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Engineering of efficient visible light photocatalysts:Ti_(1-x+y)Cu_(x)La_(y)O_(2)(x=0.03;y=0,0.005,0.01) compositions

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Journal of Rare Earths 2024年第3期42卷 497-505,I0003页

作者： s.M.Yakout A.M.Youssef Inorganic Chemistry Department National Research Centre(NRC)El Buhouth StDokkiCairo12622Egypt

In dye-photocatalysis, widening the wavelengths absorption range of catalysts as well as aborting the recombination of the photoexcited charge carriers(electrons-holes pairs) are of paramount *** the current study, we report the photocatalytic characteristics of four compositions composed of TiO_(2),Ti_(0.97)Cu_(0.03)O_(2), Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders for two harmful dyes(Congo red and methylene blue). The X-ray diffraction technique verified the configuration of mixed anatase and rutile phases in pure TiO_(2)and Ti_(0.97)Cu_(0.03)O_(2)powders while Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders possess anatase phase only. The changes of the band gap structure and dimensions of the unit cell volume of TiO_(2)confirm the substitution of Ti^(4+)sites by Cu^(2+)and La^(3+)ions. Remarkable widening of wavelengths absorption with formation of long absorption tails were found in TiO_(2)(3.13 e V) through insertion of La^(3+)plus Cu^(2+)ions. Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)samples exhibit a visible light band gap of 2.3 and 2.7 e V, respectively. Based on sEM images, incorporation of Cu^(2+)and La^(3+)ions influences the surface morphology of TiO_(2). The resulting Ti_(0.97)Cu_(0.03)O_(2), Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders present enhanced photocatalytic activity towards Congo red dye degradation compared to pure one under natural solar spectrum. The best Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)catalyst exhibits superior photocatalytic activity of 96% for 10 ppm CR dye in 20 min as well as above average photocatalytic efficiency of 63% for 30 ppm CR dye in 120 min. As well, it showed acceptable photodegradation activity of 52% for 30 ppm MB solution in 140 min of sunlight irradiation. The heightened photodegradation efficiency of Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)catalyst can be clarified in terms of higher ch

关键词： semiconductor TiO_(2) Rare earths Congo red Methylene blue solar spectrum Photodegradation

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Mathematical modeling and simulations of stress mitigation by coating polycrystalline particles in lithium-ion batteries

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Applied Mathematics and Mechanics(English Edition) 2024年第6期45卷 947-962页

作者： N.IQBAL J.CHOI s.F.sHAH C.LEE s.LEE Department of Mechanical Roboticsand Energy EngineeringDongguk University-SeoulSeoul 04620Republic of Korea

A chemo-mechanical model is developed to investigate the effects on the stress development of the coating of polycrystalline Ni-rich LiNixMnyCo_(z)O_(2)(x≥0.8)(NMC)particles with poly(3,4-ethylenedioxythiophene)(PEDOT).The simulation results show that the coating of primary NMC particles significantly reduces the stress generation by efficiently accommodating the volume change associated with the lithium diffusion,and the coating layer plays roles both as a cushion against the volume change and a channel for the lithium transport,promoting the lithium distribution across the secondary particles more ***,the lower stiffness,higher ionic conductivity,and larger thickness of the coating layer improve the stress *** paper provides a mathematical framework for calculating the chemo-mechanical responses of anisotropic electrode materials and fundamental insights into how the coating of NMC active particles mitigates stress levels.

