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Chinese Journal of Polymer Science 2024年第8期42卷 1067-1076页

作者： Chun-Peng Zhang si-jia gao Ying Luo Lei Zou Yong-Jun Zhang State Key Laboratory of Separation Membranes and Membrane Processes School of Material Science and EngineeringTiangong UniversityTianjin 300387China State Key Laboratory of Separation Membranes and Membrane Processes School of Pharmaceutical SciencesTiangong UniversityTianjin 300387China Tianjin Key Laboratory of Extracorporeal Life Support for Critical Diseases Institute of Hepatobiliary DiseaseNankai University Affiliated Third Center HospitalTianjin 300170China Cangzhou Institute of Tiangong University Cangzhou 061000China

Glucose-sensitive membrane has potential application in self-regulating insulin *** acid(PBA)is a well-known glucose ***,most PBA-based glucose-sensitive materials are expansion-type,which are not suitable as chemical valves in membrane pores for self-regulating insulin *** to a new glucose-sensitive mechanism,we synthesized PBA-based contraction-type glucose-sensitive liner polymer and ***,a glucose-sensitive membrane was prepared by grafting PBA-based contraction-type glucose-sensitive linear polymer on the membrane *** adjusting the chain length and chain density,the glucose-sensitivity of the membrane was *** membrane can reversibly regulate insulin release at physiologically relevant glucose concentrations in simulates body fluids and fetal bovine *** membrane also has good stability,anti-fouling and biocom *** has potential application in selfregulating insulin release.

关键词： Phenylboronic acid Glucose-sensitive Membrane Surface grafting Insulin

single-wavelength Excited Ratiometric Fluorescence pH Probe to Image Intracellular Trafficking of Tobacco Mosaic Virus

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Chinese Journal of Polymer Science 2020年第6期38卷 587-592页

作者： si-jia gao Zhuang Li Zhi-Cheng Sun Jin-Yue Wen Fu-Rong Li Xiao-Yang Du Yan Liu Ye Tian Zhong-Wei Niu Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Beijing Engineering Research Centerof Printed Electronics Beijing Institute of Graphic CommunicationBeijing 102600China School of Future Technology University of Chinese Academy of SciencesBeijing 100049China

As a typical plant virus which has biocompatibility and high transfection efficiency,tobacco mosaic virus(TMV)has shown broad application potential in drug or gene delivery *** its intracellular trafficking is of great importance in investigation of its cytotoxicity,targeting site,and delivery efficiency,and is advantageous to designing new TMV-based drug delivery systems with different *** taking advantage of the regulated pH value of different organelles in a mammalian cell,we exploit a pH detection strategy to investigate the intracellular trafficking pathway of ***,we report a single-wavelength excited ratiometric fluorescent pH *** probe is constructed by simultaneously coupling pH-sensitive fluorescein isothiocyanate(FITC)and pH-insensitive rhodamine B isothiocyanate(RBIRC)onto the inner surface of *** fluorescence intensity ratio of FITC to RBITC excited at 488 nm responds specifically towards pH value over other interferential *** taking use of this single-wavelength excited ratiometric pH probe and confocal laser scanning microscopy,it is shown that the endocytosed TMV is located in a pH decreasing microenvironment and eventually enters *** work may provide important guidance on construction of TMV-based nano carriers.

关键词： Tobacco mosaic virus Ratiometric fluorescence pH probe Intracellular trafficking

Responsive Hybrid Poly(vinyl alcohol)Hydrogel Membranes with Embedded Microgels as Valves

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Chinese Journal of Polymer Science 2023年第10期41卷 1646-1655页

作者： Zi-Lin Wang Di Huang Mei-Yu Zhang Xin-Xin Fu Ying Luo Lei Zou si-jia gao Zhuo Zhao Ya-Fei Wang Yan Zhang Yong-Jun Zhang State Key Laboratory of Separation Membranes and Membrane Processes School of Material Science and EngineeringTiangong UniversityTianjin300387China Tianjin Key Laboratory of Extracorporeal Life Support for Critical Diseases Institute of Hepatobiliary DiseaseNankai University Affiliated Third Center HospitalTianjin300170China School of Chemistry Tiangong UniversityTianjin300387China

