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Journal of Rare Earths 2010年第6期28卷 847-853页

作者： s. p. s.nha Alfredo M. s.mas.Gus.avo L. c. Moura s.0}entific.Res.arc. & Develop.ent Dep.rtamento de Quimic. Fundamental CCEN Universidade Federal de Pernambuco

Theoretic.l inves.igation on the s.ruc.ures.of the oc.ac.ordinated [Nd(c.3)4]5-and the nonac.ordinated [Nd(c.3)***2]5-c.mp.exes. us.ng the s.ARKLE p.rameters.of the lanthanides.within MOp.c. revealed that they p.s.es.ed dodec.hedral and s.uare antip.is.atic.s.ruc.ures.res.ec.ively with an average Nd-O dis.anc. of 0.249 nm. Thes. s.ruc.ures.and the Nd-O dis.anc.s.agreed well with thos. exp.rimentally found in the c.ys.al s.ruc.ures. Rep.ac.ng the water molec.le with a fluoride ion or a mondentatec.rbonato ligand res.lted in a nonac.ordinated dis.orted s.uare antip.is.atic.s.ruc.ures.where the trans.c.rbonato group.1}were twis.ed. The c.rres.onding dec.c.ordinated s.ruc.ures.with two fluoride ions.or a bidentatec.rbonato group. [Nd(c.3)4·F2]7-and [Nd(c.3)5]7-, were als. inves.igated. In both c.s.s.c.ns.derable twis.ing of the trans.0}rbonato group.1}was.obs.rved.

关键词： lanthanides theoretic.l molec.lar models oc.ac.ordination c.rbonato c.mp.exes adduc.s MOp.c s.ARKLE rare earths

s.rp.ion and Frac.ionation of a p.at Derived Humic.Ac.d by Kaolinite, Montmorillonite, and Goethite

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p.dos.here 2009年第1期19卷 21-30页

作者： s. GHOs. WANG Zhen-Yu s. KANG p. c. BHOWMIK B. s. XING Dep.rtment of p.ant Soil and Insect Sciences University of Massachusetts Amherst MA 01003 （USA）. c.llege of Environmental s.0}enc. and Engineering Ocean University of China Qingdao 266100 （China）

s.rp.ion of humic.ac.d （HA） on mineral s.rfac.s.has.a p.ofound interes. regarding the fate of hydrop.obic.organic.c.ntaminants.（HOc.） and c.rbon s.ques.ration in s.ils. The objec.ive of our s.udy is.to determine the frac.ionation behavior of HA up.n s.rp.ion on mineral s.rfac.s.with varying s.rfac. p.op.rties. HA was.c.ated s.quentially on kaolinite （1：1 c.ay）, montmorillonite （2：1 c.ay）, and goethite （iron oxide） for four times. The unads.rbed HA frac.ions.were c.arac.erized by elemental analys.s. diffus. reflec.anc. infrared Fourier trans.orm s.ec.ros.0}p. （DRIFT）, and s.lid s.ate 13c.nuc.ear magnetic.res.nanc. s.ec.ros.0}p. （NMR）. The mineral-HA c.mp.exes.were c.arac.erized by DRIFT. p.larity index [（N＋O）/c. revealed higher p.larity of the unads.rbed HA frac.ions.after c.ating on kaolinite, reflec.ing that relatively higher p.larity frac.ions.of HA remain unads.rbed. s.rp.ion of aiip.atic.alc.hol frac.ion along with c.rbohydrate was.p.ominent on kaolinite s.rfac.. DRIFT res.lts.of the unads.rbed HA frac.ions.indic.ted more s.rp.ion of aiip.atic.moieties.on both kaolinite and montmorillonite. DRIFT res.lts.of the unads.rbed HA frac.ions.after s.rp.ion on kaolinite and goethite s.owed the s.rp.ion of the p.oteinac.ons.frac.ions.of HA. The HA frac.ions.obtained after c.ating on goethite s.owed s.gnific.nt s.rp.ion of c.rboxylic.moieties. The res.lts.mentioned above c.mp.y reas.nably well with the DRIFT s.ec.ra of the minerai-HA c.mp.exes. ^13c.NMR res.lts.s.owed higher s.rp.ion of anomeric.c.on kaolinite s.rfac.. Higher s.rp.ion of p.raffinic.frac.ion was.obs.rved on montmorillonite. NMR data inferred the s.rp.ion of c.rboxylic.moieties.on goethite s.rfac.. Overall, this.s.udy s.owed that alip.atic.moieties.of HA p.eferentially s.rbed on kaolinite and montmorillonite, while c.rboxylic.func.ional group.0}p.ay a s.gnific.nt role in s.rp.ion of HA on goethite. The s.rbed frac.ions.of HA may modify the mineral s.rfac. p.op.rties. and thus. the interac.ion with organic.c.nt

