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Analysis of cerium substitution in Co-Sr based spinel ferrites for high frequency application

Journal of Rare Earths 2024年第9期42卷 1755-1763页

作者： Laura Khudaysh Inas A.Ahmed Syeda Rabia Ejaz sajjad Ahmad khan Yasir A.Haleem Mohamed M.Ibrahim Mahmood Ali Hafiz Muhammad Tahir Farid Zeinhom M.El-Bahy Department of Physics Faculty of ScienceJazan University Department of Chemistry Faculty of ScienceKing Khalid University Department of Physics The Government Sadiq College Women University Institute of Physics Khwaja Fareed University of Engineering and Information Technology Department of Chemistry College of ScienceTaif University Centre of Excellence in Solid State Physics University of the Punjab Department of Physics Government College Department of Chemistry Faculty of ScienceAl-Azhar University

Spinel ferrites exhibit exceptional magnetic properties,making them a distinctive class of magnetic *** sol-gel technique was utilized for the synthesis of spinel ferrites with the chemical formula Co0.6Sr0.4CexFe2-xO4. Following that,a comprehensive X-ray diffraction analysis unveiled the crystalline cubic structure of the synthesized *** the utilization of the M-H loop approach,the ferromagnetic attributes of ferrites were assessed,and the assimilation of rare earth elements led to substantial enhancements in saturation magnetization,remanence,and *** ferrites with a high concentration of rare earth elements have improved direct current resistivity and activation *** logarithm of a material's resistance increased from 5.29 to 8.12 Ω·cm as cerium is *** a change in the amount of cerium,the activation energy goes up from 0.19 to *** changing the frequency from 5.5 to 9.5 GHz,the dielectric characteristics were *** the frequency goes up,the dielectric constant goes *** ferrites that have been made better in every way can be used in high-frequency applications.

关键词： Activation energy DC electrical resistance Remanence magnetization Cobalt strontium spinel ferrites High frequency application Rare earths

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Reconfigurable Sensing Time in Cooperative Cognitive Network Using Machine Learning

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Computers, Materials & Continua 2023年第3期74卷 5209-5227页

作者： Noor Gul Saeed Ahmed Su Min Kim Muhammad sajjad khan Junsu Kim Department of Electronics Engineering Korea Polytechnic UniversityGyeonggi-do15073Korea Department of Electronics University of PeshawarPeshawar25120Pakistan Deparment of Electrical Engineering Mirpur University of Science of TechnologyAJ&KMirpur10250Pakistan Department of Electrical Engineering International Islamic UniversityIslamabad44000Pakistan

A cognitive radio network(CRN)intelligently utilizes the available spectral resources by sensing and learning from the radio environment to maximize spectrum *** CRNs,the secondary users(SUs)opportunistically access the primary users(PUs)***,unambiguous detection of the PU channel occupancy is the most critical aspect of the operations of *** spectrum sensing(CSS)is rated as the best choice for making reliable sensing *** paper employs machinelearning tools to sense the PU channels reliably in *** sensing parameters are reconfigured to maximize the spectrum utilization while reducing sensing error and cost with improved channel *** fine-k-nearest neighbor algorithm(FKNN),employed in this paper,estimates the number of samples based on the nature of the channel under-specific detection and false alarm probability *** simulation results reveal that the sensing cost is suppressed by reducing the sensing time and exploiting the traditional fusion rules,validating the effectiveness of the proposed ***,the global decision made at the fusion center(FC)based on the modified sensing samples,results low energy consumption,higher throughput,and improved detection with low error probabilities.

