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Insights on advanced substrates for controllable fabrication of photoanodes toward efficient and stable photoelectrochemical water splitting

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Carbon Energy 2024年第4期6卷 164-221页

作者： Huilin Hou Gang Shao Yang Wang Wai‐yeung wong Weiyou Yang Institute of Micro/Nano Materials and Devices Ningbo University of TechnologyNingboChina School of Materials Science and Engineering Zhengzhou UniversityZhengzhouChina Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHong KongChina

Conversion of solar energy into H_(2) by photoelectrochemical(PEC)water splitting is recognized as an ideal way to address the growing energy crisis and environmental *** a typical PEC cell,the construction of photoanodes is crucial to guarantee the high efficiency and stability of PEC reactions,which fundamentally rely on rationally designed semiconductors(as the active materials)and substrates(as the current collectors).In this review work,we start with a brief introduction of the roles of substrates in the PEC ***,we provide a systematic overview of representative strategies for the controlled fabrication of photoanodes on rationally designed substrates,including conductive glass,metal,sapphire,silicon,silicon carbide,and flexible ***,some prospects concerning the challenges and research directions in this area are proposed.

关键词： hydrogen photoanode photoelectrochemical substrates water splitting

Polymetallaynes and Molecular Metallaynes Containing Platinum,Mercury and Gold for Optoelectronic and Magnetic Applications

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Chinese Journal of Chemistry 2023年第17期41卷 2159-2178页

作者： Chen Zhang Linli Xu Wai-yeung wong Departmentof Applied Biology and Chemical Technology The Hong Kong Polytechnic UniversityHung HomHong Kongchina

omprehensive Summary,Polymetallaynes are a promising branch of metallopolymers,in which the introduction of metal building blocks to organic conjugated backbones leads to their unique skeletons and versatile ***,the chemical structures,geometric configurations and functional properties in these organometallic systems can be adjusted flexibly by the appropriate selection of metal centers,auxiliary ligands,or bridging *** recent years,both one-dimensional and two-dimensional polymetallaynes have attracted considerable attention owing to their excellent electronic,optical and magnetic ***,the studies on molecular metallaynes provide substantial insights for the exploration of the structure-property-activity relationships in these organometallic acetylide-containing *** recent research progress of polymeric and molecular metallaynes containing platinum,mercury and gold is discussed in this article.A series of functional properties have been realized in these acetylide-containing compounds by the rational structural design and refined synthetic strategies,leading to their emerging applications including energy conversion,nonlinear optics,data storage and memory,as well as chemo/biosensing.

关键词： Polymetallayne Molecular metallayne Metallated graphyne Platinum Mercury Gold

Atomically precise copper nanoclusters as ultrasmall molecular aggregates:Appealing compositions,structures,properties,and applications

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聚集体(英文)

聚集体(英文) 2023年第1期4卷 122-147页

作者： Leon Li-Min Zhang Wai-yeung wong Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHong KongP.R.China Shenzhen Research Institute The Hong Kong Polytechnic UniversityShenzhenP.R.China

Metal nanoclusters(NCs)are ultrasmall molecular aggregates consisting of dozens to hundreds of metal atoms consolidated by organic ligands,which represent an emerging area of *** a myriad of metal NCs,copper NCs(CuNCs)comprise a low-cost,high-value subclass that has attracted great *** variable copper cores and diversity of protecting ligands have rendered CuNCs interesting molecular aggregates featuring structural and compositional versatility,hence showing distinctive properties and potential *** the present review,we have summarized the progress on atomically precise CuNCs that exhibit a range of appealing properties and applications in different *** review is expected to provide not only an overview of the current development on atomically precise CuNCs,but also possible directions for the future design of novel CuNCs for fundamental studies and practical applications.

