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Security and Privacy in Solar Insecticidal Lamps Internet of Things:Requirements and Challenges

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IEEE/CAA Journal of Automatica Sinica 2024年第1期11卷 58-73页

作者： Qingsong Zhao Lei shu Kailiang Li Mohamed Amine Ferrag Ximeng liu Yanbin Li the College of Artificial Intelligence Nanjing Agricultural UniversityNanjing 210031 the State Key Laboratory for Novel Software Technology Nanjing UniversityNanjing 210023 the State Key Laboratory of Cryptology Beijing 100878China IEEE the School of Engineering University of LincolnLincoln LN67TSUK the Artificial Intelligence and Digital Science Research Center Technology Innovation InstituteMasdar City 9639UAE the College of Computer and Data Science Fuzhou UniversityFuzhou 350108China

Solar insecticidal lamps(SIL) can effectively control pests and reduce the use of pesticides. Combining SIL and Internet of Things(IoT) has formed a new type of agricultural IoT,known as SIL-IoT, which can improve the effectiveness of migratory phototropic pest control. However, since the SIL is connected to the Internet, it is vulnerable to various security *** issues can lead to serious consequences, such as tampering with the parameters of SIL, illegally starting and stopping SIL,etc. In this paper, we describe the overall security requirements of SIL-IoT and present an extensive survey of security and privacy solutions for SIL-IoT. We investigate the background and logical architecture of SIL-IoT, discuss SIL-IoT security scenarios, and analyze potential attacks. Starting from the security requirements of SIL-IoT we divide them into six categories, namely privacy, authentication, confidentiality, access control, availability,and integrity. Next, we describe the SIL-IoT privacy and security solutions, as well as the blockchain-based solutions. Based on the current survey, we finally discuss the challenges and future research directions of SIL-IoT.

关键词： Challenges Internet of Things(IoT) privacy and security security requirements solar insecticidal lamps(SIL)

Numerical Simulation on Radon Retardation Behavior of Covering Floats in Radon-Containing Water

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Biomedical and Environmental Sciences 2024年第4期37卷 406-417页

作者： liu shu Yuan ZHANG Li YE Yong Jun DING Ku Ke National Institute for Radiological Protection Chinese Center for Disease Control and PreventionBeijing 100088China Office for Public Health Management Chinese Center for Disease Control and PreventionBeijing 102206China Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy University of South ChinaHengyang 421001HunanChina

Objective This study aimed to efficiently reduce the release of radon from water bodies to protect the *** Based on the sizes of the experimental setup and modular float,computational fluid dynamics(CFD)was used to assess the impact of the area coverage rate,immersion depth,diffusion coefficient,and radon transfer velocity at the gas–liquid interface on radon migration and exhalation of radon-containing *** on the numerical simulation results,an estimation model for the radon retardation rate was *** effectiveness of the CFD simulation was evaluated by comparing the experimental and simulated variation values of the radon retardation rate with the coverage area *** The effect of radon transfer velocity on radon retardation in water bodies was minor and insignificant according to the appropriate value;therefore,an estimation model of the radon retardation rate of the coverage of a radon-containing water body was constructed using the synergistic impacts of three factors:area coverage rate,immersion depth,and diffusion *** deviation between the experimental and simulated results was<4.3%.Conclusion Based on the numerical simulation conditions,an estimation model of the radon retardation rate of covering floats in water bodies under the synergistic effect of multiple factors was obtained,which provides a reference for designing covering floats for radon retardation in radoncontaining water.

关键词： Radon-containing water Radon retardation rate CFD Coverage experiment Optimized design

Robust Carbon-Carbon Cleavage in Lignin to Produce Phenol and Cyclohexanone

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Chemical Research in Chinese Universities 2024年第1期40卷 29-35页

作者： WANG Lulin CHENG Xiaomeng DONG Minghua LUAN sen WU Yuxuan HAN Buxing liu Huizhen Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and ThermodynamicsCAS Research/Education Center for Excellence in Molecular SciencesCenter for Carbon Neutral ChemistryInstitute of ChemistryChinese Academy of SciencesBeijing 100190P.R.China University of Chinese Academy of Sciences Beijing 100049P.R.China

The challenge of breaking 5-5'bonds in lignin,attributed to their high bonding energy,has prompted the development of a new transformation ***,an important model compound for lignin,contains these 5-5'bonds,making it crucial to devise a strategy for their cleavage in lignin *** study introduces a novel method for transforming biphenyl,involving selective hydrogenation to cyclohexylbenzene by Ni/SiO2 catalyst,followed by its oxidation to phenol and cyclohexanone through a radical *** demonstrate that the catalysts with small particles have strong catalytic activity,while there is little difference in *** reason for the high selectivity of cyclohexylbenzene is due to the limited adsorption of cyclohexylbenzene on Ni/*** work presents a fresh approach to breaking resilient C-C bonds in lignin.