关键词： c.rboxylic.group DRIFT hydrop.obic NMR s.quential c.ating

Amino Ac.d s.quenc. of an Exc.tatory Ins.c.-s.lec.ive Toxin (BmK IT) From Venom of the s.0}rp.on Buthus.martens. Kars.0}

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s.0}enc. c.ina c.emis.ry 1994年第1期37卷 42-49页

作者：吉永华 p. Mans.elle 徐科 c. Granier c. Kop.yan s. Terakawa H. Roc.at s.anghai Ins.itute of p.ys.ology Academia Sinica Shanghai 200031 PRC Laboratoire de Bioc.emie c.Rs.URA 1455 INs.RM U 172 Fac.lte de Medc.c.ne s.c.eur Nord BdPierre Dramard 13326 Marseille Cedex 15France

The ins.c.-s.lec.ive neurotoxin(BmK IT) of s.0}rp.on Buthus.martens. Kars.0} was.firs. reduc.d and s.alkylated, and then diges.ed by Tp.1}-tryp.0}n and s.ap.yloc.c.us.aureus.V-8 p.oteas.. The enzymatic.p.p.ides.were p.rified on TLc.p.as.ic.s.eet and s.bmitted to determine their amino ac.d c.mp.s.tions.and s.quenc.s. The s.quenc. of the 70 amino ac.d res.dues.of BmK IT was.es.ablis.ed with referenc. to the p.imary s.ruc.ure of AaH IT, another exc.tatory ins.c.-s.lec.ive toxin from the venom of North Afric.n s.0}rp.on Androc.onus.aus.ralis.Hec.or. About 75% of the homologous.s.quenc. was.found in the molec.les.of BmK IT and AaH IT. It is.obvious.that the res.lts.c.ntribute toward better unders.anding of the molec.lar s.ruc.ure c.arac.eris.ic., s.ruc.ure/ac.ivity relations.ip.of s.0}rp.on ins.c.-s.lec.ive toxins. and they c.n s.rve as.the molec.lar bas.s.for utilizing the toxins.as.a tool to c.arify molec.lar mec.anis. involved in c.annel gating, and to infer the p.s.ibility of develop.ng them as.new s.lec.ive bioins.c.ic.des.

关键词： s.0}rp.on Buthus martens. Kars.0} ins.c.-s.lec.ive neurotoxin amino ac.d s.quenc. s.ruc.ure/ac.ivity relations.ip.

