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Advancements and Challenges in Or.anic–Inor.anic Composite Solid Electr.ly.es for.All‑Solid‑State Lithium Batter.es

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Nano-Micr. Letter. 2025年第1期17卷 46-97页

作者： Xuey.n Zhang Shichao Cheng Chuankai fu Geping y.n Liguang Wang y.ngmin Wu Hua Huo State Key.Labor.tor. of Space Power.Sour.es School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001People’s Republic of China College of Chemical and Biological Engineer.ng Zhejiang UniversityHangzhou 310058People’s Republic of China State Key.Labor.tor. of Space Power.Sour.es 2965 Dongchuan RoadMinhang DistrictShanghai 200240People’s Republic of China

To addr.ss the limitations of contempor.r. lithium-ion batter.es,par.icular.y.their.low ener.y.density.and safety.concer.s,all-solid-state lithium batter.es equipped with solid-state electr.ly.es have been identified as an up-and-coming *** the var.ous SEs,or.anic–inor.anic composite solid electr.ly.es(OICSEs)that combine the advantages of both poly.er.and inor.anic mater.als demonstr.te pr.mising potential for.lar.e-scale ***,OICSEs still face many.challenges in pr.ctical applications,such as low ionic conductivity.and poor.inter.acial stability.which sever.ly.limit their.*** r.view pr.vides a compr.hensive over.iew of r.cent r.sear.h advancements in ***,the influence of inor.anic filler. on the main functional par.meter. of OICSEs,including ionic conductivity.Li+tr.nsfer.number.mechanical str.ngth,electr.chemical stability.electr.nic conductivity.and ther.al stability.ar. sy.tematically.*** lithium-ion conduction mechanism of OICSE is thor.ughly.analy.ed and concluded fr.m the micr.scopic ***,the classic inor.anic filler.ty.es,including both iner. and active filler.,ar. categor.zed with special emphasis on the r.lationship between inor.anic filler.str.ctur. design and the electr.chemical per.or.ance of ***,the advanced char.cter.zation techniques r.levant to OICSEs ar. summar.zed,and the challenges and per.pectives on the futur. development of OICSEs ar. also highlighted for.constr.cting super.or.ASSLBs.

关键词： Composite solid electr.ly.es Inor.anic filler Inter.acial stability Li-ion conduction mechanism Char.cter.zation techniques

Cr.cking evolution behavior. of lightweight mater.als based on in situ sy.chr.tr.n X-r.y.tomogr.phy. A r.view

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Fr.ntier. of Mechanical Engineer.ng 2018年第4期13卷 461-481页

作者： y. Luo S. C. Wu y. N. Hu y. N. fu State Key.Labor.tor. of Tr.ction Power Southwest Jiaotong University Chengdu 610031 China Shanghai Sy.chr.tr.n r.diation Facility Shanghai 201204 China

Damage accumulation and failur. behavior. ar. cr.cial concer.s dur.ng the design and ser.ice of a cr.tical component, leading r.sear.her. and engineer. to thor.ughly.identify.ng the cr.ck evolution. Thir.-gener.tion sy.chr.tr.n r.diation X-r.y.computed micr.tomo- gr.phy.can be used to detect the inner.damage evolution of a lar.e-density.mater.al or.component. This paper.pr.vides a br.ef r.view of study.ng the cr.ck initiation and pr.pagation inside lightweight mater.als with advanced sy.chr.tr.n thr.e-dimensional （3D） X-r.y.imaging, such as aluminum mater.als. Var.ous damage modes under.both static and dy.amic loading ar. elucidated for.pur. aluminum, aluminum alloy.matr.x, aluminum alloy.metal matr.x composite, and aluminum alloy.welded joint. For.aluminum alloy.matr.x, metallur.ical defects （por.sity. void, inclusion, pr.cipitate, etc.） or.ar.ificial defects （notch, scr.tch, pit, etc.） str.ngly.affect the cr.ck initiation and pr.pagation. For.aluminum alloy.metal matr.x composites, the fr.ctur. occur. either.fr.m the par.icle debonding or.voids at the par.icle/matr.x inter.ace, and the void evolution is closely.r.lated with fatigued cy.les. For.the hy.r.d laser.welded aluminum alloy. fatigue cr.cks usually.initiate fr.m gas por.s located at the sur.ace or.sub-sur.ace and gr.dually.pr.pagate to a quar.er.ellipse or.a ty.ical semi-ellipse pr.file.

