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A kinetic model for a single step biodiesel production from a high free fatty acid (FFA) biodiesel feedstock over a solid heteropolyacid catalyst

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Green Energy & Environment 2019年第3期4卷 328-341页

作者： Aashish Gaurav Stéphane Dumas Chau T.q.Mai Flora T.T.ng Department of Chemical Engineering University of Waterloo

Production of biodiesel from yellow grease(waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids(FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkalicatalyzed production systems due to saponification problems.'Green' methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina(HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel.

关键词： Yellow grease Canola oil Free fatty acids Heteropolyacid Kinetics for esterification and transesterification

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On the first negative Hecke eigenvalue of an automorphic representation of GL_(2)(A_(q))

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Science China Mathematics 2021年第11期64卷 2381-2394页

作者： Yuk-Kam Lau Ming Ho ng Hengcai Tang Yingnan Wang Department of Mathematics The University of Hong KongHong KongChina Department of Mathematics The Chinese University of Hong KongHong KongChina Institute of Modern Mathematics School of Mathematics and StatisticsHenan UniversityKaifeng 475004China Shenzhen Key Laboratory of Advanced Machine Learning and Applications College of Mathematics and StatisticsShenzhen UniversityShenzhen 518060China

Letπbe a self-dual irreducible cuspidal automorphic representation of GL_(2)(A_(q))with trivial central *** Hecke eigenvalue λπ(n)is a real multiplicative function in *** show that λπ(n)<0 for some n<<q^(2/5)_(π... 详细信息

关键词： automorphic representation Hecke eigenvalue Maass cusp form sign change

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Acute and chronic excitotoxicity in ischemic stroke and late-onset Alzheimer's disease

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Neural Regeneration Research 2025年第7期20卷 1981-1988页

作者： Shan Ping Yu Emily Choi Michael qJiang Ling Wei Department of Anesthesiology Emory University School of MedicineAtlantaGAUSA Center for Visual and Neurocognitive Rehabilitation Atlanta Veterans Affairs Medical CenterDecaturGAUSA

Stroke and Alzheimer's disease are common neurological disorders and often occur in the same *** comorbidity of the two neurological disorders represents a grave health threat to older *** review presents a brief background of the development of novel concepts and their clinical *** activity of glutamatergic N-methyl-D-aspartate receptors and N-methyl-D-aspartate receptor-mediated Ca^(2+)influx is critical for neuronal *** ischemic insult induces prompt and excessive glutamate release and drastic increases of intracellular Ca^(2+)mainly via N-methyl-D-aspartate receptors,particularly of those at the extrasynaptic *** Ca^(2+)-evoked neuronal cell death in the ischemic core is dominated by necrosis within a few hours and days known as acute ***,mild but sustained Ca^(2+)increases under neurodegenerative conditions such as in the distant penumbra of the ischemic brain and early stages of Alzheimer's disease are not immediately toxic,but gradually set off deteriorating Ca^(2+)-dependent signals and neuronal cell loss mostly because of activation of programmed cell death *** on the Ca^(2+)hypothesis of Alzheimer's disease and recent advances,this Ca^(2+)-activated“silent”degenerative excitotoxicity evolves from years to decades and is recognized as a unique slow and chronic *** N-methyl-D-aspartate receptor subunit GluN3A,primarily at the extrasynaptic site,serves as a gatekeeper for the N-methyl-D-aspartate receptor activity and is neuroprotective against both acute and chronic *** stroke and Alzheimer's disease,therefore,share an N-methyl-D-aspartate receptor-and Ca^(2+)-mediated mechanism,although with much different time *** is thus proposed that early interventions to control Ca^(2+)homeostasis at the preclinical stage are pivotal for individuals who are susceptible to sporadic late-onset Alzheimer's disease and Alzheimer's disease-related

关键词： Ca^(2+)hypothesis cognitive deficits hyperactivity late-onset Alzheimer's disease neurodegeneration N-methyl-D-aspartate receptors N-methyl-D-aspartate receptor subunits pathogenesis preventive treatment

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SUBCONVERGENCE OF FINITE ELEMENTS AND A SELF-ADAPTIVE ALGORITHM

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Journal of Computational Mathematics 1996年第4期14卷 336-344页

作者： Zhu q D Lin q 南京大学数力系江苏南京中科院系统科学所北京

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High mechanical strengths and ductility of stainless steel 304L fabricated using selective laser melting

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Journal of Materials Science & Technology 2019年第2期35卷 388-394页

作者： q.B.nguyen Z.Zhu F.L.ng B.W.Chua S.M.L.Nai J.Wei Singapore Institute of Manufacturing Technology Institute of Research and Development Duy Tan University

Achieving not only high mechanical strengths but also high ductility is recently established using an additive manufacturing technique called selective laser melting. In the present study, stainless steel 304 L fully dense samples were successfully printed using the 3 D systems – ProX 300 printing machine. The ductility and tensile yield strength were almost two and three times higher compared to those of ASTM cast's alloy. Honey comb like nano-cellular structure with different orientation was observed in the fine grains(~4μm) due to fast cooling rate. In addition, the formation of martensite phase in random grains is also a contributor to the strengths. Furthermore, negative residual stresses in the build and horizontal directions were detected and assisted further increase in the tensile strength. Fractography revealed the ductile feature of plastic deformation and the crack openings at unmelted particles or pores.

