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Chinese Journal of Polymer Science 2024年第6期42卷 775-786页

作者： Shuang-Cheng Li Wei-Jia Zhou Wen-Jie Wu Jun Shao Shui-Liang Chen hao-qing Hou Sheng Xiang College of Chemistry&Chemical Engineering and Nanofiber Engineering Center of Jiangxi Province Jiangxi Normal UniversityNanchang330022China National Engineering Research Center for Carbohydrate Synthesis/Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal UniversityNanchang330022China Wenzhou Institute University of Chinese Academy of SciencesWenzhou325001China

For a polymer/polymer dismissible blend with two crystallizable components,the crystallization behavior of different components and the reciprocal influences between different crystals are interesting and important,but did not investigate in *** this study,the L-poly(lactic acid)/polypropylene(PLLA/PP)blends with different weight ratios were prepared by melt mixing and the crystallization behavior of the blends were *** showed that the crystalline structures of PLLA and PP were not altered by the *** the crystallization of PLLA,both the diffusion of chain segments and crystallization rate were enhanced under the existence of PP *** the crystallization of PP,its crystallization rate was depressed under the existence of amorphous PLLA molecular *** the PP crystallized from the existence of PLLA crystals,although the diffusion rate of PP was reduced by PLLA crystals,the nucleation positions were obviously enhanced,which accelerated the formation of PP *** investigation would supply more basic data for the application of PLLA/PP blend.

关键词： L-poly(lactic acid) Polypropylene Blends Crystalization behavior Crystallization acceleration

Ultrastable graphene isolated Au Ag nanoalloy for SERS biosensing and photothermal therapy of bacterial infection

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Chinese Chemical Letters 2024年第3期35卷 198-203页

作者： Shengkai Li Zhiyang Li qing hao Shen Wang Yanxia Yang Jieqiong Xu Zhiwei Yin Liang Zhang Zhuo Chen Molecular Science and Biomedicine Laboratory(MBL) State Key Laboratory of Chemo/Biosensing and ChemometricsCollege of Chemistry and Chemical EngineeringCollege of BiologyAptamer Engineering Center of Hunan ProvinceHunan UniversityChangsha 410082China School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials/Key Laboratory for Water Quality and Conservation of the Pearl River Delta Ministry of EducationGuangzhou UniversityGuangzhou 510006China

Plasmonic metal nanomaterials with intrinsic surface–enhanced Raman scattering(SERS)and photothermal properties,especially AuAg nanoalloys with both the outstanding merits of Au and Ag nanocrystals,show huge application prospects in bacterial ***,the direct exposure of AuAg nanoalloys in external conditions probably cause undesirable reactions and poisonous metal ion leakage during SERS detection and photothermal antibacterial therapy process,which severely hinder bacterial theranostics ***,we report an ultrastable graphene–isolated AuAg nanoalloy(GAA)with AuAg core confined in few–layer graphitic shell as a versatile platform for bacterial detection and *** encapsulation of graphene ensures the good stability of AuAg core,that its superior SERS and photothermal properties are therefore further *** is used for SERS detection of two vital bacterial biomarkers(including corrosive cyanide and pyocyanin),exhibiting good SERS quantitative and multiplexing *** is further used for photothermal antibacterial therapy application,and ultrahigh antibacterial efficacies for both Gram–negative Escherichia coli and Gram–positive Staphylococcus aureus are achieved under 808 nm laser *** work proposes a valuable method to develop robust bacterial theranostic platform.

关键词： Localized surface plasmon resonance Graphitic shell isolated AuAg nanoalloy(GAA) Surface–enhanced Raman scattering(SERS) Bacterial biomarker detection Photothermal antibacterial therapy

Dynamic Sulfur-Rich Polymers from Elemental Sulfur and Epoxides

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Chinese Journal of Polymer Science 2024年第10期42卷 1479-1487,I0010页

作者： Ke-Xiang Chen Chen-Hui Cui Zhen Li Ting Xu hao-qing Teng Zhi-Yuan He Yin-Zhou Guo Xiao-qing Ming Zhi-Shen Ge Yan-Feng Zhang Tie-Jun Wang School of Chemistry Engineering Research Center of Energy Storage Materials and DevicesMinistry of EducationXi’an Jiaotong UniversityXi’an710049China State Key Lab for Strength and Vibration of Mechanical Structures Department of Engineering MechanicsXi’an Jiaotong UniversityXi’an710049China

