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Particle focusing by 3D inertial microfluidics

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Microsystems & Nanoengineering 2017年第1期3卷 204-211页

作者： Petra Paiè Francesca Bragheri Dino Di Carlo roberto Osellame Istituto di Fotonica e Nanotecnologie(IFN)-CNR and Dipartimento di Fisica-Politecnico di Milano Piazza Leonardo da Vinci 3220133 MilanItaly Department of Bioengineering Department of Mechanical EngineeringCalifornia NanoSystems Instituteand Jonsson Comprehensive Cancer CenterUniversity of California-Los Angeles420 Westwood Plaza5121 Engineering VLos AngelesCA 90095USA

Three-dimensional(3D)particle focusing in microfluidics is a fundamental capability with a wide range of applications,such as on-chip flow cytometry,where high-throughput analysis at the single-cell level is ***,3D focusing is achieved mainly in devices with complex layouts,additional sheath fluids,and complex pumping *** this work,we present a compact microfluidic device capable of 3D particle focusing at high flow rates and with a small footprint,without the requirement of external fields or lateral sheath flows,but using only a single-inlet,single-outlet microfluidic sequence of straight channels and tightly curving vertical *** device exploits inertial fluidic effects that occur in a laminar regime at sufficiently high flow rates,manipulating the particle positions by the combination of inertial lift forces and Dean drag *** device is fabricated by femtosecond laser irradiation followed by chemical etching,which is a simple two-step process enabling the creation of 3D microfluidic networks in fused silica glass *** use of tightly curving three-dimensional microfluidic loops produces strong Dean drag forces along the whole loop but also induces an asymmetric Dean flow decay in the subsequent straight channel,thus producing rapid cross-sectional mixing flows that assist with 3D particle *** use of out-of-plane loops favors a compact parallelization of multiple focusing channels,allowing one to process large amounts of *** addition,the low fluidic resistance of the channel network is compatible with vacuum driven *** resulting device is quite interesting for high-throughput on-chip flow cytometry.

关键词： 3D fluidic network 3D particle focusing Dean flow inertial microfluidics

Methane oxidation and attenuation of sulphur compounds in landfill top cover systems: Lab-scale tests

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Journal of Environmental Sciences 2018年第3期30卷 317-326页

作者： roberto Raga Alberto Pivato Maria Cristina Lavagnolo Laura Megido Raffaello Cossu DII-Department of Industrial Engineering University of Padova Department of Chemical and Environmental Engineering Polytechnic School of Engineering Gijón Campus University of Oviedo

In this study,a top cover system is investigated as a control for emissions during the aftercare of new landfills and for old landfills where biogas energy production might not be *** materials were studied as landfill cover system in lab-scale columns：mechanical–biological pretreated municipal solid waste（MBP）;mechanical–biological pretreated biowaste（PB）;fine（PBSf）and coarse（PBSc）mechanical–biological pretreated mixtures of biowaste and sewage sludge,and natural soil（NS）.The effectiveness of these materials in removing methane and sulphur compounds from a gas stream was tested,even coupled with activated carbon *** of CO2,CH4,O2,N2,H2S and mercaptans were analysed at different depths along the *** degradation was assessed using mass balance and the results were expressed in terms of methane oxidation rate（MOR）.The highest maximum and mean MOR were observed for MBP（17.2 g CH4/m^2/hr and 10.3 g CH4/m^2/hr,respectively）.Similar values were obtained with PB and *** lowest values of MOR were obtained for NS（6.7 g CH4/m^2/hr）and PBSf（3.6 g CH4/m^2/hr）,which may be due to their low organic content and void index,*** membranes with high load capacity did not seem to have an influence on the methane oxidation process：MBP coupled with 220 g/m^2and 360 g/m^2membranes gave maximum MOR of 16.5 g CH4/m^2/hr and 17.4 g CH4/m^2/hr,*** carbon membranes proved to be very effective on H2S ***,carbonyl sulphide,ethyl mercaptan and isopropyl mercaptan seemed to be easily absorbed by the filling materials.

