检索结果-南通市图书馆

Mechanism and characterization of microplastic aging process: A review

Frontiers of Environmental Science & Engineering 2023年第8期17卷 107-125页

作者： Qinwei Lu Yi Zhou qian sui Yanbo Zhou State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and TechnologyShanghai 200237China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

With the increasing production of petroleum-based plastics,the problem of environmental pollution caused by plastics has aroused widespread ***,which are formed by the fragmentation of macro plastics,are bio-accumulate easily due to their small size and slow degradation under natural *** aging of plastics is an inevitable process for their degradation and enhancement of adsorption performance toward pollutants due to a series of changes in their physiochemical properties,which significantly increase the toxicity and harm of ***,studies should focus on the aging process of microplastics through reasonable characterization methods to promote the aging process and prevent white *** review summarizes the latest progress in natural aging process and characterization methods to determine the natural aging mechanism of *** addition,recent advances in the artificial aging of microplastic pollutants are *** degradation status and by-products of biodegradable plastics in the natural environment and whether they can truly solve the plastic pollution problem have been *** from the literature pointed out that the aging process of microplastics lacks professional and exclusive characterization methods,which include qualitative and quantitative *** lessen the toxicity of microplastics in the environment,future research directions have been suggested based on existing problems in the current *** review could provide a systematic reference for in-depth exploration of the aging mechanism and behavior of microplastics in natural and artificial systems.

关键词： Microplastics Aging Degradation Characterization Mechanism

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Toward a rapid and convenient nanoplastic quantification method in laboratory-scale study based on fluorescence intensity

引用

Frontiers of Environmental Science & Engineering 2024年第5期18卷 117-126页

作者： Ruiqi Yan Sen Lin qian Ding Lei Zhang Xia Yu Wentao Zhao qian sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai200237China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai200092China

The thorough investigation of nanoplastics(NPs)in aqueous environments requires efficient and expeditious quantitative analytical methods that are sensitive to environmentally relevant NP concentrations and convenient to *** analysis-based quantitative methods have been acknowledged as effective and rapid approaches for quantifying NP concentrations in laboratory-scale ***,we compared three commonly used optical response indicators,namely fluorescence intensity(FI),ultraviolet absorbance,and turbidity,to assess their performance in quantifying ***,orthogonal experiments were conducted to evaluate the influence of various water quality parameters on the preferred indicator-based quantification *** results revealed that FI exhibits the highest correlation coefficient(>0.99)with NP ***,the limit of quantification(LOQ)for various types of NPs is exceptionally low,ranging from 0.0089 to 0.0584 mg/L in ultrapure water,well below environmentally relevant *** variations in water quality parameters such as pH,salinity,suspended solids(SS),and humic acid,a robust relationship between detectable FI and NP concentration was ***,an increased matrix,especially SS in water samples,results in an enhanced LOQ for ***,the quantitative method remains applicable in real water bodies,especially in drinking water,with NP LOQ as low as 0.0157–0.0711 mg/*** exceeds the previously reported detectable concentration for 100 nm NPs at 40µg/mL using surface-enhanced Raman *** study confirms the potential of FI as a reliable indicator for the rapid quantification of NPs in aqueous environments,offering substantial advantages in terms of both convenience and cost-effectiveness.

关键词： Nanoplastic quantification Fluorescence intensity Drinking water Limit of quantification(LOQ) Matrix effects

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Coking wastewater treatment for industrial reuse purpose: Combining biological processes with ultrafiltration, nanofiltration and reverse osmosis

引用

Journal of Environmental Sciences 2013年第8期25卷 1565-1574页

作者： Xuewen Jin Enchao Li Shuguang Lu Zhaofu Qiu qian sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and Technology Shanghai Baosteel Chemical Co. Ltd.