关键词： lithium-ion battery(LIB) polycrystalline particle coating finite element simulation Ni-rich LiNixMnyCo_(z)O_(2)(x>0.8)(NMC)

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Decomposition solutions and Bäcklund transformations of the B-type and C-type Kadomtsev-Petviashvili equations

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Communications in Theoretical Physics 2024年第6期76卷 34-44页

作者： Xiazhi Hao s Y Lou College of science Zhejiang University of TechnologyHangzhou 310014China school of Physical science and Technology Ningbo UniversityNingbo 315211China

This paper introduces a modified formal variable separation approach,showcasing a systematic and notably straightforward methodology for analyzing the B-type Kadomtsev-Petviashvili(BKP)*** the application of this approach,we successfully ascertain decomposition solutions,Bäcklund transformations,the Lax pair,and the linear superposition solution associated with the aforementioned ***,we expand the utilization of this technique to the C-type Kadomtsev-Petviashvili(CKP)equation,leading to the derivation of decomposition solutions,Bäcklund transformations,and the Lax pair specific to this *** results obtained not only underscore the efficacy of the proposed approach,but also highlight its potential in offering a profound comprehension of integrable behaviors in nonlinear ***,this approach demonstrates an efficient framework for establishing interrelations between diverse systems.

关键词： decomposition solution Backlund transformation Lax pair linear superposition solution

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Plethysmograph training:A refinement for collection of respiration data in mice

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动物模型与实验医学(英文) 2023年第4期6卷 369-374页

作者： Jorid B.s.rli Karin s.Hougaard Niels Hadrup Chemical Work Environment The National Research Centre for the Working EnvironmentCopenhagenDenmark Department of Public Health University of CopenhagenCopenhagenDenmark Research Group for Risk-Benefit National Food InstituteTechnical University of DenmarkLyngbyDenmark

Inhaled chemicals can harm the *** effects can result in distinct changes in respiratory patterns;the type of change indicates where and how the respiratory system is ***,changes in respiratory patterns may be detected at much lower substance concentrations than those that cause more serious effects,such as histopathological *** in respiratory patterns can be studied experimentally by monitoring the breathing of mice placed in plethysmographs and exposing head-out to the test *** method is well established;however,it is not known if training mice in being restrained in the plethysmograph could increase the quality of data *** we report the results of training mice to be restrained in plethysmographs for 5 consecutive days,with respect to body weight,respiratory parameters,and time spent in the plethysmograph,before they are removed because of unstable breathing *** mice tolerated the procedure better(measured by time in the plethysmograph)on the second day of training than the first *** did not change the breathing parameters between *** parameters stabilized within 5 min after the mice were placed in the plethysmographs on all *** was an average of 3%weight loss between the first and last days of the training,indicating that the training procedure placed some strain on the *** reduces the number of mice attempting to escape from the plethysmograph.

关键词： Alarie assay refinement sensory irritation

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Quantized autoencoder(QAE)intrusion detection system for anomaly detection in resource-constrained loT devices using RT-loT2022 dataset

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Cybersecurity 2024年第2期7卷 13-27页

作者： B s sharmila Rohini Nagapadma Depatment of Electronics and Communication Engineering The National Institute of EngineeringMysoreKarnataka 570008India

In recent years,many researchers focused on unsupervised learning for network anomaly detection in edge devices to identify *** deployment of the unsupervised autoencoder model is computationally expensive in resource-constrained edge *** study proposes quantized autoencoder(QAE)model for intrusion detection systems to detect *** is an optimization model derived from autoencoders that incorporate pruning,clustering,and integer quantization *** autoencoder uint8(QAE-u8)and quantized autoencoder float16(QAE-f16)are two variants of QAE built to deploy computationally expensive Al models into Edge ***,we have generated a Real-Time Internet of Things 2022 dataset for normal and attack *** autoencoder model operates on normal traffic during the training *** same model is then used to reconstruct anomaly traffic under the assumption that the reconstruction error(RE)of the anomaly will be high,which helps to identify the ***,we study the performance of the autoencoders,QAE-u8,and QAE-f16 using accuracy,precision,recall,and F1 score through an extensive experimental *** showed that QAE-u8 outperforms all other models with a reduction of 70.01%in average memory utilization,92.23%in memory size compression,and 27.94%in peak CPU ***,the proposed QAE-u8 model is more suitable for deployment on resource-constrained IoT edge devices.

