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The effect of Laves phases and nano-precipitates on the electrochemical corrosion resistance of Mg-Al-Ca alloys under alkaline conditions

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Journal of Magnesium and Alloys 2024年第6期12卷 2447-2461页

作者： Markus Felten Veronika Chaineux Siyuan Zhang Ali Tehranchi Tilmann Hickel Christina Scheu Joshua Spille Marta Lipińska-Chwałek Joachim Mayer Benjamin Berkels Marcus Hans Imke Greving Silja Flenner sandra sefa Daniela Zander Chair of Corrosion and Corrosion Protection RWTH Aachen UniversityAachen 52072 Germany Max-Planck-Institut für Eisenforschung GmbH Düsseldorf 40237 Germany Central Facility for Electron Microscopy RWTH Aachen UniversityAachen 52074 Germany Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons Forschungszentrum Jülich GmbHJülich 52428Germany Mathematical Image and Signal Processing Aachen Institute for Advanced Study in Computational Engineering ScienceRWTH Aachen UniversityAachen 52062 Germany Materials Chemistry RWTH Aachen UniversityAachen 52074 Germany Institute of Materials Physics Helmholtz-Zentrum HereonGeesthacht 21502 Germany

The electrochemical corrosion mechanisms of Mg alloys were extensively studied in previous investigations of different chemical com-positions,modified surface states and various electrolyte ***,recent research focused on the active state of Mg dissolution,leading to unresolved effects of secondary phases adjacent to a stableα-solid solution passive *** present study investigates the fundamental electrochemical corrosion mechanisms of three different Laves phases with varying phase morphologies and phase fractions in the passive state of Mg-Al-Ca *** microstructure was characterized by(transmission-)electron microscopy and synchrotron-based transmission X-ray *** electrochemical corrosion resistance was determined with a standard three-electrode setup and advanced in-situ flow cell measurements.A new electrochemical activity sequence(C15>C36>α-Mg>C14)was obtained,as a result of a stable passive layer formation on theα-solid ***,nm-scale Mg-rich precipitates were identified within the Laves phases,which tend to inhibit the corrosion kinetics.

关键词： Laves phase STEM Magnesium Corrosion Passive layer

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Detailing the influence of PEO-coated biodegradable Mg-based implants on the lacuno-canalicular network in sheep bone:A pilot study

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Bioactive Materials 2023年第8期26卷 14-23页

作者： Jonathan Espiritu sandra sefa Hanna Cwieka Imke Greving Silja Flenner Regine Willumeit-Römer Jan-Marten Seitz Berit Zeller-Plumhoff Syntellix AG HannoverGermany Institute of Metallic Biomaterials Helmholtz-Zentrum HereonGeesthachtGermany Institute of Materials Physics Helmholtz-Zentrum HereonGeesthachtGermany

An increasing prevalence of bone-related injuries and aging geriatric populations continue to drive the orthopaedic implant market.A hierarchical analysis of bone remodelling after material implantation is necessary to better understand the relationship between implant and ***,which are housed and communicate through the lacuno-canalicular network(LCN),are integral to bone health and remodelling ***,it is essential to examine the framework of the LCN in response to implant materials or surface *** materials offer an alternative solution to permanent implants,which may require revision or removal *** alloys have resurfaced as promising materials due to their bone-like properties and safe degradation in *** further tailor their degradation capabilities,surface treatments such as plasma electrolytic oxidation(PEO)have demonstrated to slow *** the first time,the influence of a biodegradable material on the LCN is investigated by means of non-destructive 3D *** this pilot study,we hypothesize noticeable variations in the LCN caused by altered chemical stimuli introduced by the *** synchrotron-based transmission X-ray microscopy,we have characterised morphological LCN differences around uncoated and PEO-coated WE43 screws implanted into sheep *** specimens were explanted after 4,8,and 12 weeks and regions near the implant surface were prepared for *** from this investigation indicate that the slower degradation of PEO-coated WE43 induces healthier lacunar shapes within the ***,the stimuli perceived by the uncoated material with higher degradation rates induces a greater connected LCN better prepared for bone disturbance.

