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Importance of oxygen-containing functionalities and pore structures of biochar in catalyzing pyrolysis of homologous poplar

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Chinese Journal of Chemical Engineering 2024年第1期65卷 200-211页

作者： Li Qiu Chao Li Shu Zhang shuang Wang Bin Li Zhenhua cui Yonggui Tang Obid Tursunov Xun Hu School of Material Science and Engineering University of JinanJinan 250022China Joint International Research Laboratory of Biomass Energy and Materials College of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037China School of Energy and Power Engineering Jiangsu UniversityZhenjiang 212013China Shandong BASAN Graphite New Material Plant Zibo 255311China Department of Power Supply and Renewable Energy Sources National Research University TIIAMETashkent 100000Uzbekistan

Biochar and bio-oil are produced simultaneously in one pyrolysis process,and they inevitably contact and may interact,influencing the composition of bio-oil and modifying the structure of biochar.In this sense,biochar is an inherent catalyst for pyrolysis.In this study,in order to investigate the influence of functionalities and pore structures of biochar on its capability for catalyzing the conversion of homologous volatiles in bio-oil,three char catalysts(600C,800C,and 800AC)produced via pyrolysis of poplar wood at 600 or 800℃or activated at 800℃,were used for catalyzing pyrolysis of homologous poplar wood at 600℃,respectively.The results indicated that the 600C catalyst was more active than 800C and 800AC for catalyzing cracking of volatiles to form more gas(yield increase by 40.2%)and aromatization of volatiles to form more light or heavy phenolics,due to its abundant oxygen-containing functionalities acting as active sites.The developed pores of the 800AC showed no such catalytic effect but could trap some volatiles and allow their further conversion via sufficient aromatization.Nevertheless,the interaction with the volatiles consumed oxygen on 600C(decrease by 50%),enhancing the aromatic degree and increasing thermal stability.The dominance of deposition of carbonaceous material of a very aromatic nature over 800C and 800AC resulted in net weight gain and blocked micropores but formed additional macropores.The in situ diffuse reflectance infrared Fourier transform spectroscopy characterization of the catalytic pyrolysis indicated superior activity of 600C for removal of -OH,while conversion of the intermediates bearing C=O was enhanced over all the char catalysts.

关键词： Poplar wood Catalytic pyrolysis Char catalyst Volatile-char interaction Bio-oil

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Antigen-induced chimeric antigen receptor multimerization amplifies on-tumor cytotoxicity

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Signal Transduction and Targeted Therapy 2024年第1期9卷 259-270页

作者： Yan Sun Xiu-Na Yang shuang-shuang Yang Yi-Zhu Lyu Bing Zhang Kai-Wen Liu Na Li Jia-Chen cui Guang-Xiang Huang Cheng-Lin Liu Jie Xu Jian-Qing Mi Zhu Chen Xiao-Hu Fan Sai-Juan Chen Shuo Chen Shanghai Institute of Hematology National Research Center for Translational MedicineState Key Laboratory of Medical GenomicsRuijin Hospital Affiliated to Shanghai Jiao Tong University School of MedicineShanghai 200025China Shanghai Institute for Advanced Immunochemical Studies and School of Life Science and Technology ShanghaiTech UniversityShanghai 201210China Department of Hematology Second Hospital of Dalian Medical UniversityDalian 116023China National Facility for Protein Science Shanghai Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201210China Legend Biotech China Nanjing 211112China Shanghai Immune Therapy Institute Shanghai Cancer InstituteState Key Laboratory of Oncogenes and Related GenesRenji Hospital Affiliated to Shanghai Jiao Tong University School of MedicineShanghai 200127China Wondercel Biotechnology Shenzhen 518052China

