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Thermally activated delayed fluorescence carbazole-triazine dendrimer with bulky substituents

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Aggregate 2024年第1期5卷 236-243页

作者： Hiroki Ikebe Kohei Nakao Eri Hisamura Minori Furukori Yasuo Nakayama Takuya Hosokai Minlang Yang Guanting Liu takuma Yasuda Ken Albrecht Interdisciplinary Graduate School of Engineering Sciences Kyushu UniversityFukuokaJapan Institute for Materials Chemistry and Engineering Kyushu UniversityKasugaJapan Department of Pure and Applied Chemistry Graduate School of Science and TechnologyTokyo University of ScienceNodaChibaJapan National Metrology Institute of Japan(NMIJ) National Institute of Advanced Industrial Science and Technology(AIST)TsukubaIbarakiJapan Institute for Advanced Study Kyushu UniversityNishi-kuFukuokaJapan

Carbazole-triazine dendrimers with a bulky terminal substituent were synthesized,and the thermally activated delayed fluorescence(TADF)property was *** to unsubstituted carbazole dendrimers,dendrimers with bulky terminal substituents showed comparable to better photoluminescence quantum yields(PLQY)in neat ***(PF)-substituted dendrimers showed the highest PLQY of 81%,a smallΔEst of 0.06 eV,and the fastest reverse intersystem crossing(RISC)rate of∼1×10^(5 )s^(−1) compared to other *** measurements of dendrimers and dendrons(fragments)indicate that the close proximity of the triplet energy of phenylfluorene-substituted carbazole dendrons(^(3)LE)to that of phenylfluorene-substituted dendrimers(^(1)CT,^(3)CT)contributes to RISC promotion and improves TADF *** modification fine-tunes the energy level and suppresses intermolecular interactions,and this study provides a guideline for designing efficient solution-processable and non-doped TADF materials.

关键词： dendrimer OLED TADF 1 INTRODUCTION Thermally activated delayed fluorescence(TADF)materials which are inexpensive and highly efficient alternatives to fluorescent

Nonalcoholic steatohepatitis-associated hepatocellular carcinoma:Our case series and literature review

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World Journal of Gastroenterology 2010年第12期16卷 1436-1441页

作者： Yoshitaka takuma Kazuhiro Nouso Department of Gastroenterology Kurashiki Central Hospital Department of Internal Medicine National Hospital Organization Iwakuni Clinical Center Department of Molecular Hepatology Okayama University Graduate School of MedicineDentistryand Pharmaceutical Sciences

Recently,nonalcoholic steatohepatitis(NASH) has been considered to be another cause of liver cirrhosis and hepatocellular carcinoma(HCC).The natural history and prognosis of NASH are ***,we assessed the clinicopathological features of NASH-associated HCC in our experience and reviewed the literature of NASH-associated *** experienced 11 patients with NASH-associated HCC(6 male,5 female;mean age 73.8 ± 4.9 years) who received curative ***(91%) patients had been diagnosed with obesity,diabetes,hypertension,or *** patients(64%) also had a non-cirrhotic *** recurrence-free survival rates at 1,3 and 5 years were 72%,60%,and 60%.We also summarized and reviewed 94 cases of NASH-associated HCC which were reported in the literature(64 male;mean age 66 years).The majority of patients(68%) were obese,66% of patients had diabetes,and 24% had ***,26% of the HCCs arose from the non-cirrhotic *** conclusion,patients with non-cirrhotic NASH may be a high-risk group for HCC,and regular surveillance for HCC is necessary in non-cirrhotic NASH patients as well as cirrhotic patients.

关键词： Nonalcoholic steatohepatitis Hepatocellular carcinoma Nonalcoholic fatty liver disease Cryptogenic cirrhosis

Diffusion and collective motion of rotlets in 2D space

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Chinese Physics B 2020年第6期29卷 37-43页

作者： Daiki Matsunaga Takumi Chodo takuma Kawai Graduate School of Engineering Science Osaka University5608531 OsakaJapan

