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synthesis of coral-like structures of Pr-Yb co-doped YIG: structural,optical, magnetic and antimicrobial properties

journal of Rare Earths 2024年第3期42卷 543-554,I0004页

作者： A.Fernandez Francisca P.Araujo Y.Guerra s.Castro-Lopes j.Matilla-Arias Idglan s.de Lima Edson C.silva-Filho josy A.Osajima F.Guerrero R.Pena-Garcia Federal University of Piau Graduate Program in Materials Science and EngineeringTeresinaPIBrazil Federal Rural University of Pernambuco Academic Unit of Cabo de Santo AgostinhoCabo de Santo AgostinhoPEBrazil Federal University of Piaui Department of PhysicTeresinaPBrazil Federal University of Pernambuco Graduate Program in Materials ScienceRecifePEBrazil University of Granma Departmentof Basic Sciences and Applied InformaticsFaculty of Technical SciencesBayamoCuba Federal University of Amazonas Department of PhysicManausAMBrazil Federal University of Pernambuco Department of PhysicRecifePEBrazil

Coral-like structures of the Y_(3-x)Pr_(x)Fe_(5-y)Yb_(y)O_(12),(0.00 ≤ x ≤ 0.04, 0.00 ≤ y ≤ 0.02) compound were synthesized using the sol-gel method. structural investigation certified the YIG cubic crystal structure formation, without any secondary phase. It is shown that, the relatively large ionic radius of the dopant cations results in an expansion of the lattice parameter, variations in the Iona-O-Iondangle, Iona-O,Iond-O and Ionc-O bond distances and decrease in the average crystallite size. Fourier transform infrared(FTIR) and Raman measurements are essential to testify the single-phase formation of YIG crystal structure and are observed changes in the stretching and vibrational modes, respectively. The morphological study, energy dispersive spectroscopy(EDs) spectra and textural properties show corallike structures, peaks associated with Pr^(3+) and Yb^(3+) atoms and the effect of dopants on surface area,diameter, and pore volume, respectively. The optical analysis from diffuse reflectance spectra witnessed an increase in the optical gap band, a decrease in Urbach energy and blue shift in the charge transfer,correlated with the expansion of the unit cell due to the dopant's insertion in the YIG structure. A typical ferrimagnetic behavior is exhibited by the Y_(3-x)Pr_(x)Fe_(5-y)Yb_(y)O_(12)compound. The saturation magnetization(M_(s)), cubic anisotropy constant(K_(1)) and coercive field(H_(c)) increase with the Pr^(3+)cations content, as consequence of their magnetic nature and distribution around of Fe^(3+)ions due to the coexistence with the Yb^(3+). Finally, for the first time, antibacterial tests by mean of the direct contact method were performed for YIG co-doped with Pr^(3+)and Yb^(3+)and it is shown that, relatively high dosages of Pr^(3+) cations favored the activity against s. aureus, therefore, a new biological property for YIG doped with rare earths is presented.

关键词： Yttrium iron garnet(YIG) Coral-like structures Rare earths Band gap energy Magnetic properties Antimicrobial properties

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Exploring the effects of taurolidine on tumor weight and microvessel density in a murine model of osteosarcoma

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Oncology Research 2024年第7期32卷 1163-1172页

作者： LIsANNE K.A.NEIjENHUIs LEUTA L.NAUMANN sONIA A.M.FERKEL sAMUEL j.s.RUBIN sTEPHAN ROGALLA Division of Gastroenterology and Hepatology Department of MedicineSchool of MedicineStanford UniversityStanford94305USA Department of surgery Leiden University Medical CenterLeiden2333 ZAThe Netherlands Centre for Human Drug Research Leiden2333 CLThe Netherlands Department of General VisceralVascular and Thoracic SurgeryCharite University Medicine BerlinBerlin10117Germany

