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Corrosion behavior of as-cast Mg–8Li–3Al+xCe alloy in 3.5wt% NaCl solution

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International Journal of Minerals,Metallurgy and Materials 2016年第10期23卷 1196-1203页

作者： s.manivannan P.Dinesh R.Mahemaa Nandhakumaran MariyaPillai s.P.Kumaresh Babu srinivasan sundarrajan Department of Metallurgical and Materials Engineering National Institute of Technology Tirchirappalli 620015 Tamil Nadu India TVs sundaram-Clayton Limited Chennai 600050 Tamil Nadu India

Mg-8Li-3Al＋xCe alloys（x = 0.5wt%, 1.0wt%, and 1.5wt%） were prepared through a casting route in an electric resistance furnace under a controlled atmosphere. The cast alloys were characterized by X-ray diffraction, optical microscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The corrosion behavior of the as-cast Mg-8Li-3Al＋xCe alloys were studied under salt spray tests in 3.5wt% NaC l solution at 35°C, in accordance with standard AsTM B-117, in conjunction with potentiodynamic polarization（PDP） tests. The results show that the addition of Ce to Mg-8Li-3Al（LA83） alloy results in the formation of Al_2Ce intermetallic phase, refines both the α-Mg phase and the Mg_（17）Al_（12） intermetallic phase, and then increases the microhardness of the alloys. The results of PDP and salt spray tests reveal that an increase in Ce content to 1.5wt% decreases the corrosion rate. The best corrosion resistance is observed for the LA83 alloy sample with 1.0wt% Ce.

关键词： magnesium lithium alloys cerium sodium chloride solutions corrosion rate polarization

Investigation and corrosion performance of cast Mg-6Al-1Zn+XCa alloy under salt spray test(AsTM-B117)

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Journal of Magnesium and Alloys 2015年第1期3卷 86-94页

作者： s.manivannan P.Dinesh s.P.Kumaresh Babu s.sundarrajan Department of Metallurgical and Materials Engineering National Institute of TechnologyTirchirappalliTamil NaduIndia National Institute of Technology TirchirappalliTamil NaduIndia

The corrosion behavior of cast Mg-6Al-1Zn+XCa(Where X=0.5,1.0,1.5 and 2.0 wt.%Ca)magnesium alloy,aged at different temperatures of 180 ℃,200 ℃,220 ℃ and 240 ℃ was investigated in accelerated corrosion test chamber according to AsTM-B117 standard(salt spray test).The exposed alloys were characterized by X-Ray Diffraction(XRD),Optical Microscopy(OM)and scanning Electron Microscopy(sEM)*** microstructural refinement due to calcium addition and ageing treatment results in the improvement of corrosion resistance of the experimental *** rate decreases due to fine precipitation of theβ(Mg17Al12)phase distributed along theα-grain boundaries during *** phases act as a barrier,which makes the alloy more resistant to *** found that better corrosion resistance of the alloy was observed in Mg-6Al-1Zn+1.5 wt.%Ca with 180 ℃ ageing *** corrosion behavior of Mg-6Al-1Zn+XCa alloy exhibited by AsTM B117 salt spray testing and electrochemical polarization measurements showed similar trends concluding that the calcium addition and ageing temperature decreases the corrosion rate.

关键词： AZ61 Calcium Precipitation Corrosion rate Polarization

Detection and clearance in Alzheimer’s disease: leading with illusive chemical, structural and morphological features of the targets

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Neural Regeneration Research 2024年第3期19卷 497-498页

作者： Luís Gales i3s−Instituto de Investigação e Inovação em saúde Rua Alfredo AllenPortoPortugal(Gales L)IBMC−Instituto de Biologia Molecular e CelularUniversidade do PortoRua Alfredo AllenPortoPortugal ICBAs−Instituto de Ciências Biomédicas Abel salazar Rua de Jorge Viterbo FerreiraPortoPortugal

Highly specific interactions between biomolecules,such as antigen-antibody,protein-ligand,or nucleic acid base pair complementary are on the basis of the organization of complex *** same principles may be tentatively used in molecular medicine for diagnosis and therapeutics.A molecule can be designed to selectively bind a protease and thereby inhibit the production of a peptide that forms toxic aggregates in the brain or an antibody may be produced to bind specifically to that peptide for detection or clearance ***,interference in biological systems is not that *** a start there is the inhibition of the physiological role of the protease;moreover,several cleavage fragments may be produced,which may continue to diverge due to putative post-translational modification and self-assembly processes,hiding the toxic target in a“soup”of peptide species varying in size,structure and chemical composition.A perspective of the current status and challenges in targeting peptide species for diagnosis and treatment in the context of Alzheimer’s disease is given.

