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Distinct microstructure and property evolution of 0.76(Bi_(0.5)Na_(0.5))TiO_(3)-0.24SrTiO_(3) ferroelectric ceramics synthesized with different TiO_(2) reactants

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Journal of Materials Science & Technology 2023年第20期151卷 73-79页

作者： Jian Guo Ji zhang Jing Wang shan-tao zhang National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences&Jiangsu Key Laboratory of Artificial Functional Materials&Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093China School of Materials Science and Engineering Nanjing University of Science&TechnologyNanjing 210094China State Key Laboratory of Mechanics and Control of Mechanical Structures College of Aerospace EngineeringNanjing University of Aeronautics and AstronauticsNanjing 210016China

Single phase 0.76(Bi_(0.5)Na_(0.5))TiO_(3)–0.24SrTiO_(3) ferroelectric ceramics have been synthesized with homogenous anatase and hierarchical rutile TiO_(2) raw reactants(BNST-A and BNST-R).Either calcined powder persists the microstructure characteristics of raw *** the result,when the sintering temperature increases from 1000 to 1200℃,the average grain size and density of BNST-A increase from 0.49 to 1.48μm and 5.02 to 5.61 g/cm^(3),while those of BNST-R from 0.86 to 1.44μm and 5.37 to 5.61 g/cm^(3).BNST-A illustrates a predominant ergodic relaxor state,and BNST-R prefers a non-ergodic relaxor state,as evidenced by the distinct polarization-electric field loops and current-electric field ***,such a distinct ferroelectric state is independent of sintering *** is believed that the special hierarchical microstructure of rutile TiO_(2) reactant is beneficial to form denser ceramics with larger grains,and thus suppresses the contributions of polar nanoregions and defect-induced built-in field to ferroelectric property,leading to non-ergodic relaxor *** work clearly demonstrates the nonnegligible effects of TiO_(2) reactants on the microstructure and properties of BNST ferroelectric ceramics.

关键词： BNST ferroelectric ceramics TiO_(2)raw reactants Microstructure and property evolution

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Excellent energy storage properties in non-stoichiometric Bi_(0.5)Na_(0.5)TiO_(3)-based relaxor ferroelectric ceramics

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Chinese Chemical Letters 2024年第7期35卷 470-472页

作者： Shunshun Jiang Ji zhang Jing Wang shan-tao zhang School of Materials Science and Engineering Nanjing University of Science&TechnologyNanjing 210094China State Key Laboratory of Mechanics and Control of Mechanical Structures College of Aerospace EngineeringNanjing University of Aeronautics and AstronauticsNanjing 210016China National Laboratory of Solid State Microstructures Department of Materials Science and EngineeringCollege of Engineering and Applied Science&Jiangsu Key Laboratory of Artificial Functional Materials&Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093China

The rapid development of high-power and pulsed-power techniques inspires extensive investigates on high-performance ceramic-based ***,the low recoverable energy density(Wrec)hampers their wider ***,the non-stoichiometric Bi_(0.5)Na_(0.5)TiO_(3)-based ceramics were designed and *** proper introduction of oxygen vacancies facilitated activating defect dipole,giving rise to reduced remanent ***,the optimal composition exhibited an exceptional high Wrec of 8.3 J/cm^(3),a high efficiency of 85%,and excellent anti-fatigue and thermal *** work provides an efficient approach to explore ceramic capacitors with high capacitive energy storage performances.

关键词： Non-stoichiometric Bi_(0.5)Na_(0.5)TiO_(3) Ceramic capacitor Energy density Thermal stability

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Different effect of Li^(+),Na^(+),K^(+)-doping on crystal structure and electrical property of Sr_(0.6)Ba_(0.4)Nb_(2)O_(6)

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Journal of Materiomics 2024年第5期10卷 1071-1079页

作者： Jian Guo Xinrui Yang Yulong Yang Shuting Pang shan-tao zhang Bin Yang National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences&Jiangsu Key Laboratory of Artificial Functional Materials&Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing210023China Nanjing University(Suzhou)High-tech Institute Suzhou Industrial Park215123China School of Physics Nanjing UniversityNanjing210093China Functional Materials and Acousto-Optic Instruments Institute School of Instrumentation Science and EngineeringHarbin Institute of TechnologyHarbin150080China

