检索结果-南通市图书馆

Unlocking power of neighboring vacancies in boosting hydrogen evolution reactions on two-dimensional NiPS3 monolayer

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

eScience 2024年第3期4卷 104-115页

作者： Hyun Gu Han Jae Won Choi Minsu son ki Chul kim Computational Materials Design Laboratory Department of Chemical EngineeringKonkuk UniversitySeoul 05029The Republic of Korea Division of Chemical Engineering Konkuk UniversitySeoul 05029The Republic of Korea

This study investigates the effect of defect engineering on the catalytic activity of a NiPS3 monolayer catalyst for the hydrogen evolution reaction(HER).Three different types of vacancies on the basal plane of the monolayer are explored through a multi-step mechanism involving the dissociative adsorption of a water molecule and subsequent electrochemical adsorption of the dissociated ***-formation of vacancies in both Ni and S sites is found to be the most effective in enhancing the catalytic performance of the monolayer.A key resource for the reaction thermodynamics is the S-substitution-like physisorption of a water molecule on a vacant S site,followed by the dissociative occupation of OH and H into vacant sites of S and Ni elements,boosted by the NiS di-vacancy configuration with low activation energy *** reveals the highest contribution of bonding orbitals to the monolayer-H bond makes it the most desirable defect engineering approach for transition metal phosphorus chalcogenides with high HER ***,this study highlights the significance of controlled defect engineering in augmenting the catalytic performance of NiPS3 monolayer catalysts for HER.

关键词： Hydrogen evolution reaction Defect engineering Transition metal phosphorus trichalcogenide Density functional theory Reaction thermodynamics

Effect of Eu3+,Bi3+,and Li+ doping on luminescent property of GdNbO4

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Rare Earths 2024年第1期42卷 66-75页

作者： S.W.wi Y.S.Lee Department of Physics and Integrative Institute of Basic Sciences Soongsil University

We investigated the emission properties of Eu3+-doped GdNbO4-based oxide phosphors,aiming at improving the Eu3+emission by codoping of Bi3+and Li+.Eu3+singly doped,Eu3+and Bi3+doubly doped,and Eu3+,Bi3+,and Li+triply doped GdNbO4were prepared using a high-temperature solid-state reaction *** red-orange emissions from Eu3+in the singly doped samples are significantly improved by the codoping of Bi3+,mainly due to the energy transfer from Bi3+to Eu3+.The additional codoping of Li+is found to increase the Eu3+emission *** improvement might be attributed to the increase in the photoluminescent quantum yield originating from larger grain sizes and better crystallinity.A detailed analysis of the X-ray diffraction pattern and the asymmetric ratio estimated from the photoluminescence spectra show that the local lattice environment around Eu3+in GdNbO4does not change significantly with the codoping of Bi3+and Li+.Our results indicate that Li+doping is a promising way to improve the emission properties of rare-earth ion-doped GdNbO4phosphors.

关键词： Eu 3+ GdNbO 4 Codoping of Li + Photoluminescence Sensitizer Rare earths

Ruthenium-lead oxide for acidic oxygen evolution reaction in proton exchange membrane water electrolysis

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第10期17卷 8671-8677页

作者： Feng-Yang Chen Chang Qiu Zhen-Yu Wu Tae-Ung wi YZou Finfrock Haotian Wang Department of Chemical and Biomolecular Engineering Rice UniversityHoustonTX 77005USA Structural Biology Center X-ray Science DivisionArgonne National LaboratoryLemontIL 60439USA Department of Materials Science and NanoEngineering Rice UniversityHoustonTX 77005USA Department of Chemistry Rice UniversityHoustonTX 77005USA

Developing an active and stable anode catalyst for the proton exchange membrane water electrolyzer(PEM-WE)is a critical objective to enhance the economic viability of green hydrogen ***,the expensive iridium-based electrocatalyst remains the sole practical material with industrial-level stability for the acidic oxygen evolution reaction(OER)at the ***-based catalysts have been proposed as more cost-effective alternatives with improved activity,though their stability requires *** current urgent goal is to reduce costs and noble metal loading of the OER catalyst while maintaining robust activity and *** this study,we design a Ru-based OER catalyst incorporating Pb as a supporting *** electrocatalyst exhibits an OER overpotential of 201 mV at 10 mA·cm^(-2),simultaneously reducing Ru noble metal loading by~40%.Normalization of the electrochemically active surface area unveils improved intrinsic activity compared to the pristine RuO_(2) *** a practical stability test in a PEM-WE setup,our developed catalyst sustains stable performance over 300 h without notable degradation,underscoring its potential for future applications as a reliable anodic catalyst.

