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Journal of Energy chemistry 2024年第3期90卷 388-411,I0010页

作者： mostafa Tarek Janaina s.santos Victor márquez mohammad Fereidooni mohammad Yazdanpanah supareak Praserthdam Piyasan Praserthdam Center of Excellence on Catalysis and Catalytic Reaction Engineering(CECC) Department of Chemical EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailan High-Performance Computing Unit(CECC-HCU) Center of Excellence on Catalysis and Catalytic Reaction Engineering(CECC)Chulalongkorn UniversityBangkok 10330Thailand

Hydrogen sulfide(H_(2)s) not only presents significant environmental concerns but also induces severe corrosion in industrial equipment,even at low *** various technologies,the selective oxidation of hydrogen sulfide(sOH_(2)s) to elemental sulfur(s) has emerged as a sustainable and environmentally friendly *** to its unique properties,iron oxide has been extensively investigated as a catalyst for sOH_(2)s;however,rapid deactivation has remained a significant *** causes of iron oxide-based catalysts deactivation mechanisms in sOH_(2)s,including sulfur or sulfate deposition,the transformation of iron species,sintering and excessive oxygen vacancy formation,and active site loss,are thoroughly examined in this *** focusing on the deactivation mechanisms,this review aims to provide valuable insights into enhancing the stability and efficiency of iron-based catalysts for sOH_(2)s.

关键词： selective oxidation of H_(2)s Iron-based Catalysts mechanism of deactivation sulfur or sulfate deposition Transformation of iron species sintering sDG 7

Rare earth-doped mixed Ni-Cu-Zn ferrites as an effective photocatalytic agent for active degradation of Rhodamine B dye

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Journal of Rare Earths 2024年第3期42卷 488-496,I0003页

作者： swapnil A.Jadhav sandeep B.somvanshi sudarshan s.Gawali Kranti Zakde K.m.Jadhav Department of Physics Dr.Babasaheb Ambedkar Marathwada UniversityAurangabad431004MaharashtraIndia school of materials Engineering Purdue UniversityWest Lafayette 47906USA University Department of Basic and Applied sciences MGM UniversityAurangabad431003MaharashtraIndia

In this study, a series of Gd^(3+)-doped mixed Ni-Cu-Zn ferrites with composition of Zn_(0.5)Ni_(0.3)Cu_(0.2)Fe_(2-x)Gd_(x)O_(4)(x = 0, 0.025, 0.05, 0.075, 0.1) was prepared using self-ignition sol-gel method. The prepared nanoparticles with an average size ranging from 22 to 26 nm show a single-phase cubic structure belonging to the spinel matrix. A rise in the Gd^(3+)concentration leads to an increase in crystallite size and lattice parameter. In Fourier transform infrared spectra, two main absorption bands belonging to the spinel structure are observed. The high-frequency bands(v_(1)) represent the tetrahedral complex, while the lowfrequency bands(v_(2)) signify the octahedral complex. The optical bandgap of the nanoferrites is found within the range of 2.91 to 2.41 eV, depending on their size. The magnetic characteristics of the material,such as saturation magnetization and coercivity are significantly altered with the concentration of Gd^(3+)in the solution. Using Rhodamine B(RhB) as a model organic pollutant, an in-depth investigation of the photocatalytic activity of the compounds was carried out. The present outcomes show that adding an adequate amount of Gd^(3+)significantly enhances the number of hydroxyl radicals produced by the ferrite,in turn, increasing the photocatalytic activity of the material. mechanism elucidated by scavenger studies reveals that ·OH and holes are the primary reactive radicals responsible for the degradation *** photocatalysts show an insignificant performance loss in five consecutive cycles. Thus, it is concluded that these photocatalysts are highly suitable for the remediation of dye-contaminated wastewater.

关键词： Gd^(3+)substitution spinel ferrite structural properties magnetic properties Photocatalysis Rare earths

Hybrid-Vlasov simulation of soft X-ray emissions at the Earth’s dayside magnetospheric boundaries

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Earth and Planetary Physics 2024年第1期8卷 70-88页

作者： m.Grandin H.K.Connor s.Hoilijoki m.Battarbee Y.Pfau-Kempf U.Ganse K.Papadakis m.Palmroth Department of Physics University of HelsinkiHelsinkiFinland NAsA Goddard space Flight Center GreenbeltMD20771USA space and Earth Observation Centre Finnish Meteorological InstituteHelsinkiFinland