关键词： Lignin 5-5'Bond Ni/SiO_(2) Phenol

Copper oxide-modified highly reversible Zn powder anode for aqueous Zn metal batteries

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Rare Metals 2024年第10期43卷 5005-5016页

作者： Guan-Qun liu Biao Fu Zhe-Xuan liu Lan-Yan Li shu-Quan Liang Guo-Zhao Fang School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South University School of Science Hunan University of Technology and Business National Energy Metal Resources and New Materials Key Laboratory Central South University

With the advantages of mature preparation technology,structural adjustability and suitability for large-scale application,Zn powder anode is considered to be an ideal electrode for realizing low-cost,high-energy-density aqueous Zn metal ***,the high specific surface of Zn powders leads to severe side reactions such as hydrogen evolution and corrosion,thus limiting their widespread use Here,this work develops a novel CuO@Zn powder anode with a synergy effect of surface wrapping and *** powders are uniformly wrapped by small CuO particles due to the strong adsorption between Zn and *** wrapped CuO particles build a good conductive framework to inhibit the structural collapse of the Zn powder caused by corrosion and non-uniform ***,CuO can also be used as a seed to guide the uniform deposition of Zn ions through its strong binding energy with *** a result,the Cu O@Zn anode can maintain a long cyclic life of 900 h at current density of 1 mA·cm-2and capacity of 1 mAh·cm-2,as well as contribute to an excellent capacity retention of 92%after 800cycles for CuO@Zn||NH4V4O10full *** at high current density of 5 A·g-1,the full cell exhibits a specific capacity of more than 200 mAh·g-1after 800 cycles,with a good capacity retention of 89%.This work provides a new idea for developing high-performance Zn powder-based anodes.

关键词： Aqueous Zn metal batteries Copper oxide Surface wrapping Zn anode Zn powder

CAOSA-extracted lignin improves enzymatic hydrolysis of cellulose

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Green Energy & Environment 2024年第7期9卷 1101-1111页

作者： sen Ma Zheng Li Jonathan Sperry Xing Tang Yong Sun Lu Lin Jian liu Xianhai Zeng College of Energy State Key Laboratory of Physical Chemistry of Solid SurfacesXiamen UniversityXiamen361102China Fujian Engineering and Research Centre of Clean and High-valued Technologies for Biomass Xiamen Key Laboratory of Clean and High-valued Utilization of BiomassXiamen361102China Centre for Green Chemical Science University of AucklandAuckland1142New Zealand

The conversion of biomass into sugar platform compounds is very important for the biorefinery *** is essential to the biomass of the sugar platform,however,the lignin obtained by pretreatment,as a key part of lignocellulose,generally has a passive effect on the enzymatic hydrolysis of cellulose into *** this study,p-TsOH(p-toluenesulfonic acid),DES(Deep eutectic solvent)and CAOSA(cooking with active oxygen and solid alkali)pretreatment ways were used to fraction lignin from bamboo *** CAOSA treatment,the hydrolysis efficiency of the pulp was 95.57%.Moreover,the effect of different treatment methods on lignin properties was studied and the promotion effect of lignin was investigated by adding it to the cellulose enzymatic hydrolysis *** this work,the results showed that CAOSA-extracted lignin with lower D(1.31-1.25)had a better adsorption effect on the enzyme protein.p-TsOH-extracted lignin with a larger S/G ratio enhanced the inhibition of enzymatic *** addition,the presence of-COOHs in lignin could reduce its inhibitory effect on cellulose saccharification.

关键词： Biomass pretreatment CAOSA Cellulose hydrolysis Lignin Enzyme

Footprints of axion-like particle in pulsar timing array data and James Webb Space Telescope observations

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Science China(Physics,Mechanics & Astronomy) 2024年第11期67卷 55-62页

作者： shu-Yuan Guo Maxim Khlopov Xuewen liu Lei Wu Yongcheng Wu Bin Zhu Department of Physics Yantai UniversityYantai 264005 China Institute of Physics Southern Federal UniversityRostov on Don 344090 Russia National Research Nuclear University MEPhI(Moscow Engineering Physics Institute) Moscow 115409 Russia Virtual Institute of Astroparticle Physics Paris 75018 France Department of Physics and Institute of Theoretical Physics Nanjing Normal UniversityNanjing 210023 China

Several pulsar timing array(PTA) collaborations have recently reported the evidence for a stochastic gravitational-wave background(SGWB), which can unveil the formation of primordial seeds of inhomogeneities in the early universe. With the SGWB parameters inferred from PTAs data, we can make a prediction of the seeds for early galaxy formation from the domain walls in the axion-like particles(ALPs) field distribution. This also naturally provides a solution to the observation of high redshifts by the James Webb Space Telescope. The predicted photon coupling of the ALP is within the reach of future experimental searches.