A full-scale plant using anaerobic, anoxic and oxic processes （A1/A2/O）, along with a pilot-scale membrane bioreactor （MBR）, nanofiltration （NF） and reverse osmosis （RO） integrated system developed by Shanghai Baosteel Chemical Co. Ltd., was investigated to treat coking wastewater for industrial reuse over a period of one year. The removals reached 82.5% （COD）, 89.6% （BOD）, 99.8% （ammonium nitrogen）, 99.9% （phenol）, 44.6% （total cyanide （T-CN））, 99.7% （thiocyanide （SCN-）） and 8.9% （fluoride）, during the A1/A2/O biological treatment stage, and all parameters were further reduced by over 96.0%, except for fluoride （86.4%）, in the final discharge effluent from the currently operating plant. The pilot-scale MBR process reduced the turbidity to less than 0.65 NTU, and most of the toxic organic compounds were degraded or intercepted by the A1/A2/O followed MBR processes. In addition, parameters including COD, T-CN, total nitrogen, fluoride, chloride ion, hardness and conductivity were significantly reduced by the NF-RO system to a level suitable for industrial reuse, with a total water production ratio of 70.7%. However, the concentrates from the NF and RO units were highly polluted and should be disposed of properly or further treated before being discharged.

关键词： coking wastewater industrial water reuse biological treatment MBR NF-RO

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Recent advances in pharmaceuticals and personal care products in the surface water and sediments in China

引用

Frontiers of Environmental Science & Engineering 2016年第6期10卷 29-40页

作者： Wentao Zhao Ying Guo Shuguang Lu Pingping Yan qian sui State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and Engineering Tongji University Shanghai 200092 China State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental Engineering East China University of Science and Technology Shanghai 200237 China Beijing Key Laboratory for Emerging Organic Contaminants Control Tsinghua University Beijing 100084 China

Pharmaceuticals and personal care products （PPCPs） have been regarded as an emerging problem in the surface water environment in the past few decades. In China, although related studies were initiated several years ago, an increasing number of studies on this topic have been conducted in recent years. These studies have expanded knowledge of their occurrence, behavior and associated risk in the surface water environment in China. This review compiles the most recent literature related to the studies of PPCPs in the surface water environment in China. It includes PPCP occurrence in surface water and sediments, their geographical distribution, and outcomes of the associated risk assessment. It shows that antibiotics have received much more attention in both surface water and sediments than other PPCPs. Compared to other countries; most antibiotics in the collected sediments in China showed higher contamination levels. Many more study areas have been covered in recent years; however, attention has been given to only specific areas. Environmental risk assessment based on risk quotients indicated that sulfamethoxazole presents the most significant environmental risk to relevant aquatic organisms; followed by ofloxacin, ciprofloxacin, enrofloxacin, 17α-ethynylestradiol, ibuprofen and diclofenac. Despite limited research on the environmental risk assessment of PPCPs in sediments, higher risks posed by PPCPs in the sediments rather than surfhce water were identified highlighting the need for further risk assessment of PPCPs in sediment samples.

关键词： Surface water Sediment Antibiotics Geographical distribution Risk assessment

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Enhanced carbon tetrachloride degradation by hydroxylamine in ferrous ion activated calcium peroxide in the presence of formic acid

引用

Frontiers of Environmental Science & Engineering 2020年第2期14卷 75-85页

作者： Wenchao Jiang Ping Tang Zhen Liu Huan He qian sui Shuguang Lyu State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and TechnologyShanghai 200237China Environmental Engineering and Science Program Department of Chemical and Environmental EngineeringUniversity of CincinnatiCincinnatiOH 45221-0071USA

Hydroxyl radicals(HO*)show low reactivity with perchlorinated hydrocarbons,such as carbon tetrachloride(CT),in conventional Fenton reactions,therefore,the generation of reductive radicals has attracted increasing *** study investigated the enhancement of CT degradation by the synergistic effects of hydroxylamine(HA)and formic acid(FA)(initial[CT]=0.13 mmol/L)in a Fe(il)activated calcium peroxide(CP)fenton *** degradation increased from 56.6%to 99.9%with the addition of 0.78 mmol/L HA to the CP/Fe(II)/FA/CT process in a molar ratio o f 12/6/12/*** results also showed that the presence of HA enhanced the regeneration of Fe(II)from Fe(III),and the production of HO*increased one-fold when employing benzoic acid as the HO****,FA slightly improves the production of HO*.A study of the mechanism confirmed that the carbon dioxide radical(C02·),a strong reductant generated by the reaction between FA and HO*,was the dominant radical responsible for CT *** complete CT dechlorination was achieved in the *** presence of humic acid and chloride ion slightly decreased CT removal,while high doses of bicarbonate and high pH inhibited CT *** study helps us to better understand the synergistic roles of FA and HA for HO·and C02·^-generation and the removal of perchlorinated hydrocarbons in modified Fenton systems.