关键词： Additive manufacturing Stainless steel Powder Selective laser melting

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Generation of unsteady waves by concentrated disturbances in an inviscid fluid with an inertial surface

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Acta Mechanica Sinica 2008年第3期24卷 267-275页

作者： D.q.Lu S.q.Dai Shanghai Institute of Applied Mathematics and Mechanics Shanghai University200072 ShanghaiChina Shanghai Key Laboratory of Mechanics in Energy and Environment Engineering 200072 ShanghaiChina

The surface waves generated by unsteady concentrated disturbances in an initially quiescent fluid of infinite depth with an inertial surface are analytically investigated for two- and three-dimensional cases. The fluid is assumed to be inviscid, incompressible and homogenous. The inertial surface represents the effect of a thin uniform distribution of non-interacting floating matter. Four types of unsteady concentrated disturbances and two kinds of initial values are considered, namely an instantaneous/oscillating mass source immersed in the fluid, an instantaneous/oscillating impulse on the surface, an initial impulse on the surface of the fluid, and an initial displacement of the surface. The linearized initial-boundary-value problem is formulated within the framework of potential flow. The solutions in integral form for the surface elevation are obtained by means of a joint Laplace-Fourier transform. The asymptotic representations of the wave motion for large time with a fixed distance- to-time ratio are derived by using the method of stationary phase. The effect of the presence of an inertial surface on the wave motion is analyzed. It is found that the wavelengths of the transient dispersive waves increase while those of the steady-state progressive waves decrease. All the wave amplitudes decrease in comparison with those of conventional free-surface waves. The explicit expressions for the freesurface gravity waves can readily be recovered by the present results as the inertial surface disappears.

关键词： Waves Inertial surface Concentrated disturbances Asymptotic representation

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Axisymmetric wetting of a liquid droplet on a stretched elastic membrane

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Applied Mathematics and Mechanics(English Edition) 2023年第6期44卷 997-1006页

作者： C.q.RU Department of Mechanical Engineering University of AlbertaEdmontonAB T6G 2G8Canada

Wetting of a liquid droplet on another liquid substrate is governed by the well-known Neumann *** present work aims to develop an explicit modified version of the Neumann equations for axisymmetric wetting of a liquid droplet on a highly stretched elastic membrane of non-zero bending *** explicit modified form of the Neumann equations is derived to determine the two contact angles,which is reduced to Young's equation for a liquid droplet on a rigid membrane or to the Neumann equations for a liquid droplet on another liquid *** implications of the modified Neumann equations are examined by comparison with some previous results reported in the recent literature,particularly considering the ranges of material and geometrical parameters of the liquid droplet-membrane system which have not been recently addressed in the literature.

关键词： Neumann equation Young's equation liquid droplet membrane pretension

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Interfacial Instability of Two Bonded Elastic Bodies Driven by Interface or Bulk Residual Stress

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Acta Mechanica Solida Sinica 2023年第6期36卷 914-920页

作者： C.q.Ru Department of Mechanical Engineering University of AlbertaEdmonton T6G 2G8Canada

Inspired by recent research interest in the interface wrinkling of bonded materials in diverse areas of 3D printing,the present work studies the interfacial instability of two bonded elastic bodies driven by negative interfacial tension or compressible bulk residual *** interfacial instability modes decaying exponentially with distance from the interface,the present model is formulated for two bonded elastic half-spaces with a planar interface under plane *** explicit expression is given for the wavenumber of interfacial instability driven by negative interfacial tension,and a critical condition is derived for interfacial instability driven by compressive bulk residual *** derived results are validated with comparison to known results on surface instability of an elastic half-space,and the role of shear modulus ratio and Poisson’s ratios of two bonded elastic bodies in interfacial instability,an issue to be addressed in literature,is studied with specific reference to material parameters used in some areas of 3D printing.

关键词： Interfacial tension Surface tension Interfacial instability 3D printing Interface wrinkling

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Theoretical and Experimental Study of a Numerical Aperture for Multimode PCS Fiber Optics Using an Imaging Technique

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Chinese Physics Letters 2012年第11期29卷 119-122页

作者： Saman q.Mawlud Nahlah q.Muhamad Department of Physics Education CollageScientific DepartmentSalahaddin UniversityErbilKurdistan RegionIraq

We study theoretically and experimentally the properties of numerical aperture(NA)of multimode graded-index plastic core silica(PCS)fibers by using an image technique.A He-Ne laser at wavelength 632.8 nm and output power 1 mW is used as the transmitter light *** output beam images and intensity profiles of an optical fiber are investigated by using an imaging *** laser beam profiles captured by a sensitive digital Nikon camera are processed and analyzed by using a Gaussian intensity distribution in a 2D graph.A MathCAD 14 program is used for converting the image of the laser output beam into *** theoretical and experimental values of the numerical aperture for the used optical fiber in this study are found to be 0.5 and 0.4924,*** theoretical value of V-number is also calculated to be approximately 2482.

关键词： technique fiber PCS

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A TWO-LEVEL GENETIC ALGORITHM FOR SCHEDULIng IN ASSEMBLY ISLANDS WITH FIXED-POSITION LAYOUTS

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Journal of Systems Science and Systems Engineering 2010年第2期19卷 150-161页

作者： George q.HUAng Department of Industrial and Manufacturing Systems Engineering The University of Hong Kong

This paper focuses on the scheduling problem in assembly islands environment with fixed-position layouts. In such configuration, the product normally remains in one location for its entire manufacturing period while machines, materials and workers are moved to an assembly site called an assembly island. This production layout has some unique features such as moving assembly workers, tools and materials; limited space at assembly site; considerable distance between islands. The authors first give the definition and mathematical model for the scheduling problem and then propose a two-level genetic algorithm to obtain a near optimal solution to minimize the makespan. Experimental results show that this algorithm is effective. The performance analysis of the proposed algorithm indicates that it is more efficient in the airline or shipbuilding industry than in the machine or tool final assembly companies.

关键词： Assembly islands scheduling genetic algorithm

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