关键词： Energy detection machine learning k-nearest-neighbor decision tree linear regression throughput energy consumption

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Strong interfacial charge transfer between hausmannite manganese oxide and alumina for efficient photocatalysis

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Chinese Journal of Chemical Engineering 2021年第5期34卷 147-159页

作者： Aisha Kanwal Shamaila sajjad sajjad Ahmed khan Leghari Muhammad Naeem khan International Islamic University H-10 IslamabadPakistan Pakistan Institute of Engineering and Applied Sciences Islamabad 44000Pakistan Department of Chemistry Government College of ScienceLahorePakistan

Well crystalline manganese oxide(Mn_(3)O_(4))nanoparticles anchored on gamma alumina(γ-Al_(2)O_(3))have been successfully tailored via a proficient and cost effective chemical process as an efficient material for photo *** indicated the composite formation ofγ-Al_(2)O_(3) and hausmannite structure of Mn_(3)O_(4).SEM and TEM revealed that hetero structure of Mn_(3)O_(4)/γ-Al_(2)O_(3) exhibits an amalgam of aggregated nanoparticles and *** demonstrated the chemical states of binary *** band gap tuning has been performed withγ-Al_(2)O_(3) nanoparticles by assimilating hausmannite Mn_(3)O_(4) particles into flower like microstructure of Al_(2)O_(3).The photoluminescence spectra affirmed the enhancement in charge separation in Mn_(3)O_(4)/γ-Al_(2)O_(3) binary hybrid *** band gap becomes narrow with the increase in concentrations of Mn_(3)O_(4).The narrowing of band gap is concorded with crystalline domains of primary aggregated *** elucidate the mechanism of the photocatalytic activity linear sweep voltammetry was *** results showed that Mn_(3)O_(4)/γ-Al_(2)O_(3) nanocomposite revealed the enhancement in current density as compared to pureγ-Al_(2)O_(3) which confirmed the electron transfer from Mn_(3)O_(4) toγ-Al_(2)O_(3) through the interfacial potential gradient in conduction *** optimum concentration of 6.0%Mn_(3)O_(4)/γ-Al_(2)O_(3) for hybrid structure showed an excellent photocatalytic activity under visible light due to narrow band gap *** degree distribution of Mn_(3)O_(4) nano architects overlying onγ-Al_(2)O_(3) induces a significant synergic effect betweenγ-Al_(2)O_(3) and hausmannite phase of manganese oxide(Mn_(3)O_(4)).This strong interfacial contact betweenγ-Al_(2)O_(3) and Mn_(3)O_(4) endures the quick transfer of photo generated charge carriers across interface.

关键词： Hausmannite Mn_(3)O_(4) Alumina Band gap tuning Interfacial charge transfer Nanomaterials Catalysis

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Competitive role of nitrogen functionalities of N doped GO and sensitizing effect of Bi_(2)O_(3)QDs on TiO_(2)for water remediation

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Journal of Environmental Sciences 2021年第10期33卷 107-119页

作者： Saima Noor Shamaila sajjad sajjad Ahmed khan Leghari Cristina Flox Saeed Ahmad International Islamic University Islamabad 44000Pakistan Department of Chemistry and Materials Science Aalto UniversityEspoo 16100Fl-00076Finland Pakistan Institute of Engineering and Applied Sciences Islamabad 44000Pakistan Department of Applied Physics Aalto UniversityEspoo 15100Fl-00076Finland

The promising solar irradiated photocatalyst by pairing of bismuth oxide quantum dots(BQDs)doped TiO_(2)with nitrogen doped graphene oxide(NGO)nanocomposite(NGO/BQDs-TiO_(2))was *** was used for degradation of organic pollutants like 2,4-dichlorophenol(2,4-DCP)and stable dyes,*** B and Congo Red.X-ray diffraction(XRD)profile of NGO showed reduction in oxygenic functional groups and restoring of graphitic crystal *** characteristic diffraction peaks of TiO_(2)and its composites showed crystalline anatase TiO_(2).Morphological images represent spherical shaped TiO_(2)evenly covered with BQDs spread on NGO *** surface linkages of NO-O-Ti,C-O-Ti,Bi-O-Ti and vibrational modes are observed by Fourier transform infrared spectroscopy(FTIR)and Raman *** and NGO modified TiO_(2)results into red shifting in visible region as studied in diffused reflectance spectroscopy(DRS).NGO and BQDs in TiO_(2)are linked with defect centers which reduced the recombination of free charge carriers by quenching of photoluminescence(PL)intensities.X-ray photoelectron spectroscopy(XPS)shows that no peak related to C-O in NGO/BQDs-TiO_(2)is *** indicated that doping of nitrogen into GO has reduced some oxygen functional *** functionalities in NGO and photosensitizing effect of BQDs in ternary composite have improved photocatalytic activity against organic *** byproducts during photo degradation process of 2,4-DCP were studied through high performance liquid chromatography(HPLC).Study of radical scavengers indicated that O_(2)^(·-) has significant role for degradation of 2,*** investigations propose that fabricated nanohybrid architecture has potential for degradation of environmental pollutions.