solar wind charge exchange produces emissions in the soft X-ray energy range which can enable the study of near-Earth space regions such as the magnetopause,the magnetosheath and the polar cusps by remote sensing *** solar wind magnetosphere Ionosphere Link Explorer(smILE)and Lunar Environment heliospheric X-ray Imager(LEXI)missions aim to obtain soft Xray images of near-Earth space thanks to their soft X-ray Imager(sXI)*** earlier modeling works have already simulated soft X-ray images as might be obtained by smILE sXI during its mission,the numerical models used so far are all based on the magnetohydrodynamics description of the space *** investigate the possible signatures of ion-kinetic-scale processes in soft Xray images,we use for the first time a global hybrid-Vlasov simulation of the geospace from the Vlasiator *** simulation is driven by fast and tenuous solar wind conditions and purely southward interplanetary magnetic *** first produce global X-ray images of the dayside near-Earth space by placing a virtual imaging satellite at two different locations,providing meridional and equatorial *** then analyze regional features present in the images and show that they correspond to signatures in soft X-ray emissions of mirrormode wave structures in the magnetosheath and flux transfer events(FTEs)at the *** results suggest that,although the time scales associated with the motion of those transient phenomena will likely be significantly smaller than the integration time of the smILE and LEXI imagers,mirror-mode structures and FTEs can cumulatively produce detectable signatures in the soft X-ray *** instance,a local increase by 30%in the proton density at the dayside magnetopause resulting from the transit of multiple FTEs leads to a 12%enhancement in the line-of-sight-and time-integrated soft X-ray emissivity originating from this ***,a proton density increase by 14%in the magnetosheath

关键词： magnetosphere magnetosheath numerical simulation smILE LEXI soft X-ray emissions hybrid-Vlasov model polar cusp flux transfer events mirror-mode waves

Effect of solidification cooling rate on microstructure and tribology characteristics of Zn-4si alloy

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International Journal of minerals,metallurgy and materials 2024年第2期31卷 362-373页

作者： F.Akbari m.Golkaram s.Beyrami G.shirazi K.mantashloo R.Taghiabadi m.saghafi Yazdi I.Ansarian Department of metallurgy and material science Imam Khomeini International University(IKIU)Qazvin ***Iran

The main objective of this work was to modify the microstructure and enhance the tribological properties of a new Zn-4si al-loy through a high solidification cooling rate(sCR).According to the results,by increasing the sCR from 2.0 to 59.5℃/s the average size of primary si particles and that of the grains reduced from 76.1 and 3780μm to less than about 14.6 and 460μm,***-ing the sCR also enhanced the microstructural homogeneity,decreased the porosity content(by 50%),and increased the matrix hardness(by 36%).These microstructural changes enhanced the tribological *** instance,under the applied pressure of 0.5 mPa,an in-crease in the sCR from 2.0 to 59.5℃/s decreased the wear rate and the average friction coefficient of the alloy by 57%and 23%,*** wear mechanism was also changed from the severe delamination,adhesion,and abrasion in the slowly-cooled alloy to the mild tribolayer delamination/abrasion in the high-cooling-rate-solidified sample.

关键词： zinc-silicon alloy primary silicon solidification cooling rate tribology sliding wear

Kriging-boosted CR modeling for prompt infill drilling optimization

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Petroleum 2024年第1期10卷 39-48页

作者： Elizaveta s.Gladchenko Anna E.Gubanova Denis m.Orlov Dmitry A.Koroteev skolkovo Institute of science and Technology Russian Federation Digital Petroleum LLC Russian Federation

The capacitance-resistance model(CRm) has been a useful physics-based tool for obtaining production forecasts for decades. However, the model's limitations make it difficult to work with real field cases,where a lot of various events happen. such events often include new well commissioning(NWC). We introduce a workflow that combines CRm concepts and kriging into a single tool to handle these types of events during history matching. moreover, it can be used for selecting a new well placement during infill drilling. To make the workflow even more versatile, an improved version of CRm was used. It takes into account wells shut-ins and performed workovers by additional adjustment of the model coefficients. By preliminary re-weighing and interpolating these coefficients using kriging, the coefficients for potential wells can be determined. The approach was validated using both synthetic and real datasets, from which the cases of putting new wells into operation were selected. The workflow allows a fast assessment of future well performance with a minimal set of reservoir data. This way, a lot of well placement scenarios can be considered, and the best ones could be chosen for more detailed studies.

关键词： Capacitance-resistance model (CRm) Field development optimization Infill drilling Interwell connectivity Kriging New well commissioning (NWC)

Investigation of the transformation of organic matter of carbonate deposits of the semiluksky-mendymsky horizon under hydrothermal conditions

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Petroleum 2024年第2期10卷 216-223页

作者： s.m.Petrov A.I.Lakhova E.G.moiseeva A.G.safiulina Institute of Petroleum Chemistry and Nanotechnologies Kazan National Research Technological University Institute of Geology and Oil and Gas Technologies Kazan Federal University