关键词： IoT constrained system

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A study on the Explainability of Thyroid Cancer Prediction:sHAP Values and Association-Rule Based Feature Integration Framework

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Computers, Materials & Continua 2024年第5期79卷 3111-3138页

作者： sujithra sankar s.sathyalakshmi Department of Computer Applications Hindustan Institute of Technology and ScienceChennaiTamil NaduIndia Department of Computer Engineering Hindustan Institute of Technology and ScienceChennaiTamil NaduIndia

In the era of advanced machine learning techniques,the development of accurate predictive models for complex medical conditions,such as thyroid cancer,has shown remarkable *** predictivemodels for thyroid cancer enhance early detection,improve resource allocation,and reduce ***,the widespread adoption of these models in clinical practice demands predictive performance along with interpretability and *** paper proposes a novel association-rule based feature-integratedmachine learning model which shows better classification and prediction accuracy than present *** study also focuses on the application of sHapley Additive exPlanations(sHAP)values as a powerful tool for explaining thyroid cancer prediction *** the proposed method,the association-rule based feature integration framework identifies frequently occurring attribute combinations in the *** original dataset is used in trainingmachine learning models,and further used in generating sHAP values *** the next phase,the dataset is integrated with the dominant feature sets identified through association-rule based *** new integrated dataset is used in re-training the machine learning *** new sHAP values generated from these models help in validating the contributions of feature sets in predicting *** conventional machine learning models lack interpretability,which can hinder their integration into clinical decision-making *** this study,the sHAP values are introduced along with association-rule based feature integration as a comprehensive framework for understanding the contributions of feature sets inmodelling the *** study discusses the importance of reliable predictive models for early diagnosis of thyroid cancer,and a validation framework of *** proposed model shows an accuracy of 93.48%.Performance metrics such as precision,recall,F1-score,and the area un

关键词： Explainable AI machine learning clinical decision support systems thyroid cancer association-rule based framework sHAP values classification and prediction

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Correlation Composition Awareness Model with Pair Collaborative Localization for IoT Authentication and Localization

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Computers, Materials & Continua 2024年第4期79卷 943-961页

作者： Kranthi Alluri s.Gopikrishnan school of Computer science and Engineering VIT-AP UniversityAmaravathiAndhra Pradesh522241India

secure authentication and accurate localization among Internet of Things(IoT)sensors are pivotal for the functionality and integrity of IoT *** authentication and localization are intricate and symbiotic,impacting both the security and operational functionality of IoT ***,accurate localization and lightweight authentication on resource-constrained IoT devices pose several *** overcome these challenges,recent approaches have used encryption techniques with well-known key ***,these methods are inefficient due to the increasing number of data breaches in their localization *** proposed research efficiently integrates authentication and localization processes in such a way that they complement each other without compromising on security or *** proposed framework aims to detect active attacks within IoT networks,precisely localize malicious IoT devices participating in these attacks,and establish dynamic implicit authentication *** integrated framework proposes a Correlation Composition Awareness(CCA)model,which explores innovative approaches to device correlations,enhancing the accuracy of attack detection and ***,this framework introduces the Pair Collaborative Localization(PCL)technique,facilitating precise identification of the exact locations of malicious IoT *** address device authentication,a Behavior and Performance Measurement(BPM)scheme is developed,ensuring that only trusted devices gain access to the *** work has been evaluated across various environments and compared against existing *** results prove that the proposed methodology attains 96%attack detection accuracy,84%localization accuracy,and 98%device authentication accuracy.