Ligand-induced receptor dimerization or oligomerization is a widespread mechanism for ensuring communication specificity,safeguarding receptor activation,and facilitating amplification of signal transduction across the cellular membrane.However,cell-surface antigeninduced multimerization(dubbed AIM herein)has not yet been consciously leveraged in chimeric antigen receptor(CAR)engineering for enriching T cell-based therapies.We co-developed ciltacabtagene autoleucel(cilta-cel),whose CAR incorporates two B-cell maturation antigen(BCMA)-targeted nanobodies in tandem,for treating multiple myeloma.Here we elucidated a structural and functional model in which BCMA-induced cilta-cel CAR multimerization amplifies myeloma-targeted T cell-mediated cytotoxicity.Crystallographic analysis of BCMA–nanobody complexes revealed atomic details of antigen–antibody hetero-multimerization whilst analytical ultracentrifugation and small-angle X-ray scattering characterized interdependent BCMA apposition and CAR juxtaposition in solution.BCMA-induced nanobody CAR multimerization enhanced cytotoxicity,alongside elevated immune synapse formation and cytotoxicity-mediating cytokine release,towards myeloma-derived cells.Our results provide a framework for contemplating the AIM approach in designing next-generation CARs.

关键词： cytotoxicity Antigen elevated

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面向云边端协同的多模态数据建模技术及其应用

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软件学报 2024年第3期35卷 1154-1172页

作者：崔双双吴限王宏志吴昊哈尔滨工业大学计算学部黑龙江哈尔滨150001

云边端协同架构中数据类型多样,各级存储资源与计算资源存在差异,给数据管理带来新的挑战.现有数据模型或者数据模型的简单叠加,都难以同时满足云边端中多模态数据管理和协同管理需求.因此,研究面向云边端协同的多模态数据建模技术成为... 详细信息

云边端协同架构中数据类型多样,各级存储资源与计算资源存在差异,给数据管理带来新的挑战.现有数据模型或者数据模型的简单叠加,都难以同时满足云边端中多模态数据管理和协同管理需求.因此,研究面向云边端协同的多模态数据建模技术成为重要问题.其核心在于,如何高效地从云边端三层架构中得到满足应用所需的查询结果.从云边端三层数据的数据类型出发,提出了面向云边端协同的多模态数据建模技术,给出了基于元组的多模态数据模型定义,设计了6种基类,解决多模态数据统一表征困难的问题;提出了云边端协同查询的基本数据操作体系,以满足云边端业务场景的查询需求;给出了多模态数据模型的完整性约束,为查询优化奠定了理论基础.最后,给出了面向云边端协同多模态数据模型的示范应用,并从数据存储时间、存储空间和查询时间这3个方面对所提出的数据模型存储方法进行了验证.实验结果表明,所提方案能够有效地表示云边端协同架构中的多模态数据.

关键词：多模态数据模型云边端协同查询处理

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Chromosome-level genome assembly of the Asian citrus psyllid,Diaphorina citri

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Insect Science 2024年第1期31卷 13-27页

作者： shuang Lei Shi-Jiang Yu Qi Pan Li-Li Ding Si-Chen Li Lu-Yan Cheng Shu-Qi Wang Bing-Hai Lou Jun He cui-Yun Lei Lin Cong Hao-Qiang Liu Xue-Feng Wang Chun Ran Citrus Research Institute Southwest University/Chinese Academy of Agricultural SciencesNational Engineering Research Center for CitrusChongqingChina

Diaphorina citri is a global citrus pest.As a vector insect,it can transmit the causative agents of citrus huanglongbing,causing irreversible losses to the citrus industry.The acquisition of genomic information can provide a molecular genetic basis for effective control of D.citri.Here,the DNBSEQ™,Oxford Nanopore Technologies,and Hi-C technologies are applied to generate a high-quality chromosome-level genome of D.citri.The genome size of D.citri was 523.78 Mb with a scaffold N50 of 47.05 Mb distributed on 13 chromosomes.A total of 250.64 Mb(47.85%)repeat sequences and 24048 protein-coding genes were predicted.Genome resequencing of female and male individuals indicated that the sex chromosome system of D.citri is XO.Phylogenetic analysis demonstrated that D.citri and Pachypsylla venusta,which separated from their most recent common ancestor about 336.62 million years ago,were the most closely related.Additionally,we identified genes potentially involved in detoxification metabolism,pathogen transmission,and honeydew secretion for further investigation.The high-quality genome provides an important reference for developing effective management strategies of D.citri.

