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Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction

Chinese Chemical Letters 2024年第7期35卷 139-146页

作者： Yuan Dong Mutian Ma Zhenyang Jiao Sheng Han Likun Xiong Zhao deng Yang peng Soochow Institute of Energy and Material Innovations College of EnergyJiangsu Key Laboratory of Advanced Carbon Materials and Wearable Energy TechnologiesSoochow UniversitySoochow 215006China Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow UniversitySoochow 215123China School of Chemistry and Chemical Engineering Shihezi UniversityShihezi 832003China School of Chemical and Environmental Engineering Shanghai Institute of TechnologyShanghai 201418China

The steep reduction in costs and systematic optimization of renewable electricity has ignited an intensifying interest in harnessing electroreduction of carbon dioxide(CO_(2)RR)for the generation of chemicals and *** focus of research over the past few decades has been on the optimization of the electrode and the electrolyte ***,cation species in the latter have recently been found to dramatically alter the selectivity of CO_(2)RR and even their catalytic activity by multiple orders of *** a result,the selection of cations is a critical factor in designing catalytic interfaces with high selectivity and efficiency for targeted *** decision-making regarding cation selection relies on a comprehensive understanding of prevailing electrolyte effect models that have been used to elucidate observed experimental *** this perspective,we review the hypotheses that explain how electrolyte cations influence CO_(2)RR by mechanisms such as through tuning of the interfacial electric field,buffering of the local pH,stabilization of the key intermediates and regulation of the interfacial *** endeavor is to elucidate the molecular mechanisms underpinning cation effects,thus fostering the evolution of more holistic and universally applicable predictive *** this regard,we highlight the current challenges in this area of research,while also identifying potential avenues for future investigations.

关键词： CO_(2)electrocatalytic reduction Cation effects Catalytic mechanisms Catalytic interfaces Electric double layer

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Research on Quantitative Identification of Three-Dimensional Connectivity of Fractured-Vuggy Reservoirs

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Energy Engineering 2024年第5期121卷 1195-1207页

作者： Xingliang deng peng Cao Yintao Zhang Yuhui Zhou Xiao Luo Liang Wang Exploration and Development Research Institute PetroChina Tarim Oilfield CompanyKorla841000China PetroChina Hangzhou Research Institute of Geology Hangzhou310023China School of Petroleum Engineering Yangtze UniversityWuhan430100China

The fractured-vuggy carbonate oil resources in the western basin of China are extremely *** connectivity of carbonate reservoirs is complex,and there is still a lack of clear understanding of the development and topological structure of the pore space in fractured-vuggy ***,effective prediction of fractured-vuggy reservoirs is *** view of this,this work employs adaptive point cloud technology to reproduce the shape and capture the characteristics of a fractured-vuggy *** identify the complex connectivity among pores,fractures,and vugs,a simplified one-dimensional connectivity model is established by using the meshless connection element method(CEM).Considering that different types of connection units have different flow characteristics,a sequential coupling calculation method that can efficiently calculate reservoir pressure and saturation is *** automatic history matching,the dynamic production data is fitted in real-time,and the characteristic parameters of the connection unit are *** results show that the three-dimensional connectivity model of the fractured-vuggy reservoir built in this work is as close as 90%of the fine grid model,while the dynamic simulation efficiency is much higher with good accuracy.

关键词： Fractured-vuggy reservoir three-dimensional connectivity connection unit dynamic prediction automatic history matching

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Surgical timing for primary encapsulating peritoneal sclerosis: A case report and review of literature

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World Journal of Gastrointestinal Surgery 2022年第4期14卷 352-361页

作者： peng deng Long-Xin Xiong Ping He Jian-Hua Hu Qi-Xu Zou Shi-Lian Le Sen-Lin Wen Department of General Surgery The First Hospital of NanchangNanchang 330008Jiangxi ProvinceChina Department of Emergency Surgery The First Hospital of NanchangNanchang 330008Jiangxi ProvinceChina