关键词： electrocatalysis oxygen evolution reaction water splitting proton exchange membrane water electrolyzer

Exponentially Bounded C-semigroup and the Cauchy Initial Value Problems in Complete Random Normed Modules

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Acta Mathematica Sinica,English Series 2024年第9期40卷 2195-2212页

作者： son TA CONG Thang Dang HUNG Oanh Le THI Department of Mathematics University of ScienceVietnam National University 334 Nguyen TraiThanh XuanHanoiVietnam Faculty of Natural Sciences Hong Duc University565 Quang TrungDong VeThanh HoaVietnam

In this paper,the notion of C-semigroup of continuous module homomorphisms on a complete random normal(RN)module is introduced and *** existence and uniqueness of solution to the Cauchy problem with respect to exponen... 详细信息

关键词： C-semigroup Cauchy problem random normed modules L^(0)-Lipschitz

维普期刊数据库

Two-stage dynamic recrystallization and texture evolution in Al-7Mg alloy during hot torsion

在线全文

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2024年第8期31卷 1900-1911页

作者： Kwang Tae son Chang Hee Cho Myoung Gyun kim Ji Woon Lee School of Mechanical Industrialand Manufacturing EngineeringOregon State UniversityCorvallis OR 97331USA Department of Materials Science Engineering Northwestern UniversityEvanston IL 60208USA Research Institute of Industrial Science and Technology(RIST) Pohang 37673Rep.of Korea Division of Advanced Materials Engineering Kongju National UniversityCheonan 31080Rep.of Korea Center for Advanced Materials and Parts of Powders Kongju National UniversityCheonan 31080Rep.of Korea

Hot torsion tests were performed on the Al-7Mg alloy at the temperature ranging from 300 to 500℃ and strain rates between 0.05 and 5 s^(-1) to explore the progressive dynamic recrystallization(DRX)and texture *** DRX behavior of the alloy manifested two distinct stages:Stage 1 at strain of≤2 and Stage 2 at strains of≥*** Stage 1,there was a slight increase in the DRXed grain fraction(X_(DRX))with predominance of discontinuous DRX(DDRX),followed by a modest change in X_(DRX) until the transition to Stage *** 2 was marked by an accelerated rate of DRX,culminating in a substantial final X_(DRX) of~*** backscattered diffraction(EBSD)analysis on a sample in Stage 2 revealed that continuous DRX(CDRX)predominantly occurred within the(121)[001]grains,whereas the(111)[110]grains underwent a geometric DRX(GDRX)evolution without a noticeable sub-grain ***,a modified Avrami’s DRX kinetics model was utilized to predict the microstructural refinement in the Al-7Mg alloy during the DRX *** this kinetics model did not accurately capture the DDRX behavior in Stage 1,it effectively simulated the DRX rate in Stage *** texture index was employed to assess the evolution of the texture isotropy during hot-torsion test,demonstrating significant improvement(>75%)in texture randomness before the commencement of Stage *** initial texture evolution is attributed to the rotation of parent grains and the substructure evolution,rather than to an increase in X_(DRX).

关键词： Al-7Mg alloys hot deformation hot torsion tests dynamic recrystazlliation microstructure texture

维普期刊数据库

Enhancement of mechanical and tribological performance of Ti-6Al-4V alloy by laser surface alloying with Inconel 625 and SiC precursor materials

在线全文

学校读者我要写书评

暂无评论

Friction 2024年第9期12卷 2089-2107页

作者： Hao-Ran CHENG ki-Hoon SHIN Hong Seok kiM Department of Mechanical Engineering Graduate School of Seoul National University of Science and TechnologySeoul 01811Republic of Korea Department of Mechanical and Automotive Engineering Seoul National University of Science and TechnologySeoul 01811Republic of Korea

This study focused on producing metal matrix composite(MMC)coatings on Ti–6Al–4V alloy through laser surface alloying using a novel combination of Inconel 625 and SiC precursor *** ratios of alloying powders were examined to evaluate surface properties such as microhardness,wear resistance,and friction coefficient,along with analyzing the phase composition and microstructure of the *** in situ synthesized MMC coatings exhibited the presence ofα-Ti,NiTi,NiTi_(2),and TiC ***,Ti_(5)Si_(3)andα-Ti/Ti_(5)Si_(3)eutectic structures were observed when the SiC content exceeded 20%.In comparison to the titanium substrate,the MMC coating significantly enhanced microhardness by over threefold and reduced wear by 95%.However,it was crucial to carefully select the appropriate combination of alloying powders to avoid a substantial decrease in friction performance and excessive formation of *** a comparative analysis of experimental results,the optimal precursor material composition was identified as 85%Inconel 625 and 15%*** study demonstrated the effective utilization of Inconel 625 and SiC alloying materials to enhance the surface properties of titanium alloys,thereby expanding their application in challenging environments.