关键词： applications atomically precise structures copper nanoclusters properties

An overview on AIEgen-decorated porphyrins:Current status and applications

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聚集体(英文)

聚集体(英文) 2023年第3期4卷 55-70页

作者： Govardhana Babu Bodedla Xunjin Zhu Wai-yeung wong Department of Applied Biology&Chemical Technology and Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHong KongP.R.China The Hong Kong Polytechnic University Shenzhen Research Institute ShenzhenP.R.China Department of Chemistry Hong Kong Baptist UniversityHong KongP.R.China

One of the major obstacles of porphyrins is the aggregation-caused quenching(ACQ)of photoluminescence due to the strong intermolecularπ–πinteraction of the planar porphyrin core in the solid ***,ACQ leads to the nonradiative deactivation of the photoexcited states which results in short-lived charge-separated states and thus low photoluminescence and singlet quantum *** phenomenon would limit the utilization of porphyrins in near-infrared fluorescent bioimaging,photodynamic therapy,photocatalytic hydrogen evolution,electrochemiluminescence,and chiroptical ***,to address the ACQ property of porphyrins and enhance the performance of the above applications,a limited number of AIEgen-decorated porphyrins have been designed,synthesized,and tested for their *** has been found that the introduction of AIEgens,such as tetraphenylethylene,diphenylacrylonitrile,(3,6-bis-(1-methyl-4-vinylpyridinium)-carbazole diiodide,and iridium motif into the porphyrin core,transformed the porphyrins from ACQ to aggregation-induced emission(AIE)in their solid state due to the reduced strong intermolecularπ–πstacking of ***,such porphyrins containing AIE features are employed as potential candidates in the above-mentioned *** this review,we summarize the AIEgen-decorated porphyrins which have been published to date,and also discuss the benefits of converting porphyrins from ACQ to AIE for enhanced performance within each *** far as we know,there is no review that summarizes the structures and applications of AIEgen-decorated porphyrins to ***,we presume that this review would be helpful to design more efficient AIEgen-decorated porphyrins for a wide range of applications in the future.

关键词： aggregation-caused quenching aggregation-induced emission AIE luminogen FRET and solid state emission porphyrin

Steering S-scheme charge transfer via interfacial dipoles induced by amine-containing polyelectrolytes

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Science China Chemistry 2023年第7期66卷 2098-2108页

作者： Tao Li Chuang Feng Biquan Xiong Xuhui Zhu Zhicai He Wai-yeung wong Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and DevicesSchool of Material Science and EngineeringSouth China University of TechnologyGuangzhou 510640China Department of Applied Biology&Chemical Technology and Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHung HomHong KongChina

The lack of a robust interfacial driving source over multicomponent photocatalysts is an essential contributor to the sluggish spatial charge transfer across the heterointerface and severe carrier recombination,thereby rendering maneuvering charge transfer of composite materials a thorny ***,we demonstrate an electric dipole moment-driven charge transfer photosystem utilizing amine-containing polyfluorene polyelectrolyte(i.e.,PFN)and inorganic semiconductor matrices(i.e.,WO_(3))as the building blocks to direct the interfacial charge transfer,effectively targeting the photoexcited charge carriers to the active *** results and theoretical simulations reveal that the electronic coupling interaction between the pendant electron-rich amine groups along the PFN backbone and WO_(3)surface enables the nonuniform charge distribution at the interface over the WO_(3)@PFN heterojunction,which ultimately fosters the formation of interfacial dipoles oriented from conjugated macromolecular backbone of PFN to the surface of WO_(3)*** interfacial dipoles with excellent charge transfer kinetics spontaneously activate the unidirectional and accelerated S-scheme charge motion from the WO_(3)framework to the conjugated chain of PFN due to the suitable band offsets at the interface,thus endowing WO_(3)@PFN heterostructures with a significantly enhanced net efficiency of *** findings would provide some insights into the design of advanced heterojunction photocatalysts for solar energy conversion as well as the study of the working mechanism of polyelectrolyte interlayers in optoelectronic devices.

