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the proximity between hydroxyl and single atom determines the catalytic reactivity of Rh1/CeO_(2) single-atom catalysts

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Nano Research 2024年第1期17卷 397-406页

作者： Danfeng Wu Shuyun Zhou Congcong Du Juan Li Jianyu Huang Hong-xia Shen Abhaya K.Datye Shan Jiang Jeffrey t.Miller Sen Lin Haifeng Xiong State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China State Key Laboratory of Photocatalysis on Energy and Environment College of ChemistryFuzhou UniversityFuzhou 350002China Clean Nano Energy Center State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004China College of Biology and Chemical Engineering Jiaxing UniversityJiaxing 314000China Department of Chemical&Biological Engineering University of New MexicoAlbuquerqueNM 8731-0001USA Davidson School of Chemical Engineering Purdue UniversityWest LafayetteIN 47907-2100USA Innovation Laboratory for Sciences and technologies of Energy Materials of Fujian Province(IKKEM) Xiamen 361102China Fujian Key Laboratory of Rare-earth Functional Materials Fujian Shanhai Collaborative Innovation Center of Rare-earth Functional MaterialsLongyan 366300China

the local structure of the metal single-atom site is closely related to the catalytic activity of metal single-atom catalysts(SACs).However,constructing SACs with homogeneous metal active sites is a challenge due to the surface heterogeneity of the conventional ***,we prepared two Rh1/CeO_(2)SACs(0.5Rh1/r-CeO_(2)and 0.5Rh1/c-CeO_(2),respectively)using two shaped CeO_(2)(rod and cube)exposing different facets,i.e.,CeO_(2)(111)and CeO_(2)(100).In CO oxidation reaction,the t100 of 0.5Rh1/r-CeO_(2)SACs is 120°C,while the t100 of 0.5Rh1/c-CeO_(2)SACs is as high as 200°*** in-situ CO diffuse reflectance infrared Fourier transform spectroscopy(CO-DRIFtS),we found that the proximity between OH group and Rh single atom on the plane surface plays an important role in the catalytic activity of Rh1/CeO_(2)SAC system in CO *** Rh single atom trapped at the CeO_(2)(111)crystal surface forms the Rh1(OH)adjacent species,which is not found on the CeO_(2)(100)crystal surface at room ***,during CO oxidation,the OH group far from Rh single atom on the 0.5Rh1/c-CeO_(2)disappears and forms Rh1(OH)adjacent species when the temperature is above 150°*** formation of Rh1(OH)adjacentCO intermediate in the reaction is pivotal for the excellent catalytic activity,which explains the difference in the catalytic activity of Rh single atoms on two different CeO_(2)*** formed Rh1(OH)adjacent-O-Ce structure exhibits good stability in the reducing atmosphere,maintaining the Rh atomic dispersion after CO oxidation even when pre-reduced at high temperature of 500°*** functional theory(DFt)calculations validate the unique activity and reaction path of the intermediate Rh1(OH)adjacentCO species *** work demonstrates that the proximity between metal single atom and hydroxyl can determine the formation of active intermediates to affect the catalytic performances in catalysis.

关键词： crystal plane Rh1/CeO_(2)single-atom catalyst proximity of Rh and hydroxyl coordination structure CO oxidation

Number and distribution of eosinophils and lymphocytes in the Japanese pediatric gastrointestinal tract:in search of a definition for"abnormally increased eosinophils"

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World Journal of Pediatrics 2023年第3期19卷 251-260页

作者： Mai Iwaya Shota Kobayashi Yoshiko Nakayama Sawako Kato Shingo Kurasawa t.momit.u sado Yugo lwaya takeshi uehara Hiroyoshi Ota Department of Laboratory Medicine Shinshu University Hospital3-1-1 AsahiMatsumotoNaganoJapan Department of Pediatrics Shinshu University School of MedicineMatsumotoJapan Division of Gastroenterology and Hepatology Department of MedicineShinshu University School of MedicineMatsumotoJapan Department of Laboratory Medicine Shinshu University School of MedicineMatsumotoJapan Department of Clinical Laboratory Sciences School of Health SciencesShinshu UniversityMatsumotoJapan