关键词： Alzheimer diagnosis thereby

Model dependent analysis of D^(+)_(s)→η^(′)l+v_(l) decays in beyond standard model

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Chinese Physics C 2024年第9期48卷 82-95页

作者： s.Mahata M.Mandal H.Mahapatra s.Biswas s.sahoo Department of Physics National Institute of Technology Durgapur Durgapur 713209West BengalIndia

Motivated by the recent experimental results of branching fractions for D^(+)_(s)→η^(′)l+v_(l) decays,which deviate from their sM predictions,we hve investigated these decays in W' model and scalar leptoquark model to determine potential signatures of new physics(NP) in semileptonic charm decays induced by c→(s,d)l+v_(l) *** recent experimental results of branching fractions for semileptonic D meson decays,new coupling parameters are predicted for the aforementioned NP *** fraction,forward-backward asymmetry,and lepton polarization asymmetry are examined by considering the predicted NP coupling *** results of branching fractions in scalar leptoquark model are found very close to the experimental results and exist around the range of 1σ *** presented a comparative study of the NP models to check their sensitivity on these *** anticipate that further research on these decays will significantly support our findings.

关键词： charm decay new physics W′boson scalar leptoquark flavour changing charged current

Astrophysical s-factor and reaction rate for 15N(p,γ)16O within the modified potential cluster model

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Chinese Physics C 2024年第4期48卷 130-145页

作者： s.B.Dubovichenko A.s.Tkachenko R.Ya.Kezerashvili N.A.Burkova B.M.Yeleusheva Fesenkov Astrophysical Institute 050020 AlmatyKazakhstan New York City College of Technology City University of New YorkBrooklyn11201 New YorkUSA Graduate school and University Center City University of New York10016 New YorkUSA al-Farabi Kazakh National University 050040 AlmatyKazakhstan

We study radiative p^(15)N capture on the ground state of ^(16)O at stellar energies within the framework of a modified potential cluster model(MPCM)with forbidden states,including low-lying *** investigation of the ^(15)N(p,γ0)^(16)O reaction includes the consideration of ^(3)s_(1) resonances due to E1 transitions and the contribution of the ^(3)P_(1) scattering wave in the p+^(15)N channel due to the ^(3)P_(1)→^(3)P_(0)M1 *** calculated the astrophysical low-energy s-factor,and the extrapolated s(0)turned out to be within 34.7−40.4 keV·*** important role of the asymptotic constant(AC)for the ^(15)N(p,γ0)16O process with interfering ^(3)s_(1)(312)and ^(3)s_(1)(962)resonances is elucidated.A comparison of our calculation for the s-factor with existing experimental and theoretical data is addressed,and a reasonable agreement is *** reaction rate is calculated and compared with the existing *** has negligible dependence on the variation of AC but shows a strong impact of the interference of ^(3)s_(1)(312)and ^(3)s_(1)(962)resonances in reference to the CNO Gamow windows,especially at low *** estimate the contribution of cascade transitions to the reaction rate based on the exclusive experimental data from ***.C.85,065810(2012).The reaction rate enhancement due to the cascade transitions is observed from T_(9)>0.3 and reaches the maximum factor~1.3 at T_(9)=*** present the Gamow energy window and a comparison of rates for radiative proton capture reactions ^(12)N(p,γ)^(13)O,^(13)N(p,γ)^(14)O,^(14)N(p,γ)^(15)O,and ^(15)N(p,γ)^(16)O obtained in the framework of the MPCM and provide the temperature windows,prevalence,and significance of each process.

关键词： low and astrophysical energies p^(15)N system thermonuclear reaction rate potential cluster model CNO-cycle

The autophagy protein Atg9 functions in glia and contributes to parkinsonian symptoms in a Drosophila model of Parkinson’s disease

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Neural Regeneration Research 2024年第5期19卷 1150-1155页

作者： shuanglong Yi Linfang Wang Margaret s.Ho shiping Zhang school of Life science and Technology ShanghaiTech UniversityShanghaiChina College of Life sciences University of Chinese Academy of SciencesBeijingChina

Parkinson’s disease is a progressive neurodegenerative disease characterized by motor deficits,dopaminergic neuron loss,and brain accumulation ofα-synuclein aggregates called Lewy *** in protein degradation pathways,such as autophagy,has been demonstrated in neurons as a critical mechanism for eliminating protein aggregates in Parkinson’s ***,it is less well understood how protein aggregates are eliminated in glia,the other cell type in the *** the present study,we show that autophagy-related gene 9(Atg9),the only transmembrane protein in the autophagy machinery,is highly expressed in Drosophila glia from adult *** from immunostaining and live cell imaging analysis reveal that a portion of Atg9 localizes to the trans-Golgi network,autophagosomes,and lysosomes in ***9 is persistently in contact with these *** glial atg9 reduces the number of omegasomes and autophagosomes,and impairs autophagic substrate *** suggests that glial Atg9 participates in the early steps of autophagy,and hence the control of autophagic ***,loss of glial atg9 induces parkinsonian symptoms in Drosophila including progressive loss of dopaminergic neurons,locomotion deficits,and glial *** findings identify a functional role of Atg9 in glial autophagy and establish a potential link between glial autophagy and Parkinson’s *** results may provide new insights on the underlying mechanism of Parkinson’s disease.

