检索结果-南通市图书馆

Kinetics of solid-state reduction of chromite overburden

International Journal of Minerals,Metallurgy and Materials 2023年第12期30卷 2347-2355页

作者： saida shaik Zhiyuan Chen Preeti Prakash Sahoo Chenna Rao Borra Metallurgical and Materials Engineering Department Indian Institute of Technology KharagpurKharagpurWest Bengal 721302India VITO-Flemish Institute for Technological Research Boeretang 200B-2400 MolBelgium Research and Development Division Tata Steel Ltd.Jamshedpur 831001India

The demand for alternative low-grade iron ores is on the rise due to the rapid depletion of high-grade natural iron ore resources and the increased need for steel usage in daily ***,the use of low-grade iron ores is a constant clinical task for industry *** smelting of low-grade ores consumes a substantial amount of energy due to the large volume of slag *** condition can be avoided by direct reduction followed by magnetic separation(to separate the high amount of gangue or refractory and metal parts)and *** overburden(COB)is a mine waste generated in chromite ore processing,and it mainly consists of iron,chromium,and nickel(<1wt%).In the present work,the isothermal and non-isothermal kinetics of the solid-state reduction of self-reduced pellets prepared using low-grade iron ore(COB)were thoroughly investigated via thermal *** results showed that the reduction of pellets followed a firstorder autocatalytic reaction control mechanism in the temperature range of 900-1100℃.The autocatalytic nature of the reduction reaction was due to the presence of nickel in the *** apparent activation energy obtained from the kinetics results showed that the solid-state reactions between COB and carbon were the rate-determining step in iron oxide reduction.

关键词： chromite overburden solid-state reduction kinetics autocatalytic reaction

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Optimization and validation of a fast RP-HPLC method for the determination of dobutamine in rat plasma:Pharmacokinetic studies in healthy rat subjects

引用

Journal of Pharmaceutical Analysis 2013年第6期3卷 434-439页

作者： Ramesh Thippani Nageswara Rao Pothuraju Nageswara Rao Ramisetti saida shaik Department of Chemistry National Institute of Technology Analytical Chemistry Division IICT

A novel isocratic reverse phase high performance liquid chromatography （RP-HPLC） with photo diode array （PDA） detection method for the determination of dobutamine （DBT） in rat plasma was developed and validated after optimization of various chromatographic conditions and other experimental parameters. Homoveratrylamiue was used as an internal standard. Methanol was used as the extracting solvent for the preparation of plasma samples. Samples were separated on a Symmetry C18 （250ram x4.6mm i.d., 5 pro） analytical column. Acetonitrile and 15raM potassium dihydrogen phosphate （pH 5.0 with 0.3% TEA）（20：80, v/v） was used. The column oven temperature was optimized at 35 ~C and the flow rate was 0.8 mL/min. The detection wavelength was fixed at 230 nm for entire analysis. The calibration curve was found to be linear over the concentration range of 50-2000 ng/mL （ra=0.9992）. The limit of quantification （LOQ） of the method was 50 ng/mL. The % RSD values of accuracy and precision values for intra and inter days were 〈 15% at quality control （QC） concentrations. Recovery, stability and robustness were studied within the acceptable range according to ICH guidelines. The method was efficiently applied to a pharmacokinetic study in healthy Wistar rats.

关键词： Dobutamine RP-HPLC Validation Rat plasma Pharmacokinetics

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：