Background Primary eosinophilic gastrointestinal disorders(EGIDs)constitute chronic allergic *** number of eosinophils is one of the diagnostic criteria;more than 20 eosinophils per high-power field(HPF)in the gastrointestinal(GI)tract are considered abnormal in ***,the quantity of eosinophils considered normal varies according to anatomical location and geographical region;such values have not been reported in Japanese pediatric patients,nor have the numbers of lymphocytes in the normal pediatric *** establish a reference for defining diagnostic criteria for EGIDs,we evaluated the number of eosinophils in the normal Japanese pediatric GI *** We examined 131 biopsy cases without significant clinical history,endoscopic abnormality,or histological *** analysis of CD3 and CD20 was *** the mean eosinophil density was highest in the cecum(49.5±22.4 per HPF).Counts of more than 20 eosinophils per HPF were observed in the duodenum[bulb(20.0±9.6)and second portion(30.0±15.8)],terminal ileum(38.3±22.7),cecum(49.5±22.4),ascending colon(42.3±25.3),transverse colon(29.4±17.0),and descending colon(32.2±17.9).Counts of fewer than 10 eosinophils per HPF were observed in the stomach and rectum;a count of fewer than one eosinophil per HPF was observed in the *** than 100 CD3-positive t cells per HPF were observed in the *** the mean numbers of eosinophils in the bowel were greater than 20 per *** Japanese pediatrics,the cur-rent threshold eosinophil count should be revised.

关键词： Eosinophil Gastrointestinal tract Japanese Lymphocyte Normal Pediatrics

Development,validation,and transportability of several machine-learned,non-exercise-based VO_(2max)prediction models for older adults

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Journal of Sport and Health Science 2024年第5期13卷 611-620页

作者： Benjamin t.Schumacher Michael J.LaMonte Andrea Z.LaCroix Eleanor M.Simonsick Steven P.Hooker Humberto Parada Jr. John Bellettiere Arun Kumar Herbert Wertheim School of Public Health and Human Longevity Science University of California San DiegoLa JollaCA 92093USA Department of Epidemiology and Environmental Health School of Public Health and Health ProfessionsUniversity at BuffaloState University of New YorkBuffaloNY 14214USA translational Gerontology Branch Intramural Research ProgramNational Institute on AgingNational Institutes of HealthBaltimoreMD 21225USA College of Health and Human Services San Diego State UniversitySan DiegoCA 92182USA Division of Epidemiology and Biostatistics School of Public HealthSan Diego State UniversitySan DiegoCA 92182USA university of California San Diego Moores Cancer Center La JollaCA 92093USA Computer Science and Engineering and Halicioglu Data Science Institute University of California San DiegoLa JollaCA 92093USA

Background:there exist few maximal oxygen uptake(VO_(2max))non-exercise-based prediction equations,fewer using machine learning(ML),and none specifically for older *** direct measurement of VO_(2max)is infeasible in large epidemiologic cohort studies,we sought to develop,validate,compare,and assess the transportability of several ML VO_(2max)prediction ***:the Baltimore Longitudinal Study of Aging(BLSA)participants with valid VO2_(max)tests were included(n=1080).Least absolute shrinkage and selection operator,linear-and tree-boosted extreme gradient boosting,random forest,and support vector machine(SVM)algorithms were trained to predict VO_(2max)*** developed these algorithms for:(a)the overall BLSA,(b)by sex,(c)using all BLSA variables,and(d)variables common in aging ***,we quantified the associations between measured and predicted VO_(2max)and ***:the age was 69.0±10.4 years(mean±SD)and the measured VO_(2max)was 21.6±5.9 mL/kg/*** absolute shrinkage and selection operator,linear-and tree-boosted extreme gradient boosting,random forest,and support vector machine yielded root mean squared errors of 3.4 mL/kg/min,3.6 mL/kg/min,3.4 mL/kg/min,3.6 mL/kg/min,and 3.5 mL/kg/min,*** quartiles of measured VO_(2max)showed an inverse gradient in mortality *** VO_(2max)variables yielded similar effect estimates but were not robust to ***:Measured VO_(2max)is a strong predictor of *** ML can improve the accuracy of prediction as compared to simpler approaches but estimates of association with mortality remain sensitive to *** studies should seek to reproduce these results so that VO_(2max),an important vital sign,can be more broadly studied as a modifiable target for promoting functional resiliency and healthy aging.