The paper presents the results of studies on the transformation of the organic matter of siliceous-clayey carbonate rocks of the semiluksko-mendymsky horizon of the Romashkino oil field in a hydrothermal fluid for an hour（with a water-to-rock ratio of 33） at 340℃ and 380℃ and pressu res of 17 and 20 *** a result of hydrothermal treatment,at 340℃ and 17 mPa,based on nitrogen porosimetry and electron microscopy data,transformations of rock-forming minerals in the rock are *** lead to an increase in the volume and average diameter of mesopores in it and the formation of micropores,as well,which improve its filtration *** the same time,the amount of kerogen in the composition of the organic matter decreases and the yield of the petroleum hydrocarbon extract increases,in which,according to the sARA analysis,the content of asphaltenes increases and the content of resins,aromatic and saturated hydrocarbons *** the composition of aroatic hydrocarbons,the proportion of a lkyltri methyl benzenes and dibenzothiophenes increases,phenanthrene homologues appear,and in the composition of saturated hydrocarbons,the amount of iso-structure alkanes decreases relative to the content of linear *** the temperature and pressure of the hydrothermal fluid to 380℃ and 20 mPa increases the degree of kerogen conversion from 12.4% to 23.6%.At the same time,changes occurring in the component composition of petroleum hydrocarbon extracts remains similar to the experiments carried out at 340℃ and 17 mPa;the content of naphthalenes decreases,the content of dibenzothiophenes increases and C11-C17,C19-C22alkyltrimethylbenzenes *** to IR spectroscopy,with increasing temperature and pressure of the hydrothermal fluid the intensity of the absorption bands of the aromatic ring,aliphatic fragments,and oxygen-containing groups increases in resins;the structural-group composition of asphaltenes changes little:aromaticity and the content of condensed

关键词： Carbonate deposits Organic matter Hydrothermal fluid mobile hydrocarbons

Bayesian and Non-Bayesian Analysis for the sine Generalized Linear Exponential model under Progressively Censored Data

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Computer modeling in Engineering & sciences 2024年第9期140卷 2795-2823页

作者： Naif Alotaibi A.s.Al-moisheer Ibrahim Elbatal mohammed Elgarhy Ehab m.Almetwally Department of mathematics and statistics Faculty of ScienceImam Mohammad Ibn Saud Islamic University(IMSIU)Riyadh11432Saudi Arabia Department of mathematics College of ScienceJouf UniversityP.O.Box 848Sakaka72351Saudi Arabia mathematics and Computer science Department Faculty of ScienceBeni-Suef UniversityBeni-Suef62521Egypt Department of Basic sciences Higher Institute of Administrative SciencesBelbeisEgypt Faculty of Business Administration Delta University for Science and TechnologyGamasa11152Egypt

This article introduces a novel variant of the generalized linear exponential(GLE)distribution,known as the sine generalized linear exponential(sGLE)*** sGLE distribution utilizes the sine transformation to enhance its *** updated distribution is very adaptable and may be efficiently used in the modeling of survival data and dependability *** suggested model incorporates a hazard rate function(HRF)that may display a rising,J-shaped,or bathtub form,depending on its unique *** model includes many well-known lifespan distributions as separate *** suggested model is accompanied with a range of statistical *** model parameters are examined using the techniques of maximum likelihood and Bayesian estimation using progressively censored *** order to evaluate the effectiveness of these techniques,we provide a set of simulated data for testing *** relevance of the newly presented model is shown via two real-world dataset applications,highlighting its superiority over other respected similar models.

关键词： sine G family generalized linear failure rate progressively censored data moments maximum likelihood estimation Bayesian estimation simulation

Ranking environmental and edaphic attributes driving soil microbial community structure and activity with special attention to spatial and temporal scales

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mLife 2024年第1期3卷 21-41页

作者： Vadakattu V.s.R.Gupta James m.Tiedje CsIRO Agriculture&Food UrrbraeSouth AustraliaAustralia Centre for microbial Ecology Michigan State UniversityEast LansingMichiganUSA

The incredibly complex soil microbial communities at small scales make their analysis and identification of reasons for the observed structures *** community structure is mainly a result of the inoculum(dispersal),the selective advantages of those organisms under the habitat-based environmental attributes,and the ability of those colonizers to sustain themselves over *** soil is protective,and its microbial inhabitants have long adapted to varied soil conditions,significant portions of the soil microbial community structure are likely ***,a substantial portion of the community will not correlate to often measured soil *** suggest that the drivers be ranked on the basis of their importance to the fundamental needs of the microbes:(i)those that supply energy,i.e.,organic carbon and electron acceptors;(i)environmental effectors or stressors,i.e.,pH,salt,drought,and toxic chemicals;(ii)macro-organism associations,i.e.,plants and their seasonality,animals and their fecal matter,and soil fauna;and(iv)nutrients,in order,N,P,and probably of lesser importance,other micronutrients,and *** relevance of drivers also varies with spatial and time scales,for example,aggregate to field to regional,and persistent to dynamic populations to transcripts,and with the extent of phylogenetic difference,hence phenotypic differences in organismal *** present a summary matrix to provide guidance on which drivers are important for particular studies,with special emphasis on a wide range of spatial and temporal scales,and illustrate this with genomic and population(rRNA gene)data from selected studies.

