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Dual-Porosity Apparent Permeability Models of Unconventional Gas Migration Based on Biot’s Porous Media

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Acta Mechanica Solida Sinica 2024年第3期37卷 406-415页

作者： Bin Gu Hongyuan Liu Yiuwing mai Bing Wang School of Manufacturing Science and Engineering Key Laboratory of Testing for Manufacturing ProcessMinistry of EducationSouthwest University of Science and TechnologyMianyang621010China School of Aerospace Mechanical and Mechatronic EngineeringThe University of SydneySydneyNSW2006Australia Department of Mechanical Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong KongChina

Stress-dependent permeability models are developed for the organic pores and inorganic cleats/fractures in unconventional gas reservoirs,which are modeled as Biot’s porous media of *** considering multiple flow mechanisms such as dynamic effects of gas flow and surface diffusion,apparent permeability models are obtained to investigate the characteristics of unconventional gas *** to the gas transfer in single-porosity reservoirs,the gas migration ability of cleats in dual-porosity stratums rarely changes while that of organic pores is greatly improved because cleats sustain major geomechanical shrinkage deformation when the pore pressure ***,the mass flux of reservoirs is dominated by the mass flux of cleats,which has a lower peak value,but a much longer production term than those in single-porosity reservoirs due to the interaction between organic pores and *** analysis is conducted to identify key factors significantly impacting mass flux in unconventional *** for the mass flux variation are also explored in terms of gas migration ability and pore pressure distribution.

关键词： Unconventional gas migration Apparent permeability Dual-porosity Stress dependence Multiple flow mechanisms

Integrated strategies on cobalt phosphides-based electrocatalysts for efficient hydrogen evolution reaction

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Tungsten 2024年第3期6卷 488-503页

作者： Thanh Dam mai Ha Huu Do Faculty of Mechanical Engineering and Technology Ho Chi Minh City University of Industry and Trade VKTech Research Center NTT Hi-Tech Institute Nguyen Tat Thanh University

The development of cost-effective and durable hydrogen evolution reaction(Her) electrocatalysts plays a vital role in dealing with the issues related to carbon dioxide *** phosphide-based nanomaterials are evaluated as promising advocates for Her due to high catalytic activities,good stability,and rich *** review commences with an exploration of the synthetic pathways of CoP,including solid-phase,solution-phase along with electrochemical ***,the mechanism of hydrogen formation is expressed thoroughly,after which various integrated strategies of morphology engineering with doping,assisted highly conductive materials,and construction of heterostructure were introduced for ***,burdensome tasks and possible guidance for the advancement of CoP-based nanomaterials were discussed for hydrogen production.

关键词： Cobalt phosphides Nanomaterials Electrocatalysts Hydrogen evolution reaction

Dynamic COVID Zero Strategy triggered a significant increase of chlorine-based disinfectant

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Frontiers of Environmental Science & Engineering 2024年第8期18卷 73-80页

作者： Xuhao Wang mai Su Chunyan Wang Yi Liu School of Environment Tsinghua UniversityBeijing 100084China

Chlorine-based disinfectants(CBDs)have been widely used to prevent and control the spread of the COVID-19,which may lead to the formation of carcinogenic *** China,strict disinfection strategies by local governments/communities or volunteering by residents have been implemented to meet the Dynamic COVID Zero(DCZ)***,the amount of CBDs used has not been *** author proposed an urban-scale disinfectant consumption estimation(ALICE)model to quantify weekly CBD *** results show that the CBD consumption for the urban region of Beijing during the DCZ strategy was 3704.0 t(0.43 kg/(cap-yr)),equivalent to a monthly increase of 15 g/cap(70.5%)in CBD consumption compared with that in *** to the scenario analysis,a stricter strategy with a shorter response time toward new cases will decrease the total CBD consumption by 1.2% compared with the baseline estimation.A more precise prevention strategy with a smaller delineation of risk area and a less stringent strategy with a longer response time will lower the total CBD consumption by 0.42% and 0.35%,***,the more precise prevention strategy will reduce CBD consumption of close off and lockdown area(COLD area)by 16.9%,and the stricter strategy will reduce this consumption by 37.7%.This study highlights the impact of pandemic prevention and control strategies on chlorine-based disinfectant consumption and some implications for future environmental pollution and risk assessments.

