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Influence of temperature and pressure during thermoforming of softwood pulp

Journal of Bioresources and Bioproducts 2023年第4期8卷 408-420页

作者： Eva Pasquier robert skunde Jost Ruwoldt RISE PFI AS Høgskoleringen 6BTrondheim 7491Norway TU-Berlin Institute for Polymer Technology and Polymer PhysicsErnst Reuter Platz 1Berlin 10587Germany

In this study,the influence of thermoforming conditions on the resulting material properties was investigated,which aimed at developing advanced wood-fiber-based materials for the replacement of fossil *** bleached softwood pulps were studied,i.e.,northern bleached softwood Kraft pulp(NBSK)and chemi-thermomechanical softwood pulp(CTMP).The thermoforming conditions were varied between 2–100 MPa and 150–200℃,while pressing sheets of 500 g/m^(2)for 10 min to represent thin-walled packaging more *** our results showed,the temperature had a more pronounced effect on the CTMP substrates than on the Kraft *** was explained by the greater abundance of lignin and hemicelluloses,while fibrillar dimensions and the fines content may play a role in ***,the CTMP exhibited an optimum in terms of tensile strength at intermediate thermoforming *** effect was attributed to two counteracting effects:1)Improved fiber adhesion due to enhanced densification,and 2)embrittlement caused by the loss of *** temperatures likely softened the lignin,enabling fiber collapse and a tighter *** the Kraft substrates,the tensile strength increased linearly with *** pulps showed reduced wetting at elevated thermoforming temperature and pressure,which was attributed to hornification and densification ***,the effect of temperature was again more pronounced for CTMP than for the Kraft *** was concluded that the thermoforming temperature and pressure strongly affected the properties of the final *** chemical composition of the pulps will distinctly affect their response to thermoforming,which could be useful for tailoring cellulose-based replacements for packaging products.

关键词： Thermoforming Molded pulp Fiber-based materials Softwood pulp CTMP NBSK

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