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Thermodynamic model for deoxidation of liquid steel considering strong metal-oxygen interaction in the quasichemical model framework

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International Journal of Minerals,Metallurgy and Materials 2024年第5期31卷 988-1002页

作者： Yong-Min cho youn-Bae Kang Graduate Institute of Ferrous and Eco Materials Technology Pohang University of Science and TechnologyPohangKyungbuk37673Rep.of Korea N.EX.T Hub POSCO HoldingsPohangKyungbuk37673Rep.of Korea Department of Materials Science and Engineering Pohang University of Science and TechnologyPohangKyungbuk37673Rep.of Korea

Herein,a thermodynamic model aimed at describing deoxidation equilibria in liquid steel was *** model provides explicit forms of the activity coefficient of solutes in liquid steel,eliminating the need for the minimization of internal Gibbs energy preliminarily when solving deoxidation *** elimination of internal Gibbs energy minimization is particularly advantageous during the coupling of deoxidation equilibrium calculations with computationally intensive approaches,such as computational fluid *** model enables efficient calculations through direct embedment of the explicit forms of activity coefficient in the computing *** proposed thermodynamic model was developed using a quasichemical approach with two key approximations:random mixing of metallic elements(Fe and oxidizing metal) and strong nonrandom pairing of metal and oxygen as nearest *** these approximations,the quasichemical approach yielded the activity coefficients of solutes as explicit functions of composition and temperature without requiring the minimization of internal Gibbs energy or the coupling of separate *** model was successfully applied in the calculation of deoxidation equilibria of various elements(Al,B,C,Ca,Ce,Cr,La,Mg,Mn,Nb,Si,Ti,V,and Zr).The limitations of the model arising from these assumptions were also discussed.

关键词： deoxidation equilibria thermodynamics quasichemical approach computational fluid dynamics

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Obesity promotes oxidative stress and exacerbates blood-brain barrier disruption after high-intensity exercise

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Journal of Sport and Health Science 2017年第2期6卷 225-230页

作者： Hee-Tae Roh su-youn cho Wi-young So Department of Physical Education Dong-A University Busan 604-714 Republic of Korea School of Taekwondo College of Creative Human ResourcesYoungsan UniversityYangsan-si 626-790Republic of Korea Sports and Health Care Major College of Humanities and ArtsKorea National University of TransportationChungju-si 380-702Republic of Korea

Purpose: The purpose of this study was to investigate the effects of obesity and high-intensity acute exercise on oxidant-antioxidant status,neurotrophic factor expression, and blood-brain barrier(BBB) ***: Twenty-four healthy, untrained men(12 non-obese(mean 14.9% body fat) and 12 obese subjects(mean 29.8% body fat)) performed20 min of continuous submaximal aerobic exercise at 85% maximal oxygen consumption. Blood sampling was performed to examine the oxidant-antioxidant status(reactive oxygen species(ROS) and superoxide dismutase(SOD)), neurotrophic factors(brain-derived neurotrophic factor(BDNF) and nerve growth factor(NGF)), and BBB disruption(S100β and neuron-specific enolase) before and after acute ***: The obese group showed significantly higher pre-exercise serum ROS levels and significantly lower pre-exercise serum SOD levels than the non-obese group(p suggests that episodic vigorous exercise can increase oxidative stress and blood neurotrophic factor levels and induce disruption of the BBB. Moreover, high levels of neurotrophic factor in the blood after exercise in the obese group may be due to BBB disruption,and it is assumed that oxidative stress was the main cause of this BBB disruption.

关键词：水平运动血脑屏障氧化应激高强度脑源性神经营养因子肥胖神经元特异性烯醇化酶超氧化物歧化酶

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不同类型补液对高温环境下运动时大学生运动员血清HSP70与淋巴细胞DNA损伤的影响（英文）

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Journal of Sport and Health Science 2016年第4期5卷 448-455页

作者： Hee-Tae Roh su-youn cho Wi-young So Il-young Paik Sang-Hoon suh Department of Physical Education Dong-A University Exercise Physiology Laboratory Department of Physical EducationYonsei University Sports and Health Care Major College of Humanities and ArtsKorea National University of Transportation

目的:本研究旨在调查高温环境下运动时,水或运动饮料补液对血清HSP70水平和DNA损伤的影响。方法:韩国延世大学招募运动年限为6-11年的10名男性大学生运动员参加此项研究。受试者以75%心率储备强度在跑步机上进行4种补液条件下的测试:保... 详细信息