关键词： COVID-19 Dynamic COVID Zero Strategy Disinfectants consumption Bottom-up approach Scenario analysis

An analytical model to estimate the time delay to reach spontaneous ignition considering heat loss in oil reservoirs

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Petroleum Science 2024年第4期21卷 2469-2474页

作者： James J.Sheng er-Long Yang College of Petroleum Engineering Northeast Petroleum University

During air injection into an oil reservoir, an oxidation reaction generates some heat to raise the reservoir temperature. When the reservoir temperature reaches an ignition temperature, spontaneous ignition occurs. There is a time delay from the injection to ignition. There are mixed results regarding the feasibility of spontaneous ignition in real-field projects and in laboratory experiments. No analytical model is available in the literature to estimate the oxidation time required to reach spontaneous ignition with heat *** paper discusses the feasibility of spontaneous ignition from theoretical points and experimental and field project observations. An analytical model considering heat loss is proposed. Analytical models with and without heat loss investigate the factors that affect spontaneous ignition. Based on the discussion and investigations, we find that it is more difficult for spontaneous ignition to occur in laboratory experiments than in oil reservoirs; spontaneous ignition is strongly affected by the initial reservoir temperature, oil activity, and heat loss; spontaneous ignition is only possible when the initial reservoir temperature is high, the oil oxidation rate is high, and the heat loss is low.

关键词： Spontaneous ignition Time delay Air injection Heat loss Low temperature oxidation Combustion

Comparison of engineering failures and seismic responses of 500 kV transformer-bushing systems in the 2022 Luding earthquake

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Earthquake Engineering and Engineering Vibration 2024年第4期23卷 1029-1041页

作者： Zhu Wang Wu Ming’er Xie Qiang Department of Structural Engineering Tongji UniversityShanghai 200092China Key Laboratory of Performance Evolution and Control for Engineering Structures(Tongji University) Shanghai 200092China

Cemented and mechanically clamped types of end fittings(fitting-C and fitting-M)are commonly used in transformer *** the Luding Ms 6.8 earthquake that occurred in China on September 5,2022,all transformer bushings with the two types of end fittings in a 500 kV substation were ***-earthquake field investigations were conducted,and the failures of the two types of bushings were *** elementary simulation models of the transformer-bushing systems were developed to simulate the engineering failures,and further compute their seismic responses for *** results indicate that the hitch lugs of the connection flange are structurally harmful to seismic ***-M can decrease the bending stiffness of the bushing due to the flexible sealing rubber *** it provides a more flexible connection that dissipates energy,the peak accelerations and relative displacements at the top of the bushing are significantly lower than those of the bushing with *** with fitting-C,fitting-M transfers the high-stress areas from the connection flange to the root of the porcelain,so the latter becomes the most vulnerable ***-M increases the failure risk of the low-strength porcelain,indicating the unsuitability of applying it in high-intensity fortification regions.

关键词： transformer bushing end fitting Luding earthquake,engineering failure seismic responses

Approaching high oxygen evolution reaction performance by synergetic dual-ion leaching

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Nano Research 2024年第9期17卷 7975-7983页

作者： Hancheng Ma Yao Ding Jianqi Li Wei Peng Liqiang mai School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Self-reconstruction of catalysts during oxygen evolution reaction(Oer)is crucial for the development of energy conversion ***,the relationship between the specific atomic structure of pre-catalysts and their electrocatalytic behavior after reconstruction via dual-ion leaching has not been extensively *** this work,we design a highly effective non-noble metal Oer catalyst with heterointerface through continuous self-reconstruction of Co_(2)(OH)_(3)Cl@NiMoO_(4)as pre-catalyst by a straightforward dual-ion(***_(4)^(2-)and Cl^(-))***-situ Raman and in-situ Fourier transform infrared(FT-IR)spectroscopy have precisely identified the progressive phase transformation of the pre-catalyst during self-reconstruction,which results in a stable heterojunction of CoOOH and NiOOH(CoOOH@NiOOH).Further calculations based on density functional theory(DFT)of CoOOH@NiOOH evident that more electrons will be aggregated in the Fermi level of ***,Gibbs free energy(ΔG)for different Oer steps of CoOOH@NiOOH exhibit lower energy costs of all intermediates,implying the well catalytic ***,the catalyst derived from dual-ion leaching displays outstanding Oer performance,characterized by an overpotential of 275 mV at a current density of 10 mA·cm^(-2)and exceptional stability over 12 h *** work successfully paves a way of finding high-performance Oer catalysts based on non-noble metal through dual-ion leaching during self-reconstruction.

