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Journal of Energy Chemistry 2018年第2期27卷 528-534页

作者： Parveen Sood Ki Chul Kim seung soon jang School of Materials Science and Engineering Georgia Institute of Technology Atlanta CA 30332-0245. USA Department of Chemical Engineering Konkuk University Seoul 05029 Republic of Korea Institute for Electronics and Nonotechnology Georgia Institute of Technology Atlanta GA 30332-0245 USA Parker H. Petit Institute for Bioengineering and Bioscience Georgia Institute of Technology Atlanta GA 30332-0245 USA

We have studied the redox potentials and electronic properties of C60 and C59N using density functional theory method. It is found that doping C60 with one nitrogen atom results in a slight increase in redox potential. Next, we have also studied C59N functionalized with various redox-active oxygen containing functional groups and strongly electron withdrawing functional groups. It is found that the intrinsic electronic structure of the molecule is the major determinant of the redox potential. Our DFT calculations show that the electron affinity to redox potential of functionalized C59N is correlated with the LUMO of the systems very well. This is the first systematic study on the redox properties and electronic structures of N-doped C60 systems.

关键词： DFT Redox potential C60 Doping Li-ion battery

Covalent organic frameworks:Design and applications in electrochemical energy storage devices

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InfoMat 2022年第6期4卷 1-35页

作者： Shikai Jin Omar Allam seung soon jang seung Woo Lee George W.Woodruff School of Mechanical Engineering Georgia Institute of TechnologyAtlantaGeorgiaUSA Computational NanoBio Technology Laboratory School of Material Science and EngineeringGeorgia Institute of TechnologyAtlantaGeorgiaUSA

As an emerging class of crystalline organic material,covalent organic frameworks(COFs)possess uniform porosity,versatile functionality,and precise control over designated *** from the favorable charge and mass transport pathways offered by the porous framework,COFs can also exhibit designed reversible redox *** the past few years,their potential has attracted a great deal of attention for charge storage and transport applications in various electrochemical energy storage devices,and numerous design strategies have been proposed to enhance the corresponding electrochemical *** review summarizes the working principle and synthesis methods of COFs and discusses significant findings for supercapacitors and various rechargeable battery systems,emphasizing the representative design strategies and their underlying relationship with electrochemical *** addition,key advances achieved by computations are highlighted along with the challenges and prospects in this field.

关键词： covalent organic frameworks rechargeable batteries redox-active electrodes solid electrolyte supercapacitors

Dual-light emitting 3D encryption with printable fluorescent-phosphorescent metal-organic frameworks

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Light(Science & Applications) 2023年第10期12卷 2172-2186页

作者： Jin Woo Oh Seokyeong Lee Hyowon Han Omar Allam Ji Il Choi Hyeokjung Lee Wei Jiang Jihye jang Gwanho Kim seungsoo Mun Kyuho Lee Yeonji Kim Jong Woong Park Seonju Lee seung soon jang Cheolmin Park Department of Materials Science and Engineering Yonsei UniversitySeoul 03722Republic of Korea The George W.Woodruff School of Mechanical Engineering Georgia Institute of Technology801 Ferst DriveAtlantaGA 30332-0405USA School of Materials Science and Engineering Georgia Institute of Technology771 Ferst DriveAtlantaGA 30332-0245USA Om Spin Convergence Research Center Korea Institute of Science and Technology(KIST)Seoul02792Republic of Korea

Optical encryption technologies based on room-temperature light-emitting materials are of considerable ***,we present three-dimensional(3D)printable dual-light-emitting materials for high-performance optical pattern *** are based on fluorescent perovskite nanocrystals(NCs)embedded in metal-organic frameworks(MOFs)designed for phosphorescent host-guest ***,perovskite-containing MOFs emit a highly efficient blue phosphorescence,and perovskite NCs embedded in the MOFs emit characteristic green or red fluorescence under ultraviolet(UV)*** dual-light-emitting MOFs with independent fluorescence and phosphorescence emissions are employed in pochoir pattern encryption,wherein actual information with transient phosphorescence is efficiently concealed behind fake information with fluorescence under UV ***,a 3D cubic skeleton is developed with the dual-light-emitting MOF powder dispersed in 3D-printable polymer filaments for 3D dual-pattern *** article outlines a universal principle for developing MOF-based room-temperature multi-light-emitting materials and a strategy for multidimensional information encryption with enhanced capacity and security.