目的:本研究旨在调查高温环境下运动时,水或运动饮料补液对血清HSP70水平和DNA损伤的影响。方法:韩国延世大学招募运动年限为6-11年的10名男性大学生运动员参加此项研究。受试者以75%心率储备强度在跑步机上进行4种补液条件下的测试:保持18℃中温环境,不补液(T);32℃高温环境,不补液(H);32℃高温环境下饮水(HW);32℃高温环境下补充运动饮料(HS)。分别在基线状态(PEB)、运动刚结束(IAE)、运动结束60 min(60MPE)3个时间点采集血样。结果:运动时皮肤温度显著升高,且运动刚结束时,H状态皮肤温度显著高于T和HS。在所有条件下,运动刚结束时血清HSP70比运动前显著增长,且H状态较T更高。在所有测试中,运动结束时的淋巴细胞DNA损伤(尾部DNA、尾长、尾矩)较运动前有显著增加。运动结束时,HS相比H可缓解DNA损伤(尾矩)。结论:急性运动可导致血清HSP70升高和淋巴细胞DNA损伤;在高温环境下运动时,运动饮料补液可防止脱水、减少热应激,从而减弱HSP反应与DNA损伤。

关键词：急性运动 DNA损伤补液热应激 HSP70 运动饮料

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surface-modified Ag@Ru-P25 for photocatalytic CO_(2) conversion with high selectivity over CH_(4) formation at the solid–gas interface

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Carbon Energy 2024年第1期6卷 182-196页

作者： Chaitanya B.Hiragond Sohag Biswas Niket SPowar Junho Lee Eunhee Gong Hwapyong Kim Hong Soo Kim Jin-Woo Jung Chang-Hee cho Bryan M.Wong su-Il In Department of Energy Science&Engineering Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea Department of Chemical&Environmental Engineering Materials Science&Engineering ProgramDepartment of ChemistryDepartment of Physics&AstronomyUniversity of California-RiversideRiversideCaliforniaUSA Department of Physics and Chemistry Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea NiceScience Corporation DaeguRepublic of Korea

Systematic optimization of the photocatalyst and investigation of the role of each component is important to maximizing catalytic activity and comprehending the photocatalytic conversion of CO_(2) reduction to solar fuels.A surface-modified Ag@Ru-P25 photocatalyst with H_(2)O_(2) treatment was designed in this study to convert CO_(2) and H_(2)O vapor into highly selective *** doping followed by Ag nanoparticles(NPs)cocatalyst deposition on P25(TiO_(2))enhances visible light absorption and charge separation,whereas H_(2)O_(2) treatment modifies the surface of the photocatalyst with hydroxyl(–OH)groups and promotes CO_(2) ***-resonance transmission electron microscopy,X-ray photoelectron spectroscopy,X-ray absorption near-edge structure,and extended X-ray absorption fine structure techniques were used to analyze the surface and chemical composition of the photocatalyst,while thermogravimetric analysis,CO_(2) adsorption isotherm,and temperature programmed desorption study were performed to examine the significance of H_(2)O_(2) treatment in increasing CO_(2) reduction *** optimized Ag1.0@Ru1.0-P25 photocatalyst performed excellent CO_(2) reduction activity into CO,CH4,and C2H6 with a~95%selectivity of CH4,where the activity was~135 times higher than that of pristine TiO_(2)(P25).For the first time,this work explored the effect of H_(2)O_(2) treatment on the photocatalyst that dramatically increases CO_(2) reduction activity.

关键词： gas-phase CO_(2) reduction H_(2)O_(2) treatment plasmonic nanoparticles solar fuel photocatalyst surface modification

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Capsosiphon fulvescens suppresses LPS-stimulated inflammatory responses by suppressing TLR4/NF-κB activation in RAW264.7 murine macrophages

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Asian Pacific Journal of Tropical Biomedicine 2024年第3期14卷 115-126页

作者： Seon Yeong Ji EunJin Bang Hyun Hwangbo Min Yeong Kim Da Hye Kim su Hyun Hong Shin-Hyung Park Chang-young Kwon Gi-young Kim You-Jin Jeon suengmok cho Yung Hyun choi Department of Biochemistry Dong-eui University College of Korean MedicineBusan 47227Republic of Korea Basic Research Laboratory for the Regulation of Microplastic-Mediated Diseases and Anti-Aging Research Center Dong-eui UniversityBusan 47227Republic of Korea Department of Pathology Dong-eui University College of Korean MedicineBusan 47227Republic of Korea Department of Oriental Neuropsychiatry Dong-eui University College of Korean MedicineBusan 47227Republic of Korea Department of Marine Life Science Jeju National UniversityJeju 63243Republic of Korea Department of Food Science and Technology/Institute of Food Science Pukyong National UniversityBusan 48513Republic of Korea

