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SILICA-SUPPORTED NICKEL AND ZIRCONIUM CATALYSTS FOR BRANCHED POLYETHYLENE

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chinese Journal of Polymer Science 2003年第4期21卷 453-458页

作者：孙文华 State Key Laboratory of Engineering Plastics The Center for Molecular sciences institute of {2. chinese academy of sciences beijing 100080 China State Key Laboratory of Engineering Plastics The Center for Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China

8-Aminoquinoline nickel dichloride and bis(cyclopentadienyl)zirconium dichloride (Cp_2.rCl_2. were supportedsimultaneously on silica to produce branched polyethylene successfully by combined polymerization. The supportedpolymerization results showed that the molecular weight of polyethylene increased while the molecular weight distributionbecame wider and the molecular chains of oligomers remaning in the final solution became shorter as compared to theoligomers obtained in polymerization processes with pure 8-aminoquinoline nickel dichloride catalysis, as well as theCp_2.rCl_2.and nickel combination system. With decreasing amount of Ni catalyst in the supported catalyst, the molecular chains of oligomers in the resulting solution became shorter, while α-olefin selectivity increased.

关键词： 8-Aminoquinoline nickel dichloride, Cp_2.rCl_2 Silica supported catalysts Branched polyethylene

Synthesis and Properties of Double Calix[4]arene Derivatives Linked by Schiff-base in the Lower Rim

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chinese Chemical Letters 1999年第7期10卷 539-542页

作者： Hu Shan YUAN Zhi Tang HUANG(institute of chemistry The{2.. beijing 100080) institute of chemistry The Chinese Academy of Sciences

2.,2.-bis-(2.aminoethoxy)-p-tert-butylcalix[4]arene was linked to double calix[4]arene derivatives by the Schiff-base moiety in its lower rim. They behave strong ability to complex with Ph2., Cu2. and Co2..

关键词： 2.,2.-bis-(2.aminoethoxy)-p-tert-butylcalix arenes Schiff-base double calixarene

Formation of Ultrafine Metal Particles and Metal Oxide Precursor on Anodized Al by Electrolysis Deposition

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Journal of Materials Science & Technology 2000年第1期16卷 50-54页

作者： Lingchuan LI (institute of Chemical Metallurgy, chinese academy of sciences,{2., China) institute of Chemical Metallurgy Chinese Academy of Sciences Beijing 100080 China

Nickel was deposited by ac electrolysis deposition in the pores of the porous oxide film of Al produced by anodizing in phosphoric acid. Ultrafine rod-shaped Ni particles were formed in the pores. At the same time a film of Ni oxide precursor was developed on the surface of the porous oxide film. The Ni particles and the Ni oxide precursor were examined by SEM, TEM and X-ray diffraction. The thickness of the barrier layer of the porous oxide film was thin and it attributed to the formation of the metal particles, while the formation of the oxide precursor was associated with the surface pits which were developed in the pretreatment of Al.

关键词： Al Formation of Ultrafine Metal Particles and Metal Oxide Precursor on Anodized Al by Electrolysis Deposition

Explicit analytical solutions of the anisotropic Brinkman model for the natural convection in porous media(Ⅱ)

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Science China(Physics,Mechanics & Astronomy) 2005年第4期48卷 422-430页

作者： CAI Ruixian1, GOU Chenhua1, 2.& ZHANG Na1 1. institute of Engineering Thermophysics, chinese academy of sciences,{2., China 2. Graduate School, chinese academy of sciences,{2., China institute of Engineering Thermophysics Chinese Academy of Sciences Beijing China Graduate School Chinese Academy of Sciences Beijing China

Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.

关键词： explicit analytical solution, porous medium, natural convection, Brinkman model, anisotropic.

N DIMENSIONAL FINITE WAVELET FILTERS

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Journal of Computational Mathematics 2003年第5期21卷 595-602页

作者： Si-long Peng (NADEC, institute of Automation, chinese academy of sciences,{2., China) NADEC Institute of Automation Chinese Academy of Sciences 北京 100080

In this paper, a large class of n dimensional orthogonal and biorthognal wavelet filters (lowpass and highpass) are presented in explicit expression. We also characterize orthogonal filters with linear phase in this c... 详细信息

关键词： n Dimension Linear phase Wavelet filters.

A note on the tree decompositions of graphs

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chinese Science Bulletin 1997年第23期42卷 1948-1952页

作者： shi Minyonginstitute of Software,{2.,{2., China institute of Software Chinese Academy of Sciences Beijing China

IN this note all graphs are undirected, finite and simple. For a subgraph H of G,ε（H） andμ（H） denote the number of edges in H and the number of cycles in H respectively. H[X]denotes the subgraph of H induced by X. Given two disjoint subsets X and Y of V（G）, wewrite EG（X, Y）={xy∈E（G）|x∈X, y∈Y}. Sometimes EG（H, Y）=EG（V（H）,Y） is used for a subgraph H of G-Y. If T is a tree of G and e=uv∈G-E（T）with{u,v}V（T）, then T + e contains a unique cycle, denoted by C（T, e）.A tree-decomposition {T1, T2./sub>, …, Tk} of a graph G is a partition of E （G）, say,E（G）=E1 U E2./sub> U…U Ek, such that for each i with 1≤i≤k, Ti=G[Ei] is a tree.