The research and application of responsive materials have long been hampered by their complicated designs and tedious construction ***,many current responsive materials show retard or weak *** this study,responsive hybrid poly(vinyl alcohol)hydrogel membranes with embedded poly(N-isopropylacrylamide-acrylic acid)microgels as valves were constructed by simple mixing and subsequent freezing-thawing *** the structure of the membranes,the matrix poly(vinyl alcohol)chains thread through and entangle with the microgels,and the microgels are firmly constrained within the hybrid hydrogel *** fast and sharp temperature responsiveness of the embedded microgels was largely retained and endowed the hydrogel membrane with excellent temperature and pH ***,the hydrogel membrane showed excellent fatigue resistance in both temperature and pH-responsive flux *** study presented the great potential of these hybrid hydrogel membranes in biomedical applications and provided a new strategy for the future design and construction of responsive biomaterials.

关键词： Poly(vinyl alcohol)hydrogel Microgels Hydrogel membrane

智能电动机保护器的电磁辐射定量评估方法研究

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电机与控制学报 2017年第6期21卷 34-43页

作者：赵靖英周思诺高佳雄河北工业大学电气工程学院天津300130

针对电路复杂程度不断增加、信号处理速度不断提高的智能电动机保护器的电磁辐射日益严重问题,提出一种智能电动机保护器的电磁辐射定量评估方法。采用电路图绘制软件与仿真软件相结合的方式对典型智能电动机保护器PCB布局进行了仿真建... 详细信息

针对电路复杂程度不断增加、信号处理速度不断提高的智能电动机保护器的电磁辐射日益严重问题,提出一种智能电动机保护器的电磁辐射定量评估方法。采用电路图绘制软件与仿真软件相结合的方式对典型智能电动机保护器PCB布局进行了仿真建模,完成了电流、电场强度和磁场强度等参量的定量评估,直观呈现了电磁辐射的分布情况,并进行了实验设计、测试和验证。此外,研究了关键线路的线宽对典型智能电动机保护器电磁辐射特性的影响。结果表明:提出的仿真和实验方法对复杂结构的智能电动机保护器的电磁辐射定量评估具有一定的有效性和可行性;根据使用环境适当改变线宽可以不同程度地减小智能电动机保护器的电场强度和电磁强度,为产品设计提供参考。

关键词：智能电动机保护器电磁辐射仿真分析 PCB布局定量评估

Synergistic promotion strategy of “dual-site” and “dual-path” to enhance the C–C coupling between CO2 and HCHO driven by photoelectrocatalysis

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Journal of Energy Chemistry 2025年第1期100卷 39-49页

作者： Hongqiang Yang jianfeng Zheng Guoyu Wang Yifei gao Yatao Yang jia Li Xiaojin Han Yan Cui Zhanggen Huang National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal Institute of Coal Chemistry Chinese Academy of Science University of Chinese Academy of Science Shenyang University of Chemical Technology

Photoelectrocatalytic coupling CO2and volatile organic compounds （VOCs） is a promising green strategy for the synergistic conversion of the two carbon-containing resources to *** catalytic efficiency is always at the mercy of chemical inertness of CO2and the competitive hydrogen evolution of ***,a modified g-C3N4/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely *** Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol *** revealed by in-situ characterizations and density functional theory calculations,CO2and HCHO were absorbed at Zn site and N site,***,*CO generated from CO2and HCHO was converted to*CH3O and*CHO on the dual-active-site *** detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH3O in electrocatalysis *** from the“*CO+*CH3O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic *** selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO2and HCHO simultaneously driven by light and electricity.

