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Synthesis,characterization and application of BiVO_4 photoanode for photoelectrochemical oxidation of chlorate

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Chinese Journal of Catalysis 2017年第4期38卷 710-716页

作者： seyed Ghorban Hosseini Saeid Safshekan Department of Chemistry Malek Ashtar University of Technology P. O. Box 16765‐3454 Tehran Iran Electroanalytical Chemistry Research Laboratory Faculty of Chemistry University of Mazandaran Babolsar Iran

A high‐quality polycrystalline bismuth vanadate(BiVO4)film was prepared on a fluorine‐doped tinoxide substrate via a facile two‐step strategy involving electrodeposition and annealing *** morphology and structural characterization of the resulting film were investigated by differentmethods including scanning electron microscopy,transmission electron microscopy,X‐ray diffraction(XRD),and Fourier transform infrared,ultraviolet‐visible(UV‐vis)absorption,and *** patterns as well as optical measurements revealed that BiVO4film crystallizedwith a pure monoclinic scheelite *** prepared BiVO4film was used for heterogeneousoxidation of chlorate ions in aqueous solution via electrochemical(EC),photochemical(PC),andphotoelectrochemical(PEC)*** decrease in concentration of chlorate was monitoredusing UV‐vis absorption *** results revealed that BiVO4could effectively performchlorate oxidation under light irradiation through a PEC *** kinetics of chlorate oxidationwas consistent with a first‐order reaction,and the rate constant for the PEC process was found to bemuch higher than those of EC and ***,a possible photocatalytic oxidation mechanismfor chlorate mainly based on the formation of perchlorate ions is proposed.

关键词： Bismuth vanadate Photocatalysis Electron‐hole pair Chlorate oxidation Photochemical reaction

Assessment of fracture process in forta and polypropylene fiber-reinforced concrete using experimental analysis and digital image correlation

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Frontiers of Structural and Civil Engineering 2022年第12期16卷 1633-1652页

作者： seyed Hamid KALALI Hamid ESKANDARI-NADDAF seyed Ali EMAMIAN Department of Civil Engineering Hakim Sabzevari UniversitySabzevar ***Iran

This paper aims to characterize the evolution of the fracture process and the cracking behavior in fortaferro(FF)and polypropylene(PP)fiber-reinforced concrete under the uniaxial compressive loading using experimental analysis and digital image correlation(DIC)on the surface *** this purpose,6 mix designs,including two FF volume fractions of 0.10%,and 0.20%and three PP volume fractions of 0.20%,0.30%,and 0.40%,in addition to a control mix were evaluated according to compressive strength,modulus of elasticity,toughness index,and stress–strain *** influence of fibers on the microstructural texture of specimens was analyzed by scanning electron microscope(SEM)*** show that FF fiber-reinforced concrete specimens demonstrated increased ductility and strength compared to PP *** results revealed that the major crack and fracture appeared at the peak load of the control specimen due to brittleness and sudden gain of large lateral strain,while a gradual increase in micro-crack quantity at 75%of peak load was observed in the fiber specimens,which thenbegan to connect with each other up to the final *** accuracy of the results supports DIC as a reliable alternative for the characterization of the fracture process in fiber-reinforced concrete.

关键词： fiber-reinforced concrete forta-ferro and polypropylene fiber fracture process cracking behavior digital image correlation

Effects of reinforced nanofluid with nanoparticles on cutting tool wear morphology

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Journal of Central South University 2019年第5期26卷 1050-1064页

作者： seyed Hasan MUSAVI Behnam DAVOODI seyed Ali NIKNAM School of Mechanical Engineering Iran University of Science and Technology

Superalloys are grouped as hard-to-cut materials with relatively poor *** wear is considered one of the main machinability attributes in machining *** numerous works have been reported on factors governing tool life in machining superalloys,no study was found on the effect of nanoparticles stability on nanofluid performance and consequently resulted tool wear *** the present work,the nanoparticles were reinforced by means of improving the stability of the base *** that accomplished,the surface active agent (surfactant) was added to the base cutting fluid as a reinforcing *** effects of new lubricant on the tool wear morphology of A286 works parts were assessed.