关键词： tree decomposition singular vertex maximal planar bipartite graph.

Mass Spectrometric Evidence of Heparin Disaccharides for the Catalytic Characterization of A Novel Endolytic Heparinase

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Acta Biochimica et Biophysica Sinica 2004年第12期36卷 840-844页

作者： Yapeng CHAO1,3, Shaoxiang XIONG2. Xiulan CHENG1, and shijun QIAN1* 1institute of Microbiology,{2.,{2., China 2.enter of Mass Spectrometry, institute of chemistry,{2.,{2., China 3Graduate School of the{2., beijing 100039, China institute of Microbiology Chinese Academy of SciencesBeijing 100080 China Graduate School of the chinese academy of sciencesbeijing 100039 China Center of Mass Spectrometry Institute of Chemistry Chinese Academy of SciencesBeijing 100080 China

Heparinase from different sources can eliminate heparin or/and heparan sulfate into various low-molecular weight heparins with different characteristics. Porcine intestinal mucosa heparin was de- graded into a series of oligosaccharides by a novel heparinase from the species Sphingobacterium. Disaccha- ride components from the digests were separated and purified by ultrafiltration and HPLC. Five major peaks appeared as three types according to their retention time. The mass spectrometry of peak I mainly gave the non-sulfated disaccharide with the mass of 379 Da. Peak II and III were indicated as two major monosulfated disaccharides with molecular mass of 417 and 459 Da respectively. Moreover, the peak III represented an N- acetyl disaccharide. Both peak IV and V showed the same mass of 496 Da, hinting that they were disulfate- substituted disaccharides. No trisulfate-substituted disaccharides were detected in the mixture of the heparin digest though they were abundant in the heparin structure. The results revealed that the heparinase might specifically cut the sites with low sulfated domain in heparin.

关键词： electrospray ionization-mass spectrometry heparin disaccharides heparinase high perfor- mance liquid chromatography Sphingobacterium sp.

PROBABILISTIC NUMERICAL APPROACH FOR PDE AND ITS APPLICATION IN THE VALUATION OF EUROPEAN OPTIONS

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Journal of Computational Mathematics 2001年第6期19卷 591-600页

作者： Dong-sheng Wu (institute of Systems Science, academy of Mathematics and Systems {2., chinese academy of sciences, beijing 100080, China ) 中科院系统科学所北京 100080

Presents a probabilistic numerical approach for a class of probabilistic differential equation. Application of the Brownian motion and Monte-Carlo method; Application in the valuation of European Options.

关键词： Brownian motion probabilistic numerical solution European Options

Study on the atmospheric photochemical reaction of CF_3 radicals using ultraviolet photoelectron and photoionization mass spectrometer

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Science China chemistry 2008年第4期51卷 316-321页

作者： YAO Li1,2. DU Lin1,2. YIN shi1,2.& GE MaoFa1 1 beijing National Laboratory for Molecular {2. (BNLMS), State Key Laboratory for Structural {2. of Unstable and Stable Species, institute of {2., chinese academy of sciences, beijing 100080, China 2.Graduate University of chinese academy of sciences, beijing 100080, China beijing National Laboratory for Molecular sciences (BNLMS) State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing China Graduate University of chinese academy of sciences Beijing China

A study of the atmospheric photochemical reaction of CF3 radical with CO and O2.was performed by using a homemade ultraviolet photoelectron spectrometer-photoionization mass spectrometer (PES- PIMS). The electronic structures and mechanism of ionization and dissociation of CF3OC(O)OOC(O)- OCF3 were investigated. It was indicated that the two bands on the photoelectron spectrum of CF3OC(O)OOC(O)OCF3 are the result of ionization of an electron from a lone pair of oxygen and a fluo- rine lone pair of CF3 group. The outermost electrons reside in the oxygen lone pair. The experimental and theoretical first vertical ionization energy is 13.2. and 13.178 eV, respectively, with the PES and OVGF method. They are in good agreement. The photo ionization and dissociation processes were discussed with the help of theoretical calculations and PES-PIMS experiment. After ionization, the parent ions prefer the dissociation of the C-O bond and giving the fragments CF3OCO+ and CF3+. It demonstrated that the ultraviolet photoelectron and photoionization mass spectrometer could be ap- plied widely in the study of atmospheric photochemical reaction.

关键词： photochemical reaction CF3 radical ultraviolet photoelectron and photoionization mass spectroscopy transient species