BACKGROUND Primary encapsulating peritoneal sclerosis(EPS)is a rare but devastating disease that causes fibrocollagenous cocoon-like encapsulation of the bowel,resulting in bowel *** pathogenesis,prevention,and treatment strategies of EPS remain unclear so *** most patients are diagnosed during exploratory laparotomy,for the non-surgically diagnosed patients with primary EPS,the surgical timing is also *** SUMMARY A 44-year-old female patient was referred to our center on September 6,2021,with complaints of abdominal distention and bilious vomiting for 2 *** examination revealed that the vital signs were stable,and the abdomen was slightly *** tomography scan showed a conglomerate of multiple intestinal loops encapsulated in a thick sac-like membrane,which was surrounded by abdominal *** patient was diagnosed with idiopathic *** was observed after abdominal paracentesis,and the patient was discharged on September 13 after the resumption of a normal *** case raised a question:When should an exploratory laparotomy be performed on patients who are non-surgically diagnosed with *** a result,we conducted a review of the literature on the clinical manifestations,intraoperative findings,surgical methods,and therapeutic effects of *** Recurrent intestinal obstructions and abdominal mass combined with the imaging of encapsulated bowel are helpful in diagnosing idiopathic *** intestinal resection should be avoided.

关键词： Primary encapsulating peritoneal sclerosis Abdominal cocoon Intestinal obstruction Case report

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Application of modified discontinuous deformation analysis to dynamic modelling of the Baige landslide in the Jinsha River

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Journal of Mountain Science 2024年第7期21卷 2305-2319页

作者： XIE Chenxi deng Jianhui peng Xinyan YANG Zhongkang ZHAO Siyuan LI Hua State Key Laboratory of Hydraulics and Mountain River Engineering College of Water Resource and HydropowerSichuan UniversityChengdu 610031China State Key Laboratory of Geohazard Prevention and Geoenvironment Protection Chengdu University of TechnologyChengdu 610051China MOE Key Laboratory of Deep Earth Science and Engineering Institute for Disaster Management and ReconstructionSichuan UniversityChengdu 610031China Power China Chengdu Engineering Corporation Limited Chengdu 610031China

Accurate dynamic modeling of landslides could help understand the movement mechanisms and guide disaster mitigation and *** deformation analysis(DDA)is an effective approach for investigating ***,DDA fails to accurately capture the degradation in shear strength of rock joints commonly observed in high-speed *** this study,DDA is modified by incorporating simplified joint shear strength *** on the modified DDA,the kinematics of the Baige landslide that occurred along the Jinsha River in China on 10 October 2018 are *** violent starting velocity of the landslide is considered *** cases with different violent starting velocities are investigated to show their effect on the landslide movement ***,the landslide movement process and the final accumulation characteristics are analyzed from multiple *** results show that the violent starting velocity affects the landslide motion characteristics,which is found to be about 4 m/s in the Baige *** movement process of the Baige landslide involves four stages:initiation,high-speed sliding,impact-climbing,low-speed motion and *** accumulation states of sliding masses in different zones are different,which essentially corresponds to *** research results suggest that the modified DDA is applicable to similar high-level rock landslides.

关键词： Discontinuous deformation analysis(DDA) Baige landslide Violent starting velocity movement process Accumulation characteristics

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Low-concentration and multi-component NMHCs capture from oil field exhaust using porous ZIF-8/iso-hexadecane slurry

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Green Chemical Engineering 2024年第2期5卷 245-256页

作者： Kun Li Han Tang Jin Cai Chun deng Bei Liu Yunlei peng Changyu Sun Guangjin Chen State Key Laboratory of Heavy Oil Processing China University of PetroleumBeijing102249China

Non-methane hydrocarbons(NMHCs)are a common type of volatile organic compounds(VOCs)pollutant in the petrochemical industry and have attracted widespread attention because of their adverse health effects and environmental *** this paper,we report a new porous slurry formed with zeolitic imidazolate framework-8(ZIF-8)and iso-hexadecane to capture the low-concentration and multi-component NMHCs(mainly ethane(C_(2)H_(6)),propane(C_(3)H_(8)),and n-butane(n-C_(4)H_(10)))from the oil field *** sorption capacity of C_(2)H_(6)in the slurry is significantly higher than that of nitrogen(N_(2))and methane(CH_(4)).Moreover,the slurry demonstrated a clear advantage for C_(2)H_(6)over N_(2)and CH_(4)in competitive adsorption through the pressure-drop *** the NMHCs capture experiments,the C_(3)H_(8)and n-C_(4)H_(10)concentrations after purification can be reduced to below 100 ppm,while the C_(2)H_(6)concentration can reach approximately 180 *** encouragingly,in the breakthrough tests,the slurry exhibits a perfect kinetic separation selectivity for multi-component ***,to avoid structural collapse of ZIF-8 material during long-term use in acidic and wet environments,a certain amount of 2-methylimidazole was retained in the slurry as a protective agent in the material synthesis *** this way,the ZIF-8 materials in the slurry can retain the stable characteristic structure in an aqueous and acidic environment and keep the capture capacity for NMHCs without *** believe the porous ZIF-8/iso-hexadecane slurry is a promising capture agent for low-concentration and multi-component NMHCs with strong purification capacity and stability.