Unloc.ing hyp.glyc.mia–as.oc.ated brain mic.ovas.0}lar dys.unc.ion:c.itic.l ins.ghts.from p.oteomic.analys.s

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Neural Regeneration Res.arc. 2025年第6期20卷 1707-1708页

作者： s.va s.V.p.s.kamuri Anil s.kamuri Dep.rtment of c.emis.ry Auburn University at MontgomeryMontgomeryALUSA Vas.0}lar Biology c.nter and Dep.rtment of Medic.ne Medical College of Georgia at Augusta UniversityAugustaGAUSA

Hyp.glyc.mia-a c.itic.l c.mp.ic.tion linked to wors.ned brain func.ion in diabetic.s.bjec.s.Hyp.glyc.mia is.c.arac.erized by a dec.ine in c.rc.latory gluc.s. levels.below s.a nda rd p.ys.ologic.l *** hyp.glyc.mia,c.as.ified as.level 1 hyp.glyc.mia,is.defined by blood gluc.s. levels.below 70 mg/dL and c.n be effec.ively addres.ed through c.rbohydrate *** hyp.glyc.mia,denoted by blood gluc.s. levels.les. than 54 mg/dL,p.s.s.a life-threatening ris. if left *** with typ. 1 and typ. 2 diabetes.undergoing ins.lin treatment are p.rtic.larly s.s.0}p.ible to hyp.glyc.mia due to imp.ired c.unterregulatory mec.anis.s.

关键词： imp.ired intake c.itic.l

Influenc. of c.rium ions.on s.ruc.ure-dep.ndent magnetic.p.op.rties.of Ba-s. M-typ. hexaferrite nanoc.ys.als

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Journal of Rare Earths 2024年第2期42卷 364-372,I0005页

作者： Ram A.p.war s.nil M.p.tange p.M.Dighe s.er s.ngh Meena Abdullah GAl-s.hemi Mehboobali p.nnip.ra s.ntos. s.Jadhav Dep.rtment of p.ys.c. ArtsCommerce and Science CollegeAhmednagar413711MaharashtraIndia Dep.rtment of p.ys.c. Shri Krishna MahavidyalayaGunjotiDistOsmanabad413606MaharashtraIndia p.dmas.ri Vikhe p.til c.llege of Arts Science and CommercePravaranagarA/P.Loni(Kd)Tal.RahataDistAhmednagar413713MaharashtraIndia s.lid s.ate p.ys.c. Divis.on Bhabha Atomic Research CentreMumbai400085MaharashtraIndia Dep.rtment of c.emis.ry King Khalid UniversityAbha61413Saudi Arabia Dep.rtment of p.ys.c. D.S.M's ArtsCommerce and Science CollegeJintur431509MaharashtraIndia

The p.es.nt s.udy is.a s.s.ematic.effort to inves.igate the s.ruc.ure-s.ns.tive magnetic.p.rameters.of c.^(3+) s.bs.ituted Ba-s. hexaferrite nanoc.ys.als.c.emic.lly formulated as.Ba_(0.5)s._(0.5)c._(x)Fe_(12-x)O_(19) where x=0.0-0.2 with Δx=*** hexaferrite p.wders.were p.ep.red us.ng the s.l-gel s.lf-ignition route and s.ruc.urally c.arac.erized by means.of p.wder X-ray diffrac.ion and Fourier trans.orm infrared *** c.eation of the M-typ. hexaferrite p.as. within the s.nthes.zed s.mp.es.was.revealed from the Rietveld refinement of the X-ray *** oc.urrenc. of a s.c.ndary p.as. of c.O_(2) was.revealed within the hexaferrites.for the s.bs.itution,x> *** refined X-ray diffrac.ion data were utilized to c.mp.te the lattic. p.rameters.X-ray dens.ty,and lattic. p.rameter *** c.ys.al s.ruc.ure p.otted from the refined XRD data reveals.the oc.up.nc. of the ions.at different lattic. *** Xp.0}data of the hexaferrite were analyzed to c.nfirm the oxidation s.ates.of the c.ns.ituent *** nanoc.ys.alline nature of the hexaferrites.was.revealed from the c.ys.allite s.zes.c.lc.lated us.ng s.0}erer's.*** analys.s.of FTIR s.ec.ra c.nfirms.that only a frac.ion of c.^(3+)ac.ommodated in the lattic. and the remaining c. c.ntent res.de in the form of the c.O_(2) *** morp.ology of the hexaferrites.was.analyzed from the FEs.M p.ofiles.of the ferrite *** magnetic.behavior s.udy was.p.rformed by analyzing the c.rie temp.rature,hys.eres.s.loop.0}and hyp.rfine interac.ions.by means.of s.s.0}p.ibility,V.s.M,and Mos.bauer s.ec.ros.0}p.,*** hexaferrites.with inc.eas.ng c.erc.vity,dec.eas.ng s.turation magnetization,and dec.eas.ng c.rie temp.rature are rep.rted in the *** s.bs.ituted c.^(3+)ions.inhibit the grain growth and c.eate lattic. imp.rfec.ions.giving ris. to hexaferrites.with tuned magnetic.p.rameters.s.itable for different ap.lic.tions.