Background:Osteosarcoma is the most common malignant primary bone *** prognosis for patients with disseminated disease remains very poor despite recent advancements in ***,current treatment regimens bear a signiﬁcant risk of serious side ***,there is an unmet clinical need for effective therapies with improved safety proﬁ*** is an antibacterial agent that has been shown to induce cell death in different types of cancer cell ***:In this study,we examined both the antineoplastic and antiangiogenic effects of taurolidine in animal models of osteosarcoma.K7M2 murine osteosarcoma cells were injected,both intramuscular and intraperitoneal,into 60 BALB/c mice on day *** were then randomized to receive treatment with taurolidine 2%(800 mg/kg),taurolidine 1%(400 mg/kg),or NaCl 0.9%control for seven days by intravenous or intraperitoneal ***:After 35 days,mice were euthanized,and the tumors were harvested for *** mice were excluded from the analysis due to *** weight was signiﬁcantly lower in the 2%taurolidine intraperitoneal treatment group from day 9 to 21,consistent with elevated mortality in this *** tumor weight was signiﬁcantly lower in the 1%(p=0.003)and 2%(p=0.006)intraperitoneal taurolidine treatment groups compared to the *** antineoplastic effects were observed on intramuscular tumors or for intravenous administration of *** were no signiﬁcant differences in microvessel density or mitotic rate between treatment *** body weight and elevated mortality in the 2%taurolidine intraperitoneal group suggest that the lower 1%dose is ***:In conclusion,there is no evidence of antiangiogenic activity,and the antitumor effects of taurolidine on osteosarcoma observed in this study are ***,its toxic proﬁle grants further *** these observations,further research is necessary to

关键词： Osteosarcoma Taurolidine Cancer treatment Chemotherapy Murine models

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Feeding ecology and interactions with mammal hosts in a symbiotic genus of birds(Buphagus spp.)in Namibia

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Avian Research 2024年第3期15卷 336-344页

作者： Michael s.Lukubwe Daniel Velarde-Garcéz Fernando sequeira susana Lopes Adrian j.F.K.Craig Vanessa A.Mata Department of Zoology and Entomology Rhodes UniversityMakhandaSouth Africa Department of Wildlife Management and Tourism studies University of NamibiaKatima Mulilo CampusNamibia Departamento de Biologia Faculdade de CiênciasUniversidade do PortoPortoPortugal CIBIO Centro de Investigação em Biodiversidade e Recursos GenéticosInBIO Laboratório AssociadoCampus de VairãoVairãoPortugal BIOPOLIs Program in Genomics Biodiversity and Land PlanningCIBIOCampus de VairãoVairãoPortugal

As the sole obligate symbiotic birds in Africa,oxpeckers offer a unique model for studying symbiotic *** to the multitrophic level they occupy and the context dependent foraging behavior they exhibit,the type of symbiotic relationship can be *** addition to providing a cleaning service to the host by removing ticks,oxpeckers frequently feed on blood,mucus,and saliva,inflicting potential damage on the ***,we used DNA metabarcoding on faecal samples to analyze the taxonomic composition of the trophic interactions of the Yellow-billed Oxpecker(Buphagus africanus)and Red-billed Oxpecker(***)in northeastern *** contrast to conventional methods,DNA metabarcoding allows for a detailed identification of dietary resources encompassing both mammal hosts and consumed arthropods within the same *** this information,we examined differences in the diet composition between oxpecker species and localities,as well as the co-occurrence between host and arthropod *** findings revealed that oxpeckers predominantly source their diet from mammals,ticks,and flies;however,ticks and flies rarely co-occur in the diet of an *** observed variability among individuals in their feeding ecology,which is strongly correlated with locality and,to a lesser extent,with the mammal *** noted a high degree of mobility between hosts within relatively short periods,with 32%of the samples showing traces of at least two mammal *** study illustrates the dynamic foraging behavior of these specialized symbiotic birds,shedding light on their potential role in pest control services and disease transmission.

