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Biosynthesized CS-MgO/zeolite hybrid material:An efficient adsorbent for chlorpyrifos removal-Kinetic studies and response surface methodology

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Emerging Contaminants 2024年第3期10卷 304-317页

作者： Mohammed t.M.H.Hamad Belal n.A.Mahran Central Laboratory for Environmental Quality Monitoring National Water Research CenterEgypt

the prevalence of organophosphate pesticides in aquatic environments raises severe concerns on a global ***,an insecticide,is included in a class of organophosphate *** is widely used on agricultural lands to control pests in cotton,fruit,and *** acute toxicity of chlorpyrifos is still dangerous to all aquatic living *** the treatment of water contaminated with chlorpyrifos is an important *** recent decade has witnessed adsorption technology emerging as an advanced organophosphate pesticide wastewater treatment with great potential and a grand blueprint,in which the specific surface area and active sites of the adsorbent are considered to be the two most important characteristics largely impacting the adsorption *** this study,a CS-MgO/Zeolite composite was prepared by the microbial method as an effective adsorbent for the removal of chlorpyrifos from an aqueous *** adsorbent's properties were carefully characterized using Xray diffraction,scanning electron microscopy,and Fourier-transform infrared *** refinement of experimental conditions,encompassing variations in adsorbent dosage,contact time,and chlorpyrifos concentration at five discrete levels,was systematically undertaken through the utilization of a composite central design rooted in response surface *** solution pH played a key role in chlorpyrifos removal,and a pH of 7.0 was selected according to its high adsorption *** highest removal(80.9%)of chlorpyrifos by CS-MgO/Zeolite was obtained at an optimum pH of 7,a contact time of 40 min,an adsorbent dosage of 0.4 g/L,and a chlorpyrifos concentration of 5 mg/L^(-1).the adsorption results were highly fitted with the Freundlich adsorption isotherm model,and the maximum adsorption was 83.3 mg/*** studies indicate that the removal of chlorpyrifos followed the pseudo-secondorder model of adsorption(0.994).the thermodynamic parameters indicate the sponta

关键词： Chlorpyrifos adsorption CS-MgO/Zeolite Response surface methodology

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Detailed seismic zoning of the East Kazakhstan region in the Republic of Kazakhstan

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Geodesy and Geodynamics 2024年第2期15卷 156-165页

作者： natalya V.Silacheva n.P.Stepanenko O.K.Kurilova A.D.Kudabayeva A.t.Danabayeva Institute of Seismology Ministry of Emergency SituationsAlmaty 050060Kazakhstan

Kazakhstan is currently drafting new construction regulations that comply with the major provisions of the *** regulations are created on the basis of seismic zoning maps of various degrees of detail,developed by our Institute of Seismology using a new methodological approach for *** article is about creating the first normative map of the Detailed Seismic Zoning on a probabilistic foundation for the Republic of Kazakhstan’s East Kazakhstan *** carried out the probabilistic assessment of seismic hazard using a methodology consistent with the main provisions of Eurocode 8and updated compared with that used in developing maps of Kazakhstan’s General Seismic Zoning and seismic microzoning of *** most thorough and current data accessible for the area under consideration were combined with contemporary analytical *** have been done to not only the databases being used but also the way seismic sources were shown,including active faults *** a scale of 1:1000000,precise seismic zoning maps of the East Kazakhstan region were created for two probabilities of exceedance:10%and 2%in 50 years in terms of peak ground accelerations and macroseismic *** obtained seismic hazard distribution is generally consistent with the General Seismic Zoning of Kazakhstan’s previous ***,because active faults were included and a thoroughly revised catalog was used,there are more pronounced zones of increased danger along the fault in the western part of the *** the west of the territory,acceleration values also increased due to a more accurate consideration of seismotectonic *** maps are the basis for developing new state building regulations of the Republic of Kazakhstan.

关键词： Probabilistic seismic hazard assessment Detailed seismic zoning Peak ground acceleration Microseismical intensity

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Large dinosaur egg accumulations and their significance for understanding nesting behaviour

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Geoscience Frontiers 2024年第5期15卷 467-488页