关键词： Photoelectrocatalysis Z-scheme C–C coupling Ethanol

Passive activity enhances residual control ability in patients with complete spinal cord injury

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Neural Regeneration Research 2025年第8期20卷 2337-2347页

作者： Yanqing Xiao Mingming gao Zejia He jia Zheng Hongming Bai jia-Sheng Rao Guiyun Song Wei Song Xiaoguang Li Beijing Key Laboratory for Biomaterials and Neural Regeneration Beijing Advanced Innovation Center for Biomedical EngineeringSchool of Biological Science and Medical EngineeringBeihang UniversityBeijingChina Department of Rehabilitation Evaluation China Rehabilitation Research CenterBeijingChina Cardiac Center Beijing Children’s HospitalCapital Medical UniversityBeijingChina The State Key Laboratory of Virtual Reality Technology and Systems Beihang UniversityBeijingChina Department of Rehabilitation Engineering China Rehabilitation Science InstituteBeijingChina

Patients with complete spinal cord injury retain the potential for volitional muscle activity in muscles located below the spinal injury ***,because of prolonged inactivity,initial attempts to activate these muscles may not effectively engage any of the remaining neurons in the descending pathway.A previous study unexpectedly found that a brief clinical round of passive activity significantly increased volitional muscle activation,as measured by surface *** this study,we further explored the effect of passive activity on surface electromyographic signals during volitional control tasks among individuals with complete spinal cord *** patients with chronic complete thoracic spinal cord injury were *** electromyography data from eight major leg muscles were acquired and compared before and after the passive activity *** results indicated that the passive activity led to an increased number of activated volitional muscles and an increased frequency of *** the cumulative root mean square of surface electromyography amplitude for volitional control of movement showed a slight increase after passive activity,the difference was not statistically *** findings suggest that brief passive activity may enhance the ability to initiate volitional muscle activity during surface electromyography tasks and underscore the potential of passive activity for improving residual motor control among patients with motor complete spinal cord injury.

关键词： complete spinal cord injury cycle training epidural electrical stimulation motor training passive activity physiological state spinal cord circuit surface electromyography volitional control task

Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption

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Nano-Micro Letters 2025年第1期17卷 507-527页

作者： Zhiqiang Guo Di Lan Zirui jia Zhenguo gao Xuetao Shi Mukun He Hua Guo Guanglei Wu Pengfei Yin College of Science Sichuan Agricultural UniversityYa’an 625014People’s Republic of China School of Materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002People’s Republic of China Institute of Materials for Energy and Environment State Key Laboratory of Bio‑Fibers and Eco‑TextilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071People’s Republic of China Shaanxi Key Laboratory of Macromolecular Science and Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’anShaanxi 710072People’s Republic of China

Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly ***-component interface engineering is considered an effective means to achieve high-efficiency EMW ***,interface modulation engineering has not been fully discussed and has great potential in the field of EMW *** this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal *** utilizing the different properties of different substances,rich heterogeneous interfaces are *** effectively promotes charge transfer and enhances interfacial polarization and conduction *** prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy *** minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 ***,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel ***,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.

关键词： Electrostatic spinning Component regulation Heterogeneous interfaces Electromagnetic wave absorption Corrosion protection

基于葫芦[8]脲主客体化学的双客体组分动态交联水凝胶的制备和性能研究

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高分子学报 2024年第1期55卷 79-90页

作者：张鹏亮张莹莹李新桐任家骏邹磊赵琢高偲嘉王亚斐张岩骆莹张拥军天津工业大学材料科学与工程学院天津300387 天津工业大学药学院天津300387 天津工业大学化学学院天津300387 天津市第三中心医院天津市肝胆疾病研究所天津市重症疾病体外生命支持重点实验室天津300170

基于超分子主客体作用的动态交联在构筑用于生物大分子和细胞载体的可注射水凝胶输送材料方面具备很多优势,但单一性质交联点的动态快慢程度固定,无法进行调节,难以实现水凝胶动态可调的性能.本研究利用葫芦[8]脲(CB[8])能够与它的客体... 详细信息

