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Separation and Determination of Cobalt, Rhodium,Nickel and Iridium with 2-(6-Methyl-2-Benzothiazolylazo)-5-Diethylamino Phenol by HPLC

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Chemical Research in Chinese Universities 1993年第1期9卷 18-23页

作者： LIU qi-ping, zhang hua-shan and CHENG Jie-ke (Department of Chemistry, Wuhan University, Wuhan, 430072)

The synthesis and spectrophotometric properties of 2-(6-methyl-2-benzothiazolylazo)-5-diethylamino phenol (MBTAE), and the use of it as a precolumn derivatizing reagent to separate Co(Ⅱ), Ni(Ⅱ), Rh(Ⅲ) and Ir( Ⅳ) complexes by HPLC are discussed. When the mobile phase consists of methanol/water(90/10 Ⅴ/Ⅴ), acetate buffer with pH 4. 0 and 5×10-5 mol/L EDTA solution, the four complexes Can be separated within 9 min on ODS column. The detection limits (20 μL sample size) are 0. 059 ppb, 0. 062 ppb, 0. 053 ppb and 0. 049 ppb for Co(Ⅱ) , Rh(Ⅲ), Ni(Ⅱ) and lr(Ⅳ) respectively at a signal-to-noise ratio of 3.

关键词： Cobalt Rhodium Nickel Iridium HPLC

Password-Authenticated Multiple Key Exchange Protocol for Mobile Applications

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China Communications 2012年第1期9卷 64-72页

作者： Li Wenmin Wen qiaoyan Su qi zhang hua Jin Zhengping State Key Laboratory of Networking and Switching Technology Beijing Uniwrsity of Posts and Telecommunications Beijing100876 P. R. China

To achieve privacy and authentication sinmltaneously in mobile applications, various Three-party Password-authenticated key exchange （3PAKE） protocols have been proposed. However, some of these protocols are vulnerable to conventional attacks or have low efficiency so that they cannot be applied to mobile applications. In this paper, we proposed a password-authenticated multiple key exchange protocol for mobile applications using elliptic curve cryptosystem. The proposed protocol can achieve efficiency, reliability, flexibility and scalability at the same time. Compared with related works, the proposed protocol is more suitable and practical for mobile applications.

关键词： mobile applications key exchange password elliptic curve cryptosystem security

Multichannel Adaptive Polarization Mode Dispersion Compensation with One Compensator in Dense Wavelength Division Multiplexing Transmission Systems

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Semiconductor Photonics and Technology 2007年第1期13卷 58-62,75页

作者： zhang qi CHEN Ming-hua zhang Ji-yu XIE Shi-zhong Department of Electronic Engineering Tsinghua University Beingjing 100084 CHN

A simple two-section polarization mode dispersion(PMD) compensator is proposed for multichannel PMD compensation, which can compensate two or even more channels simultaneously. Because of the statistical characteristics and the frequency-dependence of PMD, for current single mode fiber with moderate PMD, the probability that all channels are severely degraded at the same time is extremely small, which makes it possible to compensate a dense wavelength division multiplexing(DWDM) transmission system with moderate PMD using this compensator. It is shown that the outage probability of a 40×43 Gb/s DWDM transmission system using this compensator is decreased significantly from 3.6×10-3 to 3.6×10-5.

关键词： polarization mode dispersion dense wavelength division multiplexing transmission systemtmuhichannel adaptive compensation

Drug-eluting stents improve clinical outcomes in Chinese diabetic patients with de novo coronary artery disease

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Chinese Medical Journal 2006年第18期119卷 1576-1579页

作者： zhang qi FANG Yue-hua zhang Rui-yan HU Jian YANG Zhen-kun NI Jun zhang Jian-sheng SHEN Wei-feng Department of Cardiology Shanghai Ruijin Hospital Shanghai Jiaotong University School of Medicine Shanghai 200025 China

Diabetes mellitus （DM） has been regarded as an equivalent risk factor as coronary artery disease and is present in nearly 25% of patients who receive percutaneous coronary intervention （PCI）. DM is shown as an adverse predictor for major adverse cardiac events （MACE） after PCI in bare metal stent （BMS） era. Recently, clinical trials have demonstrated the favorable tendency of using drug-eluting stents （DES） in treating diabetic patients with coronary artery disease. This study compared the clinical outcomes between the diabetic patients receiving DES with those receiving BMS in China.

