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Thermochemical Aspects of Activated Ammonium Perchlorates with Superior Thermal Stability,Decomposition Enthalpy,Propagation Index,and Decomposition Kinetic Parameters

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Journal of Thermal Science 2021年第6期30卷 2196-2201页

作者： SHERIF Elbasuney M.Yehia shukri ismael SHERIF Farag AHMED Saleh GHARIEB S.El-Sayyad Head of Nanotechnology Research Center Military Technical College(MTC)Cairo 11646Egypt School of Chemical Engineering Military Technical College(MTC)Cairo 11646Egypt Science and Technology Center of Excellence Cairo 11646Egypt Drug Radiation Research Department National Center for Radiation Research and Technology(NCRRT)Egyptian Atomic Energy Authority(EAEA)Cairo 11646Egypt

Ammonium perchlorate(AP)includes oxidizing and reducing elements on the same *** can act as an efficient oxidizer and mono-propellant as *** this study,AP experienced crystallographic phase change from orthorhombic centrosymmetric to non-centrosymmetric under controlled isothermal heat *** diffractograms confirmed this crystallographic phase *** thermal behaviour of activated AP had been investigated using *** AP demonstrated high chemical stability with an increase in endothermic phase transition enthalpy by 170%.The enthalpy of the subsequent two main exothermic decomposition reactions was increased by 250%.Whereas AP demonstrated total decomposition enthalpy of 733 J/g,activated AP showed 2614 J/*** AP can secure self-sustained response at a high *** index(combustion enthalpy/ignition temperature)was employed to assess self-sustained reaction *** AP demonstrated high propagation index of 8.7 compared with 2.5 for un-activated *** decomposition kinetic parameters had investigated using Kissinger and KAS *** AP showed an increase in activation energy by 89%using the Kissinger method;kinetic parameters using the KAS method were in good agreement with the Kissinger *** can have concluded that AP with novel kinetic decomposition parameters for enhanced safety storage and high combustion characteristics has evolved.

关键词： solid propellants oxidizers thermal behavior Kinetic parameters activation energy

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