关键词： photocatalysis heterojunction interfacial dipole polyelectrolyte S-scheme

Dipyridyl Azo Compound 4,4'-Azopyridine as a Potential Coating Material for Toilet Sanitizer

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Chemical Research in Chinese Universities 2023年第6期39卷 864-869页

作者： WANG Qiwei JIANG Lu LAM Pik-Ling CHUI Chung-Hin wong Wai-yeung Antibiotics Research and Reevaluation Key Laboratory of Sichuan Province Sichuan Industrial Institute of AntibioticsChengdu UniversityChengdu 610052P.R.China Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic UniversityHung HomHong KongP.R.China Research and Development Division One Health International LimitedHong KongP.R.China

Good toilet hygiene can reduce the risk of pathogenic *** flushing,pathogenic bacteria can be spread by the water droplets,especially in the toilet *** coli(***)is one of the frequently occurring Gram-negative bacterial pathogens found in the toilet *** this study,we investigated the potential *** activity of some azobenzene *** them,compound 2,with the heterocyclic nitrogen in both phenyl rings,showed the strongest antibacterial effect on ***,with the minimum inhibitory concentration of 80μg/mL and the minimum bactericidal concentration of 320μg/*** 2 displayed a comparative zone of clearance[(14.50±2.29)mm]to that of ampicillin[(13.17±1.76)mm].The reactive oxygen species(ROS)assay suggested that compound 2 might induce the loss of bacteria via the oxidative stress by eliciting the generation of intracellular *** further examined the potential cytotoxicity of compound 2 to the human skin HaCaT *** 2-treated skin cells showed a good maintenance of cellular morphology and a clear definition of cell nuclei,with a satisfactory cell viability(ca.90%)at 80μg/***,compound 2 would be a possible antibacterial coating agent for the surface sanitizer of the toilet seats to inhibit the growth of ***.

关键词： Antibacterial Azobenzene Escherichia coli Skin cytotoxicity Toilet seat

Asymmetric Tris-Heteroleptic Cyclometalated Phosphorescent Iridium(III)Complexes:An Emerging Class of Metallophosphors

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Accounts of Materials Research 2022年第8期3卷 830-842页

作者： Peng Tao Xingqiang Lü Guijiang Zhou Wai-yeung wong Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHong KongP.R.China The Hong Kong Polytechnic University Shenzhen Research Institute Shenzhen 518057P.R.China School of Chemical Engineering Northwest UniversityXi’an 710069P.R.China School of Chemistry State Key Laboratory for Mechanical Behavior of MaterialsXi’an Jiaotong UniversityXi’an 710049P.R.China

CONSPECTUS:The rapid developments of cutting-edge research on photofunctional organic semiconductor materials are greatly promoting the progress of science and *** one of the most important organic semiconductor materials,phosphorescent iridium(III)complexes are a promising class of organometallic emitters because of their rich emissive excited states together with excellent chemical stability,which have been widely used in various fields,such as organic electroluminescence,solar cells,photo-catalysis,biosensing,bioimaging,cancer therapy,*** exploration of highly efficient phosphorescent iridium(III)complexes showing various structural features is blooming *** general,the traditional iridium(III)phosphors usually contain at least two identical cyclometalating bidentate *** iridophosphors with two identical bidentate ligands are termed as the bis-heteroleptic complex Ir((L1)2L2),where L denotes the free ligand or the deprotonated form of the free *** with three identical ligands are called homoleptic complex Ir(L)***,the iridium(III)complexes Ir(L1L2L3)supported by three different(cyclometalating)ligands are emerging as a novel and interesting category of *** class of iridophosphors usually refers to tris-heteroleptic cyclometalated phosphorescent iridium(III)complexes,and they usually show the asymmetry in their molecular *** with the case for the traditional iridium(III)phosphors,the independent ligand control provides tris-heteroleptic iridium(III)phosphors with more flexible molecular design/synthesis and excited-state fine-tuning ability,thereby resulting in more rich and appealing excited states and potential multifunctional *** this Account,we will highlight our recent efforts on the asymmetric tris-heteroleptic cyclometalated iridium(III)phosphors including the molecular design strategies,chemical synthesis,excited-state tuning,and structure−property relationships as well as