关键词： Asian citrus psyllid chromosome-level genome comparative genomics cytochrome P450 detoxification Huanglongbing

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Preoperative serum cortisone levels are associated with cognition in preschool‑aged children with tetralogy of Fallot after corrective surgery:new evidence from human populations and mice

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World Journal of Pediatrics 2024年第2期20卷 173-184页

作者： Si-Yu Ma Yu-Ting Liu Yue-shuang Cun Qiang Wang Ming-cui Fu Ke-De Wu Xin-Yu Cai Shu-Ting Cheng Nishant Patel Min Da Liang Hu Zhuoga Deqin Xue-Jun Kang Ming Yang Xu-Ming Mo Department of Cardiothoracic Surgery Children’s Hospital of Nanjing Medical University72 Guangzhou RoadNanjing 210008China Department of Radiology Children’s Hospital of Nanjing Medical University72 Guangzhou RoadNanjing 210008China Key Laboratory of Child Development and Learning Science Research Center For Learning ScienceSchool of Biological Sciences&Medical EngineeringMinistry of EducationSoutheast UniversityNanjing 210096China Medical School of Nanjing University Nanjing 210093China

Background Tetralogy of Fallot(TOF)is the most common cyanotic congenital heart disease.Children with TOF would be confronted with neurological impairment across their lifetime.Our study aimed to identify the risk factors for cerebral morphology changes and cognition in postoperative preschool-aged children with TOF.Methods We used mass spectrometry(MS)technology to assess the levels of serum metabolites,Wechsler preschool and primary scale of intelligence-Fourth edition(WPPSI-Ⅳ)index scores to evaluate neurodevelopmental levels and multimodal magnetic resonance imaging(MRI)to detect cortical morphological changes.Results Multiple linear regression showed that preoperative levels of serum cortisone were positively correlated with the gyrification index of the left inferior parietal gyrus in children with TOF and negatively related to their lower visual spaces index and nonverbal index.Meanwhile,preoperative SpO_(2) was negatively correlated with levels of serum cortisone after adjusting for all covariates.Furthermore,after intervening levels of cortisone in chronic hypoxic model mice,total brain volumes were reduced at both postnatal(P)11.5 and P30 days.Conclusions Our results suggest that preoperative serum cortisone levels could be used as a biomarker of neurodevelopmental impairment in children with TOF.Our study findings emphasized that preoperative levels of cortisone could influence cerebral development and cognition abilities in children with TOF.

关键词： Cognition Cortisone MRI Neurodevelopment Tetralogy of Fallot

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考虑多影响因素的渔船单船捕捞能力评估方法

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农业工程学报 2024年第5期40卷 90-98页

作者：刘爽崔修杰吕超上海海洋大学工程学院上海201306 上海海洋大学经济管理学院上海201306

针对以往海洋机动渔船捕捞能力评估研究中考虑影响因素较少,对各影响因素的主观权重值和客观权重值综合分析不足,不能给出渔船单船捕捞能力量化值等问题,该研究提出了考虑多影响因素的渔船单船捕捞能力评估模型。首先,考虑多种影响渔船... 详细信息

