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The Coexisting Clinopyroxene-Garnet Acidometer and Acidity Facies of Skarn deposits

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Acta Geologica Sinica(English Edition) 1990年第3期64卷 299-308页

作者： Lin Wenwei institute of mineral {2., chinese academy of geological sciences, beijing liu Linqun institute of mineral {2. Chinese Academy of Geological Sciences Beijing

On the basis of geological studies of skarn deposits in China and by using thermodynamic models of thesolid solution, the coexisting clinopyroxene-garnet pair in skarn deposits has been analysed and a coexistingclinopyroxene-garnet acidometer developed. They can be used to estimate the medium condition under whichthe skarn was formed. The research on the acidity for the formation of various metallic skarn deposits in Chinasuggests that skarns endowed with dissimilar types of mineralization and occurring in diverse environments dif-fer in the acidity conditions for their formation and in the trend of acidity variation of ore-bearing fluid. This,coupled with the study of oxygen fugacity of coexisting minerals, makes it possible to establish the oxygenfugacity-acidity facies of skarn deposits, which reflect the close genetic relationship between the metallizationand the formation of skarn.

关键词： OH The Coexisting Clinopyroxene-Garnet Acidometer and Acidity Facies of Skarn deposits

Quartz-Ferberite Oxygen Isotope Geothermometer and Its geological Applications

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Acta Geologica Sinica(English Edition) 1992年第3期66卷 271-281页

作者： Ding Tiping liu Yushan Wan Defang liu Zhijian Li Jincheng Zhang Guilan {2. of mineral deposits, chinese academy of geological sciences, beijing institute of mineral {2. Chinese Academy of Geological Sciences Beijing

Experiments for oxygen isotope exchange between ferberite and water were carried out and the followingequation on oxygen isotope fractionation between ferberite and water against temperature was obtained:Combining this equation with the equation of Clayton et al. (1972. on oxygen isotope fractionation be-tween quartz and water, an equation on oxygen isotope fractionation between quartz and ferberite was ob-tained:The Bigeleison-Mayer function method was used to calculate the oxygen isotope fractionation betweenquartz and ferberite. The theoretical curve obtained agrees with the experimental calibration results quite wellin the temperature range of *** above calibrated equation has been used in 5 world famous tungsten deposits to determine their tem-peratures of formation. The results show that the temperature range for an idividual deposit determined by thisgeothermometer agrees with those obtained from fluid inclusion determination and other isotopegeothermometers.

关键词： geothermometer oxygen isotope quartz--ferberite

Construction of multifunctional lanthanum manganese mixed nanoparticles mediated by ionic liquids for selective aerobic oxidation of cyclohexane

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Rare Metals 2024年第5期43卷 2205-2221页

作者： Hao Li rui-rui Zhang Ke-Xin Li Shuang Wei Yu-Mei {2. rui-Xia {2. beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and EngineeringState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China University of chinese academy of {2. Beijing 100049China

Selective oxidation of alkanes to produce highvalue chemicals is an essential strategy and means to realize efficient utilization of *** this work,a strategy of lanthanum manganese mixed metal oxides(LMMO)regulated via a facile ionic liquid(IL)-assisted hydrothermal method was proposed to construct the multifunctional catalysts,which exhibited excellent catalytic performance in the selective aerobic oxidation of *** 8.9%cyclohexane conversion with 90%KA oi(cyclohexanol and cyclohexanone)selectivity was achieved over the optimal LMMO catalyst under mild *** effects of anion type,carbon chain length and concentration of ILs on the structure and properties of catalysts were investigated through various characterizations,indicating the structure-directing and template effect of ILs on the multifunctional *** formation of self-assembled spherical nanoparticles followed the"dissolution-nucleation-proliferation"mechanism with the introduction of 1-butyl-3-methylimidazolium hydrogen sulfate,ascribing the synergistic effect between the microenvironment of ILs and the hydrothermal ***,the high reactive oxygen concentration redox capacity,and suitable basic sites of LMMO catalysts mediated by ILs enhance the activation of C-H bonds and molecular oxygen,simultaneously influencing the adsorption and desorption of the substrate.A comprehensive understanding of the high KA oil selectivity and radical reaction mechanism was elucidated based on in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS)and radical trapping *** recycling and regeneration experiments further illuminated that the removal of adsorbed cyclohexanone acting on the LMMO catalyst was the key to achieve high KA oil selectivity.