关键词： Cardiorespiratory fitness Prediction algorithms Epidemiology Mortality

Improved prediction of clay soil expansion using machine learning algorithms and meta-heuristic dichotomous ensemble classifiers

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Geoscience Frontiers 2022年第1期13卷 268-284页

作者： E.u.Eyo S.J.Abbey t.t.Lawrence F.K.tetteh Department of Geography and Environmental Management University of the West of EnglandBristolUnited Kingdom Research Centre for Fluid and Complex Systems Coventry UniversityCoventryUnited Kingdom Department of Civil Engineering University of BirminghamBirminghamUnited Kingdom

Soil swelling-related disaster is considered as one of the most devastating geo-hazards in modern ***,proper determination of a soil’s ability to expand is very vital for achieving a secure and safe ground for ***,this study has provided a novel and intelligent approach that enables an improved estimation of swelling by using kernelised machines(Bayesian linear regression(BLR)&bayes point machine(BPM)support vector machine(SVM)and deep-support vector machine(D-SVM));(multiple linear regressor(REG),logistic regressor(LR)and artificial neural network(ANN)),tree-based algorithms such as decision forest(RDF)&boosted trees(BDt).Also,and for the first time,meta-heuristic classifiers incorporating the techniques of voting(VE)and stacking(SE)were *** independent scenarios of explanatory features’combination that influence soil behaviour in swelling were *** results indicated BLR as possessing the highest amount of deviation from the predictor variable(the actual swell-strain).REG and BLR performed slightly better than ANN while the meta-heuristic learners(VE and SE)produced the best overall performance(greatest R2 value of 0.94 and RMSE of 0.06%exhibited by VE).CEC,plasticity index and moisture content were the features considered to have the highest level of *** binary classifiers(SVM,D-SVM and BPM)gave better accuracy(average accuracy and recall rate of 0.93 and 0.60)compared to ANN,LR and ***-driven diagnostic test indicated that the meta-heuristic models’best performance occurred when ML training was conducted using k-fold validation ***,it is recommended that the concepts developed herein be deployed during the preliminary phases of a geotechnical or geological site characterisation by using the best performing meta-heuristic models via their background coding resource.

关键词： Artificial neural networks Machine learning Clays Algorithm Soil swelling Soil plasticity

Analysis of a Stagnation Point Flow with Hybrid Nanoparticles over a Porous Medium

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Fluid Dynamics & Materials Processing 2023年第2期19卷 541-567页

作者： u.S.Mahabaleshwar t.Anusha M.Hatami Department of Mathematics Davangere UniversityShivagangothriDavangereIndia Department of Mechanical Engineering Ferdowsi University of MashhadMashhadIran

the unsteady stagnation-point flow of a hybrid nanofluid over a stretching/shrinking sheet embedded in a porous medium with mass transpiration and chemical reactions is *** momentum and mass transfer problems are combined to form a system of partial differential equations,which is converted into a set of ordinary differential equations via similarity *** ordinary differential equations are solved analytically to obtain the solution for velocity and concentration profiles in exponential and hypergeometric forms,*** concentration profile is obtained for four different cases namely constant wall concentration,uniform mass flux,general power law wall con-centration and general power law mass *** effect of different physical parameters such as Darcy number Da^(1-1),mass transpiration parameter V_(C),stretching/shrinking parameter (d),chemical reaction parameter(β)and Schmidt number (Sc)on velocity and concentration profile is *** show that,the axial velocity will decreases as the shrinking sheet parameter increases,regardless of whether the suction or injection case is *** concentration decreases with an increase in the shrinking sheet parameter and the chemical reaction rate parameter.