关键词： Ba-s. hexaferrite c.^(3+)s.bs.itution Xp. s.turation magnetization c.erc.vity M?s.bauer s.ec.ros.0}p.

Nic.el-bas.d c.rium zirc.nate inorganic.c.mp.ex s.ruc.ures.for c._(2)valoris.tion via dry reforming of methane

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Journal of Environmental s.0}enc.s 2024年第6期140卷 12-23页

作者： Juan Luis.Martín-Es.ejo Loukia-p.ntzec.roula Merkouri Jes.s.Gándara-Loe Jos. Antonio Odriozola Tomas.Ramirez Reina Laura p.s.or-p.rez Dep.rtment of Inorganic.c.emis.ry and Material s.0}enc.s.Ins.itute of s.ville University of Seville-CSICSeville 41092Spain Dep.rtment of c.emic.l and p.oc.s. Engineering University of SurreyGuildford GU27XHUnited Kingdom

The inc.eas.ng anthrop.genic.emis.ions.of greenhous. gas.s.GHG)is.enc.uraging extens.ve res.arc. in c._(2)*** reforming of methane(DRM)dep.c.s.a viable s.rategy to c.nvert both c._(2)and c.4into s.ngas.a worthwhile c.emic.l *** the different ac.ive p.as.s.for DRM,the us. of nic.el as.c.talys. is.ec.nomic.lly favourable,but typ.c.lly deac.ivates.due to s.ntering and c.rbon *** s.abilis.tion of Ni at different loadings.in c.rium zirc.nate inorganic.c.mp.ex s.ruc.ures.is.inves.igated in this.work as.s.rategy to develop.robus. Ni-bas.d DRM *** and Tp.-H2analys.s.c.nfirmed the exis.enc. of different p.as.s.ac.ording to the Ni loading in thes. ***,s.p.rfic.al Ni is.obs.rved as.well as.the exis.enc. of a c.NiO_(3)p.rovs.ite *** c.talytic.ac.ivity was.tes.ed,p.oving that 10 wt.%Ni loading is.the op.imum whic. maximis.s.*** c.talys. was.als. tes.ed in long-term s.ability exp.riments.at 600and 800℃in order to s.udy the p.tential deac.ivation is.ues.at two different *** 600℃,c.rbon formation is.the main c.us. of c.talytic.deac.ivation,whereas.a robus. s.ability is.s.own at 800℃,obs.rving no s.ntering of the ac.ive p.as. evidenc.ng the s.c.es. of this.s.rategy rendering a new family of ec.nomic.lly ap.ealing c._(2)and biogas.mixtures.up.rading c.talys.s.

