW@PEI)is obtained by an up-bottom post-modification *** characterization,molecular dynamics simulation and density functional theory demonstrate that the loose-packed PEI monolayer firmly and uniformly distribute on the Au-NW surface due to the strong Au-N *** experiments and product analysis display that PEI modification significantly enhance the electro-activity of Au-NW for the glycerol electro-oxidation reaction(GEOR)due to the electronic ***,the steric hindrance and electrostatic effect of PEI layer make the optimizing adsorption of intermediates ***,the selectivity of C3 product glyceric acid over Au-NW@PEI is increased by nearly 20%.The work thus indicates that the rational design of metal-organic interface can effectively elevate the electro-activity and selectivity of Au nanostructures,which may have wide application in biomass development.

关键词： Glycerol electrooxidation reaction Organic interface engineering Gold-based nanomaterials Electrocatalysis Selectivity