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Dielectric relaxation and magneto-electric characteristics of lead-free double perovskite: Sm2NiMnO6

Journal of Advanced Ceramics 2019年第2期8卷 174-185页

作者： rutuparna das R.N.P.CHOUDHARY Department of Physics Siksha ‘O’ Anusandhan University

The polycrystalline sample of a double perovskite, Sm2NiMnO6 was synthesized by a solid-state reaction route. From the X-ray structural study, it is found that the structure of the material is monoclinic with lattice parameters: a = 4.1750(63) ?, b = 7.6113(63) ?, c = 5.9896(63) ?, and β = 112.70°. These parameters are very close to and consistent with those of such type of materials. The dielectric, impedance, AC conductivity, and electrical modulus properties of the sample were studied in the temperature range of 25–300℃ and the frequency range of 1 kHz–1 MHz. Typical relaxor behavior observed in the dielectric studies was confirmed by Vogel–Fulcher fitting. From the Nyquist plots, the temperature dependent contribution of grain and grain boundary effect was confirmed. The non-Debye type of relaxation was found using the complex impedance spectroscopy. The magnetic study revealed that the sample had paramagnetic behavior at room temperature. Magneto-electric(ME) coefficient was obtained by changing DC bias magnetic field. This type of lead-free relaxor ferroelectric compound may be useful for high-temperature applications.

关键词： solid-state reaction X-ray diffraction(XRD) dielectric relaxation magneto-electric(ME) coupling

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Comparative Electrocatalytic Oxygen Evolution Reaction Studies of Spinel NiFe_(2)O_(4) and Its Nanocarbon Hybrids

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Transactions of Tianjin University 2022年第1期28卷 80-88页

作者： Pratik V.Shinde rutuparna Samal Chandra Sekhar Rout Centre for Nano and Material Sciences Jain UniversityBengaluruKarnataka 562112India

Electrocatalytic oxygen evolution reaction(OER)is one of the crucial reactions for converting renewable electricity into chemical fuel in the form of *** date,there is still a challenge in designing ideal cost-effective OER catalysts with excellent activity and robust *** hybridization of transition metal oxides and carbonaceous materials is one of the most effective and promising strategies to develop high-performance ***,this work synthesized hybrids of NiFe_2 O_4 spinel materials with two-dimensional(2D)graphene oxide and one-dimensional(1 D)carbon nanotubes using a facile solvothermal *** activities of NiFe_(2)O_(4) with 2 D graphene oxide toward OER were realized to be superior even to the 1 D carbon nanotube-based electro catalyst in terms of overpotential to reach a current density of10 mA/cm^(2) as well as Tafel *** NiFe_(2)O_(4) with 2 D graphene oxide hybrid exhibits good stability with an overpotential of 327 mV at a current density of 10 mA/cm^(2) and a Tafel slope of 103 mV/*** high performance of NiFe_(2)O_(4) with 2 D graphene oxide is mainly attributed to its unique morphology,more exposed active sites,and a porous structure with a high surface ***,an approach of hybridizing a metal oxide with a carbonaceous material offers an attractive platform for developing an efficient electrocatalyst for water electrochemistry applications.

关键词： Oxygen evolution reaction Metal oxide Graphene oxide Carbon nanotubes Stability

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