关键词： coronary disease diabetes mellitus drug-eluting stent outcome assessment

Ammonia pyrolysis oxidation excited by nanosecond pulsed discharge:Global/fluid models hybrid solution

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Journal of Energy Chemistry 2025年第1期100卷 385-396页

作者： Mingming zhang Hanyu Wu qi Chen Jiaxin Yang Bonan Liu School of Mechanical Electronic and Control Engineering Beijing Jiaotong University China University of Petroleum

The kinetic characteristics of plasma-assisted oxidative pyrolysis of ammonia are studied by using the global/fluid models hybrid solution ***,the stable products of plasma-assisted oxidative pyrolysis of ammonia are *** results show that the consumption of NH3/O2and the production of N2/H2change linearly with the increase of voltage,which indicates the decoupling of nonequilibrium molecular excitation and oxidative pyrolysis of ammonia at low ***,the detailed reaction kinetics mechanism of ammonia oxidative pyrolysis stimulated by a nanosecond pulse voltage at low pressure and room temperature is *** on the reaction path analysis,the simplified mechanism is *** detailed and simplified mechanism simulation results are compared with experimental data to verify the accuracy of the simplified ***,based on the simplified mechanism,the fluid model of ammonia oxidative pyrolysis stimulated by the nanosecond pulse plasma is established to study the pre-sheath/sheath behavior and the resultant consumption and formation of key *** results show that the generation,development,and propagation of the pre-sheath have a great influence on the formation and consumption of *** consumption of NH3by the cathode pre-sheath is greater than that by the anode pre-sheath,but the opposite is true for OH and O（1S）.However,within the sheath,almost all reactions do not ***,by changing the parameters of nanosecond pulse power supply voltage,it is found that the electron number density,electron current density,and applied peak voltages are not the direct reasons for the structural changes of the sheath and ***,the discharge interval has little effect on the sheath structure and gas mixture *** research results of this paper not only help to understand the kinetic promotion of non-equilibrium excitation in the process of oxidative pyrolysis but also help to explore th

关键词： Nanosecond pulsed discharge Ammonia Oxidative pyrolysis Fluid model Global model

1,1,1-Tris-(benzenesulfonyloxymethy 1)propane

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1,1,1-Tris-(benzenesulfonyloxymethy 1)propane

ImSpiRE: image feature-aided spatial resolution enhancement method

全国第十四届大环化学暨第六届超分子化学学术讨论会

作者： JIANG Guang-qi~* MA Pei-hua zhang Yun-qian zhang qian-jun Department of Chemistry,Guizhou University,Guiyang(550025)

The title compound,CHOS,the molecule possesses the similar orientations of the three benzene sulfonate *** angles between the aromatic ring planes are 82.61(14)°, 87.69(15)°and 67.45(11)°,*** significantly,the intermolecular hydrogen bonds and C-H-π interactions result in the zigzag chains network structure along the [100] axis direction.

关键词： 1,1,1-tris-(benzenesulfonyloxymethy 1)propane C-H…O hydrogen bonds C-H…π interactions

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Science China Life Sciences 2025年第1期 272-283页

作者： Yuwei hua Yizhi zhang Zhenming Guo Shan Bian Yong zhang State Key Laboratory of Cardiovascular Diseases and Medical Innovation Center Institute for Regenerative MedicineDepartment of NeurosurgeryShanghai East HospitalShanghai Key Laboratory of Signaling and Disease ResearchFrontier Science Center for Stem Cell ResearchSchool of Life Sciences and TechnologyTongji University

The resolution of most spatially resolved transcriptomic technologies usually cannot attain the single-cell level, limiting their applications in biological discoveries. Here, we introduce ImSpiRE, an image feature-aided spatial resolution enhancement method for in situ capturing spatial transcriptome. Taking the information stored in histological images, ImSpiRE solves an optimal transport problem to redistribute the expression profiles of spots to construct new transcriptional profiles with enhanced resolution, together with extending the gene expression profiles into unmeasured regions. Applications to multiple datasets confirm that ImSpiRE can enhance spatial resolution to the subspot level while contributing to the discovery of tissue domains, signaling communication patterns, and spatiotemporal characterization.

