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Assessing n-type organic materials for lithium batteries:A techno-economic review

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InfoMat 2023年第11期5卷 1-24页

作者： Alessandro Innocenti Henry Adenusi stefano passerini Helmholtz Institute Ulm(HIU)Electrochemical Energy Storage UlmGermany Karlsruhe Institute of Technology(KIT) KarlsruheGermany Department of Chemistry The University of Hong KongHong Kongthe People's Republic of China Hong Kong Quantum AI Lab Hong Kongthe People's Republic of China Department of Chemistry Sapienza University of RomeRomeItaly

The high demand for critical minerals such as lithium,copper,nickel,and cobalt,required for lithium-ion batteries,has raised questions regarding the feasibility of maintaining a steady and affordable supply of raw materials for their *** the last years,researchers have shifted their attention toward organic materials,which are potentially more widely available,affordable,and sustainable due to the ubiquitous presence of the constituent organic *** n-type materials have a redox mechanism analogous to that of lithium-ion cathodes and anodes,hence they are suitable for a meaningful comparison with the state-of-the-art *** many reviews have evaluated the properties of organic materials at the material or electrode level,herein,the properties of n-type organic materials are assessed in a complex system,such as a full battery,to evaluate the feasibility and performance of these materials in commercial-scale battery *** most relevant cathode materials for organic batteries are reviewed,and a detailed cost and performance analysis of n-type material-based battery packs using the BatPaC 5.0 software is *** analysis considers the influence of electrode design choices,such as the conductive carbon content,active material mass loading,and electrode density,on energy density and *** potential of n-type organic materials as a low-cost and sustainable solution for energy storage applications is highlighted,while emphasizing the need for further advancements of organic materials for energy storage applications.

关键词： batteries cost-performance analysis lithium-ion organic review

Stepwise optimization of single-ion conducting polymer electrolytes for high-performance lithium-metal batteries

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Journal of Energy Chemistry 2023年第5期80卷 174-181,I0005页

作者： Xu Dong Zhen Chen Xinpei Gao Alexander Mayer Hai-Peng Liang stefano passerini Dominic Bresser Helmholtz Institute Ulm(HIU) Helmholtzstrasse 1189081 UlmGermany Karlsruhe Institute of Technology(KIT) P.0.Box 364076021 KarlsruheGermany

Single-ion conducting polymer electrolytes(SIPEs)are promising candidates for high-energy and highsafety lithium-metal batteries(LMBs).However,their insufficient ionic conductivity and electrochemical stability hinder their practical ***,three new SIPEs,i.e.,poly(1,4-phenylene ether ether sulfone)-Li(PEES-Li),polysulfone-Li(PSF-Li),and hexafluoropolysulfone-Li(6FPSF-Li),all containing covalently tethered perfluorinated ionic side chains,have been designed,synthesized,and compared to investigate the influence of the backbone chemistry and the concentration of the ionic group on their electrochemical properties and cell ***,the trifluoromethyl group in the backbone and the concentration of the ionic function appear to play an essential role for the charge transport and stability towards oxidation,and the combination of both yields the best-performing SIPE with high ionic conductivity of ca.2.5×10^(-4)S cm^(-1),anodic stability of more than 4.8 V,and the by far highest capacity retention in Li‖LiNi0.6Co0.2Mn0.2O2cells.

关键词： single-ion conductor Polymer electralyte Backbone chemistry NCMu22 cathode Lithium-metal battery

Recycled graphite for more sustainable lithium-ion batteries

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Carbon Energy 2024年第5期6卷 15-24页

作者： Mayokun Olutogun Anna Vanderbruggen Christoph Frey Martin Rudolph Dominic Bresser stefano passerini Helmholtz Institute Ulm(HIU) Ulm Germany Karlsruhe Institute of Technology(KIT) KarlsruheGermany Helmholtz Zentrum Dresden-Rossendorf(HZDR) Helmholtz Institute Freiberg for Resource Technology(HIF)FreibergGermany ProGraphite GmbH UntergriesbachGermany Chemistry Department Sapienza University of RomeRomeItaly

The demand for lithium-ion batteries(LIBs)is driven largely by their use in electric vehicles,which is projected to increase dramatically in the *** great success,however,urgently calls for the efficient recycling of LIBs at the end of their ***,we describe a froth flotation-based process to recycle graphite—the predominant active material for the negative electrode—from spent LIBs and investigate its reuse in newly assembled *** has been found that the structure and morphology of the recycled graphite are essentially unchanged compared to pristine commercial anode-grade graphite,and despite some minor impurities from the recycling process,the recycled graphite provides a remarkable reversible specific capacity of more than 350 mAh g^(−1).Even more importantly,newly assembled graphite‖NMC532 cells show excellent cycling stability with a capacity retention of 80%after 1000 cycles,that is,comparable to the performance of reference full cells comprising pristine commercial graphite.