关键词： Commensalism Diet DNA metabarcoding Oxpeckers Parasitism Trophic ecology

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A facile strategy for tuning the density of surface-grafted biomolecules for melt extrusion-based additive manufacturing applications

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Bio-Design and Manufacturing 2024年第3期7卷 277-291页

作者： I.A.O.Beeren G.Dos santos P.j.Dijkstra C.Mota j.Bauer H.Ferreira Rui L.Reis N.Neves s.Camarero-Espinosa M.B.Baker L.Moroni Department of Complex Tissue Regeneration MERLN Institute for Technology-Inspired Regenerative MedicineMaastricht University6229 ER MaastrichtThe Netherlands 3B’s Research Group I3Bs–Research Institute on BiomaterialsBiodegradables and BiomimeticsHeadquarters of the European Institute of Excellence on Tissue Engineering and Regenerative MedicineUniversity of MinhoAveParkZona Industrial da Gandra4805-017 BarcoGuimarãesPortugal ICVs/3B’s-PT Government Associate Laboratory 4806-909 Braga/GuimarãesPortugal POLYMAT University of the Basque Country UPV/EHU20018 Donostia/San SebastiánSpain IKERBAsQUE Basque Foundation for Science48009 BilbaoSpain

Melt extrusion-based additive manufacturing(ME-AM)is a promising technique to fabricate porous scaffolds for tissue engi-neering ***,most synthetic semicrystalline polymers do not possess the intrinsic biological activity required to control cell *** of biomolecules on polymeric surfaces of AM scaffolds enhances the bioactivity of a construct;however,there are limited strategies available to control the surface ***,we report a strategy to tune the surface density of bioactive groups by blending a low molecular weight poly(ε-caprolactone)5k(PCL5k)containing orthogonally reactive azide groups with an unfunctionalized high molecular weight PCL75k at different *** porous three-dimensional(3D)scaf-folds were then fabricated using a high weight percentage(75 wt.%)of the low molecular weight PCL *** a proof-of-concept test,we prepared films of three different mass ratios of low and high molecular weight polymers with a thermopress and reacted with an alkynated fluorescent model compound on the surface,yielding a density of 201-561 pmol/cm^(2).subsequently,a bone morphogenetic protein 2(BMP-2)-derived peptide was grafted onto the films comprising different blend compositions,and the effect of peptide surface density on the osteogenic differentiation of human mesenchymal stromal cells(hMsCs)was *** two weeks of culturing in a basic medium,cells expressed higher levels of BMP receptor II(BMPRII)on films with the conjugated *** addition,we found that alkaline phosphatase activity was only significantly enhanced on films contain-ing the highest peptide density(i.e.,561 pmol/cm^(2)),indicating the importance of the surface *** together,these results emphasize that the density of surface peptides on cell differentiation must be considered at the cell-material ***,we have presented a viable strategy for ME-AM community that desires to tune the bulk and surface functionality via blending of(m

关键词： Additive manufacturing Blending surface functionalization surface density Click chemistry Human

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Pharmacological methods for ovarian function and fertility preservation in women with cancer:A literature review

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Oncology Research 2024年第8期32卷 1309-1322页

作者： ANA s.CVETANOVIC MATTEO LAMBERTINI KEVIN PUNIE GORANA G.MATOVINA BRKO NIKOLA D.ZIVKOVIC MAjA j.POPOVIC MARIjANA M.MILOVIC KOVACEVIC LAZAR s.POPOVIC Department for Oncology Medical Faculty NisUniversity of NisNis18000Serbia Clinic of Oncology University Clinical Centre NisNis18000Serbia Department of Internal Medicine and Medical sciences(DiMI) School of MedicineUniversity of GenovaGenova16100Italy Department of Medical Oncology U.O.C Clinica di Oncologia MedicaIRCCS Ospedale Policlinico San MartinoGenova16100Italy Department of General Medical Oncology and Multidisciplinary Breast Centre Leuven Cancer InstituteUniversity Hospitals LeuvenLeuven3001Belgium Department of Medical Oncology Oncology Institute of VojvodinaSremska Kamenica21208Serbia Department for Pathology Medical Faculty NisUniversity of NisNis18000Serbia Center for Pathology University Clinical Centre NisNis18000Serbia Faculty of Medicine University of Novi SadNovi Sad21000Serbia Department of Medical Oncology Institute of Oncology and Radiology SerbiaBelgrade11000Serbia