Objective:To evaluate the effects of Capsosiphon fulvescens(***)ethanolic extract on inflammation in lipopolysaccharide(LPS)-induced RAW296.7 ***:The protective effects of *** ethanolic extract on LPS-induced inflammation in RAW264.7 macrophages were assessed using biochemical analysis,including enzyme-linked immunosorbent assay,quantitative reverse transcription-polymerase chain reaction,and Western blot *** examine reactive oxygen species(ROS)production,flow cytometry analysis,and immunofluorescence staining were ***,the modulatory effect of *** ethanolic extract on NF-κB activation was ***:*** ethanolic extract significantly attenuated LPS-induced levels of pro-inflammatory cytokines and notably reduced the secretion and mRNA levels of LPS-mediated matrix *** addition,*** ethanolic extract decreased ROS production and suppressed the TLR4/NF-κB signaling ***:*** ethanolic extract alleviates inflammation as well as oxidative stress by modulating the TLR4/NF-κB signaling in LPS-induced RAW264.7 *** can be used as a potential therapeutic agent to suppress inflammation and oxidative stress-associated diseases.

关键词： Capsosiphon fulvescens Inflammation Oxidative stress NF-κB Nrf2 TLR4

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Catalpa bignonioides extract improves exercise performance through regulation of growth and metabolism in skeletal muscles

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Asian Pacific Journal of Tropical Biomedicine 2024年第2期14卷 47-54页

作者： Hoibin Jeong Dong-joo Lee sung-Pil Kwon SeonJu Park Song-Rae Kim Seung Hyun Kim Jae-Il Park Deug-chan Lee Kyung-Min choi WonWoo Lee Ji-Won Park Bohyun Yun su-Hyeon cho Kil-Nam Kim Seoul Center Korea Basic Science InstituteSeoul 02841Republic of Korea Chuncheon Center Korea Basic Science InstituteChuncheon 24341Republic of Korea Research&Development Center Chungdam CDC JNPharm LLC.Chuncheon 24341Republic of Korea Department of Biomedical Technology Kangwon National UniversityChuncheon 24341Republic of Korea Yonsei Institute of Pharmaceutical Sciences College of PharmacyYonsei UniversityIncheon 21983Republic of Korea Gwangju Center Korea Basic Science InstituteGwangju 61751Republic of Korea Honam National Institute of Biological Resources 99Gohadoan-gilMokpo-siJeollanam-do58762Republic of Korea Department of Bio-analysis Science University of Science&TechnologyDaejeon34113Republic of Korea

Objective:To evaluate the effects of Catalpa bignonioides fruit extract on the promotion of muscle growth and muscular capacity in vitro and in ***:Cell viability was measured using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide *** proliferation was assessed using a 5-bromo-2’-deoxyuridine(BrdU)assay *** blot analysis was performed to determine the protein expressions of related *** effects of Catalpa bignonioides extract were investigated in mice using the treadmill exhaustion test and whole-limb grip strength *** composition analysis was performed using high-performance liquid chromatography(HPLC).Results:Catalpa bignonioides extract increased the proliferation of C2C12 mouse myoblasts by activating the Akt/mTOR signaling *** also induced metabolic changes,increasing the number of mitochondria and glucose metabolism by phosphorylating adenosine monophosphate-activated protein *** an in vivo study,the extract-treated mice showed improved motor abilities,such as muscular endurance and grip ***,HPLC analysis showed that vanillic acid may be the main component of the Catalpa bignonioides extract that enhanced muscle ***:Catalpa bignonioides improves exercise performance through regulation of growth and metabolism in skeletal muscles,suggesting its potential as an effective natural agent for improving muscular strength.

关键词： Catalpa bignonioides Skeletal muscle Cell proliferation Mitochondria Energy metabolism C2C12

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Mode of Operation for Modification, Insertion, and Deletion of Encrypted Data

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Computers, Materials & Continua 2022年第10期73卷 151-164页

作者： Taek-young youn Nam-su Jho Dankook University YonginGyeonggi16890Korea Electronics and Telecommunications Research Institute Daejeon34129Korea

Due to the development of 5G communication,many aspects of information technology(IT)services are *** the development of communication technologies such as 5G,it has become possible to provide IT services that were difficult to provide in the *** of the services made possible through this change is cloud-based *** order to support secure collaboration over cloud,encryption technology to securely manage dynamic data is ***,since the existing encryption technology is not suitable for encryption of dynamic data,a new technology that can provide encryption for dynamic data is required for secure cloudbased *** this paper,we propose a new encryption technology to support secure collaboration for dynamic data in the ***,we propose an encryption operation mode which can support data updates such as modification,addition,and deletion of encrypted data in an encrypted *** support the dynamic update of encrypted data,we invent a new mode of operation technique named linked-block cipher(LBC).Basic idea of our work is to use an updatable random value so-called link to link two encrypted *** to the use of updatable random link values,we can modify,insert,and delete an encrypted data without decrypt it.