关键词： anode graphite lithium-ion battery recycling sustainability

Beneficial impact of lithium bis(oxalato)borate as electrolyte additive for high-voltage nickel-rich lithium-battery cathodes

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InfoMat 2023年第8期5卷 67-80页

作者： Fanglin Wu Angelo Mullaliu Thomas Diemant Dominik Stepien Tatjana NParac-Vogt Jae-Kwang Kim Dominic Bresser Guk-Tae Kim stefano passerini Helmholtz Institute Ulm(HIU) UlmGermany Karlsruhe Institute of Technology(KIT) KarlsruheGermany Department of Chemistry KU LeuvenLeuvenBelgium Department of Energy Convergence Engineering Cheongju UniversityCheongjuRepublic of Korea Chemistry Department Sapienza University of RomeRomeItaly

High-voltage nickel-rich layered cathodes possess the requisite,such as excellent discharge capacity and high energy density,to realize lithium batteries with higher energy ***,such materials suffer from structural and interfacial instability at high voltages(>4.3 V).To reinforce the stability of these cathode materials at elevated voltages,lithium borate salts are investigated as electrolyte additives to generate a superior cathode-electrolyte ***,the use of lithium bis(oxalato)borate(LiBOB)leads to an enhanced cycling stability with a capacity retention of 81.7%.Importantly,almost no voltage hysteresis is detected after 200 cycles at *** outstanding electrochemical performance is attributed to an enhanced structural and interfacial stability,which is attained by suppressing the generation of micro-cracks and the superficial structural degradation upon *** improved stability stems from the formation of a fortified borate-containing interphase which protects the highly reactive cathode from parasitic reactions with the ***,the decomposition process of LiBOB and the possible adsorption routes to the cathode surface are deduced and elucidated.

关键词： cathode electrolyte interphase electrolyte additive high voltage cathodes LiBOB nickel-rich cathodes

Fast interfacial electrocatalytic desolvation enabling lowtemperature and long-cycle-life aqueous Zn batteries

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InfoMat 2024年第7期6卷 76-89页

作者： Jian Wang Hongfei Hu Lujie Jia Jing Zhang Quan Zhuang Linge Li Yongzheng Zhang Dong Wang Qinghua Guan Huimin Hu Meinan Liu Liang Zhan Henry Adenusi stefano passerini Hongzhen Lin i-Lab&CAS Key Laboratory of Nanophotonic Materials and Devices Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhouthe People’s Republic of China Helmholtz Institute Ulm(HIU) UlmGermany Karlsruhe Institute of Technology(KIT) KarlsruheGermany Inner Mongolia Key Laboratory of Carbon Nanomaterials Nano Innovation Institute(NII)Inner Mongolia Minzu UniversityTongliaothe People’s Republic of China State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghaithe People’s Republic of China School of Materials Science&Engineering and International Center of Future Science Jilin UniversityChangchunJilinthe People’s Republic of China Department of Science and Engineering of Matter Environment and Urban PlanningMarche Polytechnic UniversityAnconaItaly Department of Chemistry The University of Hong KongHong Kongthe People’s Republic of China Hong Kong Quantum AI Lab Hong Kongthe People’s Republic of China Chemistry Department Sapienza University of RomeRomeItaly

Low-temperature zinc batteries(LT-ZIBs)based on aqueous electrolytes show great promise for practical applications owing to their natural resource abundance and low ***,they suffer from sluggish kinetics with elevated energy barriers due to the dissociation of bulky Zn(H2O)62+solvation structure and free Zn2+diffusion,resulting in unsatisfactory lifespan and ***,dissimilar to solvation shell tuning or layer spacing enlargement engineering,delocalized electrons in cathode through constructing intrinsic defect engineering is proposed to achieve a rapid electrocatalytic desolvation to obtain free Zn2+for insertion/*** revealed by density functional theory calculations and interfacial spectroscopic characterizations,the intrinsic delocalized electron distribution propels the Zn(H2O)62+dissociation,forming a reversible interphase and facilitating Zn2+diffusion across the electrolyte/cathode *** as-fabricated oxygen defect-rich V2O5 on hierarchical porous carbon(ODVO@HPC)electrode exhibits high capacity robustness from 25 to20℃.Operating at-20℃,the ODVO@HPC delivers 191 mAh g-1 at 50 A g-1 and lasts for 50000 cycles at 10 A g-1,significantly enhancing the power density and lifespan under low-temperature environments in comparison to previous *** with areal mass loading of-13 mg cm2,both coin cells and pouch batteries maintain excellent stability and areal capacities,realizing practical high-performance LT-ZIBs.

关键词： defect catalysis delocalized electron engineering diffusion kinetics modulation lowtemperature Zn batteries V2O5 cathode