Oncofertility is an extremely signiﬁcant topic that is increasingly being discussed owing to increased evidence indicating that fertility preservation does not affect the treatment outcomes of patients with cancer but signiﬁcantly contributes to preserving life *** effect of chemotherapy can range from minimal effects to complete ovarian *** data are available on the effects of monoclonal antibodies and targeted therapies on the ovaries and *** ovarian suppression by administering a gonadotropin-releasing hormone agonist(GnRHa)during chemotherapy decreases the gonadotoxic effect of chemotherapy,thereby diminishing the chance of developing premature ovarian insufﬁciency(POI).At present,the concomitant administration of GnRH analogs during chemotherapy is the only accepted pharmacological method for preserving ovarian ***,most randomized studies on the effectiveness of luteinizing hormone-releasing hormone agonists during chemotherapy in preventing POI have been conducted in women with breast cancer,with a considerably small number of studies on patients with hematological ***,most randomized controlled trials on breast cancer have revealed a decrease in treatment-induced POI risk,regardless of the hormone receptor *** addition,studies on hematological malignancies have yielded negative results;nevertheless,theﬁndings must be interpreted with caution owing to numerous *** guidelines from the American society of Clinical Oncology and EsMO Clinical Practice Guidelines recommend sperm,oocyte,and embryo cryopreservation as a standard practice and only offering GnRHa to patients when proven fertility preservation methods are not *** this manuscript,we present a comprehensive literature overview on the application of ovarian suppression with GnRHa during chemotherapy in patients with cancer by addressing preclinical and clinical data,as well as future perspectives in thisﬁeld

关键词： Gonadotropin-releasing hormone agonists(GnRHa) Fertility preservation Premature ovarian insufficiency(POI) Premenopausal patients

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Effects of low molecular weight polysaccharide from sargassum thunbergii against palmitic acid-induced intracellular lipid accumulation in 3T3-L1 adipocyte and HepG2 cells

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Food science and Human Wellness 2024年第4期13卷 2244-2252页

作者： Hyo-Geun Lee D.P.Nagahawatta M.j.M.s.Kurera Kyung-Mo song Yun-sang Choi You-jin jeon Min-Cheol Kang Department of Marine Life sciences Jeju National UniversityJeju 63243Republic of Korea Department of Biotechnology Faculty of Agriculture and Plantation ManagementWayamba University of Sri LankaMakanduraGonawila(NWP)60170Sri Lanka Research Group of Food Processing Korea Food Research Institute245Wanju 55365Republic of Korea

Low molecular weight polysaccharides can be isolated from sargassum thunbergii(LMPsT)and in vitro experiments were conducted to evaluate the inhibitory effects on *** natures of LMPsT were attained from *** and appraised their LMPsT on palmitic acid(PA)induced lipid accretion in Hep G2,and 3T3-L1 *** treatment lessened lipid deposition and intracellular free fatty acid and triglyceride intensities in PA-treated above mentioned *** mechanistic study publicized that LMPsT2 significantly suppressed adipogenesis and stimulated the PA-treated 3T3-L1 cells occupied in the lipolysis ***,in PA-treated Hep G2 cells,the free fatty acid oxidation was significantly increased by *** these constructive properties of LMPsT2 from ***,is a potential candidate for diminishing the intracellular lipids,and for a therapeutic agent in those conditions.