关键词： Bi_(2)O_(3)quantum dots Nitrogen doped graphene oxide Nitrogen defects TiO_(2) 2,4-Dichlorophenol Water treatment

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Designing single atom catalysts for exceptional electrochemical CO_(2) reduction

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Chinese Journal of Structural Chemistry 2024年第1期43卷 3-5页

作者： Muhammad Humayun Mohamed Bououdina Abbas khan sajjad Ali Chundong Wang Energy Water and Environment LabCollege of Humanities and SciencesPrince Sultan UniversityRiyadh11586Saudi Arabia School of Integrated Circuits Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan430074PR China Department of Chemistry Abdul Wali Khan University MardanMardan23200Pakistan

The release of anthropogenic CO_(2)emissions into the atmosphere has significantly accelerated global warming within the past few *** to the latest data,it is predicted that the concentration of CO_(2)will rise to 800 ppm over this century,and could reach 2000 ppm by *** high level of CO_(2)is expected to result in significant increase in global temperature as well as ocean acidification[1].

关键词： exceptional global release

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Construction of robust and durable Cu_(2)Se-V_(2)O_(5) nanosheet electrocatalyst for alkaline oxygen evolution reaction

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Frontiers of Chemical Science and Engineering 2024年第6期18卷 71-83页

作者： Tauseef Munawar Ambreen Bashir Khalid Mujasam Batoo Saman Fatima Faisal Mukhtar sajjad Hussain Sumaira Manzoor Muhammad Naeem Ashiq Shoukat Alim khan Muammer Koc Faisal Iqbal Institute of Physics The Islamia University of BahawalpurBahawalpur 63100Pakistan King Abdullah Institute for Nanotechnology King Saud UniversityRiyadh 11451Saudi Arabia Hybrid Materials Center(HMC) Sejong UniversitySeoul 05006Republic of Korea Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Institute of Chemical Sciences Bahauddin Zakariya UniversityMultan 60800Pakistan Division of Sustainable Development College of Science and EngineeringHamad Bin Khalifa UniversityQatar FoundationDoha 34110Qatar

Reducing the production costs of clean energy carriers such as hydrogen through scalable water electrolysis is a potential solution for advancing the hydrogen *** the various material candidates,our group demonstrated transition-metal-based materials with tunable electronic characteristics,various phases,and ***,electrochemical water oxidation using Cu_(2)Se-V_(2)O_(5) as a non-precious metallic electrocatalyst via a hydrothermal approach is *** water-splitting performance of all the fabricated electrocatalysts was evaluated after direct growth on a stainless-steel *** electrochemically tuned Cu_(2)Se-V_(2)O_(5) catalyst exhibited a reduced overpotential of 128 mV and provided a reduced Tafel slope of 57 mV·dec^(−1) to meet the maximum current density of 250 mA·cm^(−2).The optimized strategy for interfacial coupling of the fabricated Cu_(2)Se-V_(2)O_(5) catalyst resulted in a porous structure with accessible active sites,which enabled adsorption of the intermediates and afforded an effective charge transfer rate for promoting the oxygen evolution ***,the combined effect of the catalyst components provided long-term stability for over 110 h in an alkaline solution,which makes the catalyst promising for large-scale practical *** aforementioned advantages of the composite catalyst overcome the limitations of low conductivity,agglomeration,and poor stability of the pure catalysts(Cu2Se and V2O5).