基于超分子主客体作用的动态交联在构筑用于生物大分子和细胞载体的可注射水凝胶输送材料方面具备很多优势,但单一性质交联点的动态快慢程度固定,无法进行调节,难以实现水凝胶动态可调的性能.本研究利用葫芦[8]脲(CB[8])能够与它的客体分子以摩尔比为1/2的比例形成同种三元复合物主客体的相互作用,设计了一种双组分超分子动态交联水凝胶系统.在水凝胶聚合物骨架的侧链上同时引入偶氮苯与苯基吡啶盐2种客体基团,其中偶氮苯客体与CB[8]的结合较弱,呈现较快的动态可逆性质;苯基吡啶盐客体与CB[8]的结合较强,呈现较慢的动态可逆性质.设计不同比例的2种动态交联,得到了系列网络结构相同,但交联点性质动态可调的水凝胶材料.水凝胶性能研究结果显示,得到的材料能够在流变学机械性能、自修复、剪切变稀、应力松弛、大分子药物释放等生物医用关键性质上随客体比例变化而进行调控,具备良好的应用前景.

关键词：葫芦脲水凝胶主客体化学动态交联

Stability analysis of cut-fill and deep patch unsaturated slopes under steady infiltration conditions

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Science China Technological Sciences 2025年第1期 356-367页

作者： Fei ZHANG Shilin jia Yufeng gao Key Laboratory of the Ministry of Education for Geomechanics and Embankment Engineering College of Civil and Transportation EngineeringHohai University

Cut-fill slopes, as an economical solution in mountainous road construction, are typically jeopardized by cracks and rainfall. Deep patch repair with geosynthetics is an effective technique to mitigate these issues. This paper proposes an upperbound analytical framework for evaluating the stability of cracked cut-fill slopes and deep patch slopes under one-dimensional steady infiltration. The proposed framework is employed to investigate suction-induced effects on slope stability and critical failure surface through a series of parametric analyses. The findings indicate that the suction-induced effect generally increases with air-entry pressure and approaches a constant value. The stability of a cracked cut-fill slope can be enhanced by deep patch repair with geosynthetics. Increasing the deep patch depth enhances local stability and reduces the required reinforcement strength. Generally, the depth of the deep patch should be greater than the crack depth to avoid local failures. Furthermore, a design method involving both local and global stability for deep patch slopes is presented, along with a design example for illustration.

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Low-cost and fluoride-free synthesis of MFI zeolite nanosheets with enhanced stability for benzene alkylation with ethanol

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Journal of Energy Chemistry 2025年第1期100卷 458-468页

作者： Peng Zhu Cun Liu Yiren Yu Guoshu gao Yumeng Zhao Xiongfu Zhang Guodong Liu Guohui Yang State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

Zeolite nanosheets with a short b-axis thickness are highly desirable in lots of catalytic reactions due to their reduced diffusion resistance. Nevertheless, conventional synthesis methods usually require expensive structure-directing agents(SDAs), pricey raw materials, and eco-unfriendly fluorine-containing additives. Here, we contributed a cost-effective and fluoride-free synthesis method for synthesizing high-quality MFI zeolite nanosheets through a silicalite-1(sil-1) seed suspension and urea cooperative strategy, only with inexpensive colloidal silica as the si source. Our approach was effective for synthesizing both sil-1 and aluminum-containing ZSM-5 nanosheets. By optimizing key synthesis parameters,including seed aging time, seed quantity, and urea concentration, we achieved precise control over the crystal face aspect ratio and b-axis thickness. We also revealed a non-classical oriented nanosheet growth mechanism, where sil-1 seeds induced the formation of quasi-ordered precursor particles, and the(010)crystal planes of these particles facilitated urea adsorption, thereby promoting c-axis-oriented *** obtained ZSM-5 nanosheets exhibited exceptional catalytic performance in the benzene alkylation with ethanol, maintaining stability for over 500 h, which is 5 times longer than traditional ZSM-5 catalysts. Furthermore, large-scale production of ZSM-5 nanosheets was successfully carried out in a 3 L highpressure autoclave, yielding samples consistent with those from laboratory-scale synthesis. This work marks a significant step forward in the sustainable and efficient production of MFI nanosheets using inexpensive and environmentally friendly raw materials, offering the broad applicability in catalysis.

关键词： MFI zeolite ZSM-5 Nanosheets Scale-up synthesis Aromatic alkylation