关键词： nanofluid surface active agent (surfactant) nanoparticles dispersion built-up edge

Large-scale seismic isolation through regulated liquefaction： a feasibility study

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Earthquake Engineering and Engineering Vibration 2016年第4期15卷 579-595页

作者： seyed Amin Mousavi Morteza Bastami seyed Mehdi Zahrai School of Civil Engineering College of Engineering University of Tehran Tehran Iran International Institute of Earthquake Engineering and Seismology TehranIran Center of Excellence for Engineering and Management of Civil Infrastructures School of Civil Engineering Faculty of EngineeringUniversity of Tehran Tehran Ivan

Using controlled liquefaction, a seismic isolation technique is introduced by which a large area with dozens of structures can be seismically isolated. The proposed Large Scale Seismic Isolation （LSSI） is in many ways similar to conventional base isolations. The required bearing is provided by a fully undrained pre-saturated liquefiable layer which has substantial vertical stiffness/capacity and minimal lateral stiffness. Moreover, required energy dissipation would be provided through material damping and Biot flow-induced damping within the liquefied layer. LSSI consists of a thick non- liquefiable crust layer and an underlying engineered pre-saturated liquefiable layer bounded by two impermeable thin clay layers. The liquefiable layer should be designed to trigger liquefaction as soon as possible within the early seconds of a design level seismic event. Adopting the energy-based GMP liquefaction theory, optimum gradation of the liquefiable layer is also investigated. It tumed out that LSSI would effectively reduce acceleration response spectrum within short to medium periods. Contribution of the proposed LSSI is more pronounced in the case of stronger ground motions such as near field events as well as ground motions with longer return periods.

关键词： liquefaction seismic isolation effective stress analysis ground response analysis passive control

Correlation of the mean activity coefficient of aqueous electrolyte solutions using an equation of state

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Chinese Journal of Chemical Engineering 2016年第10期24卷 1456-1463页

作者： seyed Hossein Mazloumi Chemical Engineering Department Faculty of EngineeringFerdowsi University of Mashhad

Accurate calculation of thermodynamic properties of electrolyte solution is essential in the design and optimization of many processes in chemical industries. A new electrolyte equation of state is developed for aqueous electrolyte solutions. The Carnahan-Starling repulsive model and an attractive term based on square-well potential are adopted to represent the short range interaction of ionic and molecular species in the new electrolyte EOS. The long range interaction of ionic species is expressed by a simplified version of Mean Spherical Approximation theory （MSA）. The new equation of state also contains a Born term for charging free energy of ions. Three adjustable parameters of new eEOS per each electrolyte solution are size parameter, square-well potential depth and square-well potential interaction range. The new eEOS is applied for correlation of mean activity coefficient and prediction of osmotic coefficient of various strong aqueous electrolyte solutions at 25℃ and 0.1 MPa. In addition, the extension of the new eEOS for correlation of mean activity coefficient and solution density of a few aqueous electrolytes at temperature range of 0 to 100℃ is carried out.

关键词： Aqueous electrolyte solution Electrolyte equation of state Activity coefficient Osmotic coefficient Solution density

Vanadium oxide nanotubes for selective catalytic reduction of NO_x with NH_3

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Chinese Journal of Chemical Engineering 2016年第7期24卷 914-919页

作者： seyed Mahdi Mousavi Faculty of Chemistry University of Kashan

Vanadium oxide （VOx） nanostructures, synthesized by hydrothermal treatment using dodecylamine as template, were evaluated for the selective catalytic reduction of NOx with ammonia （NH3-SCR）, The effect of solvent type in the reaction mixture （EtOH/（EtOH ＋ H20）） and time of hydrolysis was studied. The obtained materials were characterized by XRD, SEM, TEM and BET, The VOx nanorods （80-120 nm diameter and 1-4 μm length） were synthesized in 25 vol% EtOH/（EtOH ＋ H20） and the open-ended multiwalled VOx nanotube （50-100 nm inner diameter, 110-180 nm outer diameter and 0,5-2 pm length） synthesized in 50 vol% EtOH/（EtOH ＋ H20）. VOx nanotuhes performed the superior NH3-SCR activity under a gas hourly space velocity of 12,000 h-1 at low temperature of 250 ~C （NOx conversion of 893g ＆ N2 selectivity of 100%）, while most of the developed Vanadia base catalysts are active at high temperature （〉350 ℃）. The superior NH3-SCR activity ofVOx nanotubes at low tem- perature is related to nanocrystalline structure, special nanotube morphology as well as high specific surface area.