关键词： Emission reduction Greenhouse gas emissionLandfill Methane oxidation H2S Soil cover

Experimental characterization and CFD simulation of gas maldistribution in turbulent fluidization of Group A particles

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Particuology 2023年第11期82卷 192-203页

作者： Maurizio Troiano Benjamin Amblard Sina Tebianian roberto Solimene Piero Salatino Thierry Gauthier Dipartimento di Ingegneria Chimica dei Materiali e della Produzione IndustrialeUniversitàdegli Studi di Napoli Federico IIPiazzale Vincenzo Tecchio 8080125NapoliItaly IFP Energies nouvelles Rond-point de l'échangeur de Solaize BP 369360SolaizeFrance Istituto di Scienze e Tecnologie per l’Energia e la MobilitàSostenibili(STEMS) Consiglio Nazionale delle Ricerche(CNR)Piazzale Vincenzo Tecchio 8080125NapoliItaly

The study presented hereby investigates experimentally and with CFD simulations the gas distribution effect on the hydrodynamic of a Geldart Group A turbulent fluidized bed. Experiments were carried out on a cold flow fluidized bed column with an even and uneven gas distribution. Local solid volume fraction profiles were measured using optical probes at different bed heights and along two radial directions. Optical probe measurements allow catching a clear hydrodynamic difference between both even and uneven gas distributions. These results were then used to assess CFD simulations with the code Barracuda^(TM) (MP-PIC approach). It is noteworthy that the choice of drag correlation and boundary conditions strongly influences the agreement between the experimental and CFD results. Once the correct parameters are chosen, CFD simulations captured the effect of gas distribution changes.

关键词： Characterization of multiphase reactors Fluidized bed Turbulent Gas distribution Jet Optical probe CFD simulations

Treatment of discontinuities inside Earth models:Effects on computed coseismic deformations

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Earth and Planetary Physics 2021年第1期5卷 90-104页

作者： Jie Dong Gabriele Cambiotti HanJiang Wen roberto Sabadini WenKe Sun Chinese Academy of Surveying and Mapping Beijing 100036China Department of Earth Sciences University of MilanMilano 20133Italy Key Laboratory of Computational Geodynamics University of Chinese Academy of SciencesBeijing 100049China

In this paper,we study how coseismic deformations calculated in 1066 Earth models are affected by how the models treat Earth *** the results of applying models 1066A(continuous)and 1066B(discontinuous),we find that the difference in Love numbers of strike-slip and horizontal tensile sources are bigger than dip-slip and vertical tensile *** collectively,discontinuities have major effects on Green’s functions of four independent *** the near-field coseismic deformations of the 2013 Okhotsk earthquake(Mw 8.3),the overall differences between theoretical calculations in vertical displacement,geoid,and gravity changes caused by discontinuities are 10.52 percent,9.07 percent and 6.19 percent,with RMS errors of 0.624 mm,0.029 mm,and 0.063μGal,*** difference in far-field displacements is small,compared with GPS data,and we can neglect this *** the shallow earthquake,2011 Tohoku-Oki earthquake(Mw 9.0),the differences in near-field displacements are 0.030 m(N-S),0.093 m(E-W),and 0.025 m(up-down)in our study area with the ARIA slip model,which gives results closer to GPS data than those from the USGS *** difference in vertical displacements and gravity changes on the Earth’s surface caused by discontinuities are larger than 10 *** difference in the theoretical gravity changes at spatially fixed points truncated to degrees 60,as required by GRACE data,is 0.0016μGal and the discrepancy is 11 percent,with the theoretical spatial gravity changes from 1066B closer to observations than from *** results show that an Earth model with discontinuities in the medium has a large effect on the calculated coseismic deformations.

关键词： discontinuities Earth model coseismic deformations GPS GRACE

Authigenic titanite in weathered basalts: Implications for paleoatmospheric reconstructions

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Geoscience Frontiers 2020年第6期11卷 2183-2196页

作者： Alexey A.Novoselov Dailto Silva Carlos roberto de Souza Filho Institute of Applied Economic Geology Universidad de ConcepcionConcepcionChile Institute of Geosciences University of CampinasCampinasSPBrazil