关键词： excited complexes substituent

Bandgap tunable preparation of GaS nanosheets and their application in photoelectrochemical photodetectors

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Science China(Technological Sciences) 2022年第10期65卷 2297-2303页

作者： YOU Qi ZHU JiaQi PENG Chao ZHANG YanHui RUAN BanXian DAI XiaoYu WANG Xin wong Wai-yeung XUE DongFeng XIANG YuanJiang Institute of Microscale Optoelectronics(IMO) Shenzhen UniversityShenzhen 518060China Shenzhen Institute of Advanced Technology Chinese Academy of SciencesShenzhen 518055China School of Physics and Electronics Central South UniversityChangsha 410083China School of Physics and Electronics Hunan UniversityChangsha 410082China Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic UniversityHong KongChina

Bandgap engineering of two-dimensional(2D)materials is essential for the design of photoelectrochemical(PEC)***(II)sulfide(GaS),a layered semiconductor material with a direct bandgap of approximately 3.05 eV,has recently gained extensive attention owing to its unique photoresponse ***,its bandgap tunability relative to the number of layers has not been experimentally confirmed;thus,the effect of bandgap on the photoresponse has not been explored ***,fewlayered GaS nanosheets(Ns)are prepared using a simple liquid-phase exfoliation(LPE)*** centrifuging at different speeds,GaS Ns with defined layers are obtained,which enable verification of the tunable bandgap from 2.02 to 3.15 *** applied as a PEC-type photodetector,the responsivity of the photodetector is 4.77 mA W^(−1)and 33.7μA W^(−1)under bias voltages of 0.6 and 0 V,*** models of the electronic structure suggest that a reduction in the number of layers,leading to a decrease of the effective mass at the valence band maximum(VBM),can enhance the carrier mobility of GaS *** results in high photocurrents and indicates that 2D GaS Ns are ideal materials for future high-performance optoelectronic systems.

关键词： two-dimensional materials gallium sulfide nanosheets bandgap engineering photodetector

Verification of tropical cyclones(TC)wind structure forecasts from global NWP models and ensemble prediction systems(EPSs)

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Tropical Cyclone Research and Review 2022年第2期11卷 88-102页

作者： Xiaoqin Lu Wai Kin wong Kin Chung Au-yeung Chun Wing Choy Hui Yu Shanghai Typhoon Institute and Laboratory of Typhoon Forecast Technique China Meteorological AdministrationShanghaiChina Hong Kong Observatory Hong KongChina

Forecasting wind structure of tropical cyclone(TC)is vital in assessment of impact due to high winds using Numerical Weather Prediction(NWP)*** usual verification technique on TC wind structure forecasts are based on grid-to-grid comparisons between forecast field and the actual ***,precision of traditional verification measures is easily affected by small scale errors and thus cannot well discriminate the accuracy or effectiveness of NWP model *** this study,the Method for Object-Based Diagnostic Evaluation(MODE),which has been widely adopted in verifying precipitation fields,is utilized in TC’s wind field verification for the first *** TC wind field forecast of deterministic NWP model and Ensemble Prediction System(EPS)of the European Centre for Medium-Range Weather Forecasts(ECMWF)over the western North Pacific and the South China Sea in 2020 were evaluated.A MODE score of 0.5 is used as a threshold value to represent a skillful(or good)*** is found that the R34(radius of 34 knots)wind field structure forecasts within 72 h are good regardless of DET or *** performance of R50 and R64 is slightly worse but the R50 forecasts within 48 h remain good,with MODE exceeded *** R64forecast within 48 h are worth for reference as well with MODE of around *** study states that the TC wind field structure forecast by ECMWF is skillful for TCs over the western North Pacific and the South China Sea.

关键词： Verification Tropical cyclones wind structure forecasts Numerical weather prediction models Ensemble prediction system