关键词： Ionic liquids Nanoparticle Multifunctional catalyst Cyclohexane oxidation

The Discovery of Phlogopite Exsolution Lamellae in Garnets of Eclogite Inclusions, Liaoning Province

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Acta Geologica Sinica(English Edition) 1997年第1期71卷 33-42页

作者： Zhou Xiuzhong institute of mineral {2., chinese academy of geological sciences, beijing liu Xinzhu institute of mineral {2. Chinese Academy of Geological Sciences Beijing [?]Zhou Xiuzhong Born in May 1939 graduated from Specialty of Geology and Prospecting of Metallic and Nonmetallic minerals Beijing College of Geology in 1964. She is now Associated Research Professor in the Institute of Mineral Deposits CAGs and has long been engaged in researches on mineralogy and petrology.

In No. 50 kimberlite pipe of Fuxian County, Liaoning Province, an eclogite inclusion(nodule), which is extremely rare in kimberlites, was discovered and phlogopite exsolutionlamellae were found in garnets of the inclusion. Microscopic, TEM and energy spectral observa-tions and studies confirmed that these lamellae are phlogopite. They are colourless and acicularin section, generally 0.5-5μm in width and 10-100μm in length. Nevertheless, fine lamellae,0.05-0.1μm wide and 1-2.m long, are also well developed. Along [111] of the garnet, three setsof phlogopite lamellae show oriented arrangement approximately at angles of 60°-70°, indi-cating that these lamellae might be the product of exsolution from garnet as a result ofpressure-release when eclogite ascended from the relatively deep level to the relatively shallowlevel of the mantle. Tiny acicular exsolution minerals (or inclusions) are commonly found ingarnet and pyroxene in eclogite inclusions of kimberlites all over the world and it has been re-ported that the identified exsolution minerals include pyroxene and rutile. This is the first timethat phlogopite exsolution lamillae were found in eclogite inclusions in the world.

关键词： eclogite garnet phlogopite exsolution lamellae Liaoning Province

Some Recognitions on the Sedimentary-Tectonic Development of the Meso-Cenozoic Basins in Eastern China

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Acta Geologica Sinica(English Edition) 1988年第4期1卷 365-379页

作者： liu Xun institute of Geology,{2., beijing chinese ACAD GEOL SCI INST GEOLBEIJINGPEOPLES R CHINA

Since Jurassic. intense and repeated tectonic movements have taken place in eastern China, of which theYanshanian movement is the most important. Thereby the development of the basins between the Jurassic andEogene in the studied areas may by divided into two different stages, i.e. the Yanshanian subcycle （J-K;） andthe North China subcycle （K;-E）. The basement and tectonic stress field of the basins played an obvious role in controlling thesedimentary-tectonic development of the basins. and down-faulted basins might form under different stressstates. Besides. the shearing stress also played an important part while the basins were forming in the notedareas.

关键词： Some Recognitions on the Sedimentary-Tectonic Development of the Meso-Cenozoic Basins in Eastern China

The Mechanism of Structural Control of Ore Formation and Geochemical Characteristics in the Massive Sulfide deposits of the Wushan Copper Ore Field,Jiangxi

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Acta Geologica Sinica(English Edition) 1990年第3期64卷 261-274页

作者： liu Xun institute of Geomechanics,{2., beijing Zhang Zhongmin institute of Geomechanics Chinese Academy of Geological Sciences Beijing