关键词： Hydrothermal Nanotubes NOx Pollution SCR

Creep rupture assessment for Level-2 PSA of a 2-loop PWR： accounting for phenomenological uncertainties

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Nuclear Science and Techniques 2017年第8期28卷 117-125页

作者： Faramarz Yousefpour seyed Mohsen Hoseyni seyed Mojtaba Hoseyni seyed Ali Hashemi Olia Kaveh Karimi Nuclear Science and Technology Research Institute TehranIran Young Researchers and Elite Club East Tehran BranchIslamic Azad University Tehran Iran

The Level-2 probabilistic safety assessment(PSA) of pressurized water reactors studies the possibility of creep rupture for major reactor coolant system components during the course of high pressure severe accident sequences. The present paper covers this technical issue and tries to quantify its associated phenomenological uncertainties for the development of Level-2 PSA. A framework is proposed for the formal quantification of uncertainties in the Level-2 PSA model of a PWR type nuclear power plant using an integrated deterministic and PSA approach. This is demonstrated for estimation of creep rupture failure probability in station blackout severe accident of a 2-loop PWR, which is the representative case for high pressure sequences. MELCOR 1.8.6 code is employed here as the deterministic tool for the assessment of physical phenomena in the course of accident. In addition, a MATLAB code is developed for quantification of the probabilistic part by treating the uncertainties through separation of aleatory and epistemic sources of *** probability for steam generator tube creep rupture is estimated at 0.17.

关键词：模型不确定性蠕变断裂 PSA 压水堆断裂评价二级现象学反应堆冷却剂系统

Application of computational fluid dynamics in design of viscous dampers-CFD modeling and full-scale dynamic testing

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Earthquake Engineering and Engineering Vibration 2023年第4期22卷 1065-1080页

作者： Hassan Lak seyed Mehdi Zahrai seyed Mohammad Mirhosseini Ehsanollah Zeighami Department of Civil Engineering Collage of EngineeringArak BranchIslamic Azad UniversityArak ***Iran School of Civil Engineering College of EngineeringUniversity of TehranTehran ***Iran

Computational fluid dynamics(CFD)provides a powerful tool for investigating complicated fluid *** paper aims to study the applicability of CFD in the preliminary design of linear and nonlinear fluid viscous *** fluid viscous dampers were designed based on CFD *** first device was a linear viscous damper with straight *** second was a nonlinear viscous damper containing a one-way pressure-responsive valve inside its *** dampers were detailed based on CFD simulations,and their internal fluid flows were ***-scale specimens of both dampers were manufactured and tested under dynamic *** to the tests results,both dampers demonstrate stable cyclic behaviors,and as expected,the nonlinear damper generally tends to dissipate more energy compared to its linear *** compatibility was achieved between the experimentally measured damper force-velocity curves and those estimated from CFD *** a thermography camera,a rise in temperature of the dampers was measured during the *** was found that output force of the manufactured devices was virtually independent of temperature even during long duration ***,temperature dependence can be ignored in CFD models,because a reliable temperature compensator mechanism was used(or intended to be used)by the damper manufacturer.

关键词： fluid viscous damper passive control dynamic testing energy dissipation device computational fluid dynamic thermography

Computational analysis of neutronic effects of ThO_2 rods loaded in CANDU 6 fuel assemblies

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Nuclear Science and Techniques 2016年第4期27卷 14-20页

作者： seyed Mohammad Mirvakili Zohreh Gholamzadeh seyed Amir Hossein Feghhi Reactor Research School Nuclear Science and Technology Research Institute Department of Radiation Application Shahid Beheshti UniversityG.C

Thorium as a suitable fertile with higher natural resources in comparison with uranium resources has been remarkably considered by different nuclear energy user countries in the last decades. Its prominent features such as suitable possibility for power flattening of a nuclear reactor, applicable breeder blanket to produce^(233)U fissile as well as neutron leakage prevention from a nuclear core has caused its application as power flatter, breeder material or other aimed utilizations be evaluated by the researches. In the present study, neutronics of a modeled CANDU 6loaded with Th O_2 and UO_2fuel rods have been computationally studied. The study aimed at reprocessing of burned Th O_2 seeds at CANDU 6 reactor to recover the total produced uranium, which is to be going under another compound fuel cycle. The obtained results showed all the core reactivity coefficients are sufficiently negative. The modeled core 949 GWd burn-up concluding in 99.99 %depletion of^(235)U initial loads. 18.38 kg of^(233) U was produced in the burnt Th O_2 fuel after 1-year burn-up time. In addition, 31.84 kg of^(239) Pu was produced in the UO_2 spent fuel rods after the burn-up time. After a proposed cooling time, about 50.01 kg of^(233)U will be available in the spent Th O_2 fuel.

关键词： CANDU堆中子泄漏燃料组件稳定杆计算核反应堆燃烧时间自然资源