We investigate the collective motion of rotlets that are placed in a single plane. Due to the hydrodynamic interactions,the particles move through the two-dimensional(2D) plane and we analyze these diffusive motions. By analyzing the scaling of the values, we predict that the diffusion coefficient scales with φ0.5, the average velocity with φ, and relaxation time of the velocity autocorrelation function with φ-1.5, where φ is the area fraction of the particles. In this paper, we find that the predicted scaling could be seen only when the initial particle position is homogeneous. The particle collective motions are different by starting the simulation from random initial positions, and the diffusion coefficient is the largest at a minimum volume fraction of our parameter range, φ = 0.05. The deviations based on two initial positions can be explained by the frequency of the collision events. The particles collide during their movements and the inter-particle distances gradually increase. When the area fraction is large, the particles will result in relatively homogeneous configurations regardless of the initial positions because of many collision events. When the area fraction is small(φ < 0.25), on the other hand, two initial positions would fall into different local solutions because the rare collision events would not modify the inter-particle distances drastically. By starting from the homogeneous initial positions, the particles show the maximum diffusion coefficient at φ≈ 0.20. The diffusion coefficient starts to decrease from this area fraction because the particles start to collide and hinder each other from a critical fraction ~23%. We believe our current work contributes to a basic understanding of the collective motion of rotating units.

关键词： rotlet diffusion Stokes flow

Effect of microstructure on outer surface roughening of magnesium alloy tubes in die-less mandrel drawing

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Journal of Magnesium and Alloys 2022年第10期10卷 2730-2744页

作者： takuma Kishimoto Peihua Du Tsuyoshi Furushima Department of Mechanical and Biofunctional Systems Institute of Industrial ScienceThe University of Tokyo4-6-1 KomabaMeguroTokyo 153-8505Japan

The crystal orientation and outer surface roughening of magnesium alloy tubes were evaluated to clarify the effect of the mandrel on the microstructure and outer surface roughness in die-less mandrel drawing. Locally heated ZM21 tubes with an outer diameter of 6.0 mm and an inner diameter of 3.8 mm were drawn with and without a mandrel. The outer surface roughness and crystal orientation were evaluated in the same measurement area. The results indicated that the outer surface becomes rougher in the die-less mandrel drawing than in die-less drawing for a given outer circumferential strain. The outer surface roughness developed when there was large difference in the pyramidal slip system Schmid factor. Therefore, the slip deformation of the pyramidal slip system seems to be mainly responsible for the outer surface roughening in the die-less mandrel drawing. Furthermore, the crystal grain with the {2110} crystal plane vertical to the normal direction of outer surface had a larger Schmid factor than the other crystal grains. The large number of crystal grains with the {2110} crystal plane in the die-less mandrel drawing is one of the reasons that the outer surface roughness develops more in the die-less mandrel drawing than in die-less drawing for a given outer circumferential strain. These results will contribute significantly to the development of fabrication process of the microtube with high surface quality, which prevents rapid corrosion of biomedical applications.

关键词： Tube forming Die-less drawing Surface roughness Crystal plasticity Magnesium alloy Electron backscatter diffraction

Physiological significance of Rag1 in retinal ganglion cell death

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Neural Regeneration Research 2015年第2期10卷 192-194页

作者： takuma Hayashi Toshinori Murata Department of Immunology and Infectious Disease Shinshu University Graduate School of Medicine Department of Ophthalmology Shinshu University Graduate School of Medicine

Although the transcription factor, nudear factor-κB （NF-κB） is known to regulate cell death and survival, its precise role in cell death within the central nervous system （CNS） remains unknown. We previously reported that mice with a homozygous deficiency for NF-κBp50 spon- taneously developed optic neuropathy. We examined the expression and activation of pro-apoptotic factor（s） that mediate optic neuropathy in p50-/- mice. Recombination activating gene 1 （Ragl） is known to regulate the recombination of immunoglobulin V（D）J.

关键词： RGCs Physiological significance of Rag1 in retinal ganglion cell death cell

Level-of-Detail Rendering of Large-Scale Irregular Volume Datasets Using Particles

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Journal of Computer Science & Technology 2010年第5期25卷 905-915页

作者： takuma Kawamura Naohisa Sakamoto Koji Koyamada Member, IEEE Graduate School of Engineering Kyoto University Kyoto 6068501 Japan Center for the Promotion of Excellence in Higher Education Kyoto University Kyoto 6068501 Japan

This paper describes a level-of-detail rendering technique for large-scale irregular volume *** is well known that the memory bandwidth consumed by visibility sorting becomes the limiting factor when carrying out volume rendering of such *** develop a sorting-free volume rendering technique,we previously proposed a particle-based technique that generates opaque and emissive particles using a density function constant within an irregular volume cell and projects the particles onto an image plane with *** the density function changes significantly in an irregular volume cell,the cell boundary may become prominent,which can cause blocky *** the number of the sub-pixels increases,the required frame buffer tends to be *** solve this problem,this work proposes a new particle-based volume rendering which generates particles using metropolis sampling and renders the particles using the ensemble average. To confirm the effectiveness of this method,we applied our proposed technique to several irregular volume datasets,with the result that the ensemble average outperforms the sub-pixel average in computational complexity and memory usage. In addition,the ensemble average technique allowed us to implement a level of detail in the interactive rendering of a 71-million-cell hexahedral volume dataset and a 26-million-cell quadratic tetrahedral volume dataset.