关键词： stochastic gravitational-wave background pulsar timing array axion-like particle JWST

Asymmetric Zn-N_4 atomic sites embedded hollow fibers as stable Zn anode for high-performance Zn-ion hybrid capacitor

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Journal of Energy Chemistry 2024年第10期97卷 460-469,I0009页

作者： Yukun liu Bing Li Jin Wang Caiyun Li Hongrui Yang Yang Song sen Zhang Chao Deng Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of EducationCollege of Physics and Electronic EngineeringHarbin Normal UniversityHarbin 150025HeilongjiangChina College of Material Science and Chemical Engineering Harbin Engineering UniversityHarbin 150001HeilongjiangChina

Zn based electrochemical energy storage systems(EES)have attracted tremendous interests owing to their low cost and high intrinsic ***,the uncontrolled growth of Zn dendrites and the side reactions of Zn metal anodes(ZMAs)severely restrict their *** address these issues,we design the asymmetric Zn-N_(4) atomic sites embedded hollow fibers(AS-IHF)as the flexible host for stable *** introducing different nitrogen resources in the synthesis,two kinds of coordination,i,***-N(pyridinic)and Zn-N(pyrrolic),are introduced in the Zn-N_(4) atomic module *** asymmetric Zn-N_(4) module with regulated micro-environment facilitates the superior zincophilic features and promotes the Zn ***,the highly porous structure of the hollow fiber effectively reduces local current density,homogenize Zn ion flux,and alleviate structure *** the advantages endow the high efficiency and good stability for Zn plating/*** theoretical and experimental results demonstrate the high reversibility,low nucleation overpotential,and dendritefree behavior of the AS-IHF@Zn anode,which afford the high stability in high-rate and long-term ***,the solid-state Zn-ion hybrid capacitor(ZIHC)based on AS-IHF@Zn anode shows the high flexibility,reliability,and superior long-term cycling capability in a wide-range of temperatures(-20-25℃).Therefore,the present work not only gives a new strategy for modulating local environments of single atomic sites,but also propels the development of flexible power sources for diverse electronics.

关键词： Asymmetric coordination Single atomic sites Zincophilic sites Dendrite free behavior Zn-ion hybrid capacitor

Highly Red Emissive Conjugated Homopolymers Based on Double B←N Bridged Bipyridine Unit

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Chinese Journal of Polymer Science 2024年第8期42卷 1029-1037页

作者： Yu-Yue Gao Kai-Yuan Zhang shu-Meng Wang Hui Tong Jun liu State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026China

Conjugated homopolymers based on six-member rings,e.g.,polyfluorene,always exhibit blue emission and conjugated homopolymers based on five-member rings,e.g.,polythiophene,can give red emission with low *** this work,we report a series of new conjugated homopolymers based on six-member rings with high-efficiency deep-red *** repeating units of the red light emitting homopolymers are double B←N bridged bipyridine(BNBP)with the boron atoms functionalized with diphenyl,borafluorene,and 2,7-di-tert-butyl-borafluorene groups,*** relationship between the chemical structures and the opto-electronic properties of the monomers and the homopolymers has been systematically *** three polymers emit pure red light(λ_(max)=656 nm)or deep red light(λ_(max)=693 nm)with fluorescence quantum efficiency in solution higher than 60%.The polymers can be used as the emitters in solution-processed organic light-emitting diodes with red emission and decent device *** work indicates a new strategy to design highly efficient light emitting conjugated polymers.

关键词： Conjugated homopolymers Double B←N bridged bipyridine(BNBP) Deep-red emission High fluorescent efficiency

Prediction for permeability index of blast furnace based on VMD-PSO-BP model

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Journal of Iron and Steel Research International 2024年第3期31卷 573-583页

作者： Xiao-jie liu Yu-jie Zhang Xin Li Zhi-feng Zhang Hong-yang Li Ran liu shu-jun Chen School of Metallurgy and Energy North China University of Science and TechnologyTangshan 063210HebeiChina Chengde Branch HBIS Group Co.Ltd.Chengde 067000HebeiChina

The permeability index is one of the important production indicators to monitor the operation of blast *** is crucial to grasp the trends of changes in the new permeability index in *** the complex vibration spectrum of the permeability index,a prediction model of the permeability index based on the VMD-PSO-BP(variational mode decomposition-particle swarm optimization-back propagation)method was ***,the key factors that affect the permeability index of blast furnace were studied from multiple ***,the permeability index was divided into multiple sub-modes based on the difference of frequency bands by the VMD algorithm,and a PSO-BP prediction model was established for each ***,the prediction results of each sub-mode were summed to obtain the final *** results show that the composite prediction accuracy by using the VMD algorithm is 3%higher than that of the traditional prediction method,which has better applicability.

关键词： Big data-Blast furnace Air permeability Variational mode decomposition Particle swarm optimization Back propagation Model prediction