关键词： Calcium peroxide Hydroxylamine Modified Fenton Reactive oxygen species Perchlorinated hydrocarbon

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Enhanced reductive degradation of carbon tetrachloride by carbon dioxide radical anion-based sodium percarbonate/ Fe（ll）/formic acid system in aqueous solution

引用

Frontiers of Environmental Science & Engineering 2018年第2期12卷 61-70页

作者： Wenchao Jiang Ping Tang Shuguang Lu Xiang Zhang Zhaofu Qiu qian sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and Technology Shanghai 200237 China

The performance of sodium percarbonate （SPC） activated with ferrous ion （Fe（Ⅱ） with the addition of formic acid （FA） to stimulate the degradation of carbon tetrachloride （CT） was investigated. Results showed that CT could be entirely reduced within 15 min in the system at a variety of SPC/Fe（Ⅱ）/FA/CT molar ratios in experimental level. Scavenging tests indicated that carbon dioxide radical anion （CO2-） was the dominant reactive oxygen species responsible for CT degradation. CT degradation rate, to a large extent, increased with increasing dosages of chemical agents and the optimal molar ratio of SPC/Fe（Ⅱ）/FAJCT was set as 60/60/60/1. The initial concentration of CT can hardly affect the CT removal, while CT degradation was favorable in the pH range of 3.0-9.0, but apparently inhibited at pH 12. C1- and HCO3 of high concentration showed negative impact on CT removal. Cl- released from CT was detected and the results confirmed nearly complete mineralization ofCT. CT degradation was proposed by reductive C-C1 bond splitting. This study demonstrated that SPC activated with Fe（Ⅱ） with the addition of FA may be promising technique for CT remediation in contaminated groundwater.

关键词： Carbon tetrachloride Sodium percarbonate Formic acid Reductive radicals Groundwater

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Rapid determination of pharmaceuticals from multiple therapeutic classes in wastewater by solid-phase extraction and ultra-performance liquid chromatography tandem mass spectrometry

引用

Chinese Science Bulletin 2009年第24期54卷 4633-4643页

作者： sui qian HUANG Jun DENG ShuBo YU Gang POPs Research Centre Department of Environmental Science and Engineering Tsinghua University Beijing 100084 China

A new analytical method utilizing ultra-performance liquid chromatography (UPLC) tandem mass spectrometry (MS/MS) has been developed to determine 16 pharmaceuticals from 8 therapeutic classes in wastewater: bezafibrate, clofibric acid, carbamazepine, caffeine, chloramphenicol, diclofenac, gemfibrozil, indomethacin, ketoprofen, mefenamic acid, metoprolol, nalidixic acid, N,N-diethyl-metatoluamide, propranolol, sulpiride and trimethoprim. Key parameters of MS/MS, UPLC and solid phase extraction (SPE) were optimized. In general, recovery of target pharmaceuticals was over 70% for the wastewater effluent samples and 50% for the influent samples. The effects of matrix suppression, loss during the pretreatment as well as instrument variability were successfully corrected by two internal standards, and acceptable relative recovery was obtained. Target compounds were quantitatively analyzed using multiple reaction monitoring (MRM) mode, and the detection limits ranged from 0.3 to 20 ng/L. A detailed study, matrix effect in effluent wastewater was also present. The method was applied to detecting pharmaceuticals in the wastewater from three wastewater treatment plants (WWTPs) in Beijing, China and the results demonstrated that most target compounds were detectable in both the influent and effluent, with the mean concentrations ranging from 20.5 to 5775.6 ng/L and 4.6 to 418.6 ng/L, respectively.