关键词： VOCs capture NMHCs capture MOFs ZIF-8 Porous slurry

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Hierarchical assembly of NiFe-PB-derived bimetallic phosphides on 3D Ti_(3)C_(2) MXene ribbon networks for efficient oxygen evolution

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ChemPhysMater 2024年第1期3卷 118-124页

作者： Chulong Jin Hanlei peng Xiaojun Zeng Zhenyuan Liu deng Ding School of Materials Science and Engineering Jingdezhen Ceramic UniversityJingdezhen 333403China School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212100China College of Chemistry and Environmental Engineering Wuhan Polytechnic UniversityWuhan 430023China

The development of MXene-based heterostructures for electrocatalysis has garnered significant attention owing to their potential as high-performance catalysts that play a pivotal role in hydrogen ***,we present a multistep strategy for the synthesis of a Ti_(3)C_(2) MXene ribbon/NiFePx@graphitic N-doped carbon(NC)heterostructure that enables the formation of three-dimensional(3D)Ti_(3)C_(2) MXene ribbon networks and bimetallic phosphide *** the assistance of HF etching and KOH shearing,the MXene sheets were successfully transformed into 3D MXene networks with interlaced MXene ***,a hydrothermal method,ion exchange route,and phosphorization process were used to anchor NiFeP_(x)@NC nanocubes derived from Ni(OH)_(2)/NiFe-based Prussian blue(NiFe-PB)onto the MXene ribbon *** resulting MXene ribbon/NiFeP_(x)@NC heterostructure demonstrated enhanced oxygen evolution reaction(OER)activity,characterized by a low overpotential(164 mV at a current density of 10 mA cm^(-2))and a low Tafel slope(45 mV dec^(-1)).At the same time,the MXene ribbons/NiFeP_(x)@NC heterostructure exhibited outstanding long-term stability,with a 12 mV potential decay after 5000 cyclic voltammetry(CV)*** study provides a robust pathway for the design of efficient MXene-based heterostructured electrocatalysts for water splitting.

关键词： Metal phosphides Prussian blue nanocubes Ti_(3)C_(2)MXene ribbons Interfacial matching OER

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Transparent micropatterned conductive films based on highlyordered nanowire network

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Nano Research 2024年第5期17卷 4288-4297页

作者： Xin-Ran Zhang Hai-Tao deng Xu Zeng Yi-Lin Wang peng Huang Xiao-Sheng Zhang School of Integrated Circuit Science and Engineering University of Electronic Science and Technology of ChinaChengdu 611731China

Transparent conductive films that are based on nanowire networks are essential to construct flexible,wearable,and even stretchable ***,large-scale precise micropatterning,especially with regard to the controllability of the organizing orientation of nanowires,is a critical ***,we proposed a liquid film rupture self-assembly approach for manufacturing transparent conductive films with microstructure arrays based on a highly ordered nanowire *** large-scale microstructure conductive films were fabricated through air-liquid interface self-assembly and liquid film rupture *** typical micropattern morphologies,including square,hexagon,circle,serpentine,etc.,were prepared to reveal the universal applicability of the proposed *** homogeneity and controllability of this approach were verified for multiple *** the assembly cycles increasing,the optical transmittance decreases *** addition,theoretical model analysis is carried out,and the analytical formula of the speed of the film moving with the surface tension and the density of the liquid film is ***,the feasibility of this approach for piezoresistive strain sensors is *** fabrication approach demonstrated a cost-effective and efficient method for precisely arranging nanowires,which is useful in transparent and wearable applications.