The ore-controlling mechanism of the bedding fault system in the massive sulfide deposits of the Wushancopper orefield may be generalized as the control of ore deposition by optimum surface in an ore-formingstructural trap. The mechanism has three major features: (1) timing of mineralization; (2. positioning of hostformation; and (3) dependence of ore-controlling structure on properties of rocks. The 'optimum surface' is adivisional structural plane which marks obvious difference in physical, chemical and mechanical properties andis favorable for mineralization. It is also a unity of structures. lithofacies and orebodies. The structural and geochemical characteristics of the ore deposits indicate the migration trend of the ma-jor characteristic clements in the ore-controlling fault belt: elements with a small radius (Si, Fe, Mg and Al)moved towards and concentrated at the center of the belt while large-radius ones (Ca, K and Na) were remotefrom the center.

关键词： The Mechanism of Structural Control of Ore Formation and Geochemical Characteristics in the Massive Sulfide deposits of the Wushan Copper Ore Field Jiangxi

Experimental Study on the Leaching of Gold from Greenstone

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Acta Geologica Sinica(English Edition) 1993年第2期67卷 211-221页

作者： liu Yushan, Zhang Guilan institute of {2. deposits, chinese academy of geological sciences, beijing and Tian Jun Changchun College of Geology, Changchun, Jilin institute of mineral {2. Chinese Academy of Geological Sciences Beijing China

Experiments were conducted on the leaching of gold from greenstone by chloride solution under the temperature of 2.0—550℃ and the pressure of 60 MPa. During part of the experiments, the oxygen fugacity was controlled. The results show that the leaching rate of gold is related to temperature, composition of the solution, pH and oxygen fugacity. In the experiment with oxidative acidic solution, the leaching rate was up to 50％ or more. It is known that the leaching of gold is restricted by the reaction in which the gold is dissolved from the rock to form gold chloride complex. Therefore, the authors hold that the acidic chloride solution derived from granite magma has caused the remobilization-migration of gold from greenstone and its enrichment into ore.

关键词： leaching gold deposits greenstone

Origin, Evolution and Mechanism of the Jehol Fauna

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Acta Geologica Sinica(English Edition) 1991年第2期65卷 203-215页

作者： Wang Si’en institute of Geology, chinese academy of geological sciences, {2. liu Linqun institute of Geology Chinese Academy of Geological Sciences Beijing

This paper deals with the geographic distribution and geological setting of the Jehol (northeastHebei-southwest Liaoning-southeast Inner Mongolia) fauna, and discusses the origination and the evolution ofits major biological groups. It is demonstrated that the Yan-Liao (northern Hebei-western Liaoning) area is theprovenance for the fauna. Why the fauna originated and developed in the area was intimately related to suchfactors as the palaeoclimate, palaeogeography, crustal movement, volcanism and frequent reversals of magnet-ic polarity at that time, in addition to the internal factors of the organisms themselves.

关键词： Origin Evolution and Mechanism of the Jehol Fauna

Discovery of Fossil Charophytes from the Late Triassic Xujiahe Formation and Early Jurassic Lower Yimen Formation, Sichuan Province, and Its Significance

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Acta Geologica Sinica(English Edition) 1992年第3期66卷 301-309,327页

作者： liu Junying Chen Zhongliang institute of Geology,{2., beijing Panxi geological Party, Sichuan Bureau of Geology and mineral Resources, Xichang liu Linqun institute of Geology Chinese Academy of Geological Sciences Beijing China

This paper describes the fossil charophytes collected from the Late Triassic Xujiahe Formation in Dazuand Early Jurassic Lower Yimen Formation in Xichang, Sichuan Province, and their significance. Up to now,papers dealing with fossil charophytes of the Late Triassic, especially of the Early Jurassic, have been rarelypublished. The description of the two new species of Porochara, P. dazuensis and P. xichangensis, and theirfossil assemblage not only provides an important basis for classification and correlation of red beds insouthwestern China but reveals for the first time the features of the charophyte flora of the Late Triassic-EarlyJurassic in the area, thus offering valuable data for the establishment of Triassic and Jurassic charophyte fossilzones in China.

关键词： Sichuan Late Triassic Early Jurassic charophyte fossil