作者： L.Ezquerro R.Coimbra B.Bauluz C.núñez-Lahuerta t.Román-Berdiel M.Moreno-Azanza Departamento de Geodinámica Estratigrafía y PaleontologíaFacultad de Ciencias GeológicasUniversidad Complutense de MadridC/JoséAntonio Novais1228040MadridSpain Aragosaurus-IUCA:Recursos Geológicos y Paleoambientales.Departamento de Ciencias de la tierra.Facultad de Ciencias Universidad de ZaragozaC/Pedro Cerbuna 1250009 ZaragozaSpain Museu da Lourinha LourinhaPortugal GeoBiotec Department of Earth SciencesNOVA School of Science and TechnologyUniversidade Nova de LisboaCaparicaPortugal GeoBiotec Departamento de GeocienciasUniversidade de AveiroAveiroPortugal Insitut Catalàde Paleoecologia Humana i EvolucióSocial(IPHES-CERCA) Zona Educacional 4Campus Sescelades URV(Edifici W3)43007 TarragonaSpain Departament d´Història i Història de l´Art Universitat Rovira i VirgiliAv.Catalunya 3543002 TarragonaSpain Geotransfer IUCA Departamento de Ciencias de La TierraFacultad de CienciasUniversidad de ZaragozaZaragozaSpain

the accurate identification of dinosaur egg accumulations as nests or clutches is crucial for understanding the reproductive behaviour of these extinct ***,existing methods often rely on the presence of complete eggs and embryo remains,and sedimentological criteria that are only applicable to well-structured *** this study,we introduce an innovative approach to characterize egg accumulations in structureless sediments,where traditional nest structures may not be *** methodology employs a unique combination of sedimentological,taphonomic,geochemical,and geophysical proxies for the study of egg *** applied this approach to the egg accumulation from Paimogo(Jurassic,Portugal),traditionally interpreted as a *** findings reveal that the Paimogo egg assemblage is a secondary deposit,resulting from a flooding event in a fluvial plain that dismantled several allosauroid and crocodylomorph *** eggshell vapor conductance results,coupled with sedimentological evidence,suggest that allosauroid dinosaurs buried their eggs in the dry terrain of overbank areas close to a main channel during the breeding season,likely during the dry season to prevent the embryos from *** research underscores the necessity of multidisciplinary approaches in interpreting egg accumulations and offers a novel methodology for studying these accumulations in structureless *** findings provide new insights into the breeding behaviour and nesting preferences of these extinct organisms,contributing to our understanding of dinosaur ecology.

关键词： Breeding behaviour theropod taphonomy Stable isotopes Magnetic susceptibility Jurassic

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A concise review on surface and structural modification of porous zeolite scaffold for enhanced hydrogen storage

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Chinese Journal of Chemical Engineering 2024年第6期70卷 33-53页

作者： B.A.Abdulkadir R.S.R.Mohd Zaki A.t.Abd Wahab S.n.Miskan Anh-tam nguyen Dai-Viet n.Vo H.D.Setiabudi Centre for Research in Advanced Fluid&Processes Universiti Malaysia Pahang Al-Sultan AbdullahLebuh Persiaran Tun Khalil YaakobGambangPahang 26300Malaysia Faculty of Chemical&Process Engineering technology Universiti Malaysia Pahang Al-Sultan AbdullahLebuh Persiaran Tun Khalil YaakobGambangPahang 26300Malaysia Center of Excellence for Green Energy and Environmental nanomaterials(CE@GrEEn) Nguyen Tat Thanh University300A Nguyen Tat ThanhDistrict 4Ho Chi Minh City 755414Viet Nam

Investigating zeolites as hydrogen storage scaffolds is imperative due to their porous nature and favorable physicochemical ***,the storage capacity of the unmodified zeolites has been rather unsatisfactory(0.224%-1.082%(mass))compared to its modified ***,the contemporary focus on enhancing hydrogen storage capacities has led to significant attention towards the utilization of modified zeolites,with studies exploring surface modifications through physical and chemical treatments,as well as the integration of various active *** enhanced hydrogen storage properties of zeolites are attributed to the presence of aluminosilicates from alkaline and alkaline-earth metals,resulting in increased storage capacity through interactions with the charge density of these ***,there is a great demand to critically review their role such as well-defined topology,pore structure,good thermal stability,and tunable hydrophilicity in enhanced hydrogen *** article aimed to critically review the recent research findings based on modified zeolite performance for enhanced hydrogen *** of the factors affecting the hydrogen storage capacities of zeolites that can affect the rate of reaction and the stability of the adsorbent,like pressure,structure,and morphology were studied,and ***,future perspectives,recommendations,and directions for modified zeolites were discussed.

关键词： Zeolites Hydrogen storage Surface modification Adsorption Active metal

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Al-Ca-Cu三元合金体系中与铝平衡的金属间化合物

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transactions of nonferrous Metals Society of China 2024年第5期34卷 1380-1392页

作者： t.K.AKOPYAn t.A.SVIRIDOVA n.A.BELOV n.V.LEtYAGIn A.V.KOROtItSKIY national University of Science and technology MISiS 4 Leninsky pr.Moscow 119049Russia

对三元Al-Ca-Cu合金体系中与铝固溶体平衡的(Al,Cu)_(4)Ca、Al_(27)Ca_(3)Cu_(7)和Al_(8)CaCu_(4)金属间化合物的结构和性能进行全面分析。基于Al4Ca相中部分Al原子被Cu取代,将(Al,Cu)_(4)Ca金属间化合物视为线性化合物。化合物中铜的... 详细信息