Sulfur-containing dynamic polymers had attracted significant attention due to their unique chemical structures with high *** sulfur, an inexpensive industrial waste product, to synthesize dynamic polysulfide polymers through reverse vulcanization has been a notable approach. However, this method required high temperatures and resulted in the release of unpleasant oders. In this study, we presented a robust method for the preparation of sulfur-rich polymers with dynamic polysulfide bonds from elemental sulfur and inexpensive epoxide monomers via a one-pot strategy at the mild room temperature. Different types of polysulfide molecules and polymers were synthesized by reacting various epoxide compounds with sulfur, along with the investigation of their structures and dynamic behaviors. It was noteworthy that the obatined polymers prepared from m-(2,3-epoxypropoxy)-N,N-bis(2,3-epoxypropyl)aniline and elemental sulfur exhibit multiple dynamic behaviors, including polysulfide metathesis and polysulfide-thiol exchange, enabling their rapid stress relaxation, self-healing, reprocessing and degradable properties of the cross-linked polymer. More importantly, the hydroxyl groups at the side chains from epoxide ring opening exhibited potential transesterification. This work provided a facile strategy for designing dynamic sulfur-rich polymers via a mild synthesis route.

关键词： Elemental sulfur Sulfur-containing polymer Dynamic covalent bond Dynamic polymer

Verteporfin fluorescence in antineoplastic-treated pancreatic cancer cells found concentrated in mitochondria

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World Journal of Gastrointestinal Oncology 2024年第3期16卷 968-978页

作者： Ying-Qiao Zhang qing-hao Liu Lu Liu Peng-Yu Guo Run-Ze Wang Zhi-Chang Ba Department of Radiology Harbin Medical University Cancer HospitalHarbin 150010Heilongjiang ProvinceChina Department of Digestive Internal Medicine Harbin Medical University Cancer HospitalHarbin 150010Heilongjiang ProvinceChina

BACKGROUND Traditional treatments for pancreatic cancer(PC)are *** therapy(PDT)is non-invasive,and proven safe to kill cancer cells,including ***,the mitochondrial concentration of the photosensitizer,such as verteporfin,is *** To investigate the distribution of fluorescence of verteporfin in PC cells treated with antitumor drugs,*** Workable survival rates of PC cells(AsPC-1,BxPC-3)were determined with chemotherapy[doxorubicin(DOX)and gemcitabine(GEM)]and non-chemotherapy[sirolimus(SRL)and cetuximab(CTX)]drugs in vitro,with or without verteporfin,as measured via MTT,flow cytometry,and laser confocal *** cell proliferation was associated with GEM that was more enduring compared with *** laser microscopy allowed observation of GEM-and verteporfin-treated PC cells co-stained with 4’,6-diamidino-2-phenylindole and MitoTracker Green to differentiate living and dead cells and subcellular localization of verteporfin,*** Cell survival significantly dropped upon exposure to either chemotherapy drug,but not to SRL or *** cell lines responded similarly to *** intensity of fluorescence was associated with the concentration of *** experiments using GEM showed that survival rates of the PC cells treated with 10μmol/L verteporfin(but not less)were significantly lower relative to nil *** and dead stained cells treated with GEM were *** GEM treatment,verteporfin was observed primarily in the *** Verteporfin was observed in living *** GEM-treated human PC cells,verteporfin was particularly prevalent in the *** study supports further study of PDT for the treatment of PC after neoadjuvant chemotherapy.

关键词： Photodynamic therapy Pancreatic cancer Verteporfin Mitochondria Chemotherapy Gemcitabine

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吉林省生态系统碳储量影响因素分析

中国环境科学 2024年第3期44卷 1706-1717页

作者：吴皓晴刘子刚中国人民大学环境学院北京100872

基于1990年、2000年、2010年和2020年吉林省土地利用数据,通过InVEST模型估算1990~2020年吉林省生态系统碳储量,并进一步探究吉林省生态系统碳储量的影响因素及其区域差异.结果表明:1990~2020年吉林省生态系统碳储量呈现先上升后下降的... 详细信息

基于1990年、2000年、2010年和2020年吉林省土地利用数据,通过InVEST模型估算1990~2020年吉林省生态系统碳储量,并进一步探究吉林省生态系统碳储量的影响因素及其区域差异.结果表明:1990~2020年吉林省生态系统碳储量呈现先上升后下降的趋势并存在空间正相关性.吉林省生态系统碳储量受到气候、植被等自然因素以及经济发展、城市建设和农业生产等人为因素的影响,年均NDVI和地表人类活动强度是主要的正向和负向影响因素,影响系数分别为1.09和-0.32.吉林省生态系统碳储量受空间因素的影响,忽略空间因素可能会高估气候因素对吉林省生态系统碳储量的影响.年均NDVI和地表人类活动强度均有正向的空间溢出效应,影响系数分别为0.83和0.73.吉林省东、中、西部生态系统碳储量的影响因素存在区域异质性.