关键词： titanium alloy Inconel 625 SiC ceramic laser surface alloying metal matrix composite(MMC)

The SARS-CoV-2 spike protein induces lung cancer migration and invasion in a TLR2-dependent manner

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Cancer Communications 2024年第2期44卷 273-277页

作者： Mi-Jeong kim Ji Young kim Ji Hye Shin Juhee son Yeeun Kang Soo-Kyung Jeong Duk-Hwan kim Kyun-Hwan kim Eunyoung Chun ki-Young Lee Department of Immunology Samsung Biomedical Research InstituteSungkyunkwan University School of MedicineSuwonRepublic of Korea Research and Development Center CHA Vaccine InstituteSeongnam-siRepublic of Korea Department of Molecular Cell Biology Sungkyunkwan University School of MedicineSuwonRepublic of Korea Department of Precision Medicine Sungkyunkwan University School of MedicineSuwonRepublic of Korea Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences&TechnologySamsung Medical CenterSungkyunkwan UniversitySeoulRepublic of Korea

Dear editor,Severe acute respiratory syndrome coronavirus2(SARS-CoV-2)infection can lead to severe outcomes in patients with cancer[1].It has been reported that patients with lung cancers disproportionately manifest severe COVID-19 with a high rate of hospitalization and death[2].Notably,the SARS-CoV-2 Spike(S)protein can induce hyper-inflammation in both epithelial cells and macrophages through toll-like receptor(TLR)1/TLR2 or TLR2/6-dependent nuclear factor-kappaB(NF-κB)path-way[3].However,molecular and cellular evidence on whether the SARS-CoV-2 virus affects the severity of lung cancer patients through TLR1/2 or TLR2/6 signaling remains unclear.

关键词： lung TLR2 invasion

Regional economic assessment of a novel place-based model for sustainable food systems

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Geography and Sustainability 2024年第2期5卷 220-229页

作者： Susanna Kujala Kari Koppelmäki University of Helsinki Ruralia InstituteKampusranta 9 C 60320SeinäjokiFinland University of Helsinki Ruralia InstituteLönnrotinkatu 750100MikkeliFinland Wageningen University&Research Farming Systems Ecology GroupDroevendaalsesteeg 16708PBWageningenThe Netherlands

Several actions from both the environmental and human viewpoints have already been made to meet the sustainability goals targeted at food ***,new place-based ideas to improve sustainability are *** symbiosis(AES),a novel food system model,is an example of a suggested system-level change to attain sustainability targets;it is a symbiosis of food production and processing using renewable energy that uses its own *** has already been found advantageous from the ecological and biophysical viewpoints,but a regional economic evaluation of the model is still ***,the aim of our paper is to assess the regional economic impact of a possible systemic change in the food system using the network of agroecological symbiosis(NAES)as an *** applied scenarios representing different ways of moving towards envisioned NAES models in Mäntsälä,Finland,and a computable general equilibrium model to evaluate the regional economic *** to our results,both regional economy and employment would increase,and the regional production base would diversify with NAES implementation applied to the region,but the extent of the benefits varies between *** scenario that includes change in both public and private food demand,production of bioenergy and utilization of by-products would cause the largest ***,realizing NAES requires investments that may influence the actual implementation of such ***,a change towards NAES can promote an economically and spatially just transition to sustainability,as NAES seems to be economically most beneficial for rural areas.

关键词： Sustainability Regional economy Localized food system Renewable energy Circularity

Modification strategies improving the electrochemical and structural stability of high-Ni cathode materials

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第9期96卷 185-205页

作者： Yoon Bo Sim Hami Lee Junyoung Mun ki Jae kim Department of Energy Science Sungkyunkwan UniversitySuwon 16419Republic of Korea School of Advanced Materials Science and Engineering Sungkyunkwan UniversitySuwon 16419Republic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan UniversitySuwon 16419Republic of Korea

with the increasing spotlight in electric vehicles,there is a growing demand for high-energy-density batteries to enhance driving ***,several studies have been conducted on high-energy-density LiNi_(x)Co_(y)Mn_(z)O_(2)***,there is a limit to permanent performance deterioration because of side reactions caused by moisture in the atmosphere and continuous microcracks during cycling as the Ni content to express high energy increases and the content of Mn and Co that maintain structural and electrochemical stabilization *** direct modification of the surface and bulk regions aims to enhance the capacity and long-term performance of high-Ni cathode ***,an efficient modification requires a study based on a thorough understanding of the degradation mechanisms in the surface and bulk *** this review,a comprehensive analysis of various modifications,including doping,coating,concentration gradient,and single crystals,is conducted to solve degradation issues along with an analysis of the overall degradation mechanism occurring in high-Ni cathode *** also summarizes recent research developments related to the following modifications,aims to provide notable points and directions for post-studies,and provides valuable references for the commercialization of stable high-energy-density cathode materials.

关键词： High energy density High-Ni cathode materials Degradation Structural stability Lithium-ion battery

维普期刊数据库