关键词： sargassum thunbergii Low molecular weight polysaccharide Lipid accumulation Obesity Liver steatosis

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Entropy generation minimization in the Carreau nanofluid flow over a convectively heated inclined plate with quadratic thermal radiation and chemical reaction:A stefan blowing application

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Propulsion and Power Research 2024年第2期13卷 233-244页

作者： B.Lavanya j.Girish Kumar M.jayachandra Babu C.s.K.Raju Bander Almutairi Nehad Ali shah Department of Mathematics Manipal Institute of TechnologyManipal Academy of Higher EducationManipalKarnataka 576104India Department of Mathematics S.V.A Government CollegeSrikalahasti 517644India Department of Mathematics GITAM School of Science(GSS)GITAMBangaloreKarnatakaIndia Department of Mathematics College of ScienceKing Saud UniversityRiyadh 11451Saudi Arabia Department of Mechanical Engineering Sejong UniversitySeoul 05006South Korea

Entropy analysis can help to identify the sources of entropy generation in a heat transfer process more accurately than other methods,such as energy efﬁciency *** is because entropy analysis takes into account the quality of energy as well as its ***-noﬂuids have already been shown to have superior heat transfer characteristics compared to conventionalﬂ*** blowing can further enhance the heat transfer capabilities of nano-ﬂuids by increasing the massﬂux and turbulence at the *** can be beneﬁcial in a wide range of applications,such as heat exchangers,electronic cooling,and solar energy *** convective boundary condition accounts for heat transfer effects,inﬂuencing temperature distribution and the thermal boundary *** on the direction of heat transfer,the convective boundary condition can induce cooling or heating effects on the inclined *** has practical implications for various engineering applications,such as the cooling of electronic devices or heating in industrial *** nanofluids have a wide range of potential applications in heat transfer,energy storage,drug delivery,and food *** research investigates how the presence of stefan blowing affects the properties of Carreau nanofluid flow across a convectively heated tilted *** and mass transport phenomena are studied using quadratic thermal radiation and chemical reaction *** mathematical model for this work is based on the Buongiorno *** governing equations are converted into a system of ordinary differential equations and then solved using the bvp4c *** parameters such as the mass transfer rate can be visualized using bar *** study’s primary findings are that when the Weissenberg number increases,the velocity rises and the concentration profile declines due to Brownian *** is discovered that,when 0.5≤γ≤3(the inverse porosity parameter),the friction factor declines by 0.34001(

关键词： Thermal radiation BVP4C stefan blowing Biot number Brownian motion Irreversibilit

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Optimization of a photovoltaic-battery system using deep reinforcement learning and load forecasting

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Energy and AI 2024年第2期16卷 168-183页

作者： António Corte Real G.Pontes Luz j.M.C.sousa M.C.Brito s.M.Vieira IDMEC Instituto Superior TécnicoUniversidade de LisboaLisboa1049-001Portugal Instituto Dom Luiz Faculdade de CiênciasUniversidade de LisboaCampo Grande1749-016LisboaPortugal

Home Energy Management systems(HEMs)are increasingly relevant for demand-side management at the residential level by collecting data(energy,weather,electricity prices)and controlling home appliances or storage *** control can be performed with classical models that find optimal solutions,with high real-time computational cost,or data-driven approaches,like Reinforcement Learning,that find good and flexible solutions,but depend on the availability of load and generation data and demand high computational resources for *** this work,a novel HEMs is proposed for the optimization of an electric battery operation in a real,online and data-driven environment that integrates state-of-the-art load forecasting combining CNN and LsTM neural networks to increase the robustness of *** Reinforcement Learning agents are trained with different algorithms(Double DQN,Dueling DQN,Rainbow and Proximal Policy Optimization)in order to minimize the cost of electricity purchase and to maximize photovoltaic self-consumption for a PV-Battery residential *** show that the best Reinforcement Learning agent achieves a 35%reduction in total cost when compared with an optimization-based agent.