关键词： perovskite light pattern

Anti-Proliferative Effects of Ginsenosides Extracted from Mountain Ginseng on Lung Cancer

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Chinese Journal of Integrative Medicine 2016年第5期22卷 344-352页

作者： Dong Gyu Lee Sung-ll jang Young-Rang Kim Kyeong Eun Yang So Jung Yoon Zee-Won Lee Hyun Joo An Ik-soon jang Jong-soon Choi Hwa-seung Yoo Division of Life Science Korea Basic Science InstituteDaejeon 305-333Korea East-West Cancer Center Dunsan Oriental Hospital of Daejeon UniversityDaejeon 302-122Korea Graduate School of Analytical Science and Technology Chungnam National UniversityDaejeon 305-764Korea

Objective： To investigate the effect of three major ginsenosides from mountain ginseng as anti- cancer substance and explore the underlying mechanism involved in lung cancer. Methods： The inhibitory proliferation of lung cancer by major five ginsenosides （Rbl, Rb2, Rgl, Rc, and Re） was examined using 3-（4,5-dimethylthiazol-2-yl）-2,5-diphenyl tetrazolium bromide assay. Calculated 50% inhibition （IC50） values of five ginsenosides were determined and compared each other. Apoptosis by the treatment of single ginsenoside was performed by fluorescence-assisted cytometric spectroscopy. The alterations of apoptosis-related proteins were evaluated by Western blot analysis. Results： The abundance of ginsenosides in butanol extract of mountain ginseng （BX-MG） was revealed in the order of Rbl, Rgl, Re, Rc and Rb2. Among them, Rbl was the most effective to lung cancer cell, followed by Rb2 and Rgl on the basis of relative IC50 values of IMR90 versus A549 cell. The alterations of apoptotic proteins were confirmed in lung cancer A549 cells according to the administration of Rbl, Rb2 and Rgl. The expression levels of caspase-3 and caspase-8 were increased upon the treatment of three ginsenosides, however, the levels of caspase-9 and anti-apoptotic protein Bax were not changed. Conclusion： Major ginsenosides such as Rbl, Rb2 and Rgl comprising BX-MG induced apoptosis in lung cancer cells via extrinsic apoptotic pathway rather than intrinsic mitochondrial pathway.

关键词： Butanol extract of mountain ginseng ginsenoside lung cancer apoptosis

Rational design of ultrafine FeSe_(2) nanocrystals emb e dde d within hollow mesoporous carbon bowls for potassium-ion batteries with long-term cycling stability and high volumetric capacity

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Journal of Materials Science & Technology 2023年第12期143卷 129-139页

作者： Yu Jin jang Hong Geun Oh seung-Keun Park Department of Advanced Materials Engineering Chung-Ang University4726Seodong-daeroDaedeok-myeonAnseong-siGyeonggi-do 17546Republic of Korea

Hollow structures are commonly used to alleviate the mechanical stress on electrode materials and to provide more active sites in potassium-ion batteries(KIBs).Nevertheless,the excessive internal voids within these structures significantly reduce the packing density of particles,resulting in a relatively low volumetric energy density of the fabricated electrodes,which is undesirable for practical *** designed a hollow mesoporous carbon bowl embedded with ultrafine bis(selanylidene)iron(FeSe 2)nanocrystals(FeSe 2@HMCB)via a controllable impregnation method and subsequent selenization pro-cess for high-performance *** as-obtained FeSe 2@HMCB can inherit the advantages of conventional hollow carbon-based composites,such as alleviation of volume variation in active materials,abundant ion storage sites,and high electrical ***,the bowl structure has a higher pack-ing density than the conventional hollow structure,resulting in a significant increase in the volumet-ric energy density of the fabricated *** of these advantages,the FeSe 2@HMCB exhibits a high,stable reversible capacity of 326 mA h g^(-1) even after 1000 cycles at 0.5 A g^(-1),and excellent rate capacities(182 mA h g^(-1) at 3.0 A g^(-1)).Compared with the hollow structured counterpart,the vol-umetric capacity(mA h cm−3)of FeSe 2@HMCB increased by 60%.Furthermore,a full cell consisting of FeSe 2@HMCB//Prussian blue(PB)exhibits excellent electrochemical performance(99 mA h g^(-1) after 100 cycles at 0.1 A g^(-1)).