针对以往海洋机动渔船捕捞能力评估研究中考虑影响因素较少,对各影响因素的主观权重值和客观权重值综合分析不足,不能给出渔船单船捕捞能力量化值等问题,该研究提出了考虑多影响因素的渔船单船捕捞能力评估模型。首先,考虑多种影响渔船捕捞能力的因素,建立单船捕捞能力评估指标体系,将其分为可量化指标和不可量化指标,并初步制定了不可量化指标评估标准。其次,利用专家、渔民调查问卷中的数据,运用层次分析法计算各指标主观权重值,结果表明各指标权重依次为:捕捞装备(0.108)、功率(0.094)、拖网(0.074)、作业时长(0.071)、总吨(0.049)、探鱼仪器(0.047)、刺网(0.040)、船长(0.032)、张网(0.028)、围网(0.024)、钓业(0.021)、作业环境(0.019)、钢质材质(0.019)、罩网(0.017)、玻璃钢材质(0.016)、船龄(0.013)、木制材质(0.012);渔具相关指标权重依次为:网具主尺寸(0.402)、网具结构(0.149)、装配技术(0.093)、制造材料(0.051)。最后,为兼顾主客观权重优点,基于加法合成法、博弈论法、最小鉴别信息法对各指标权重值进行组合计算,以获得目标权重值,并根据某省渔船数据对建立的模型进行验证分析,通过Spearman等级相关系数法计算捕捞能力评估值与实际渔获量之间的等级相关系数,结果表明基于博弈论法得到的结果相关性最高,相关系数为0.937,证实了组合权重值和评估模型的科学性和合理性。研究结果可为渔业管理部门制定科学合理的渔业资源调控政策提供依据。

关键词：渔船组合权重多因素分析层次分析法单船捕捞能力

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Adaptive strategies of overwintering adults： Reproductive diapause and mating behavior in a grasshopper, Stenocatantops splendens （Orthoptera： Catantopidae）

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Insect Science 2013年第2期20卷 235-244页

作者： Dao-Hong Zhu shuang-shuang cui Yong-Sheng Fan Zhiwei Liu Laboratory of Insect Behavior & Evolutionary Ecology Central South University of Forestry & Technology Laboratory of Zoology Hunan First Normal University Changsha China Department of Biological Sciences Eastern Illinois University Charleston Illinois USA

To understand the adaptive strategies of the overwintering adults of Steno- catantops splendens, the mechanism of maintenance and termination of the reproductive diapause, the variation in mortality between overwintering females and males, and the mating strategy of the males were investigated. The results indicated that the adult repro- ductive diapause in natural conditions was mainly regulated by photoperiod in the fall - long photoperiods promoted reproductive development and short photoperiods maintained reproductive diapause, and the sensitivity of the overwintering adults to photoperiod was over before the end of the winter. When transferred from natural conditions to controlled laboratory conditions on dates from September through February, pre-oviposition became increasingly shorter with increasingly deferred transfer dates regardless of photoperiod conditions. The adults treated with low temperature for 30 days in September through November had significantly shorter pre-oviposition, suggesting that low temperatures in winter had an important role in the termination of reproductive diapause. The female had a significantly lower supercooling point than the male, which was related to their lower mortality after winter. In addition, observations of wild populations of the species indicated that mating behavior prior to winter and the duration of pre-mating period were not affected by photoperiod; mating and sperm transfer were mostly completed by November. Compared with females only mating before winter, females mating in the spring had shorter life span, longer pre-oviposition, lower hatching rate and laid fewer egg pods while showing no significant difference with regard to ovipositional interval, per pod number of eggs and nymph dry weight.

关键词： fecundity mating behavior photoperiod reproductive diapause Stenocatan-tops splendens supercooling point

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铸牢中华民族共同体意识视域下地方民族团结促进立法的实证研究

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贵州民族研究 2024年第3期45卷 156-163页

作者：胡曼周云霜崔扬西北政法大学国家安全学院陕西西安710122

新时期,随着各民族在社会生活中的广泛交往、全面交流、深度交融,民族工作的主体、对象、内容均发生了深刻变化。铸牢中华民族共同体意识是中国共产党回应新时期民族工作的新局面、新形势和新要求提出的主线和纲领。党的十八大以后,地... 详细信息