关键词： flexible electronics transparent conductive network micropatterning nanowires micro electromechanical systems(MEMS)

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Design,preparation,application of advanced array structured materials and their action mechanism analyses for high performance lithium-sulfur batteries

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Journal of Energy Chemistry 2024年第2期89卷 266-303,I0007页

作者： Nanping deng Xiaofan Feng Yongbing Jin Zhaozhao peng Yang Feng Ying Tian Yong Liu Lu Gao Weimin Kang Bowen Cheng State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes School of Textile Science and EngineeringTiangong UniversityTianjin 300387China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China

Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage *** widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,*** various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li *** many novel array structured materials are applied to battery for tackling thorny problems mentioned *** this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are ***,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery ***,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are *** hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.

关键词： Array structured materials Preparation methods and structural designs Action mechanism analyses Advanced Li-S batteries Excellent electrochemical performances and safety

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Efficacy and safety of single microneedle radiofrequency *** therapy on moderate-to-severe acne vulgaris:A prospective,randomized,controlled study

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Chinese Medical Journal 2024年第8期137卷 1006-1008页

作者： Chuchu Huang Mengping Mao Yiran peng Ben Wang Yuxuan deng Hongfu Xie Dan Jian Department of Dermatology Xiangya HospitalCentral South UniversityChangshaHunan 410008China National Clinical Research Center for Geriatric Disorders Xiangya HospitalCentral South UniversityChangshaHunan 410008China Hunan Key Laboratory of Aging Biology Xiangya HospitalCentral South UniversityChangshaHunan 410008China Department of Dermatology and Allergy and Christine Kühne-Center for Allergy Research and EducationUniversity Hospital of BonnD-53127BonnGermany

To the Editor:Acne vulgaris is a prevalent skin disorder affecting both physical and psychosocial health.[1]Although photodynamic therapy(PDT)exists for moderate-to-severe acne,due to its adverse reactions,we are still looking forward to a novel therapeutic option with fewer side ***,radiofrequency has been used to treat moderate acne.[2]In this study,we aimed to evaluate the efcacy and safety of moderate-to-severe acne treatment based on a single microneedle with radiofrequency(MRF)*** during three consecutive sessions through a prospective,randomized,and controlled trial study.

关键词： needle prospective randomized

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高固含量NTO的连续流合成及性能表征

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含能材料 2024年第3期32卷 242-248页

作者：杨炜赵登鹏卢欢唱张祯琦黄靖伦马卿田均均荆苏明范桂娟中国工程物理研究院化工材料研究所四川绵阳621999 中北大学环境与安全工程学院山西太原030051

为改善3-硝基-1,2,4-三唑-5-酮(NTO)釜式硝化工艺的高放热安全风险、间歇合成效率低的问题,依据NTO硝化合成不同阶段的反应体系特点与动力学特征,设计了针对高固含量体系的连续流反应装置系统。以2,4-二氢-1,2,4-三唑-5-酮(TO)为原料,... 详细信息

为改善3-硝基-1,2,4-三唑-5-酮(NTO)釜式硝化工艺的高放热安全风险、间歇合成效率低的问题,依据NTO硝化合成不同阶段的反应体系特点与动力学特征,设计了针对高固含量体系的连续流反应装置系统。以2,4-二氢-1,2,4-三唑-5-酮(TO)为原料,结合微通道反应技术与管式反应技术实现了NTO连续流合成,并优化了连续流合成工艺条件及装置。在硝化反应温度为45℃、反应停留时间为9 min,物料摩尔比n(TO):n(HNO_(3))=1:6的条件下,以81.4%的收率合成了NTO,纯度99.53%。利用核磁(NMR)、元素分析(EA)、红外(FTIR)等结构分析方法确认了合成产物结构,采用粉末X射线衍射(XRD)、热质联用(TG-DSC)、BAM感度仪、偏光显微镜对连续流合成产物和釜式合成产物进行了性能表征与对比。结果表明,在10℃·min^(-1)的升温速率下,其热分解峰温为276.23℃,热分解过程质量损失为85.12%,撞击感度大于40 J,摩擦感度大于360 N。与釜式合成NTO相比,连续流合成NTO的热分解峰温提高2.95℃,热分解过程质量损失增加4.44%,撞击与摩擦感度相当,晶体形貌规整、粒度分布更均一。连续流合成时间较釜式工艺缩短90%,收率较釜式工艺提高3.4%,制备效率与安全性有所提高。

关键词： 3-硝基-1,2,4-三唑-5-酮(NTO) 连续流合成高固含量防堵塞性能分析

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