Ferroelectric Sr_(0.6)Ba_(0.4)Nb_(2)O_(6)(SBN)shows typical unfilled tetragonal tungsten bronze structure where 1/6 A sites and all C sites are *** presence of such structural vacancy provides the possibility to further modulate the crystal structure and electrical *** this work,alkali ions(Li^(+),Na^(+),K^(+))doped SBN ceramics have been fabricated via solid-solution reaction *** general,each doping promotes the crystal structure evolves from unfilled toward filled tungsten ***,the different doping ion radius causes the differences in occupying initial structural vacancies,resulting in significantly different electrical properties,Li^(+)doping enhances relaxor characteristic whereas Na+and K^(+)doping lead to normal ferroelectric behavior,accompanying an increase in Curie temperature(TC)from 36℃ of SBN to 40,212,148℃ of Li^(+),Na^(+)and K^(+)doping,*** from improved relaxor degree and high density,the Li^(+)doped SBN displays a good energy storage *** the ratio of Sr/Ba and(Sr+Ba)/Nb has not been changed,this work presents direct evidence for the effect of structural vacancy on crystal structure and properties,as well as inspiration for further work on unfilled tungsten bronze.

关键词： Sr_(0.6)Ba_(0.4)Nb_(2)O_(6) oxides Structural vacant Alkali ions doping

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Enhanced unipolar electrical fatigue resistance and related mechanism in grain-oriented Pb(Mg_(1/3)Nb_(2/3))O_(3)-Pb(Zr,Ti)O_(3)piezoceramics

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Journal of Materials Science & Technology 2023年第14期145卷 40-47页

作者： Linjing Liu Bin Yang Rui Lv Qiangwei Kou Shuai Yang Hang Xie Yuan Sun Yunfei Chang shan-tao zhang Fei Li Functional Materials and Acousto-Optic Instruments Institute School of Instrumentation Science and EngineeringHarbin Institute of TechnologyHarbin 150080China Electronic Materials Research Laboratory(Key Lab of Education Ministry) State Key Laboratory for Mechanical Behavior of Materials and School of Electronic Science and EngineeringXi’an Jiaotong UniversityXi’an 710049China National Laboratory of Solid State Microstructures and College of Engineering and Applied Science Nanjing UniversityNanjing 210093China

Piezoceramics with high and fatigue-resisted piezoelectric properties are strongly desired for actuator *** this work,textured Pb(Mg_(1/3)Nb_(2/3))O_(3)-Pb(Zr,Ti)O_(3)ceramics with Lotgering factor F_(001)∼98%were fabricated by templated grain growth ***[001]c-grain orientation(f∼90%and r∼0.22)of the textured ceramics effectively produced about 230%enhanced piezoelectric coefficient d_(33)^(∗)(i.e.,S_(max)/E_(max))and substantially improved unipolar electrical fatigue *** polarization P max and d_(33)^(∗)of the textured ceramics were nearly maintained up to 106 unipolar cycles,while 19%and 14%degradations were respectively observed from randomly oriented ***,normal-ized d_(33)^(∗)of the textured ceramics shows better unipolar fatigue resistance than those of piezoceramics reported *** lower bipolar strain asymmetryγs(∼4%)was observed from the textured samples fatigued after 106 unipolar cycles as compared toγs∼23%for randomly oriented *** charged defect accumulation model described the serious fatigue deteriorations in randomly ori-ented ceramics,the current work revealed that substantially enhanced unipolar fatigue resistance of the textured ceramics is mainly associated with the inherent fatigue anisotropy,weakened local bias fields owing to both enhanced domain mobility and lower defect density near grain boundaries/interfaces,and increased intrinsic contribution due to more tetragonal *** superior characteristics suggest the great potential of textured ceramics for high-performance and robust actuator applications.

关键词： Ceramics Grain orientation Piezoelectric strain Unipolar fatigue Defect accumulation

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Novel lead-free NaNbO_(3) -based relaxor antiferroelectric ceramics with ultrahigh energy storage density and high efficiency

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Journal of Materiomics 2022年第2期8卷 295-301页

作者： Jie Jiang Xiongjie Li Ling Li Shun Guo Ji zhang Jing Wang Heguo Zhu Yiping Wang shan-tao zhang School of Materials Science and Engineering Nanjing University of Science and TechnologyNanjing210094China State Key Laboratory of Mechanics and Control of Mechanical Structures College of Aerospace EngineeringNanjing University of Aeronautics and AstronauticsNanjing 210016China National Laboratory of Solid State Microstructures Department of Materials Science and EngineeringCollege of Engineering and Applied Science&Jiangsu Key Laboratory of Artificial Functional Materials&Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093China