关键词： Atg9 autophagy glia Parkinson’s disease

Uniform assembly of gold nanoparticles on s-doped g-C3N4 nanocomposite for effective conversion of 4-nitrophenol by catalytic reduction

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Journal of Materials science & Technology 2020年第5期40卷 176-184页

作者： Vellaichamy Balakumar Hyungjoo Kim Ji Won Ryu Ramalingam manivannan Young-A son Department of Advanced Organic Materials Engineering Chungnam National University220 Gung-dongYuseong-guDaejeon305-764South Korea

In this work,a simple synthesis of sulfur doped graphitic carbon nitride(s-g-C3N4)act as a support cum stabilizers for gold nanoparticles(Au)and its was characterized by UV–vis and XRD to measure the absorbance and crystallinity,*** functional group and morphology of the samples were identified using FT-IR and ***,the Au@s-g-C3N4 nanocatalyst exhibits good catalytic performance and stability in the reduction of hazardous 4-nitrophenol(NP)compared to s-g-C3N4 using Na ***,the Au@s-g-C3N4 nanocomposite holds a good catalytic efficiency(near 100%)achieved by within 5 *** highest catalytic reduction of NP is due to the synergistic effect of Au nanoparticles decorated on *** fast electron transfer reduction mechanism was elucidated and *** reusability and stability of the developed nanocomposites were also observed in consecutive reduction *** filtering and catalyzing device was used for the direct conversion of NP polluted *** method can open a new avenue for the metal nanoparticles based carbon materials heterogeneous catalyst and its reduction of toxic contaminants.

关键词： Gold nanoparticles s-doped g-C3N4 Catalytic reduction 4-nitrophenol

synthesis, Characterization and Gas sensing Properties of Graphene Oxide-Multiwalled Carbon Nanotube Composite

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Journal of Materials science & Technology 2016年第7期32卷 626-632页

作者： T. Kavinkumar s. manivannan Carbon Nanomaterials Laboratory Department of Physics National Institute of Technology Tiruchirappalli 620 015 India

Graphene oxide （GO）-multiwalled carbon nanotube （MWCNT） composite was synthesized and characterized by X-ray diffraction, atomic force microscopy, scanning electron microscopy, micro Raman, Fourier transform infrared and ultraviolet-visible near infrared spectroscopy techniques. spectral characteris- tics of cladding modified fiber optic gas sensors were studied for various concentrations of ammonia, ethanol and methanol at 27 ℃. Thickness of the gas sensing layer was controlled by varying the concentration of composite in ethanol medium （0.5 and 1 mg/mL） for three times dipping process. The O.s mg/ mL concentrated GO-MWCNT coated sensor showed 1.20, 1.40 and 1.15 times higher sensitivity than the GO coated sensor for ammonia, ethanol and methanol vapors, respectively. Furthermore, it exhibited 1.50, 1.80 and 1.80 times better sensitivity than 1 mg/mL concentrated GO-MWCNT coated sensor for ammonia, ethanol and methanol vapors, respectively. The presence of functional groups in GO increased the sen- sitivity. This is mainly attributed to the effective electron charge transfer between the composite materials and analytes.

关键词： Graphene oxide (GO) Multiwalled carbon nanotube (MWCNT) Fiber optic gas sensor GO-MWCNT composite

The Ca^(2+)-sensing receptor and the pocketome:comparing nature's complexity with human intervention in receptor modulation

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signal Transduction and Targeted Therapy 2024年第8期9卷 3153-3154页

作者： Edda s.F.Matthees Carsten Hoffmann Institut fur Molekulare Zellbiologie CMB-Center for Molecular BiomedicineUniversitatsklinikum JenaHans-Knoll StraBe 2D-07745 JenaGermany Friedrich-schiller-Universitat Jena Hans-KnollStraBe2D-07745 JenaGermany

In a recent paper published in Nature,the relatively understudied Ca^(2+)-sensing,receptor(CasR)within the Gprotein-coupled receptor(GPCR)family C,gained attention due to pioneering research led by Georgios skiniotis ... 详细信息

关键词： stanford gained skin