关键词： dual-ion leaching oxygen evolution reaction chemical reconstruction NiMoO_(4) Co_(2)(OH)_(3)Cl

Chloride ion battery:A new emerged electrochemical system for next-generation energy storage

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Journal of Energy Chemistry 2024年第1期88卷 154-168,I0004页

作者： Shulin Chen Lu Wu Yu Liu Peng Zhou Qinyou An Liqiang mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070HubeiChina State Key Laboratory of Refractories and Metallurgy Institute of Advanced Materials and NanotechnologyWuhan University of Science and TechnologyWuhan 430081HubeiChina

In the scope of developing new electrochemical concepts to build batteries with high energy density,chloride ion batteries(CIBs)have emerged as a candidate for the next generation of novel electrochemical energy storage technologies,which show the potential in matching or even surpassing the current lithium metal batteries in terms of energy density,dendrite-free safety,and elimination of the dependence on the strained lithium and cobalt ***,the development of CIBs is still at the initial stage with unsatisfactory performance and several challenges have hindered them from reaching *** this review,we examine the current advances of CIBs by considering the electrode material design to the electrolyte,thus outlining the new opportunities of aqueous CIBs especially combined with desalination,chloride redox battery,*** respect to the developing road of lithium ion and fluoride ion batteries,the possibility of using solid-state chloride ion conductors to replace liquid electrolytes is tentatively *** beyond,perspectives and clear suggestions are concluded by highlighting the major obstacles and by prescribing specific research topics to inspire more efforts for CIBs in large-scale energy storage applications.

关键词： Chloride ion battery Anion shuttling Conversion reaction Chloride redox

Health diagnosis of ultrahigh arch dam performance using heterogeneous spatial panel vector model

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Water Science and Engineering 2024年第2期17卷 177-186页

作者： er-feng Zhao Xin Li Chong-shi Gu The National Key Laboratory of Water Disaster Prevention Hohai UniversityNanjing 210098China NationalEngineering Research Centerof Water Resources Eficient Utilization and Engineering Safety Hohai UniversityNanjing 20098China

Currently,more than ten ultrahigh arch dams have been constructed or are being constructed in *** control is essential to long-term operation of these *** study employed the flexibility coefficient and plastic complementary energy norm to assess the structural safety of arch dams.A comprehensive analysis was conducted,focusing on differences among conventional methods in characterizing the structural behavior of the Xiaowan arch dam in ***,the spatiotemporal characteristics of the measured performance of the Xiaowan dam were explored,including periodicity,convergence,and time-effect *** findings revealed the governing mechanism of main ***,a heterogeneous spatial panel vector model was developed,considering both common factors and specific factors affecting the safety and performance of arch *** model aims to comprehensively illustrate spatial heterogeneity between the entire structure and local regions,introducing a specific effect quantity to characterize local deformation ***,the proposed model was applied to the Xiaowan arch dam,accurately quantifying the spatiotemporal heterogeneity of dam ***,the spatiotemporal distri-bution characteristics of environmental load effects on different parts of the dam were reasonably *** of the model prediction enhances its credibility,leading to the formulation of health diagnosis criteria for future long-term operation of the Xiaowan *** findings not only enhance the predictive ability and timely control of ultrahigh arch dams'performance but also provide a crucial basis for assessing the effectiveness of engineering treatment measures.

关键词： Ultrahigh arch dam Structural performance Deformation behavior Diagnosis criterion Panel data model

Nanomedicine targeting ferroptosis to overcome anticancer therapeutic resistance

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Science China(Life Sciences) 2024年第1期67卷 19-40页

作者： Jing Cai Xiaoding Xu Phei er Saw Guangdong Provincial Key Laboratory of Malignant Tumor Epigenetics and Gene Regulation Guangdong-Hong Kong Joint Laboratory for RNA MedicineMedical Research CenterSun Yat-sen Memorial HospitalSun Yat-sen UniversityGuangzhou 510120China Nanhai Translational Innovation Center of Precision Immunology Sun Yat-sen Memorial HospitalSun Yat-sen UniversityFoshan 528200China

A potential reason for the failure of tumor therapies is treatment *** to chemotherapy,radiotherapy,and immunotherapy continues to be a major obstacle in clinic,resulting in tumor recurrence and *** major mechanisms of therapy resistance are inhibitions of cell deaths,like apoptosis and necrosis,through drug inactivation and excretion,repair of DNA damage,tumor heterogeneity,or changes in tumor microenvironment,*** studies have shown that ferroptosis play a major role in therapies resistance by inducing phospholipid peroxidation and iron-dependent cell *** ferroptosis inducers in combination with clinical treatment techniques have been used to enhance the effect in tumor ***,versatile ferroptosis nanoinducers exhibit an extensive range of functions in reversing therapy resistance,including directly triggering ferroptosis and feedback ***,we provide a detailed description of the design,mechanism,and therapeutic application of ferroptosis-mediated synergistic tumor *** also discuss the prospect and challenge of nanomedicine in tumor therapy resistance by regulating ferroptosis and combination therapy.

关键词： ferroptosis cancer therapy therapy resistance nanoinducers