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Enhancing BiVO_(4)photoanode performance by insertion of an epitaxial BiFeO_(3)ferroelectric layer

Journal of Energy Chemistry 2024年第2期89卷 71-78,I0003页

作者： Haejin Jang Yejoon Kim Hojoong Choi Jiwoong Yang Yoonsung Jung Sungkyun Choi Donghyeon lee Ho Won Jang sanghan lee School of Materials Science and Engineering Gwangju Institute of Science and TechnologyGwangju 61005Republic of Korea Department of Materials Science and Engineering Seoul National UniversitySeoul 08826Republic of Korea

BiVO_(4)(BVO)is a promising material as the photoanode for use in photoelectrochemical ***,the high charge recombination and slow charge transfer of the BVO have been obstacles to achieving satisfactory photoelectrochemical *** address this,various modifications have been attempted,including the use of ferroelectric *** materials can form a permanent polarization within the layer,enhancing the separation and transport of photo-excited electron-hole *** this study,we propose a novel approach by depositing an epitaxial BiFeO_(3)(BFO)thin film underneath the BVO thin film(BVO/BFO)to harness the ferroelectric property of *** self-polarization of the inserted BFO thin film simultaneously functions as a buffer layer to enhance charge transport and a hole-blocking layer to reduce charge *** a result,the BVO/BFO photoanodes showed more than 3.5 times higher photocurrent density(0.65 mA cm^(-2))at 1.23 V_(RHE)under the illumination compared to the bare BVO photoanodes(0.18 m A cm^(-2)),which is consistent with the increase of the applied bias photon-to-current conversion efficiencies(ABPE)and the result of electrochemical impedance spectroscopy(EIS)*** results can be attributed to the self-polarization exhibited by the inserted BFO thin film,which promoted the charge separation and transfer efficiency of the BVO photoanodes.

关键词： Photoelectrochemical Photoanode BiVO_(4) Ferroelectric materials BiFeO_(3)

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Domain-engineered BiFeO3 thin-film photoanodes for highly enhanced ferroelectric solar water splitting

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Nano Research 2018年第2期11卷 642-655页

作者： Song, Jaesun Kim, Taemin Ludvic lee, Jongmin Cho, Sam Yeon Cha, Jaeseong Jeong, Sang Yun An, Hyunji Kim, Wan Sik Jung, Yen-Sook Park, Jiyoon Jung, Gun Young Kim, Dong-Yu Jo, Ji Young Bu, Sang Don Jang, Ho Won lee, sanghan School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) Gwangju Republic of Korea Department of Materials Science and Engineering Research Institute of Advanced Materials Seoul National University Seoul Republic of Korea Department of Physics Chonbuk National University Jeonju Republic of Korea

In photoelectrochemical （PEC） water splitting, charge separation and collection by the electric field in the photoactive material are the most important factors for improved conversion efficiency. Hence, ferroelectric oxides, in which electrons are the majority carriers, are considered promising photoanode materials because their high built-in potential, provided by their spontaneous polarization, can signifi＇canfly enhance the separation and drift of photogenerated carriers. In this regard, the PEC properties of BiFeO3 thin-film photoanodes with different crystallographic orientations and consequent ferroelectric domain structures are investigated. As the crystallographic orientation changes from （001）pc via （ll0）pc to （lll）p~, the ferroelastic domains in epitaxial BiFeO3 thin films become mono-variant and the spontaneous polarization levels increase to 110 btC/cm2. Consequent136 the photocurrent density at 0 V vs. Ag/AgC1 increases approximately 5.3-fold and the onset potential decreases by 0.180 V in the downward polarization state. It is further demonstrated that ferroelectric switching in the （lll）pc BiFeO3 thin-film photoanode leads to an approximate change of 8,000% in the photocurrent density and a 0.330 V shift in the onset potential. This study strongly suggests that domain-engineered ferroelectric materials can be used as effective charge separation and collection layers for efficient solar water-splitting photoanodes.

关键词： BiFeO3 ferroelectric photoelectrochemical domain orientation pulsed laser deposition

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Highly ordered lead-free double perovskite halides by design

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Journal of Materiomics 2020年第4期6卷 651-660页

作者： Chang Won Ahn Jae Hun Jo Jong Chan Kim Hamid Ullah Sangkyun Ryu Younghun Hwang Jin San Choi Jongmin lee sanghan lee Hyoungjeen Jeen Young-Han Shin Hu Young Jeong Ill Won Kim Tae Heon Kim Department of Physics and Energy Harvest-Storage Research Center(EHSRC) University of UlsanUlsan44610Republic of Korea UNIST Central Research Facilities(UCRF)&School of Materials Science and Engineering Ulsan National Institute of Science and Technology(UNIST)Ulsan44919Republic of Korea Multiscale Materials Modelling Laboratory Department of PhysicsUniversity of UlsanUlsan44610Republic of Korea Department of Physics Pusan National UniversityPusan46241Republic of Korea School of Electrical and Electronics Engineering Ulsan CollegeUlsan44610Republic of Korea School of Materials Science and Engineering Gwangju Institute of Science and TechnologyGwangju61005Republic of Korea

Lead-free double perovskite halides are emerging optoelectronic materials that are alternatives to leadbased perovskite ***,single-crystalline double perovskite halides were synthesized,and their intriguing functional properties were *** such pioneering works,lead-free double perovskite halides with better crystallinity are still in demand for applications to novel optoelectronic ***,we realized highly crystalline Cs2AgBiBr6 single crystals with a well-defined atomic ordering on the microscopic *** avoided the formation of Ag vacancies and the subsequent secondary Cs3Bi2Br9 by manipulating the initial chemical environments in hydrothermal *** suppression of Ag vacancies allows us to reduce the trap density in the as-grown crystals and to enhance the carrier mobility *** design strategy is applicable for fabricating other lead-free halide materials with high crystallinity.

关键词： Cs2AgBiBr6 Lead-free Double perovskite Single crystal

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