关键词： oxygen evolution reaction Cu_(2)Se-V_(2)O_(5)composite nanosheets metal-diffused ions accessible adsorption sites

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An Intelligent Hybrid Mutual Authentication Scheme for Industrial Internet of Thing Networks

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Computers, Materials & Continua 2021年第7期68卷 447-470页

作者： Muhammad Adil Jehad Ali Muhammad sajjad khan Junsu Kim Ryan Alturki Mohammad Zakarya Mukhtaj khan Rahim khan Su Min Kim Department of Computer Science Virtual University of PakistanLahore54000Pakistan Department of Computer Engineering Department of AI Convergence NetworkAjou UniversitySuwon16499South Korea Department of Electronics Engineering Korea Polytechnic UniversitySlheungSouth Korea Department of Computer Science Abdul Wali Khan University Mardan23200Pakistan

Internet of Things(IoT)network used for industrial management is vulnerable to different security threats due to its unstructured deployment,and dynamic communication *** literature various mechanisms addressed the security issue of Industrial IoT networks,but proper maintenance of the performance reliability is among the common *** this paper,we proposed an intelligent mutual authentication scheme leveraging authentication aware node(AAN)and base station(BS)to identify routing attacks in Industrial IoT *** AAN and BS uses the communication parameter such as a route request(RREQ),node-ID,received signal strength(RSS),and round-trip time(RTT)information to identify malicious devices and routes in the deployed *** feasibility of the proposed model is validated in the simulation environment,where OMNeT++was used as a simulation *** compare the results of the proposed model with existing field-proven schemes in terms of routing attacks detection,communication cost,latency,computational cost,and *** results show that our proposed scheme surpasses the previous schemes regarding these performance parameters with the attack detection rate of 97.7%.

关键词： Security industrial Internet of Things routing attacks routing protocols base station authentication aware nodes

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PdCu alloy anchored defective titania for photocatalytic conversion of carbon dioxide into methane with 100% selectivity

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Journal of Energy Chemistry 2024年第4期91卷 254-265页

作者： Lina Zhang sajjad Hussain Qiuye Li Jianjun Yang National&Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials Henan UniversityKaifeng 475004HenanChina

The photoreduction of CO_(2)into CH_(4)with simultaneous high activity and selectivity is a promising strategy to increase energy supply and alleviate global ***,the absence of the active sites that is responsible for the adsorption and activation of CO_(2)and the generation of CO and H2via side reactions often lead to poor efficiency and low selectivity of the ***,Cu,Pd,and PdCu metal clusters cocatalyst-anchored defective TiO_(2)nanotubes(Cu/TiO_(2)-SBO,Pd/TiO_(2)-SBO,and Pd1Cu1/TiO_(2)-SBO)were designed via a simple solution impregnation reduction and applied for photocatalytic conversion of CO_(2)to CH_(4).The Pd1Cu1/TiO_(2)-SBO photocatalyst exhibits excellent catalytic performance among the other catalysts for photoreduction of CO_(2)into CH_(4).More interestingly,the product selectivity of CH_(4)reaches up to 100%with a rate of 25μmol g^(-1)h^(-1).In-situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS)and density functional theory(DFT)simulations indicate that the main reasons for the high selectivity of CH_(4)are attributed to the PdCu alloy and oxygen vacancies,which jointly enhance the photoinduced carrier separation and lower energy barriers of key ***,due to the tunable d-band center of the Cu site in the PdCu alloy,the generated intermediates can be well prevented from poisoning and promoted to participate in further ***,the current study will provide insight into the development of new,highly selective photocatalysts for the visible light-catalytic reduction of CO_(2)into CH_(4).