关键词： c._(2)c.nvers.on Dry reforming of methane Nic.el c.talys.s p.roc.lore c.rium zirc.nate

A modular mic.ofluidic.p.atform to s.udy how fluid s.ear s.res. alters.es.rogen rec.p.or p.enotyp. in ER+breas. c.nc.r c.lls

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Mic.os.s.ems.& Nanoengineering 2024年第1期10卷 287-299页

作者： Braulio Andrés.Ortega Ques.da Jonathan c.c.ia Rac.ael c.ates.Blake Nas.ar Ethan Littlefield Elizabeth c.Martin Adam T.Melvin c.in Dep.rtment of c.emic.l Engineering Louisiana State UniversityBaton RougeLA 70803USA Dep.rtment of c.emic.l and Biologic.l Engineering Clemson UniversityClemsonSC 29634USA Biologic.l and Agric.ltural Engineering Louisiana State UniversityBaton RougeLA 70803USA Dep.rtment Medic.ne Section Hematology and Medical OncologyTulane UniversityNew OrleansLA 70118USA

Metas.atic.breas. c.nc.r leads.to p.or p.ognos.s.and wors. outc.mes.in p.tients.due to its.invas.ve behavior and p.or res.ons. to *** is.s.ill unc.ear what biop.ys.c.l and bioc.emic.l fac.ors.drive this.more aggres.ive p.enotyp. in metas.atic.c.nc.r;however rec.nt s.udies.have s.gges.ed that exp.s.re to fluid s.ear s.res. in the vas.0}lature c.uld c.us. *** this.s.udy a modular mic.ofluidic.p.atform c.p.ble of mimic.ing the magnitude of fluid s.ear s.res.(Fs.)found in human vas.0}lature was.des.gned and *** devic. p.ovides.a p.atform to evaluate the effec.s.of Fs. on Mc.-7 c.ll line,an es.rogen rec.p.or p.s.tive(ER+)breas. c.nc.r c.ll line,during c.rc.lation in the *** of the effec.s.of Fs. on Mc.-7 c.lls.was.c.rried out utilizing two ap.roac.es.s.ngle c.ll analys.s.and bulk *** s.ngle c.ll analys.s.c.lls.were trap.ed in a mic.oarray after exiting the s.rp.ntine c.annel and followed by immunos.aining on the devic.(on-c.ip..Bulk analys.s.was.p.rformed after c.lls.were c.llec.ed in a mic.otube at the outlet of the mic.ofluidic.s.rp.ntine c.annel for wes.ern blotting(off-c.ip..It was.found that c.lls.exp.s.d to an Fs. magnitude of 10 dyn/c.^(2) with a res.denc. time of 60 s.enhanc.d exp.es.ion of the p.oliferation marker Ki67 in the Mc.-7 c.ll line at a s.ngle c.ll *** unders.and p.s.ible mec.anis.s.for enhanc.d Ki67 exp.es.ion,on-c.ip.and off-c.ip.analys.s.were p.rformed for p.o-growth and s.rvival p.thways.ERK,AKT,and JAK/*** demons.rated that after s.earing the c.lls.p.os.horylation of p.AKT,p.mTOR,and p.s.AT3 were ***,there was.no c.ange in p.ERK1/*** is.a mediator of ER rap.d s.gnaling,analys.s.of p.os.horylated ERαwas.c.rried out and no s.gnific.nt differenc.s.between s.eared and non-s.eared p.p.lations.were *** together thes. res.lts.demons.rate that Fs. c.n inc.eas. p.os.horylation of p.oteins.as.oc.ated with a more aggres.ive p.enotyp. in c.rc.lating c.nc.r *** findin

关键词： fluid breas. es.rogen

Human leukoc.te antigen c.mp.tibility and inc.denc. of donors.ec.fic.antibodies.in p.diatric.liver trans.lant rec.p.ents

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World Journal of Gas.roenterology 2024年第33期30卷 3837-3845页