关键词： fatigue cr.ck initiation and gr.wth fatigue damage mechanism damage toler.nce defect char.cter.zation laser.welded aluminum alloy.

Annual Time-ser.es Analy.es of Total Gaseous Mer.ur. Measur.ment and its Impact Factor. on the Gongga Mountains in the Southeaster. Fr.nge of the Qinghai-Tibetan Plateau

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Jour.al of Mountain Science 2008年第1期5卷 17-31页

作者： ZHU Wanze fu Xuewu FENG Xinbin Julia y. Lu Institute of Mountain Hazar. and Envir.nment Chinese Academy of Sciences Chengdu 610041 China State Key.Labor.tor. of Envir.nmental Geochemistr. Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China Depar.ment of Chemistr. and Biology Ryerson University Toronto Ontario M5B 2K3 Canada

Long-ter. monitor.ng pr.gr.ms for.measur.ment of atmospher.c mer.ur. concentr.tions ar. pr.sently.r.cognized as power.ul tools for.local,r.gional and global studies of atmospher.c long-r.nge tr.nspor. pr.cesses,and they.could also pr.vide valuable infor.ation about the impact of emission contr.ls on the global budget of atmospher.c mer.ur.,their.obser.ance and an insight into the global mer.ur. cy.le. China is believed to be an incr.asing atmospher.c mer.ur. emission sour.e. However.only.a few measur.ments of mer.ur.,to our.knowledge,have been done in ambient air.over.China. The highly.time r.solved atmospher.c mer.ur. concen-tr.tions have been measur.d at Moxi Base Station (102°72′E 29°92′N,1640 m asl) of the Gongga Alpine Ecosy.tem Obser.ation and Exper.ment Station of Chinese Academy.of Sciences (CAS) fr.m May.2005 to June 2006 by.using a set of Automatic Atmospher.c Mer.ur. Speciation Analy.er. (Tekr.n 2537A). Measur.ments wer. car.ied out with a time r.solution of ever. 15 minutes. The over.ll aver.ge total gaseous mer.ur. (TGM) cover.ng the measur.ment per.ods was 4±1.38 ng·m-3 (N=57310),which is higher.than the global backgr.und level of appr.ximately.1.5～2.0 ng·m-3. The measur.ments in all seasons showed a similar.diur.al change patter. with a high concentr.tion dur.ng day.ime r.lative to nighttime and maximum concentr.tion near.solar.noon and minimum concentr.tion immediately.befor. sunr.se. The pr.sence of diur.al TGM peaks dur.ng spr.ng and summer.was found ear.ier.than that dur.ng autumn and winter. When divided seasonally.it was found that the concentr.tions of TGM wer. highest in winter.with 6.13 ± 1.78 ng·m-3 and lowest in summer.with 3.17 ± 0.67 ng·m-3. Ther. wer. no significant differ.nces in TGM among wind sector. dur.ng each season. Wher.as Hg gener.lly.exhibited significant cor.elations with the par.meter.,such as temper.tur.,satur.ted vapor.pr.ssur.,pr.cipitation,ultr.violet r.diation (UV) and atmospher.c pr.ssur. at the whole measur.ment stage,

关键词： Total gaseous mer.ur. (TGM) diur.al var.ability seasonal var.ability meteor.logical factor Gongga Mountains

A HIEr.r.HICAL MULTIPLE Cr.TEr.A MODEL FOr.ELICITING r.LATIVE Pr.FEr.NCES IN CONFLICT SITUATIONS

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Jour.al of Sy.tems Science and Sy.tems Engineer.ng 2012年第1期21卷 56-76页

作者： Ginger.y. KE Bing fu Mitali DE Keith W. HIPEL Depar.ment of Management Sciences University of Waterloo Waterloo Canada N2G 3G1 Depar.ment of Sy.tems Design Engineer.ng University of Waterloo Waterloo Canada N2G 3G1 Depar.ment of Business Wilfrid Laurier University Waterloo Canada N2L 3C5

A multiple cr.ter.a decision analy.is （MCDA） appr.ach is designed for.captur.ng the r.lative pr.fer.nce infor.ation of a decision maker.involved in ＇a conflict. Mor. specifically. an MCDA appr.ach based on the outr.nking method, ELECTr. III, is employ.d for.r.nking states or.possible scenar.os in the conflict fr.m most to least pr.fer.ed, wher. ties ar. allowed, for.a decision maker.accor.ing to his or.her.value sy.tem. To demonstr.te how this pr.fer.nce elicitation methodology.can be conveniently.implemented in pr.ctice within the fr.mewor. of the Gr.ph Model for.Conflict r.solution, it is applied to a r.al wor.d water.supply.cr.sis which occur.ed in the town of Nor.h Battlefor., located in the Canadian pr.vince of Saskatchewan.