关键词： Potassium-ion batteries Iron selenide Bowl-like structure Mesoporous carbon Anode material

Exploring anharmonic lattice dynamics and dielectric relations in niobate perovskites from first-principles self-consistent phonon calculations

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npj Computational Materials 2023年第1期9卷 757-766页

作者： Kwangrae Kim Woohyun Hwang seung-Hyun Victor Oh Aloysius soon Department of Materials Science&Engineering Yonsei UniversitySeoul 03722Republic of Korea

Group I niobates(KNbO_(3) and NaNbO_(3))are promising lead-free alternatives for high-performance energy storage *** their potential,their complex phase transitions arising from temperature-dependent phonon softening and anharmonic effects on dielectric properties remain poorly *** this study,we employ density-functional theory(DFT)and self-consistent phonon(SCP)calculations to investigate finite-temperature phonons in cubic niobate *** include explicit anharmonic vibrational effects,SCP frequencies are shifted by the bubble self-energy correction within the quasiparticle(QP)approximation,providing precise descriptions of phonon softening in these strongly anharmonic *** further calculate the static dielectric constant of KNbO_(3) and NaNbO_(3) as a function of temperature using the Lyddane-Sachs-Teller(LST)relation and QP-corrected phonon *** theoretical results align with experimental data,offering reliable temperature-dependent phonon dispersions while considering anharmonic self-energies and thermal expansion effects,enhancing our understanding of the complex relations between lattice vibrations and phase transitions in these anharmonic oxides.

关键词： harmonic phonon dielectric

Extreme venous letting and cupping resulting in life-threatening anemia and acute myocardial infarction:A case report

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World Journal of Clinical Cases 2020年第24期8卷 6432-6436页

作者： Albert Youngwoo jang soon Yong Suh Department of Cardiology Gachon University Gil Medical CenterIncheon 21565South Korea Department of Cardiology Gachon University Gil HospitalIncheon 21565South Korea

BACKGROUND Wet cupping (WC) is a traditional therapy of skin suction-assisted bloodlettingthat is widely used in modern alternative medicine in Asia and the Middle ***, we report the case of a male who presented with ST-elevation myocardialinfarction (STEMI) and life-threatening anemia and underwent excessive *** SUMMARY A 55-year-old male presented with chest pain (30 min) and dyspnea (3 wk). Hisinitial electrocardiogram suggested STEMI in the anterior wall. Furthermore, hislaboratory results showed severe anemia with a hemoglobin level of 4.1 g/dL. Ofnote, the patient underwent regular WC therapy for chronic back pain, which hehad recently intensified. His WC practice resulted in life-threatening anemia andeventually STEMI. Percutaneous coronary intervention in the left anteriordescending artery was performed to treat the STEMI. His dyspnea dramaticallyimproved after the transfusion, and his hemoglobin level returned to 14.8 g/dLwithin 2 mo after discharge. He has been uneventful for the last seven years *** The current case demonstrates that excessive WC without adequate medicalmonitoring can result in severe anemia, which can further develop into STEMI.

关键词： Bloodletting ST-elevation myocardial infarction Anemia Cupping Wet cupping Case report

ELK3-ID4 axis governs the metastatic features of triple negative breast cancer

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Oncology Research 2024年第1期32卷 127-138页

作者： JIN-HO CHOI JOO DONG PARK seung HEE CHOI EUN-SU KO HYE JUNG jang KYUNG-soon PARK Department of Biomedical Science CHA UniversitySeongnamKorea

Purpose:Cancer cell metastasis is a multistep process,and the mechanism underlying extravasation remains ***3 is a transcription factor that plays a crucial role in regulating various cellular processes,including cancer *** on the finding that ELK3 promotes the metastasis of triple-negative breast cancer(TNBC),we investigated whether ELK3 regulates the extravasation of TNBC by forming the ELK3-ID4 ***4 functions as a transcriptional regulator that interacts with other transcription factors,inhibiting their activity and subsequently influencing various biological processes associated with cell differentiation,survival,growth,and ***:We assessed the correlation between the expression of ELK3 and that of ID4 in TNBCs using bioinformatics analyses,QRT-PCR,western blot analysis,luciferase reporter assays,and chromatin ***,adhesion,invasion,and lung metastasis assays were employed to determine whether the ELK3-ID4 axis regulates the metastatic features of ***:We found that ELK3 binds directly to a binding motif close to the ID4 promoter to repress promoter *** expression of E-cadherin in TNBC was regulated by the ELK3-ID4 *** vitro and in vivo analyses showed that inhibiting ID4 expression in ELK3-knockdown MDA-MB-231(ELK3KD)cells restored the ability to extravasate and ***:The results indicate that the ELK3 regulates ID4 promoter activity,and that the ELK3-ID4 axis regulates the metastatic characteristics of TNBC ***,the data suggest that the ELK3-ID4 axis regulates metastasis of TNBCs by modulating expression of E-cadherin.