对三元Al-Ca-Cu合金体系中与铝固溶体平衡的(Al,Cu)_(4)Ca、Al_(27)Ca_(3)Cu_(7)和Al_(8)CaCu_(4)金属间化合物的结构和性能进行全面分析。基于Al4Ca相中部分Al原子被Cu取代,将(Al,Cu)_(4)Ca金属间化合物视为线性化合物。化合物中铜的溶解度达到10 at.%(19 wt.%),导致化合物的晶格结构、物理和力学性能发生显著变化。例如,化合物的密度从2.22 g/cm^(3)增加到2.79 g/cm^(3),显微硬度从HV 180增加到HV 250。将Al_(27)Ca_(3)Cu_(7)相视为具有严格化学计量比和BaHg11型初始晶体结构的三元化合物,其空间群为Pm3m,晶格参数为8.514Å,密度为3.45 g/cm^(3)。Al_(8)CaCu_(4)相也是严格化学计量比的三元化合物,具有Mn_(12)th型晶格结构,最高的显微硬度(HV 505)和密度(4.57 g/cm^(3))。属于二元(Al)+(Al,Cu)_(4)Ca相场和准二元(Al)+Al_(27)Ca_(3)Cu_(7)截面的合金,有前景作为新型天然铝基复合材料的基材。

关键词：金属间化合物 Al-Ca合金显微组织晶体结构物理性能力学性能

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Efficient guiding and focusing of intense laser pulse using periodic thin slits

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Matter and Radiation at Extremes 2024年第4期9卷 29-39页

作者： L.Xu t.W.Huang K.Jiang C.n.Wu H.Peng P.C.hen R.Li H.B.Zhuo C.t.Zhou Shenzhen Key Laboratory of Ultraintense Laser and Advanced Material technology Center for Intense Laser ApplicationTechnologyand College of Engineering PhysicsShenzhen Technology UniversityShenzhen 518118People’s Republic of China

Slits have been widely used in laser-plasma interactions as plasma optical components for generating high-harmonic light and controlling laser-driven particle ***,we propose and demonstrate that periodic thin slits can be regarded as a new breed of optical elements for efficient focusing and guiding of intense laser *** fundamental physics of intense laser interaction with thin slits is studied,and it is revealed that relativistic effects can lead to enhanced laser focusing far beyond the pure diffractive focusing *** addition,the interaction of an intense laser pulse with periodic thin slits makes it feasible to achieve multifold enhancement in both laser intensity and energy transfer efficiency compared with conventional *** results provide a novel method for manipulating ultra-intense laser pulses and should be of interest for many laser-based applications.

关键词： laser pulse intense

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Effectiveness of external prestressing in enhancing the non-ductile hanger failure mechanism in reinforced concrete inverted t-beams

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Frontiers of Structural and Civil Engineering 2024年第7期18卷 1050-1065页

作者： Ahmed M.AttA Reda n.BEHIRY Mohammed I.HARAZ Structural Engineering Department Faculty of EngineeringTanta UniversityTanta 33511Egypt nile Higher Institute for Engineering and technology Mansoura 11001Egypt

Recently,inverted t-beams have been used in reinforced concrete(RC)bridges to support transverse precast *** t-beams,contrary to practice with conventional beams,are loaded on the flanges upper *** loading configuration causes hanger failure due to the generation of vertical tensile stresses near the bottom of the *** key purpose of this study is to investigate the efficiency of vertical external prestressing stainless-steel bars in mitigating non-ductile hanger failure in reinforced concrete inverted *** experimental study on six inverted-t beams,including two un-strengthened specimens,was carried *** study showed that the value of the prestressing level had a considerable impact on the performance of hanger mechanism in relation to crack pattern,ultimate loads,cracking behavior,load-deflection,strains,and *** experimental results indicated that the suggested method for strengthening inverted t-beams had efficacy in reducing the seriousness of the non-ductile hanger failure and resulted in a strength increase of up to 53% when compared to that of the un-strengthened ***,two analytical models for estimating the hanger capacity and the average crack width of the strengthened RC inverted t-beams were *** models that were proposed exhibited a high degree of agreement with the experimental results.