关键词： Nanotomography Lacuno-canalicular network Bone Magnesium Biodegradable implants

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Multiscale morphological analysis of bone microarchitecture around Mg-10Gd implants

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Bioactive Materials 2023年第12期30卷 154-168页

作者： sandra sefa Jonathan Espiritu Hanna Cwieka Imke Greving Silja Flenner Olga Will Susanne Beuer D.C Florian Wieland Regine Willumeit-Romer Berit Zeller-Plumhoff Institute of Metallic Biomaterials Helmholtz Zentrum HereonGeesthachtGermany Syntellix AG HannoverGermany Institute of Materials Physics Helmholtz Zentrum HereonGeesthachtGermany Molecular Imaging North Competence Center Kiel UniversityKielGermany Fraunhofer Institut für Integrierte Systeme und Bauelementetechnologie(IISB) ErlangenGermany

The utilization of biodegradable magnesium(Mg)-based implants for restoration of bone function following trauma represents a transformative approach in orthopaedic *** such alloy,magnesium-10 weight percent gadolinium(Mg-10Gd),has been specifically developed to address the rapid degradation of Mg while enhancing its mechanical properties to promote bone *** studies have demonstrated that Mg-10Gd exhibits favorable osseointegration;however,it exhibits distinct ultrastructural adaptation in comparison to conventional implants like titanium(Ti).A crucial aspect that remains unexplored is the impact of Mg-10Gd degradation on the bone *** address this,we employed hierarchical three-dimensional imaging using synchrotron radiation in conjunction with image-based finite element *** using the methods outlined,the vascular porosity,lacunar porosity and the lacunar-canaliculi network(LCN)morphology of bone around Mg-10Gd in comparison to Ti in a rat model from 4 weeks to 20 weeks post-implantation was *** investigation revealed that within our observation period,the degradation of Mg-10Gd implants was associated with significantly lower(p<0.05)lacunar density in the surrounding bone,compared to ***,the LCN morphology and the fluid flow analysis did not significantly differ for both implant *** summary,a more pronounced lower lacunae distribution rather than their morphological changes was detected in the surrounding bone upon the degradation of Mg-10Gd *** implies potential disparities in bone remodelling rates when compared to Ti *** findings shed light on the intricate relationship between Mg-10Gd degradation and bone microarchitecture,contributing to a deeper understanding of the implications for successful osseointegration.

关键词： Biodegradable magnesium implants Lacunar-canalicular network(LCN) Vascular porosity Synchrotron radiation micro computed tomography(SRμCT) Transmission x-ray microscopy(TXM)

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Degradation behavior and osseointegration of Mg-Zn-Ca screws in different bone regions of growing sheep:a pilot study

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Regenerative Biomaterials 2023年第1期10卷 1-14页

作者： Romy Marek Hanna C´wieka Nicholas Donohue Patrick Holweg Julian Moosmann Felix Beckmann Iva Brcic Uwe Yacine Schwarze Kamila Iskhakova Marwa Chaabane sandra sefa Berit Zeller-Plumhoff Annelie-Martina Weinberg Regine Willumeit-Ro¨mer Nicole Gabriele Sommer Department of Orthopaedics and Traumatology Medical University of Graz8010 GrazAustria Institute of Metallic Biomaterials Helmholtz-Zentrum Hereon GmbH21502 GeesthachtGermany National Institute for Bioprocessing Research and Training University College DublinDublin 4Ireland Institute of Materials Physics Helmholtz-Zentrum Hereon GmbH21502 GeesthachtGermany D&R Institute of Pathology Medical University of Graz8010 GrazAustria Department of Dental Medicine and Oral Health Medical University of Graz8010 GrazAustria SCANCO Medical AG 8306 Wangen-BruttisellenSwitzerland

Magnesium(Mg)-based implants are highly attractive for the orthopedic field and may replace titanium(Ti)as support for fracture *** determine the implant-bone interaction in different bony regions,we implanted Mg-based alloy ZX00(Mg<0.5 Zn<0.5 Ca,in wt%)and Ti-screws into the distal epiphysis and distal metaphysis of sheep *** implant degradation and osseointegration were assessed in vivo and ex vivo after 4,6 and 12weeks,using a combination of clinical computed tomography,medium-resolution micro computed tomography(mCT)and high-resolution synchrotron radiation mCT(SRmCT).Implant volume loss,gas formation and bone growth were evaluated for both implantation sites and each bone region ***,histological analysis of bone growth was performed on embedded hard-tissue *** demonstrate that in all cases,the degradation rate of ZX00-implants ranges between 0.23 and 0.75mm/*** highest degradation rates were found in the ***-to-implant contact varied between the time points and bone types for both ***,bone-volume-to-total-volume was higher around ***,we found an increased cortical thickness around the ZX00-screws when compared with the *** results showed the suitability of ZX00-screws for implantation into the distalmeta-and epiphysis.

关键词： biodegradable implants magnesium-based alloys computed tomography Mg-Zn-Ca sheep histology

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