关键词： Chemical reaction parameter mass transpiration hybrid nanofluid porous medium Schmidt number

Ground-based and additional science support for SMILE

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Earth and Planetary Physics 2024年第1期8卷 275-298页

作者： J.A.Carter M.Dunlop C.Forsyth K.Oksavik E.Donovon A.Kavanagh S.E.Milan t.Sergienko R.C.Fear D.G.Sibeck M.Connors t.Yeoman X.tan M.G.G.t.taylor K.McWilliams J.Gjerloev R.Barnes D.D.Billet G.Chisham A.Dimmock M.P.Freeman D.-S.Han M.D.Hartinger S.-Y.W.Hsieh Z.-J.Hu M.K.James L.Juusola K.Kauristie E.A.Kronberg M.Lester J.Manuel J.Matzka I.McCrea Y.Miyoshi J.Rae L.Ren F.Sigernes E.Spanswick K.Sterne A.Steuwer t.Sun M.-t.Walach B.Walsh C.Wang J.Weygand J.Wild J.Yan J.Zhang Q.-H.Zhang Planetary Sciences Group School of Physics and AstronomyUniversity of LeicesterUniversity RoadLeicesterLE17RHUK Rutherford Appleton Laboratory Space Science Technology Facilities CouncilOxfordshireUK School of Space and Environment Beihang UniversityBeijing 100191China Key Laboratory of Space Environment Monitoring and Information Processing Ministry of Industry and Information TechnologyBeijing 100017China Department of Space and Climate Physics UCLMullard Space Science LaboratoryHolmbury St.MaryDorkingSurreyRH56NTUK Birkeland Centre for Space Science Department of Physics and Technology.University of BergenBergenNorway Department of Physics and Astronomy University of Calgary2500 University DriveCalgaryAlbertaCanada T2N 1N4 British Antarctic Survey CambridgeUK Swedish Institute of Space Physics KirunaSweden West Highfield Campus University of SouthamptonUniversity RoadSO171BJUK Goddard Space Flight Center NASAGreenbeltMarylandUSA Athabasca university AthabascaCanada EStEC European Space AgencyNetherlands university of Saskatchewan SaskatoonCanada the Johns Hopkins university Applied Physics Laboratory LaurelMarylandUSA Swedish Institude of Space Physics UppsalaSE 75121Sweden tongji university Shanghai 200092China Center for Space Plasma Physics Space Science Institute4765 Walnut Street Suite BBoulderColorado80301USA Polar Research Institute of China Shanghai 200136China Finnish Meteorological Institute(FMI) Finland Department of Earth and Environmental Sciences(Geophysics) Ludwig Maximilian University of Munich(LMU)MunichTheresienstr.41MunichD-80333Germany Canadian Space Agency MontrealCanada GFZ German Research Centre for Geosciences PotsdamGermany Nagoya university Institute for Space Earth Environment ResearchCenter for Integrated Data ScienceNagoyaAichiJP 464-8601 Northumbria university Newcastle upon TyneTyne and WearUK NE18ST National Space Science Center Chinese Academy SciencesBeijing 100190China Arctic Geophysics University Centre in Svalbard

the joint European Space Agency and Chinese Academy of Sciences Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)mission will explore global dynamics of the magnetosphere under varying solar wind and interplanetary magnetic field conditions,and simultaneously monitor the auroral response of the Northern Hemisphere *** these large-scale responses with medium and fine-scale measurements at a variety of cadences by additional ground-based and space-based instruments will enable a much greater scientific impact beyond the original goals of the SMILE ***,we describe current community efforts to prepare for SMILE,and the benefits and context various experiments that have explicitly expressed support for SMILE can offer.A dedicated group of international scientists representing many different experiment types and geographical locations,the Ground-based and Additional Science Working Group,is facilitating these *** include constructing an online SMILE Data Fusion Facility,the discussion of particular or special modes for experiments such as coherent and incoherent scatter radar,and the consideration of particular observing strategies and spacecraft *** anticipate growing interest and community engagement with the SMILE mission,and we welcome novel ideas and insights from the solar-terrestrial community.

关键词： magnetosphere ionosphere magnetosphere-ionosphere coupling ground-based experimentation SMILE conjunctions missions

Vibrational resonance in a multistable system with position-dependent mass

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Communications in theoretical Physics 2023年第11期75卷 115-134页