The development of environmentally friendly ceramics for electrostatic energy storage has drawn growing interest due to the wide application in high power and/or pulsed power electronic ***,it is difficult to simultaneously achieve ultrahigh recoverable energy storage density(W rec>8 J/cm^(3))and high efficiency(η>80%),which restricts their application in the miniaturized,light weight and easy integrated electronic ***,the novel NaNbO_(3)-(Bi_(0.8)Sr_(0.2))(Fe_(0.9) Nb_(0.1))O_(3) relaxor antiferro-electric ceramics,which integrates the merits of antiferroelectrics and relaxors,are demonstrated to exhibit stabilized antiferroelectric phase and enhanced dielectric relaxor *** particular impor-tance is that the 0.88NN-0.12BSFN ceramic achieves giant electric breakdown strength E_(b)=98.3 kV/mm,ultrahigh W _(rec)=16.5 J/cm^(3) and high h=83.3%,as well as excellent frequency,cycling and thermal reliability *** comprehensive energy storage performance of NN-BSFN not only out-performs state-of-the-art dielectric ceramics by comparison,but also displays outstanding potential for next-generation energy storage capacitors.

关键词： Lead-free NaNbO_(3) Relaxor antiferroelectric Energy storage property

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Low-temperature sintered(Na_(1/2)Bi_(1/2))TiO_(3)-based incipient piezoceramics for co-fired multilayer actuator application

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Journal of Materiomics 2019年第3期5卷 480-488页

作者： Pengyuan Fan Yangyang zhang shan-tao zhang Bing Xie Yiwei Zhu Mohsin Ali Marwat Weigang Ma Kai Liu Liang Shu Haibo zhang School of Materials Science andEngineering State Key Laboratory of Material ProcessingDie&Mould TechnologyHuazhong University of Science and TechnologyWuhan430074China Information Engineering Institute Huanghe Science and Technology CollegeZhengzhou450000China National Laboratory of Solid State Microstructures Department of Materials Science and EngineeringCollege of Engineering and Applied ScienceCollaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing210093China Research Centre for Functional Ceramics Ministry of EducationHuazhong University of Science and TechnologyWuhan430074China

Low-temperature sintered(Na_(1/2)Bi_(1/2))_(0.935)Ba_(0.065)Ti_(0.975)(Fe_(1/2)Nb_(1/2))_(0.025)O_(3)(NBT-BT-0.025FN)lead-free incipient piezoceramics were investigated using high-purity Li_(2)CO_(3) as sintering *** the ≤0.5 wt%Li_(2)CO_(3) addition,the introduced Li^(+) cations precede to enter the A-sites of the perovskite lattice to compensate for the A-site *** the addition exceeds 0.5 wt%,the excess Lit cations will occupy B-sites and give rise to the generation of oxygen vacancies,which accelerate the mass transport and thus lower the sintering temperature effectively from 1100℃ down to 925℃.It was also found that a small amount of Lit addition has little effect on the phase structure and electromechanical properties of the system,but overweight seriously disturbs these characteristics because of the large lattice *** sintered NBT-BT-0.025FN incipient piezoceramics with 1.25 wt%Li_(2)CO_(3) addition at 925℃ provides a large strain of 0.33% and a corresponding large signal piezoelectric coefficient d_(33)^(*) of 550 pm/V at 60 kV/cm,indicating this system is a very promising candidate for lead-free co-fired multilayer actuator application.

关键词： Lead-free piezoceramics (Na_(1/2)Bi_(1/2))TiO_(3) Low-temperature sintering Electric-field-induced strain

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Progress and perspective of high strain NBT-based lead-free piezoceramics and multilayer actuators

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Journal of Materiomics 2021年第3期7卷 508-544页

作者： Pengyuan Fan Kai Liu Weigang Ma Hua Tan Qi zhang Ling zhang Changrong Zhou David Salamon shan-tao zhang Yangjun zhang Bo Nan Haibo zhang School of Materials Science and Engineering State Key Laboratory of Material Processing and Die&Mould TechnologyHuazhong University of Science and TechnologyWuhan430074PR China School of Materials Science and Engineering University of New South WalesSydney2052Australia School of Mechanical and Electrical Engineering Shihezi UniversityShiheziChina College of Materials Science and Engineering Guilin University of Electronic TechnologyGuilin541004PR China Central European Institute of Technology(CEITEC)Brno University of Technology Czech Republic National Laboratory of Solid State Microstructures Department of Materials Science and EngineeringCollege of Engineering and Applied ScienceCollaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing210093China State Key Laboratory of Automotive Safety and Energy School of Vehicle and MobilityTsinghua UniversityBeijing100084PR China Guangdong HUST Industrial Technology Research Institute Dongguan523808PR China

In this review,the evolution of high strain Na_(0.5)Bi_(0.5)TiO_(3)-based lead-free piezoceramics and their multilayer actuators has been ***,in terms of Na_(0.5)Bi_(0.5)TiO_(3)-based ceramic materials,the origin of high strain,the typical chemical modification methods of obtaining large strain and extrinsic factors affecting the large strain are *** it briefly summarizes the problems existing in Na_(0.5)Bi_(0.5)TiO_(3)-based ceramics for multilayer actuator *** to optimize strain performance by means of microstructure control and phase structure design are also ***,in terms of multilayer actuator,we describe its characteristics,applications and preparation process systematically,as well as the recent development of Na_(0.5)Bi_(0.5)TiO_(3)-based multilayer *** last,perspectives on directions of following work and promising fields for the applications of the materials and their devices are presented.