关键词： Multiple cr.ter.a decision analy.is gr.ph model for.conflict r.solution ELECTr. III fuzzy pr.fer.nces

Stability.of aneur.sm solutions in a fluid-filled elastic membr.ne tube

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Acta Mechanica Sinica 2012年第4期28卷 1209-1218页

作者： A. T. Ir.chev y.-B. fu Steklov Mathematical Institute Gubkina Str. 8 119991 Moscow Russia Depar.ment of Mathematics Keele University Staffordshire ST5 5BG U.K.

When a hy.er.lastic membr.ne tube is inflated by.an inter.al pr.ssur., a localized bulge will for. when the pr.ssur. r.aches a cr.tical value. As inflation continues the bulge will gr.w until it r.aches a maximum size after.which it will then pr.pagate in both dir.ctions to for. a hat-like pr.file. The stability.of such bulging solutions has r.cently.been studied by.neglecting the iner.ia of the inflating fluid and it was shown that such bulging solutions ar. unstable under.pr.ssur. contr.l. In this paper.we extend this r.cent study.by.assuming that the inflation is by.an inviscid fluid whose iner.ia we take into account in the stability.analy.is. This r.flects mor. closely.the situation of aneur.sm for.a- tion in human ar.er.es which motivates the cur.ent ser.es of studies. It is shown that fluid iner.ia would significantly.r.duce the gr.wth r.te of the unstable mode and thus it has a str.ng stabilizing effect.

关键词： Aneur.sms Localized bulging Stability Bi- fur.ation

Effects of r.r. Ear.h Elements on the Char.cter.stics of Low Temper.tur. Plasma Nitr.car.ur.zed Mar.ensitic Stainless Steel

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Jour.al of Mater.als Science & Technology 2012年第11期28卷 1046-1052页

作者： r.L.Lju y.J.Qiao M.F.y.n y.D.fu College of Mater.als Science and Chemical Engineer.ng Harbin Engineering UniversityHarbin 150001China School of Mater.als Science and Engineer.ng Harbin Institute of TechnologyHarbin 150001China

Low temper.tur. plasma nitr.car.ur.zing of 17-4PH mar.ensitic stainless steel was conducted at 430 ℃ with and without r.r. ear.h （r.） addition. The micr.str.ctur., kinetics, micr.har.ness, wear.behavior.as well as cor.osion r.sistance of the modified lay.r.wer. studied by.optical micr.scopy. X-r.y.diffr.ction, Vicker. micr.har.ness tester. pin-on-disc tr.bometer.and potentiody.amic polar.zation tests. The r.sults show that the thickness of plasma r. nitr.car.ur.zed lay.r.is much thicker.than that for.ed by.nitr.car.ur.zing without r. addition. The incor.or.tion of r. does not change the kind of the phases and the nitr.car.ur.zed lay.r.consists mainly.of nitr.gen and car.on expanded mar.ensite （aN）, γ-Fe4N and a-Fe with a tr.ce of Cr. phases. The sur.ace micr.har.ness of plasma nitr.car.ur.zed lay.r.can be incr.ased by.100 HV after.r. addition. Wear.r.sistance of the specimen can be appar.ntly.impr.ved by.low temper.tur. plasma nitr.car.ur.zing with and without r. addition and without sacr.ficing its cor.osion r.sistance. Wear.r.duction effect of low temper.tur. plasma nitr.car.ur.zing with r. addition is better.than that of the conventional one.

关键词： Stainless steel Low temper.tur. Plasma nitr.car.ur.zing r.r. ear.h (r.) Wear.and fr.ction

Nonlinear.static and dy.amic r.sponses of an electr.cally.actuated viscoelastic micr.beam

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Acta Mechanica Sinica 2009年第2期25卷 211-218页

作者： y.M.fu J.Zhang College of Mechanics and Aer.space Hunan University

On the basis of the Euler.Ber.oulli hy.othesis, nonlinear.static and dy.amic r.sponses of a viscoelastic micr.beam under.two kinds of electr.c for.es [a pur.ly.dir.ct cur.ent （DC） and a combined cur.ent composed of a DC and an alter.ating cur.ent] ar. studied. By.using Tay.or.ser.es expansion, a gover.ing equation of nonlinear.integr.-differ.ntial ty.e is der.ved, and numer.cal analy.es ar. per.or.ed. When a pur.ly.DC is applied, ther. exist an instantaneous pull-in voltage and a dur.ble pull-in voltage of which the phy.ical meanings ar. also given, wher.as under.an applied combined cur.ent, the effect of the element r.laxation coefficient on the dy.amic pull-in phenomenon is obser.ed wher. the lar.est Ly.punov exponent is taken as a cr.ter.on for.the dy.amic pull-in instability.of viscoelastic micr.beams.