关键词： RC bridges inverted t-beams strengthening hanger failure external prestressing

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Energy exchange between charged relativistic fluids in f(t) gravity

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Communications in theoretical Physics 2024年第10期76卷 108-120页

作者： Z Yousaf U A Khokhar nasser Bin turki t Suzuki Department of Mathematics University of the Punjab Quaid-i-Azam Campus Department of Mathematics College of Science King Saud University Department of Regional Management Faculty of Management Fukushima College

this study focuses on the effects of a polytropic fluid on a charged gravitational source within f(t) gravity, where t is the torsion scalar. We investigate how the electromagnetic field affects the flow of energy in spherically symmetric and static celestial objects that contain relativistic fluids. By using the gravitational decoupling technique, we analyze the effects of polytropic fluid on the dynamics of the gravitational source, accompanied by the matching of the interior geometry with an exterior at the hypersurface Σ. Finally, with the help of the tolman ⅡV solution, we observe the conduct of energy conditions with the existence of charge using f(t)field equations and got the intended outcomes.

关键词： anisotropy complexity energy exchange hydrodynamics self-gravitating systems

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Al-Ca-Fe合金中Al_(10)CaFe_(2)化合物的形成与表征

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transactions of nonferrous Metals Society of China 2024年第2期34卷 361-377页

作者： n.A.BELOV t.K.AKOPYAn E.A.nAUMOVA V.V.DOROSHEnKO t.A.SVIRIDOVA n.O.KOROtKOVA national University of Science and technology MISIS 4 Leninsky pr.Moscow 119049Russia Baikov Institute of Metallurgy and Materials Science 49 Leninsky pr.Moscow 119991Russia

采用热力学计算和实验技术研究铝角的Al-Ca-Fe体系相图,包括液相面投影图和凝固反应。结果表明,与铝固溶体(Al)平衡的不是Al_(3)Fe相,而是一种组成符合化学式Al_(10)CaFe_(2)的三元化合物。通过包晶转变L+Al_(3)Fe→(Al)+Al_(10)CaFe_(2... 详细信息

采用热力学计算和实验技术研究铝角的Al-Ca-Fe体系相图,包括液相面投影图和凝固反应。结果表明,与铝固溶体(Al)平衡的不是Al_(3)Fe相,而是一种组成符合化学式Al_(10)CaFe_(2)的三元化合物。通过包晶转变L+Al_(3)Fe→(Al)+Al_(10)CaFe_(2)(638℃,3.3%Ca和0.5%Fe,摩尔分数)发生从二元化合物到三元化合物的转变。与针状Al_(3)Fe相夹杂物不同,三元化合物的初晶和共晶具有致密的形貌。使用第一性原理计算和X射线衍射分析确定三元化合物Al_(10)CaFe_(2)的晶格结构。此外,近共晶合金Al-6%Ca-1%Fe(质量分数)在500~600℃退火后具有细晶组织,过量相的总体积分数约为25%。因此,Al-Ca-Fe体系可用于制造新的铝基复合合金。

关键词： Al-Ca合金金属间化合物相图相变显微组织铝基复合材料

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Measurement of yields and angular distributions ofγ-quanta from the interaction of 14.1 MeV neutrons with oxygen,phosphorus,and sulfur

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Chinese Physics C 2024年第3期48卷 79-92页

作者： D.n.Grozdanov n.A.Fedorov S.B.Dabylova Yu.n.Kopatch I.n.Ruskov V.R.Skoy t.Yu.tretyakova C.Hramco P.I.Kharlamov G.V.Pampushik P.G.Filonchik A.V.Andreev Joint Institute for nuclear Research(JInR) DubnaRussia Institute for nuclear Research and nuclear Energy Bulgarian Academy of SciencesSofiaBulgaria Faculty of Physics Lomonosov Moscow State UniversityMoscowRussia L.n.Gumilyov Eurasian national University AstanaKazakhstan Skobeltsyn Institute of nuclear Physics Moscow State UniversityMoscowRussia Institute of Chemistry of Moldova ChisinauRepublic of Moldova Moscow Institute of Physics and technology MoscowRussia

A study of the inelastic scattering of neutrons with an energy of 14.1 MeV on the nuclei of oxygen,phosphorus,and sulfur was performed at the tAnGRA facility at JInR(Dubna).the experiment aimed to refine existing data and obtain new data on the yields and angular distributions ofγ-quanta emitted by the studied nuclei due to neutron-induced nuclear reactions using the tagged neutron *** types of detector systems were used to registerγ-***γ-ray yields were measured using a high-purity germanium(HPGe)*** angular distributions ofγ-rays were obtained using a system of 18 scintillation detectors based on bismuth germanite Bi_(4)Ge_(3)O_(12)(BGO)located around the *** performed experiments measured the yields of two transitions for the reaction of tagged neutrons with 16O,nine transitions for the reaction with ^(31)P,and nine transitions for the reaction with ^(32)S for the first *** angular anisotropy of theγ-radiation accompanying the inelastic scattering of neutrons with an energy of 14.1 MeV on ^(31)P nuclei was also measured for the first time.

关键词： tagged neutron method yields of gamma-quanta high-resolution gamma-spectrometry neutron-nuclear reactions neutron scattering

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