关键词： large-scale irregular volume level-of-detail volume rendering of unstructured meshes

Autothermal reforming of biogas over a monolithic catalyst

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Journal of Natural Gas Chemistry 2010年第5期19卷 477-481页

作者： Sadao Araki Naoe Hino takuma Mori Susumu Hikazudani Hitachi Zosen Corporation Business & Product Development HeadquartersTechnical Research Institute

This study focused on measurement of the autothermal reforming of biogas over a Ni based monolithic catalyst. The effects of the steam/CH4 （S/C） ratio, O2/CH4 （O2/C） ratio and temperature were investigated. The CH4 conversions were higher under all examined temperatures than the equilibrium conversion calculated using the blank outlet temperature, because the catalyst layer was heated by the exothermic catalytic partial oxidation reaction. The CH 4conversion increased with increasing O2/C ratio. Moreover, the CH4 conversion was higher than the equilibrium conversion calculated using the blank outlet temperature for O2/C〉0.42 and reached about 100% at O2/C=0.55. However, the hydrogen concentration decreased for O2/C〉0.45 because hydrogen was combusted to steam in the presence of excess oxygen. On the other hand, the hydrogen and CO2 concentrations increased and the CO concentration decreased with increasing SIC ratio. As a result, it was found that the highest hydrogen concentrations and CH4 conversions were attained at the O2/C ratios of 0.45-0.55 and the SIC ratios of 1.5-2.5. Moreover, the H2/CO ratio could also be controlled in the range from about 2 to 3.5 to give at least 90% CH4 conversion, by regulating the O2/C or S/C ratios.

关键词： autothermal reforming biogas hydrogen production monolithic catalyst Ni based catalyst

Phenyl-triggered photophysical switching between normal fluorescence and delayed fluorescence in phthalonitrile-based luminophores

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聚集体(英文)

聚集体(英文) 2021年第1期2卷 145-150页

作者： In Seob Park Hyukgi Min takuma Yasuda INAMORI Frontier Research Center(IFRC) Kyushu UniversityFukuokaJapan Department of Applied Chemistry Graduate School of EngineeringKyushu UniversityFukuokaJapan

Herein,a facile strategy for switching luminescent properties between normal fluorescence and thermally activated delayed fluorescence(TADF)is *** luminophoric molecules,VPN-Ph and VPN-H,combining phthalonitrile as an electron-accepting core and triphenylamines as electron-donating peripheries with and without two phenyl groups,are newly developed.A comparative study on their structural and photophysical properties is *** non-phenyl VPN-H does not exhibit TADF but normal fluorescence,phenyl-introduced VPNPh exhibits TADF with a high photoluminescence quantum yield as a consequence of the phenyl-triggered steric *** virtue of the TADF feature,an organic light-emitting diode(OLED)incorporating VPN-Ph as an emitter achieves a maximum external electroluminescence(EL)quantum efficiency as high as 28.0%,which is five times higher than that of the VPN-H-based ***,phenyl-triggered geometric modulation has a drastic impact on the resulting photophysical and EL properties,leading to TADF on/off switching.

关键词： intramolecular charge transfer molecular orientation organic light-emitting diodes photophysical switching phthalonitrile thermally activated delayed fluorescence

Image of Ne Trap by a Microwave Cavity

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Chinese Physics Letters 1997年第2期14卷 93-95页

作者： XU Lei Satoshi Oishi Kazuko Shimizu Hiroshi takuma Fujio Shimizu Department of Physics Fudan UniversityShanghai 200433 Institute for Laser Science The University of Electro-communicationsChofugaokaChofushiTokyo 182Japan Department of Applied Physics University of TokyoBunkyo-kuTokyo 113Japan

The focusing of Ne metastable atoms trapped in magnetic-optical trap by a microwave cavity was *** cavity was operated at TM010 *** a microwave power of 14W,the Ne trap was imaged to a spot of about 0.25mm(full width ... 详细信息

关键词： microwave Microwave cavity