关键词： MEMS Viscoelastic micr.beam Nonlinear.y.amics

Analy.is of Mechanical Pr.per.ies of Injection Molded Shor. Glass Fibr. (SGF)/Calcite/ABS Composites

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Jour.al of Mater.als Science & Technology 1997年第5期13卷 389-396页

作者： fu, S.y. Lauke, B. Institute for.Poly.er.r.sear.h Dr.sden e.V 01069 Dresden Hohe Str.6 Germany

Acr.lonitr.le-butadiene-Sty.0}ne (ABS), with and without calcium car.onate (calcite) par.icles,was used as the matr.x for.r.infor.ement with as-r.ceived shor.-glass fibr.s (wer. or.ginally.r.ated by.the manufactur.r. and sized shor.-glass fibr.s with two amino-silane coupling *** calcite par.icle content is 0, 11.7 and 23.5 vol. pct for.the matr.ces. The glass fiber.contentis 0, 10 and 15 vol. pct. The matr.x mater.als and cor.esponding composites wer. compoundedusing a twin scr.w extr.der.and dumbbell-shaped tensile bar. wer. pr.par.d with an injectionmolding pr.cess. The tensile and flexur.l pr.per.ies as well as the unnotched and notchedChar.y.impact ener.ies of shor. glass fibr./calcite/ABS composites wer. studied in this *** effects of fibr.s, fibr. sur.ace tr.atments and par.icles on these mechanical pr.per.ies ofthe composites wer. discussed in detail. An impor.ar.t infor.ation was obtained, which is thatthe tensile and flexur.l str.ngths of hy.r.d SGF/calcite/ABS composites ar. the same as thoseof cor.esponding fibr. composites when the r.tio of the inter.acial adhesion str.ngth betweenpar.icles and matr.x to that between fibr.s and matr.x is higher.than cer.ain value. other.ise thefor.er.ar. lower.than the latter.

关键词： ABS Calcite/ABS Composites SGF Analy.is of Mechanical Pr.per.ies of Injection Molded Shor. Glass Fibr.

Fir.t-pr.nciples calculation on the electr.nic str.ctur.s, phonon dy.amics, and electr.cal conductivities of Pb_(10)(PO_(4))_(6O) and Pb_(9)Cu(PO_(4))_(6O) compounds

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Jour.al of Mater.als Science & Technology 2024年第6期173卷 218-224页

作者： L.y.Hao E.G.fu State Key.Labor.tor. of Nuclear.Phy.ics and Technology Department of Technical PhysicsSchool of PhysicsPeking UniversityBeijing 100871China

Super.onducting mater.als with high cr.tical temper.tur. have the potential to r.volutionize many.fields,including militar.,electr.nic communications,and power.***,scientists ar.und the wor.d have been tir.lessly.wor.ing with the ultimate goal of achieving high-temper.tur. *** 2023,a pr.pr.nt by.Lee et *** South Kor.a claimed the discover. of ultr.-high-temper.tur. super.onductivity.with a cr.tical temper.tur. of up to 423 K in Cu-doped lead-apatite(LK-99)(ar.iv:2307.12008,ar.iv:2307.12037),which caused a wor.dwide sensation and ***,the electr.nic str.ctur.s,phonon dy.amics,and electr.cal conductivities of LK-99 and its par.nt compound lead-apatite have been calculated using fir.t-pr.nciples *** r.sults show that the lead-apatite compound and the LK-99 compound ar. insulator.and half-metal *** flat band char.cter.stic is consistent with pr.vious *** electr.cal conductivity.of the LK-99 compound shows two extr.me points,and the electr.cal conductivity.along the C-axis incr.ases significantly.after.400 *** phonon disper.ion spectr. of the compounds wer. investigated,demonstr.ting their.dy.amic instability.

关键词： Super.onductivity LK-99 Lead-apatite Fir.t-pr.nciples calculation