关键词：生态系统碳储量 InVEST模型空间杜宾模型吉林省

Impact of baseline body mass index on the long-term prognosis of advanced hepatocellular carcinoma treated with immunotherapy

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World Journal of Gastroenterology 2024年第37期30卷 4132-4148页

作者： Yu-Qin Wang Di Pan Zhi-Yuan Yao Yu-Qi Li Peng-Fei Qu Run-Bang Wang qing-hao Gu Jie Jiang Zheng-Xiang Han hao-Nan Liu Department of General Surgery The Affiliated Hospital of Xuzhou Medical UniversityXuzhou 221000Jiangsu ProvinceChina Department of Oncology The Affiliated Hospital of Xuzhou Medical UniversityXuzhou 221000Jiangsu ProvinceChina Department of Gastroenterology The Second Affiliated Hospital of Xuzhou Medical UniversityXuzhou 221000Jiangsu ProvinceChina The First College of Clinical Medicine Xuzhou Medical UniversityXuzhou 221000Jiangsu ProvinceChina Department of Oncology Suining County People’s HospitalXuzhou 221000Jiangsu ProvinceChina

BACKGROUND Primary liver cancer is the sixth most common cancer worldwide,with hepato-cellular carcinoma(HCC)being the most prevalent *** the current availability of multiple immune or immune combination treatment options,the prognosis is still poor,so how to identify a more suitable population is extremely *** To evaluate the clinical effectiveness of combining lenvatinib with camrelizumab for patients with hepatitis B virus(HBV)-related HCC in Barcelona Clinic Liver Cancer(BCLC)stages B/C,considering various body mass index(BMI)in diffe-rent *** Retrospective data were collected from 126 HCC patients treated with lenvatinib plus *** were divided into two groups based on BMI:The non-overweight group(BMI<25 kg/m2,n=51)and the overweight/obese group(BMI≥25 kg/m2,n=75).Short-term prognosis was evaluated using mRECIST criteria,with subgroup analyses for non-overweight(BMI:18.5-24.9 kg/m2),overweight(BMI:25-30 kg/m2),and obese(BMI≥30 kg/m2)patients.A Cox proportional hazards regression analysis identified independent prognostic factors for overall survival(OS),leading to the development of a column-line graph *** subgroup analyses for non-overweight(BMI:18.5-24.9 kg/m2),overweight(BMI:25-30 kg/m2),and obese(BMI≥30 kg/m2)patients.A Cox proportional hazards regression analysis identified independent prognostic factors for overall survival(OS),leading to the development of a column-line graph *** Median progression-free survival was significantly longer in the obese/overweight group compared to the non-overweight ***,the median OS was significantly prolonged in the obese/overweight group than in the non-overweight *** objective remission rate and disease control rate for the two groups of patients were,respectively,objective remission rate(5.88%vs 28.00%)and disease control rate(39.22%vs 62.67%).Fatigue was more prevalent in the obese/overweight group,while other adverse effects showed n

关键词： Hepatocellular carcinoma Camrelizumab Lenvatinib Efficacy Safety

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敷设约束阻尼层的工字梁振动特性研究

振动工程学报 2024年第8期37卷 1320-1329页

作者：李小珍李昊卿蒋希昊毕然西南交通大学土木工程学院桥梁工程系四川成都610031

本文提出了一种计算带约束阻尼层梁振动响应的方法。以工字梁为研究对象,开展了室内振动试验,测得了不同位置的振动响应。并基于有限元法同步建立了数值仿真模型,利用模态应变能法准确计算了结构的自振频率和模态损耗因子。基于上述结果... 详细信息

本文提出了一种计算带约束阻尼层梁振动响应的方法。以工字梁为研究对象,开展了室内振动试验,测得了不同位置的振动响应。并基于有限元法同步建立了数值仿真模型,利用模态应变能法准确计算了结构的自振频率和模态损耗因子。基于上述结果,利用模态叠加法进行谐响应分析,得到了约束阻尼层工字梁的振动响应结果。将振动响应的实测值与仿真值进行对比,验证了模型的准确性。分析了设计参数(阻尼层厚度、约束层厚度)对构件自振频率、模态损耗因子及加速度总振级的影响。研究结果表明:各板件的振动响应有着相似的变化规律,腹板加速度总振级最大,底板次之,顶板最小;总体上阻尼层厚度对工字梁前5阶自振频率影响不大,而随着约束层厚度的增大,构件前5阶自振频率先减小后增大;增大阻尼层厚度和约束层厚度都能持续增大构件的模态损耗因子,进而有效降低加速度总振级,且对腹板的减振效果好于顶板和底板。