关键词：高效液相色谱串联质谱法固相萃取废水药品快速测定治疗污水处理厂

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Promoting Environmental Risk Assessment and Control of Emerging Contaminants in China

引用

Engineering 2024年第6期37卷 13-17页

作者： Bin Wang qian sui Huijuan Liu Gang Yu Jiuhui Qu School of Environment Tsinghua UniversityBeijing 100084China School of Resources and Environmental Engineering East China University of Science and TechnologyShanghai 200237China Advanced Interdisciplinary Institute of Environmental and Ecology Beijing Normal UniversityZhuhai 519000China

*** In recent years,China has carried out an extensive preventative battle against air,water,and soil pollution,and the nation’s environmental quality-as reflected by conventional pollutant indicators—has significantly *** the same time,the issue of emerging contaminants(ECs)is beginning to receive increasing *** generally refer to newly discovered or noticeable pollutants that pose risks to the ecological environment or human *** they have not been included in environmental management,or existing management measures are insufficient to effectively prevent and control their *** ECs of greatest concern generally include persistent organic pollutants(POPs),endocrine-disrupting chemicals(EDCs),pharmaceuticals and personal care products(PPCPs),and *** four categories of ECs are not entirely separate,as they interrelate with each other(Fig.1).Chemical production and product usage are the main sources of *** is the world’s largest producer and consumer of bulk chemicals,and the production value of China’s chemical industry is predicted to reach 50%of the global total by 2030[1].Scientific control of ECs based on their environmental risk assessment is a necessary way to support the prevention and legal governance of ECs.

关键词： legal entirely prevention

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Screening of indicator pharmaceuticals and personal care products in landfill leachates: a case study in Shanghai, China

引用

Frontiers of Environmental Science & Engineering 2023年第9期17卷 245-256页

作者： Xiping Kan Xia Yu Wentao Zhao Shuguang Lyu Shuying Sun Gang Yu qian sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Advanced Interdisciplinary Institute of Environment and Ecology Beijing Normal University at ZhuhaiZhuhai 519087China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

Identifying potential sources of pharmaceuticals and personal care products(PPCPs)in the environment is critical for the effective control of PPCP *** leachate is an important source of PPCPs in water;however,it has barely been involved in source apportionment due to the lack of indicator-PPCPs(i-PPCPs)in landfill *** study provides the first systematic framework for identifying i-PPCPs for landfill leachates based on the wide-scope target monitoring of *** number of target PPCPs increased from<20 in previous studies to 68 in the present ***-nine PPCPs were detected,with median concentrations in leachate samples ranging from below the method quantification limit(MQL)to 41μg/L,and 19 of them were rarely reported previously.A total of 29 target compounds were determined to be PPCPs of high concern by principal component analysis according to multiple criteria,including occurrence,exposure potential,and ecological *** with source-specificity and representativeness analysis,erythromycin,gemfibrozil,and albendazole showed a significant difference in their occurrence in leachate compared to other potential sources(untreated and treated municipal wastewater and livestock wastewater)and correlated with total PPCP concentrations;these were recommended as i-PPCPs for *** screening procedure can be used to develop a sophisticated source apportionment method to identify sources of PPCPs from adjacent landfills.

关键词： Landfill leachates PPCPs Indicator Screening criteria Source-specificity

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Identification and ecotoxicity assessment of intermediates generated during the degradation of clofibric acid by advanced oxidation processes

引用

Frontiers of Environmental Science & Engineering 2012年第4期6卷 445-454页

作者： Wenzhen LI Yu DING qian sui Shuguang LU Zhaofu QIU Kuangfei LIN State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process Shanghai Key Laboratory of Functional Materials ChemistryEast China University of Science and TechnologyShanghai 200237China Datang Energy Corporation Hulunbeier 021008China

The aim of this study was to identify the intermediates in clofibric acid degradation under various advanced oxidation processes, namely ultraviolet （UV）, UV/H2O2, vacuum ultraviolet （VUV）, VUV/H2O2, and solar/TiO2 processes, as well as to assess the toxicity of these intermediates. Eleven intermediates have been detected by gas chromatography-mass spectrometer, most of which were reported for the first time to our best knowledge. Combining the evolution of the dissolved organic carbon, CF and specific ultraviolet absorption at 254 nm, it could be deduced that cleavage of aromatic ring followed by dechlorination was the mechanism in solar/ TiO2 process, while dechlorination happened first and accumulation of aromatic intermediates occurred in the other processes. Different transformation pathways were proposed for UV-, VUV-assisted and solar/TiO2 processes, respectively. The acute toxicity was evaluated by means of Photobacterium phosphoreurn T3 spp. bioassay. It was believed that aromatic intermediates increased the toxicity and the ring-opening pathway in solar/TiO2 process could relieve the toxicity.

关键词： clofibric acid advanced oxidation processes intermediates toxicity Photobacterium phosphoreum T3 spp.

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：