新时期,随着各民族在社会生活中的广泛交往、全面交流、深度交融,民族工作的主体、对象、内容均发生了深刻变化。铸牢中华民族共同体意识是中国共产党回应新时期民族工作的新局面、新形势和新要求提出的主线和纲领。党的十八大以后,地方层面民族团结促进立法日渐活跃,成为从法治层面铸牢中华民族共同体意识的有益探索。本文以各地出台的33部民族团结促进立法的法规文本作为研究对象,从铸牢中华民族共同体意识的视角分析了这些立法的基本现状、特点以及其中存在的问题,提出了要将铸牢中华民族共同体意识全面贯彻到民族团结进步地方立法中,以民族团结进步地方立法促进中华文化认同、构建中华民族共有精神家园,建立区域间促进民族团结进步的合作机制,适时出台国家层面的民族团结进步促进立法的法律法规、统筹民族团结进步事业的发展。

关键词：铸牢中华民族共同体意识民族团结进步促进立法实证研究

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基于DEABC算法的EH-CRAIoT的资源分配算法研究

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现代电子技术 2024年第13期47卷 55-60页

作者：崔馨月富爽黑龙江八一农垦大学黑龙江大庆163319

针对具有无线能量收集功能的认知农业物联网中上行链路资源分配的优化问题,提出一种基于差分蜂群算法的资源分配算法。首先建立了认知农业物联网资源分配的系统模型,以系统的平均传输速率最大化为优化目标,通过在传统的人工蜂群算法中... 详细信息

针对具有无线能量收集功能的认知农业物联网中上行链路资源分配的优化问题,提出一种基于差分蜂群算法的资源分配算法。首先建立了认知农业物联网资源分配的系统模型,以系统的平均传输速率最大化为优化目标,通过在传统的人工蜂群算法中引入差分算法的更新策略,提升人工蜂群算法的收敛速度和搜索能力;再利用改进后的差分蜂群算法求解得出最优分配方案。仿真实验表明,差分蜂群算法具有良好的寻优效率和收敛性能,通过调整传感器节点的发射功率和感知时隙,能够有效在传感器节点进行频谱感知、信息传输的能量需求的前提下提升系统的平均传输速率。

关键词：认知无线电农业物联网资源分配无线能量收集系统平均传输速率蜂群算法

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共享单车与公共交通多元关系分类及阈值研究

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交通运输系统工程与信息 2024年第2期24卷 208-216页

作者：邓亚娟刘霜白钰刘文凤崔亮斌长安大学运输工程学院西安710064 青岛市市政工程设计研究院山东青岛266000

为准确评估共享单车和公共交通之间的复杂时空关系,根据替代或补充关系的具体成因类型,结合共享单车出行起讫点的分布情况,定义共享单车与公共交通多元关系;其次,考虑公共汽电车与轨道交通的差异性,提出一种基于弱监督全连接神经网络的... 详细信息

为准确评估共享单车和公共交通之间的复杂时空关系,根据替代或补充关系的具体成因类型,结合共享单车出行起讫点的分布情况,定义共享单车与公共交通多元关系;其次,考虑公共汽电车与轨道交通的差异性,提出一种基于弱监督全连接神经网络的共享单车与公共交通多元关系的分类模型,并根据共享单车轨迹数据,计算不同关系分类和交通方式下的公共交通可达范围、共享单车骑行时长及步行接驳距离边界阈值。结果表明:共享单车与公共交通的多元关系可分为接驳补充、空白补充、替代关系1和替代关系2。其中,共享单车与公共汽电车多元关系的三参数划分阈值分别为329.75 m、5.07 min和182.93 m,与轨道交通多元关系的划分阈值分别为816.96 m、10.27 min和653.91 m。共享单车与公共汽电车以替代关系1为主,占总行程的54.98%;共享单车与轨道交通以空白补充关系为主,占总行程的48.90%。共享单车与公共汽电车关系主要为多元替代与接驳补充,与轨道交通主要为多元补充与替代关系2。共享单车与公共汽电车的关系相比于轨道交通会更为复杂。本文可为促进共享单车与公共交通在各自优势距离上的协同发展提供支撑。

关键词：交通工程多元关系全连接神经网络共享单车公共交通

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