关键词： sensor localization IoT authentication network security data accuracy precise location access control security framework

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Evaluation of red soil-bentonite mixtures for compacted clay liners

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第2期16卷 697-710页

作者： A.s.Devapriya T.Thyagaraj Department of Civil Engineering Indian Institute of Technology MadrasChennai600036India

Compacted clay liners are an integral part of the waste landfills,which are provided to contain the leachate within the landfills and protect the surrounding ***,locally available natural soils are used for the construction of compacted clay liners if they satisfy the design ***,not all soils in their natural state satisfy all the design criteria for the liner ***,there is a definite need to modify the locally available natural soils by blending with bentonite to meet the required design criteria for the *** view of this,the present study evaluates the suitability of an Indian red soil enhanced with bentonite as a liner *** achieve this,a series of experiments were carried out using locally available red soil and ***,the suitability of the red soil was evaluated as a liner *** experimental results showed that the red soil met all the selection criteria stipulated by the Environmental Protection Agencies(EPAs)for the liners except the hydraulic conductivity ***,the red soil was mixed with bentonite contents of 10%,20%and 30%,and the red soil-bentonite mixtures were evaluated for their suitability for liners in their compacted ***,as the liners in the arid and semi-arid regions are subjected to moisture variations due to seasonal moisture fluctuations and other factors,the red soil-bentonite mixtures were subjected to wetdry cycles,and their suitability was evaluated after wet-dry *** experimental results revealed that all the red soil-bentonite mixtures met the stipulated EPA criteria for the liners in the as-compacted ***,the red soil-bentonite mixtures with 20%and 30%bentonite contents only satisfied the hydraulic conductivity requirement even after wet-dry *** experimental findings were supplemented with the microstructural insights captured through digital camera images,scanning electron microscopy(sEM),and mercury intrusion porosimetry(M

关键词： Compacted clay lines Hydraulic conductivity Wet-dry cycles Microstructure

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Big data challenge for monitoring quality in higher education institutions using business intelligence dashboards

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Journal of Electronic science and Technology 2024年第1期22卷 25-41页

作者： Ali sorour Anthony s.Atkins Faculty of Digital TechnologyInnovationand BusinessStaffordshire UniversityStoke-on-TrentST42DEUnited Kingdom

As big data becomes an apparent challenge to handle when building a business intelligence(BI)system,there is a motivation to handle this challenging issue in higher education institutions(HEIs).Monitoring quality in HEIs encompasses handling huge amounts of data coming from different *** paper reviews big data and analyses the cases from the literature regarding quality assurance(QA)in *** also outlines a framework that can address the big data challenge in HEIs to handle QA monitoring using BI dashboards and a prototype dashboard is presented in this *** dashboard was developed using a utilisation tool to monitor QA in HEIs to provide visual representations of big *** prototype dashboard enables stakeholders to monitor compliance with QA standards while addressing the big data challenge associated with the substantial volume of data managed by HEIs’QA *** paper also outlines how the developed system integrates big data from social media into the monitoring dashboard.

关键词： Big data Business intelligence(BI) Dashboards Higher education(HE) Quality assurance(QA) social media

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Evaluation of a software positioning tool to support sMEs in adoption of big data analytics

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Journal of Electronic science and Technology 2024年第1期22卷 13-24页

作者： Matthew Willetts Anthony s.Atkins Faculty of Digital TechnologyInnovationand BusinessStaffordshire UniversityStoke-on-TrentST42DEUnited Kingdom

Big data analytics has been widely adopted by large companies to achieve measurable benefits including increased profitability,customer demand forecasting,cheaper development of products,and improved stock *** and medium sized enterprises(sMEs)are the backbone of the global economy,comprising of 90%of businesses ***,only 10%sMEs have adopted big data analytics despite the competitive advantage they could *** research has analysed the barriers to adoption and a strategic framework has been developed to help sMEs adopt big data *** framework was converted into a scoring tool which has been applied to multiple case studies of sMEs in the *** paper documents the process of evaluating the framework based on the structured feedback from a focus group composed of experienced *** results of the evaluation are presented with a discussion on the results,and the paper concludes with recommendations to improve the scoring tool based on the proposed *** research demonstrates that this positioning tool is beneficial for sMEs to achieve competitive advantages by increasing the application of business intelligence and big data analytics.

关键词： Big data analytics Evaluation small and medium sized enterprises (sMEs) strategic framework

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