关键词： abundance community structure diversity functional microbiome microorganisms

Isolation of microcrystalline Cellulose from Wood and Fabrication of Polylactic Acid (PLA) Based Green Biocomposites

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Journal of Renewable materials 2024年第8期12卷 1455-1474页

作者： sekar s.m. Nagarajan R. selvakumar P. Oluwarotimi I.s. Krishnan K. mohammad F. shaik m.R. Ayrilmis N. Department of mechanical Engineering Kalasalingam Academy of Research and Education Krishnankoil 626126 India Department of mechanical Engineering SSM Institute of Engineering and Technology Dindigul 624002 India Department of Engineering Centre for Engineering Research School of Physics Engineering and Computer Science University of Hertfordshire Hatfield AL10 9AB United Kingdom INTI International University Persiaran Perdana BBN Nilai 71800 Malaysia Department of chemistry College of Science King Saud University P.O. Box 2455 Riyadh 11451 Saudi Arabia Department of Wood mechanics and Technology Faculty of Forestry Istanbul University–Cerrahpasa Bahcekoy Sariyer Istanbul 34473 Turkey

An innovative microcrystalline cellulose (mCC) natural fibre powder-reinforced PLA biocomposite was investigated using the hand lay-up technique. The polymer matrix composite (PmC) samples were prepared by varying the weight percentages (wt.%) of both PLA matrix and mCC reinforcement: pure PLA/100:0, 90:10, 80:20, 70:30, 60:40 and 50:50 wt.%, respectively. From the results obtained, mCC powder, with its impressive aspect ratio, proved to be an ideal reinforcement for the PLA, exhibiting exceptional mechanical properties. It was evident that the 80:20 wt.% biocomposite sample exhibited the maximum improvement in the tensile, flexural, notched impact, compressive strength and hardness by 28.85%, 20.00%, 91.66%, 21.53% and 35.82%, respectively compared to the pure PLA sample. similarly, during the thermogravimetric analysis (TGA), the same 80:20 wt.% biocomposite sample showed a minimum weight loss of 20% at 400°C, among others. The morphological study using Field Emission scanning Electron microscopy (FE-sEm) revealed that the uniform distribution of cellulose reinforcement in the PLA matrix actively improved the mechanical properties of the biocomposites, especially the optimal 80:20 wt.% sample. Importantly, it was evident that the optimal PLA/cellulose biocomposite sample could be a suitable and alternative sustainable, environmentally friendly and biodegradable material for semi/structural applications, replacing synthetic and traditional components. © 2024 The Authors.

关键词： biocomposite characterizations environmental pollution FEsEm micro crystalline cellulose Polylactic acid

Effect of Ta_(2)O_(5)nanoparticles on bioactivity,composition,structure,in vitro and in vivo behavior of PEO coatings on mg-alloy

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Journal of magnesium and Alloys 2024年第6期12卷 2360-2379页

作者： D.V.mashtalyar I.m.Imshinetskiy V.V.Kashepa K.V.Nadaraia m.A.Piatkova A.I.Pleshkova K.A.Fomenko A.Yu.Ustinov s.L.sinebryukhov s.V.Gnedenkov Institute of chemistry Far Eastern BranchRussian Academy of SciencesVladivostok690022Russia Far Eastern Federal University Vladivostok690950Russia Regional Clinical Dermatovenerological Dispensary Vladivostok690033Russia

The present study investigates the physical and chemical characteristics,behavior in vitro and in vivo,and biocompatibility of coatings containing Ta_(2)O_(5),which are obtained by plasma electrolytic oxidation(PEO)on mA8 magnesium *** obtained coatings demonstrate in vivo biocompatibility and in vitro *** to the base PEO coating,the layers containing Ta_(2)O_(5)facilitate the development of apatite in simulated body fluid,suggesting that the inclusion of nanoparticles improves bioactivity of the *** was found that incorporation of Ta_(2)O_(5)nanoparticles increases roughness and porosity of the formed layers by increasing particle concentration in electrolytes for the PEO process contributing to sufficient soft tissue ingrowth in *** on in vivo studies,these coatings also provide favorable tissue response and minimal inflammatory reaction in comparison with the bare magnesium alloy due to protection of living tissues from deleterious corrosion events of magnesium implant such as local alkalization and intense hydrogen *** results obtained in the present study concluded biocompatibility,tissue integration of the PEO coatings containing Ta_(2)O_(5)nanoparticles making them a promising protective layer for biodegradable magnesium implants.

关键词： Plasma electrolytic oxidation Bioactive coatings Tantalum pentoxide simulated body fluid(sBF) Apatite formation Histology