关键词： E-cadherin Extravasation Colonization

Environmental friendly synthesis of hierarchical mesoporous platinum nanoparticles templated by fucoidan biopolymer for enhanced hydrogen evolution reaction

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Journal of Materials Science & Technology 2020年第11期42卷 185-190页

作者： seung Man Lim Kyunglee Kang Hongje jang Jung Tae Park Department of Chemical Engineering Konkuk University120 Neungdong-roGwangjin-guSeoul 05029Republic of Korea Department of Chemistry Kwangwoon University20 Cwangwoon-roNowon-guSeoul 01897Republic of Korea

Researching novel hydrogen evolution reaction(HER)catalysts with enhanced electrocatalytic activity,excellent stability,and cost-efficiency is of great significance for the large-scale hydrogen production from industrial electrolysis *** report the preparation of hierarchical mesoporous-Pt nanoparticles(HM-Pt NPs)with coral-like rough surface morphologies using environmental friendly and biocompatible fucoidan(Fu)biopolymer as a surface engineering compound and its application to electrocatalysts for *** designed HM-Pt NPs yields better mass activity of electrocatalysts compared to a commercial Pt/***-Pt NPs showed an overpotential of 33 mV at 10 mA cm-2 for the HER in 0.5 MH2SO4,which was highly comparable to that of the commercial Pt/C catalysts(29 mV).However,the amount of HM-Pt NPs loaded in glassy carbon electrode(0.033 mg mL-1)was approximately 20 times lower than that of the commercial Pt/C(0.64 mg *** HM-Pt NPs also maintained high catalytic stability with a consistent HER current density after 1000 continuous *** excellent HER performance is attributed to the improved electrochemical surface area,highly porous structure,and good surface wettability of the HM-Pt NPs,which results in enhanced electrocatalytic activity,decreased resistance at the electrode/electrolyte interface,and facile penetration of the electrolytes inside the electrode.

关键词： Mesoporous Fucoidan Biopolymer Low Pt content Hydrogen evolution reaction

Carbon Dioxide Concentration and Flux in an Urban Residential Area in Seoul,Korea

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Advances in Atmospheric Sciences 2014年第5期31卷 1101-1112页

作者： Moon-Soo PARK seung Jin JOO soon-Ung PARK Weather Information Service Engine Center for Atmospheric Science & Earthquake ResearchSeoul 121-835 Korea Center for Atmospheric and Environmental Modeling Seoul 152-775 Korea

The carbon dioxide （CO2） concentrations and fluxes measured at a height of 17.5 m above the ground by a sonic anemometer and an open-path gas analyzer at an urban residential site in Seoul, Korea from February 2011 to January 2012 were analyzed. The annual mean CO2 concentration was found to be 750 mg m-3, with a maximum monthly mean concentration of 827 mg m-3 in January and a minimum value of 679 mg m-3 in August. Meanwhile, the annual mean CO2 flux was found to be 0.45 mg m-2 s-1, with a maximum monthly mean flux of 0.91 mg m-2 s-1 in January and a minimum value of 0.19 mg m-2 s-1 in June. The hourly mean CO2 concentration was found to show a significant diurnal variation; a maximum at 0700-0900 LST and a minimum at 1400-1600 LST, with a large diurnal range in winter and a small one in summer, mainly caused by diurnal changes in mixing height, CO2 flux, and surface complexity. The hourly mean CO2 flux was also found to show a significant diurnal variation, but it showed two maxima at 0700-0900 LST and 2100-2400 LST, and two minima at 1100-1500 LST and 0300-0500 LST, mainly caused by a diurnal pattern in CO2 emissions and sinks from road traffic, domestic heating and cooking by liquefied natural gas use, and the different horizontal distribution of CO2 sources and sinks near the site. Differential advection with respect to wind direction was also found to be a cause of diurnal variations in both the CO2 concentration and flux.

关键词： CO2 concentration CO2 flux liquefied natural gas (LNG) Seoul urban residential area