关键词：振动试验工字梁约束阻尼层模态应变能理论数值仿真

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Design and prototyping of the readout electronics for the transition radiation detector in the high energy cosmic radiation detection facility

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Nuclear Science and Techniques 2024年第4期35卷 189-199页

作者： Jie-Yu Zhu Yang-Zhou Su Hai-Bo Yang Fen-Hua Lu Yan Yang Xi-Wen Liu Ping Wei Shu-Cai Wan hao-qing Xie Xian-Qin Li Cong Dai Hui-Jun Hu Hong-Bang Liu Shu-Wen Tang Cheng-Xin Zhao Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China Guangxi Key Laboratory for Relativistic Astrophysics School of Physical Science and TechnologyGuangxi UniversityNanning 530004China

The high energy cosmic-radiation detection(HERD)facility is planned to launch in 2027 and scheduled to be installed on the China Space *** serves as a dark matter particle detector,a cosmic ray instrument,and an observatory for high-energy gamma rays.A transition radiation detector placed on one of its lateral sides serves dual purpose,(ⅰ)calibrating HERD's electromagnetic calorimeter in the TeV energy range,and(ⅱ)serving as an independent detector for high-energy gamma *** this paper,the prototype readout electronics design of the transition radiation detector is demonstrated,which aims to accurately measure the charge of the anodes using the SAMPA application specific integrated circuit *** electronic performance of the prototype system is evaluated in terms of noise,linearity,and *** the presented design,each electronic channel can achieve a dynamic range of 0–100 fC,the RMS noise level not exceeding 0.15 fC,and the integral nonlinearity was<0.2%.To further verify the readout electronic performance,a joint test with the detector was carried out,and the results show that the prototype system can satisfy the requirements of the detector's scientific goals.

关键词： HERD Dark matter particle detection TRD Readout electronics SAMPA Data acquisition Performance test

Theoretical characterization of the adsorption configuration of pyrrole on Si(100)surface by x-ray spectroscopy

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Chinese Physics B 2024年第2期33卷 430-435页

作者：李好情明静姜志昂李海波马勇宋秀能 School of Physics and Electronics Shandong Normal UniversityJinan 250358China

The possible configurations of pyrrole absorbed on a Si(100)surface have been investigated by x-ray photoelectron spectroscopy(XPS)and near-edge x-ray absorption fine structure(NEXAFS)*** C-1s XPS and NEXAFS spectra of these adsorption configurations have been calculated by using the density functional theory(DFT)method and fullcore hole(FCH)approximation to investigate the relationship between the adsorption configurations and the *** result shows that the XPS and NEXAFS spectra are structurally dependent on the configurations of pyrrole absorbed on the Si(100)*** with the XPS,the NEXAFS spectra are relatively sensitive to the adsorption configurations and can accurately identify *** NEXAFS decomposition spectra produced by non-equivalent carbon atoms have also been calculated and show that the spectral features vary with the diverse types of carbon atoms and their structural environments.

关键词： pyrrole silicon surface x-ray photoelectron spectroscopy(XPS) near-edge x-ray absorption fine structure(NEXAFS)

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环境规制与重污染企业的ESG表现

广东财经大学学报 2024年第1期39卷 85-99页

作者：徐浩庆林浩锋邢洁中国社会科学院经济研究所北京100005 丽水学院商学院浙江丽水323000 中国社会科学院大学经济学院北京102488

环境、社会和公司治理(ESG)在一定程度上可衡量上市公司的综合水平,是体现双碳目标、推进绿色可持续转型的重要标准。以2014年《环境保护法》修订及17个省份颁布或修订环保条例作为准自然实验,根据彭博数据提供的ESG得分衡量上市公司的... 详细信息

环境、社会和公司治理(ESG)在一定程度上可衡量上市公司的综合水平,是体现双碳目标、推进绿色可持续转型的重要标准。以2014年《环境保护法》修订及17个省份颁布或修订环保条例作为准自然实验,根据彭博数据提供的ESG得分衡量上市公司的ESG表现,探讨环境规制对上市公司ESG表现的影响及其内在机制。研究发现,相比于非重污染上市公司,环境规制显著提升了重污染上市公司的ESG表现;从分项来看,环境规制显著促进了上市公司的环境和社会责任表现,但对公司治理的改善作用不明显;异质分析来看,环境规制对国有企业、研发投入高的上市公司ESG表现的影响更为显著。为此,政府应加快ESG信息披露的标准化建设,提高上市公司ESG信息披露质量;加强组织领导,完善相关法律和部门规章制度,推动企业积极践行ESG理念。

关键词：环境规制重污染企业 ESG表现创新能力绿色发展