The stability of titanite is sensitive to temperature and partial pressure of *** finding of authigenic titanite grains in weathering regolith formed on Parana basalts,Brazil,under tropical climatic conditions,reveals the thermodynamically-driven conversion from calcite to titanite at elevated ambient *** unusual nowadays,this phase transition provides important implications for the understanding of silicate weathering in earlier geological *** types of secondary titanites were identified in the weathering profile of the study *** tiny grains of 10 μm are forming in the microscopic voids in the ***,large fractures filled with Fe-rich clay minerals contain bigger specimens of up to 170μ*** titanites of second type often coexist with chalcedony and *** carbonate minerals were found in the weathering *** sphene can be discriminated from other titanite types by its strong positive Eu anomaly,increased Al2 O3 content and low content of trace *** specific chemical composition and reactive transport modeling link this secondary mineral with dissolution of *** titanite precipitation is controlled by slow diffusion in poorly-aerated,highly-alkaline pore *** subaerial weathering of basaltic rocks provides a significant reservoir for atmospheric ***,the deposition of carbonate minerals is thermodynamically avoided at the stability field of *** demonstrate a complex feedback between CO2 and soil *** rise in pCO2 triggers the precipitation of calcite in the weathering regolith,but the greenhouse effect increasing the temperature can cease carbonate *** titanites were found in several paleosols and at least a part of them can be of weathering origin.

关键词： Titanite Sphene Calcite Paleosols Weathering Paleoclimates

Validations of new cut-offs for surgical drains management and use of computerized tomography scan after pancreatoduodenectomy:The DALCUT trial

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World Journal of Clinical Cases 2022年第15期10卷 4836-4842页

作者： Damiano Caputo Alessandro Coppola Vincenzo La Vaccara roberto Passa Ludovico Carbone Massimo Ciccozzi Silvia Angeletti roberto Coppola Department of Surgery University Campus Bio-Medico of RomeRome 00128Italy Unit of Medical Statistic and Molecular Epidemiology University Campus Bio-Medico of RomeRome 00128Italy Unit of Clinical Laboratory Science University Campus Bio-Medico of RomeRome 00128Italy

BACKGROUND Postoperative pancreatic fistula(POPF)is the most fearful complication after pancreatic surgery and can lead to severe postoperative complications such as surgical site infections,sepsis and bleeding.A previous study which identified cut-offs of drains amylase levels(DALs)determined on postoperative day(POD)1 and POD3,was able to significantly predict POPF,abdominal collections and biliary fistulas,when related to specific findings detected at the abdominal computerized tomography(CT)scan routinely performed on *** To validate the cut-offs of DALs in POD1 and POD3,established during the previous study,to assess the risk of clinically relevant POPF and confirm the usefulness of abdominal CT scan on POD3 in patients at increased risk of abdominal *** The DALCUT trial is an interventional prospective *** patients who will undergo pancreatoduodenectomy(PD)for periampullary neoplasms will be considered *** patients will receive clinical staging and,if eligible for surgery,will undergo routine preoperative *** the PD,daily DALs will be evaluated from *** removal and possible requirement of abdominal CT scans in POD3 will be managed on the basis of the outcome of DALs in the first three postoperative *** This prospective study could validate the role of DALs in the management of surgical drains and in assessing the risk or relevant complications after *** could be removed in POD3 in case of POD1 DALs<666 U/L and POD3 DALs<207 U/*** case of POD3 DALs≥252,abdominal CT scan will be performed in POD3 to identify abdominal collections≥5 *** this latter category of patients,drains could be maintained beyond *** The results of this trial will contribute to a better knowledge of POPF and management of surgical drains.

关键词： Pancreatic surgery Drains amylase Pancreatic fistula Postoperative complications Computerized tomography scan

Do supplemental perches influence electrocution risk for diurnal raptors?

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Avian Research 2020年第2期11卷 139-149页

作者： roberto Sánchez Javier Sánchez Javier Oria Francisco Guil Fundación CBD-Hábitat C/Gustavo Fernández Balbuena28002 MadridSpain Tragsa Group C/Conde de Peñalver8428006 MadridSpain Boscaje S.L. Plaza Conde de Cheste540001 SegoviaSpain Ministry for the Ecological Transition and the Demographic Challenge Plaza San Juan de la CruzS/N28071 MadridSpain