作者： t O Roy-Layinde K A Omoteso O t Kolebaje F O Ogunmefun R A Fasasi J A Laoye u E Vincent Department of Physics Olabisi Onabanjo UniversityAgo-IwoyeOgun StateNigeria Department of Physics Adeyemi Federal University of EducationOndoNigeria Department of Physical Sciences Redeemer’s UniversityP.M.B.230EdeNigeria Department of Physics Lancaster UniversityLancaster LA14 YBUnited Kingdom

the occurrence of vibrational resonance(VR)in a dual-frequency-driven multistable system with a spatially varying mass modelling particle with position-dependent mass(PDM)and evolving in a one-dimensional symmetric periodic potential has been investigated and reported in this *** numerically compute and analyze the response amplitude,the effects of the PDM parameters(m0,a)on the potential structure,the occurrence of VR and the bifurcation of the equilibrium *** is shown that the PDM parameters,besides controlling VR,can induce unconventional resonance patterns through the variation of the potential well *** resonant states can be influenced through the cooperation of the PDM parameters and the external forcing leading the system from multiresonance state into single and double resonance *** contributions of the fixed rest mass m0 on the VR and the PDM-induced resonance are determined by threshold conditions imposed by the magnitude of the mass nonlinear strength a.

关键词： vibrations resonance position-dependent mass multistable oscillator dualfrequency force nonlinear systems

Impact of Radiation and Slip on Newtonian Liquid Flow Past a Porous Stretching/Shrinking Sheet in the Presence of Carbon Nanotubes

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Fluid Dynamics & Materials Processing 2023年第4期19卷 929-939页

作者： u.S.Mahabaleshwar t.Anusha M.EL Ganaoui R.Bennacer Department of Mathematics Davangere UniversityShivagangothriDavangere577007India Institut universitaire de technologie de Longwy Universitéde Lorraine186 rue de LorraineCosnes et Romain54400France LMt/ENS-Cachan/CNRS/universitéParis Saclay Cachan94235France

the impacts of radiation,mass transpiration,and volume fraction of carbon nanotubes on the flow of a Newtonian fluid past a porous stretching/shrinking sheet are *** this purpose,three types of base liquids are considered,namely,water,ethylene glycol and engine ***,single and multi-wall carbon nanotubes are examined in the *** overall physical problem is modeled using a system of highly nonlinear partial differential equations,which are then converted into highly nonlinear third order ordinary differential equations via a suitable similarity *** equations are solved analytically along with the corresponding boundary *** is found that the carbon nanotubes can significantly improve the heat transfer *** potential application in cutting-edge areas is also discussed to a certain extent.

关键词： Carbon nanotubes porous media newtonian fluid radiation

Ion-acoustic wave structures in the fluid ions modeled by higher dimensional generalized Korteweg-de Vries-Zakharov-Kuznetsov equation

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Journal of Ocean Engineering and Science 2023年第6期8卷 623-635页

作者： u.Younas J.Ren Muhammad Z.Baber Muhammad W.Yasin t.Shahzad State Key Laboratory of Power Grid Environmental Protection/Henan Academy of Big Data Zhengzhou UniversityZhengzhou 450001China Department of Mathematics and Statistics The University of LahoreLahorePakistan Department of mathematics University of NarowalNarowalPakistn Department of Basic Sciences and Humanities Narowal CampusUniversity of Engineering and Technology Lahore 54890Pakistan

In this paper,the higher dimensional generalized Korteweg-de-Varies-Zakharov-Kuznetsov(gKdV-ZK)equation is under *** model is used in the field of plasma physics which describes the effects of magnetic field on the weak ion-acoustic *** have applied two techniques,called asφ^(6)-model expansion method and the Hirota bilinear method(HBM)to explore the diversity of wave *** solutions are expressed in the form of hyperbolic,periodic and Jacobi elliptic function(JEF)***,the solitary wave solutions are also extracted.A comparison of our results to well-known results is made,and the study concludes that the solutions achieved here are ***,3-dimensional and contour profiles of achieved outcomes are drawn in order to study their dynamics as a function of parameter *** the basis of the obtained results,we can assert that the pro-posed computational methods are straightforward,dynamic,and well-organized,and will be useful for solving more complicated nonlinear problems in a variety of fields,particularly in nonlinear sciences,in conjunction with symbolic ***,our discoveries provide an important milestone in comprehending the structure and physical behavior of complex *** hope that our findings will contribute significantly to our understanding of ocean *** study,we hope,is appropriate and will be of significance to a broad range of experts involved in ocean engineering models.

关键词： Wave solutions gKdV-ZK equation Bilinear transformation φ^(6)-model expansion method