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Flexible molecules dedicate to release strain of inverted inorganic perovskite solar cell

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Journal of Energy Chemistry 2025年第1期100卷 87-93页

作者： Hongrui Sun Sanlong Wang Pengyang Wang Yali Liu Shanshan qi Biao Shi Ying Zhao Xiaodan zhang Institute of Photoelectronic Thin Film Devices and Technology Renewable Energy Conversion and Storage Center State Key Laboratory of Photovoltaic Materials and CellsNankai University Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin Haihe Laboratory of Sustainable Chemical Transformations Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

The tensile strain in inorganic perovskite films induced by thermal annealing is one of the primary factors contributing to the inefficiency and instability of inorganic perovskite solar cells （IPSCs）,which reduces the defect formation ***,a flexible molecule 5-maleimidovaleric acid （5-MVA） was introduced as a strain buffer to release the residual strain of *** anhydride and carboxyl groups in 5-MVA interact strongly with the uncoordinated Pb2+through Lewis acid-base reaction,thus tightly“pull”the perovskite *** in-between soft carbon chain increased the structural flexibility of CsPbI2.85Br0.15perovskite materials,which effectively relieved the intrinsic internal strain of CsPbI2.85Br0.15,resisted the corrosion of external strain,and also reduced the formation of defects such as VIand *** addition,the introduction of 5-MVA improved crystal quality,passivated residual defects,and narrowed energy level ***,power conversion efficiency （PCE） of NiOxbased inverted IPSCs increased from 19.25% to 20.82% with the open-circuit voltage enhanced from 1.164 V to 1.230 *** release of strain also improved the stability of CsPbI2.85Br0.15perovskite films and devices.

关键词： Inverted inorganic perovskite solar cells Flexible molecules Strain release Crystallization Energy barrier High PCE

混凝土冲击拉伸力学性能及裂纹扩展试验研究和数值模拟

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三峡大学学报（自然科学版） 2018年第3期40卷 56-60页

作者：戚亚珍张华郭继鑫河海大学土木与交通学院南京210098

为真实反映混凝土材料劈裂拉伸力学性能,基于应变片法采用分离式霍普金森压杆对混凝土平台巴西圆盘试件进行了劈裂拉伸试验,研究了不同加载角对试件起裂方式及破坏模式的影响,并对试件破坏过程进行了扩展有限元模拟,同时与试验结果进行... 详细信息

为真实反映混凝土材料劈裂拉伸力学性能,基于应变片法采用分离式霍普金森压杆对混凝土平台巴西圆盘试件进行了劈裂拉伸试验,研究了不同加载角对试件起裂方式及破坏模式的影响,并对试件破坏过程进行了扩展有限元模拟,同时与试验结果进行了对比分析,得到用于测试混凝土拉伸力学性能的最优加载角.基于此得到动态劈拉下3种不同强度混凝土的劈裂拉伸应力-径向应变曲线及抗拉强度、极限应变、拉伸敏感系数等参数的应变率效应.结果表明:20°加载角可以保证圆盘在中心起裂,用于测试混凝土劈裂拉伸性能最为可靠.在高应变率下,混凝土动态力学参数均具有明显的应变率效应,裂纹沿试件受力方向扩展、贯通直至试件沿加载直径方向劈裂为两半,破坏面表现为骨料破坏,与数值模拟结果一致.

关键词：霍普金森压杆加载中心角平台巴西圆盘裂纹扩展力学性能扩展有限元