关键词： PdCu alloy Defective TiO_(2) Photoreduction of CO_(2) Photocatalytic mechanism

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M_(4)X_(3) MXenes:Application in Energy Storage Devices

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Nano-Micro Letters 2024年第10期16卷 522-542页

作者： Iftikhar Hussain Waqas Ul Arifeen Shahid Ali khan Sikandar Aftab Muhammad Sufyan Javed sajjad Hussain Muhammad Ahmad Xi Chen Jiyun Zhao PRosaiah Khaled Fahmi Fawy Adnan Younis Sumanta Sahoo Kaili Zhang Department of Mechanical Engineering City University of Hong Kong83 Tat Chee AvenueKowloon TongHong KongPeople's Republic of China School of Mechanical Engineering Yeungnam UniversityDaehak-roGyeongsan-siGyeongbuk-do 38541South Korea Department of Semiconductor Systems Engineering and Clean Energy Sejong UniversitySeoul 05006Republic of Korea School of Physical Science and Technology Lanzhou UniversityLanzhou 730000People's Republic of China Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Department of Physics Saveetha School of EngineeringSaveetha Institute of Medical and Technical Sciences(SIMATS)ThandalamChennai 602105India Department of Chemistry Faculty of ScienceKing Khalid UniversityP.O.Box 900461413 AbhaSaudi Arabia Department of Physics College of ScienceUnited Arab Emirates UniversityP.O.Box 15551Al-AinUnited Arab Emirates School of Chemical Engineering Yeungnam UniversityGyeongsanGyeongbuk 38541South Korea

MXene has garnered widespread recognition in the scientific com-munity due to its remarkable properties,including excellent thermal stability,high conductivity,good hydrophilicity and dispersibility,easy processability,tunable surface properties,and admirable *** have been categorized into different families based on the number of M and X layers in M_(n+1)X_(n),such as M_(2)X,M_(3)X_(2),M_(4)X_(3),and,recently,M_(5)X_(4).Among these families,M_(2)X and M_(3)X_(2),par-ticularly Ti_(3)C_(2),have been greatly explored while limited studies have been given to M_(5)X_(4)MXene ***,studies on the M_(4)X_(3)MXene family have developed recently,hence,demanding a compilation of evaluated ***,this review provides a systematic overview of the latest advancements in M_(4)X_(3)MXenes,focusing on their properties and applications in energy storage *** objective of this review is to provide guidance to researchers on fostering M_(4)X_(3)MXene-based nanomaterials,not only for energy storage devices but also for broader applications.

关键词： MXene M_(4)X_(3)MXenes 2D materials Energy storage Properties

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Development of a Comparison Based Hotel and Resort Booking System in Bangladesh

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Journal of Software Engineering and Applications 2021年第5期14卷 133-149页

作者： Md. sajjad Mahmud khan sajjad Kashem Mohammad Monirujjaman khan Department of Electrical and Computer Engineering North South University Dhaka Bashundhara

With the rise of population and the industrial revolution, it is obvious that hotels and resorts are increasing drastically day by day. In the 21st century, tourism is a trend. Everyone loves to travel and the reasons vary from person to person. Whether it is to have a cheerful and peaceful mind and place or business purposes, either way, hotels and resorts actually doing their jobs very well. This, tourism is a promising sector for any country and Bangladesh is no different. But the problem is we have to do the hotel booking and reservation manually most of the time. Sometimes it is too troublesome and knowing about the suitable hotels and resorts is too difficult. Though there are some online platforms available, they are not our country-oriented such as the payment system is not preferable for us. To solve this problem Vhromon is developed, a comparison-based hotel and resort booking system where anyone can book a hotel or resort by just login from the internet. Vhromon is an interactive online platform and it is user-friendly and easy to get like most of the platforms available nowadays. But they do not have all the hotels and resorts enlisted, only the well-known ones. On the other hand, Vhromon has everything enlisted where customers can compare them and can choose the right one for them. Furthermore, this system has a vendor panel where any hotel or resort owner can add their hotel or resort easily without any hassle, unlike the existing one.

关键词： Hotel Booking Hotel Comparison Resort Booking Resort Comparison Hotel Search Hotel Reviews Resort Search Resort Reviews Hotel Ratings Resort Ratings

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