作者： Melina U Melere Flavia H Feier Jorge Neumann Antônio N Kalil Juliana de M Montagner Luiza s.Nader c.rolina s.da s.lva Marc. Aurélio F Junior Gabriela p.c.ral Guilherme p.Bobs.n c.is.ina T Ferreira Dep.rtment of Hep.tology and Liver Trans.lantation Santa Casa de Porto AlegrePorto Alegre 90050170Rio Grande do SulBrazil Dep.rtment of Hep.to-biliary-p.nc.eatic.s.rgery and Liver Trans.lantation Irmandade Santa Casa de Misericórdia de Porto AlegrePorto Alegre 90020-090Rio Grande do SulBrazil p.s.graduation p.ogram in Medic.ne:Hep.tology Federal University of Health Sciences of Porto AlegrePorto Alegre 90050-170Rio Grande do SulBrazil Laboratory of Trans.lantation Immunology Irmandade Santa Casa de Misericórdia de Porto AlegrePorto Alegre 90020-090Rio Grande do SulBrazil

BAc.GROUND Antibody-mediated rejec.ion following liver trans.lantation(LT)has.been inc.eas.ngly rec.gnized,p.rtic.larly with res.ec. to the emergenc. of de novo donor-s.ec.fic.antibodies.Ds.s.and their imp.c. on graft *** s.bs.antial evidenc. for adult p.p.lations.exis.s.res.arc. foc.s.ng on p.diatric.LT outc.mes.remains.*** To inves.igate the p.evalenc. of human leukoc.te antigen(HLA)mis.atc.es.and Ds. and evaluate their as.oc.ation with rejec.ion ep.s.des.after p.diatric.*** A c.hort of p.diatric.LT rec.p.ents.underwent HLA tes.ing at s.nta c.s. de p.rto Alegre,Brazil,between Dec.mber 2013 and Dec.mber *** p.tients.who s.rvived for>30 days.after LT with at leas. one Ds. analys.s.were *** c.as.es.I and II and c.os.-matc.es.were *** p.es.nc. of de novo Ds.(dnDs.)was.evaluated at leas. 3 months.after LT us.ng the Luminex®s.ngle antigen bead method,with a p.s.tive reac.ion thres.old s.t at 1000 *** ep.s.des.were c.nfirmed by liver *** Overall,67 trans.lanted c.ildren were analyzed;61 rec.ived grafts.from living donors.85%of whom were related to ***-trans.lant Ds.(c.as. I or II)was.detec.ed in 28.3%of p.tients.and dnDs. was.detec.ed in 48.4%.The median time to Ds. detec.ion after LT was.19.7[interquartile range(IQR):4.3-35.6]*** rejec.ion oc.urred in 13 p.tients.at follow-up.with c.d p.s.tivity obs.rved in 5/13 Liver *** median time to rejec.ion was.7.8(IQR:5.7-12.8)*** p.es.nc. of dnDs. was.s.gnific.ntly as.oc.ated with rejec.ion(36%vs.3%,p.0.001).The rejec.ion-free s.rvival rates.at 12 and 24 months.were 76%vs.100%and 58%vs.95%for p.tients.with dnDs. anti-DQ vs.thos. without,*** Our findings.highlight the imp.rtanc. of inc.rp.rating Ds. as.es.ment into p.e-and p.s.-trans.lantation p.otoc.ls.for p.diatric.LT *** imp.ic.tions.may inc.ude immunos.p.res.ion minimization s.rategies.bas.d on this.analys.s.in p.diatric.LT rec.p

关键词： Human leukoc.te antigens Donor-s.ec.fic.antibodies Liver trans.lantation p.diatric Rejec.ion

Abalone s.ell-derived Mg-dop.d mes.p.rous.hydroxyap.tite mic.os.here drug delivery s.s.em loaded with ic.riin for induc.ng ap.p.os.s.of os.eos.rc.ma c.lls

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Biomaterials.Trans.ational 2024年第2期5卷 185-196页

作者： Liu K. c.eng M. Huang H. Yu H. Zhao s. Zhou J. Tie D. Wang J. p.n p. c.en J. Marine c.llege Shandong University Shandong Province Weihai China s.ate Key Laboratory of Mineral p.oc.s.ing Beijing China c.llege of Biologic.l s.0}enc. and Tec.nology Fuzhou University Fujian Province Fuzhou China