关键词： Energy management system Deep reinforcement learning Demand-side management Load forecasting Deep learning Energy storage systems

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Deploying Hybrid EnsembleMachine Learning Techniques for Effective Cross-site scripting (Xss) Attack Detection

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Computers, Materials and Continua 2024年第1期81卷 707-748页

作者： Bacha N.U. Lu s. Ur Rehman A. Idrees M. Ghadi Y.Y. Alahmadi T.j. school of Cyber science and Engineering Huazhong University of Science and Technology Wuhan 430073 China Department of Computer science and Engineering University of Engineering and Technology Lahore 54000 Pakistan Department of Computer science and software Engineering Al Ain University Al Ain Abu Abu Dhabi 12555 United Arab Emirates Department of Information systems College of Computer and Information Sciences Princess Nourah bint Abdulrahman University Riyadh 84428 Saudi Arabia

Cross-site scripting (Xss) remains a significant threat to web application security, exploiting vulnerabilities to hijack user sessions and steal sensitive data. Traditional detection methods often fail to keep pace with the evolving sophistication of cyber threats. This paper introduces a novel hybrid ensemble learning framework that leverages a combination of advanced machine learning algorithms-Logistic Regression (LR), support Vector Machines (sVM), eXtreme Gradient Boosting (XGBoost), Categorical Boosting (CatBoost), and Deep Neural Networks (DNN). Utilizing the Xss-Attacks-2021 dataset, which comprises 460 instances across various real-world trafficrelated scenarios, this framework significantly enhances Xss attack detection. Our approach, which includes rigorous feature engineering and model tuning, not only optimizes accuracy but also effectively minimizes false positives (FP) (0.13%) and false negatives (FN) (0.19%). This comprehensive methodology has been rigorously validated, achieving an unprecedented accuracy of 99.87%. The proposed system is scalable and efficient, capable of adapting to the increasing number of web applications and user demands without a decline in performance. It demonstrates exceptional real-time capabilities, with the ability to detect Xss attacks dynamically, maintaining high accuracy and low latency even under significant loads. Furthermore, despite the computational complexity introduced by the hybrid ensemble approach, strategic use of parallel processing and algorithmtuning ensures that the system remains scalable and performs robustly in real-time applications. Designed for easy integration with existing web security systems, our framework supports adaptable Application Programming Interfaces (APIs) and a modular design, facilitating seamless augmentation of current defenses. This innovation represents a significant advancement in cybersecurity, offering a scalable and effective solution for securing modern web applications a

关键词： Cross-site scripting hybrid learning machine learning stacking ensemble learning Xss detection

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Chronic disease patients have fewer social contacts:A pilot survey with implications for transmission dynamics

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Infectious Disease Modelling 2024年第3期9卷 926-930页

作者： j.Vanderlocht s.Møgelmose K.Van Kerckhove P.Beutels N.Hens Interuniversity Institute of Biostatistics and statistical Bioinformatics Data Science InstituteHasselt UniversityHasseltBelgium Centre for Health Economic Research and Modelling Infectious Diseases University of AntwerpAntwerpBelgium

Non-communicable diseases(NCD)are the most important cause of death in the *** socio-economic costs associated with NCDs makes it imperative to prevent and control them in the 21st *** severe toll that the COVID-19 pandemic has taken worldwide is an unfortunate illustration of our limited insight into the infectious risk for the global ***-incidence between NCD and infection offers an underexplored opportunity to design preventive *** a pilot survey,we observed that the NCD population displays a substantial reduction in their social contacting behavior as compared to the general *** indicates that existing mathematical models based on contact surveys in the general population are not applicable to the NCD population and that the risk of acquiring an infection following a contact is probably *** demonstration of reduced social mixing in several chronic conditions,raises the question to what extent the social mixing is influenced by the burden of *** advocate the design of disease-specific contact surveys to address how the burden of disease associates with social contact behavior and the risk of *** sARs-CoV-2 pandemic offers an unprecedented opportunity to gain insight into the importance of infection in the NCD population and to find ways to improve healthcare procedures.

关键词： survey mixing insight

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