关键词： Data encryption cloud-based collaboration dynamic data update

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Newly-modeled graphene-based ternary nanocomposite for the magnetophotocatalytic reduction of CO_(2) with electrochemical performance

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Frontiers of Chemical Science and Engineering 2022年第10期16卷 1438-1459页

作者： Zambaga Otgonbayar Kwang youn cho chong-Hun Jung Won-Chun Oh Department of Advanced Materials Science&Engineering Hanseo UniversitySeosan-Si 31962Korea Korea Institutes of Ceramic Engineering and Technology Jinju-Si 660031Korea Decommissioning Technology Research Division Korea Atomic Energy Research InstituteDaejeon 305-600Korea Anhui International Joint Research Center for Nano Carbon-based Materials and Environmental Health College of Materials Science and EngineeringAnhui University of Science&TechnologyHuainan 232001China

The development of CO_(2)into hydrocarbon fuels has emerged as a green method that could help mitigate global *** novel structured photocatalyst is a promising material for use in a photocatalytic and magneto-electrochemical method that fosters the reduction of CO_(2)by suppressing the recombination of electron−hole pairs and effectively transferring the electrons to the surface for the chemical reaction of CO_(2)*** our study,we have developed a novel-structured AgCuZnS_(2)–graphene–TiO_(2)to analyze its catalytic activity toward the selective evolution of CO_(2).The selectivity of each nanocomposite substantially enhanced the activity of the AgCuZnS_(2)–graphene–TiO_(2)ternary nanocomposite due to the successful interaction,and the selectivity of the final product was improved to a value 3 times higher than that of the pure AgCuZnS_(2)and 2 times higher than those of AgCuZnS_(2)–graphene and AgCuZnS_(2)–TiO_(2)under ultraviolet(UV)-light(λ=254 nm)irradiation in the photocatalytic *** electrochemical CO_(2)reduction test was also conducted to analyze the efficacy of the AgCuZnS_(2)–graphene–TiO_(2)when used as a working electrode in laboratory electrochemical *** electrochemical process was conducted under different experimental conditions,such as various scan rates(mV·s^(–1)),under UV-light and with a 0.07 T *** evolution of CO_(2)substantially improved under UV-light(λ=254 nm)and with 0.07 T magnetic-core treatment;these improvements were attributed to the facts that the UV-light activated the electron-transfer pathway and the magnetic core controlled the pathway of electrontransmission/prevention to protect it from chaotic electron *** all tested nanocomposites,AgCuZnS_(2)–graphene–TiO_(2)absorbed the CO_(2)most strongly and showed the best ability to transfer the electron to reduce the CO_(2)to *** believe that our newly-modeled ternary nanocomposite opens up new opportunities for the evolution of C

关键词： ternary nanocomposite photocatalytic electrochemical CO_(2) reduction UV-light magnetic core

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Periorbital necrotizing fasciitis accompanied by sinusitis and intracranial epidural abscess in an immunocompetent patient

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International Journal of Ophthalmology(English edition) 2022年第5期15卷 848-850页

作者： su youn suh Jung Hyo Ahn Department of Ophthalmology Research Institute for Convergence of Biomedical Science and TechnologyPusan National University Yangsan HospitalPusan National University School of MedicineYangsanGyeongnam 50612Republic of Korea

Dear Editor,We have presented the unusual case of periorbital necrotizing fasciitis(NF) coexisting with sinusitis and intracranial epidural abscess in a healthy young patient that was successfully managed with medical and surgical treatments. The authors obtained informed consent in person and adhered to the tenets of the Declaration of Helsinki.

关键词： patient sinusitis intracranial

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Docurity: A New Cryptographic Primitive for Collaborative Cloud Systems

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Intelligent Automation & Soft Computing 2023年第6期36卷 3725-3742页

作者： Byeori Kim Minseong choi Taek-young youn Jeong Hyun Yi Haehyun cho Soongsil University Seoul06978Korea Dankook University Yongin16890Korea

Recently,there has been a sudden shift from using traditional office applications to the collaborative cloud-based office suite such as Microsoft Office *** cloud-based systems allow users to work together on the same docu-ment stored in a cloud server at once,by which users can effectively collaborate with each ***,there are security concerns unsolved in using cloud *** of the major concerns is the security of data stored in cloud ser-vers,which comes from the fact that data that multiple users are working together cannot be stored in encrypted form because of the dynamic characteristic of cloud *** this paper,we propose a novel mode of operation,DL-ECB,for AES by which we can modify,insert,and delete the ciphertext based on changes in ***,we can use encrypted data in collaborative cloud-based *** demonstrate that the DL-ECB mode can preserve the confidential-ity,integrity,and auditability of data used in collaborative cloud systems from adversaries,we implement and evaluate the prototype of the DL-ECB mode.

关键词： Cloud collaboration mode of operation auditability of ciphertext

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