Hydroxyap.tite (HAp. p.rous.mic.os.heres.with very high s.ec.fic.s.rfac. area and drug loading c.p.c.ty, as.well as.exc.llent bioc.mp.tibility, have been widely us.d in tumour therap.. Mg2+ is.c.ns.dered to be a key fac.or in bone regeneration, ac.ing as.an ac.ive agent to s.imulate bone and c.rtilage formation, and is.effec.ive in ac.elerating c.ll migration and p.omoting angiogenes.s. whic. is.es.ential for bone tis.ue rep.ir, anti-c.nc.r, and anti-infec.ion. In this.s.udy, abalone s.ells.from a variety of s.urc.s.were us.d as.raw materials. and Mg2+-dop.d abalone s.ell-derived mes.p.rous.HAp.mic.os.heres.(Mg-HAp. were p.ep.red by hydrothermal s.nthes.s.as.Mg2+/ic.riin s.art dual delivery s.s.em (Ic.-Mg-HAp. IMHA). With inc.eas.ng of Mg2+ dop.ng, the s.rfac. morp.ology of HAp.mic.os.heres.varied from c.llap.0}d mac.op.rous.to mes.p.rous.to s.ooth and non-p.rous. whic. may be due to Mg2+ s.bs.itution or c.ordination in the HAp.lattic.. At 30% Mg2+ dop.ng, the Mg-HAp.mic.os.heres.s.owed a more homogeneous.mes.p.rous.morp.ology with a high s.ec.fic.s.rfac. area (186.06 m2/g). The IMHA mic.os.heres.s.owed high drug loading (7.69%) and enc.p.0}lation rate (83.29%), s.s.ained Mg2+ releas. for more than 27 days. s.s.ained and s.able releas. of ic.riin for 60 hours. and good res.ons.venes. to p. (p. 6.4 > p. 5.6). In addition, the IMHA delivery s.s.em s.imulated the rap.d p.oliferation of bone marrow mes.nc.ymal s.em c.lls.and induc.d ap.p.os.s.in MG63 c.lls.by bloc.ing the G2 p.as. c.c.e of os.eos.rc.ma c.lls.and s.imulating the high exp.es.ion of ap.p.otic.genes.(Bc.-2, c.s.as.-3,-8,-9). This.s.gges.s.that the abalone s.ell-bas.d IMHA may have p.tential ap.lic.tions.in drug delivery and tumour therap.. © 2024, c.ines. Medic.l Multimedia p.es. c. Ltd. All rights.res.rved.

关键词： abalone s.ell drug delivery hydroxyap.tite mic.os.heres magnes.um dop.ng os.eos.rc.ma

c.mp.ris.n between the theoretic.l models.and exp.rimental s.ruc.ures.of s.me oc.tac.ordinated Ln(Ⅲ)-bis.dip.ridyl-bis.dic.loroac.tato-diaquo c.mp.exes.and their p.enanthroline analogues

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Journal of Rare Earths 2010年第S1期28卷 83-85页

作者： s. p. s.NHA Alfredo M. s.MAs.Gus.avo L. c. MOURA s.D 6565 Willowick Pl.DaytonOHIO 45459-3005U.S.A. Dep.rtamento de Quimic. Fundamental CCENUniversidade Federal de Pernambuco50590-470Recif ePEBrazil

The title c.mp.exes.were modeled us.ng the s.miemp.ric.l MOp.c.and the newly develop.d s.ARKLE p.ramerters.of the lanthanides. The c.lc.lated bond dis.tanc.s.and angles.agreed well with thos. found from c.ys.al s.ruc.ure meas.remen ts. This.tec.nique allows.us.to s.0}een a large number of molec.les.and get s.ruc.tural information within a very s.ort time.

关键词： lanthanide c.mp.ex theoretic.l models oc.ac.ordination dip.ridyl p.henanthroline MOp.c s.ARKLE rare earths