Background:Power lines are amongst the main causes of mortality for birds *** drives the population dynamics of several threatened species of raptors,at local and global *** the many solutions that have been tested to minimize this threat are supplemental perches;however,their efficiency has rarely been ***:We designed 43 transects in 4 districts in mainland Portugal to gather data from birds perching on pylons with or without supplemental *** 2015 to 2018,transects were surveyed by car at least *** analyzed the factors driving the use of these supplemental perches,and we analyzed if there were differences in the perceived risk(calculated from measurements and not from field surveys)depending on whether the perching was on pylons with or without supplemental ***:We recorded 548 perches of 14 *** conditions seemed to play a role in birds’choice of pylons with supplemental perches versus pylons without supplemental *** also indicated a strong influence of observational *** use of models showed us an important specific effect in the selection of supplemental perches where available:there are some species with a greater tendency to perch on supplemental perches,even when they use both pylons with and without supplemental *** most of the analyzed species and species groups,perceived risk was higher in pylons without supplemental perches compared to pylons with supplemental perches,but there were differences between ***:Supplemental perches may be a useful and efficient tool for mitigating raptor ***,there are many influential factors affecting their success,and their effectiveness with different species groups is not *** studies show higher electrocution rates for certain species and devices and thus,their efficacy must be *** propose a two-step validation process,first in controlled conditions and then in the

关键词： Aquila adalberti Circaetus gallicus Diurnal raptors Electrocution Power lines Pylons

A stable anthraquinone-derivative cathode to develop sodium metal batteries: The role of ammoniates as electrolytes

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Journal of Energy Chemistry 2023年第2期77卷 572-580,I0015页

作者： Débora Ruiz-Martínez José M.Orts roberto Gómez Departament de Química Física i Institut Universitari d’Electroquímica Universitat d’AlacantApartat 99Alicante E-03080Spain

Rechargeable sodium metal batteries constitute a cost-effective option for energy storage although sodium shows some drawbacks in terms of reactivity with organic solvents and dendritic *** we demonstrate that an organic dye,indanthrone blue,behaves as an efficient cathode material for the development of secondary sodium metal batteries when combined with novel inorganic *** electrolytes are ammonia solvates,known as liquid ammoniates,which can be formulated as NaI·3.3NH_(3) and NaBF_(4)·2.5NH_(3).They impart excellent stability to sodium metal,and they favor sodium non-dendritic growth linked to their exceedingly high sodium ion *** advantage is complemented by a high specific *** battery described here can last hundreds of cycles at 10 C while keeping a Coulombic efficiency of 99%from the first *** of the high capacity of the cathode and the superior physicochemical properties of the electrolytes,the battery can reach a specific energy value as high as 210 W h kgIB^(-1),and a high specific power of 2.2 kW kgIB^(-1),even at below room temperature(4℃).Importantly,the battery is based on abundant and cost-effective materials,bearing promise for its application in large-scale energy storage.

关键词： Sodium metal batteries Anthraquinone-based cathode Vat dye Indanthrone blue Inorganic electrolytes Liquid ammoniates

Color variation in signal crayfish Pacifastacus leniusculus

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Current Zoology 2021年第1期67卷 35-43页

作者： roberto SACCHI Stefania CANCIAN Daniela GHIA Gianluca FEA Alan COLADONATO Dipartimento di Scienze della Terra e dell'Ambiente Universita degli Studi di PaviaViale Tarameli 24Pavia1-27100Italy

External coloration in animals depends on the interaction of several different factors including the genetics and epigenetics processes that underlie the color expression,the mechanisms of color perception,and the general mechanisms controlling color evolution and *** all,camouflages from predators and conspicuousness are of particular interest because pose animal to choose between opposite adjustment in *** external coloration of crustaceans is mainly due to the accumulation of carotenoids in the exoskeleton and the epidermal layer,and the trade-off between camouflage and communication had led to a variety of responses,involving signal partitioning,spectral sensibility,changing coloration,or signaling ***,we used digital images to explore intrapopulation variability of the external coloration of Pacifastacus leniusculus among body regions within an individual and between *** found that 1)ventral coloration of claws are more saturated and brilliant than upper parts,2)males express a more saturated and brightness coloration than females,especially on the lower portion of claws,3)color intensity and brightness increases with size differently in different body regions,and 4)brightness is more variable in males than in *** the above patterns support the hypothesis that color in this species could be the result of a compromise between camouflage from predators and conspicuousness for *** results of this study suggest that carotenoid might have something to do with intraspecific communication and perform more complex functions than that of a simple pigment.

关键词： crayfish external coloration HSV individual variation sexual dimorphism