关键词： Lead-free piezoceramics Bismuth sodium titanate Electric-field-induced strain Multilayer actuators

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Semiconductor/relaxor 0-3 type composites without thermal depolarization in Bi0.5Na0.5TiO3-based lead-free piezoceramics

Semiconductor/relaxor 0-3 type composites without thermal de...

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第十七届全国晶体生长与材料学术会议(CCCG-17)

作者： shan tao zhang National Laboratory of Solid State Microstructures and Department of Materials Science and Engineering College of Engineering and Applied Science&Collaborative Innovation Center of Advanced MicrostructuresNanjing University

Commercial lead-based piezoelectric materials raised world-wide environmental concerns in the past ***

关键词： Bi0.5Na0.5TiO3 thermal depolarization composite

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omposition-sensitive electrical properties of charge nonstoichiometric 0.94Bi_(0.5+x)Na_(0.5-x)TiO_(3)–0.06BaTiO_(3)ceramics

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Journal of Advanced Dielectrics 2019年第5期9卷 28-34页

作者： Ji zhang Rui-Xue Wang Ling Li Lei Sun Zheng-Bin Gu Haibo zhang shan-tao zhang National Laboratory of Solid State Microstructures Department of Materials Science and Engineering College of Engineering and Applied Science&Jiangsu Key Laboratory of Artificial Functional Materials&Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing 210093 P.R.China College of Materials Science and Engineering State Key Laboratory of Material Processing and Die&Mould Technology Huazhong University of Science and Technology Wuhan 430074 P.R.China

Charge nonstoichiometric 0.94Bi_(0.5+x)Na_(0.5-x)TiO_(3)-0.06BaTiO_(3)(BNT-BT)(x=-0.02,-0.01,0,0.01,0.02)ceramics were pre-pared and *** depolarization temperature was dependent on composition and the ferroelectric property of x>0 was suppressed more significantly than the x<0,indicating the composition-sensitive electrical ***,the x=-0.02 was close to the insulator/conductor composition boundary while the x=0.02 was close to the ferroelectrics/relaxor *** results were attributed to the complex effect of donor doping and acceptor doping on depolarization *** work provides robust clues to tune and/or design electrical property and conductivity of Bi_(0.5)Na_(0.5)TiO_(3)-based materials.

关键词： Nonstoichiometry BNT-BT composition-sensitive electrical properties

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Synergistically enhanced ORR and HER performance on Co-N-C coupled in-situ generated PtCo intermetallic

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Journal of Energy Chemistry 2025年第1期100卷 721-729页

作者： Guanyu Luo Min Song Lulu An Xiao Huang Qian zhang Chenhao zhang tao Shen Shuang Wang Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology) Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology

Integrating multi-scale sites in a composite catalyst is vital to realize efficient ***,a synergistic composite catalyst consisting of Co atomic sites and in-situ generated PtCo intermetallic compounds （IMCs）(o-PtCo@CoNC) is proposed through Co pre-anchoring and subsequent impregnation-reduction *** loading of Co atoms provides a chance for in-situ generating PtCo ordered intermetallic *** remaining Co single atoms and PtCo IMCs construct synergistic electrocatalytic *** from the ordered structure,synergistic effect of Pt Co IMCs and Co single atoms,o-PtCo@CoNC exhibits excellent electrocatalytic performance for oxygen reduction reaction （ORR） and hydrogen evolution reaction （HER） with mass activity of 1.21 A mgPt-1（at 0.9 V） and5.70 A mgPt-1（at an overpotential of 100 mV）,***,o-PtCo@CoNC delivers negligible loss of half-wave potential and overpotential during long-term stability test in acid solutions,with 13 mV decay after 50,000 potential cycles for ORR and a 2.7 mV decay after 20,000 potential cycles for *** integration strategy of single-atomic sites coupled IMCs paves the way for enhancing the activity and durability of Pt-based electrocatalysts.

关键词： Synergistic effect Intermetallics Single atomic sites Oxygen reduction reaction Hydrogen evolution reaction

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