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Optimizing extractants selection for efficient separation of phenols and nitrogen-containing heteroaromatics using hydrogen bond interaction strategies

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Chinese Journal of Chemical Engineering 2024年第4期68卷 43-52页

作者： Pengzhi Bei rui Zhang Jie Feng Antony Rajendran Wenying Li State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of TechnologyTaiyuan 030024China Department of Chemistry Mepco Schlenk Engineering College(Autonomous)Sivakasi 626005India

Focusing on the use of imidazolium ionic liquids and quaternary ammonium salts-based deep eutectic solvents for the separation of phenols and nitrogen-containing heteroaromatics,the role of heteroaromatics as specific sites for hydrogen bond-based separation has been *** environmentally friendly solvents are known for their ability to form hydrogen bonds with heteroatoms,a key aspect in separation *** quantified the hydrogen bond interaction energy to reach the threshold energy for efficient O-and N-heteroaromatics *** article provides an in-depth study of the structural nuances of different hydrogen bonding sites and their affinity properties while conducting a comparative evaluation of the separation efficiency of ionic liquids and deep eutectic solvents from a thermodynamic *** showed that phenols with dual hydrogen bonding recognition sites were easier to separate than nitrogen-containing *** ionic liquids were more suitable for the extraction of nonbasic nitrogen-containing heteroaromatics,and quaternary ammonium salts-based deep eutectic solvents are more effective for phenols and basic nitrogen-containing heteroaromatics,which was confirmed by Fourier transform infrared spectroscopy and empirical ***,this study provides a theoretical basis for the strategy design and selection of extractants for the efficient separation of O-and N-containing aromatic compounds.

关键词： Deep eutectic solvents Hydrogen bond Ionic liquids Separation Solvents Structural characteristics

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Hydrothermal hydrogenation/deoxygenation of palmitic acid to alkanes over Ni/activated carbon catalyst

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Chinese Journal of Chemical Engineering 2024年第2期66卷 8-18页

作者： Min Lin Yuhao Yan Xiaoxian Li rui Li Yulong Wu MOE Engineering Center of Forestry Biomass Materials and Bioenergy Beijing Forestry UniversityBeijing 100083China Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China Key Laboratory of Advanced Reactor Engineering and Safety of Ministry of Education Tsinghua UniversityBeijing 100084China

To produce paraffin from hydrogenation/deoxygenation of palmitic acid,model compound of bio-oil obtained by hydrothermal liquefaction(HTL)of microalgae has been an attractive focus in recent *** order to avoid energy-intensive separation process of water and bio-oil,it is of importance that deoxygenation upgrading of fatty acids under hydrothermal conditions similar to HTL ***,it is the first time to explore the application of activated carbon(AC)-supported non-noble-metal catalysts,such as Ni,Co,and Mo,and so on,in the hydrothermal hydrogenation/deoxygenation of long-chain fatty acids,and the obtained Ni/AC-H(the Ni/AC was further H_(2)pre-reduced)is one of the best *** addition,it is found that the catalytic activity can be further improved by H_(2)pre-reduction of *** results that are more low valences of nickel and oxygen vacancy can be obtained after H_(2)pre-reduction,thus significant promoting the deoxygenation especially the decarbonylation pathway of fatty *** total alkanes yield can reaches 95.9%at optimal conditions(280℃,360 min).This work confirmed that the low-priced AC-supported non-noble-metal catalysts have great potential compared with the noble-metal catalyst,in hydrothermal upgrading of bio-oil.

关键词： Bio-oil Fatty acids Deoxygenation Hydrothermal upgrading

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A low-frequency pure metal metamaterial absorber with continuously tunable stiffness

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Applied Mathematics and Mechanics(English Edition) 2024年第7期45卷 1209-1224页

作者： Xingzhong WANG Shiteng rui Shaokun YANG Weiquan ZHANG Fuyin MA School of Mechanical Engineering Xi’an Jiaotong UniversityXi’an710049China Xi’an Precision Machinery Research Institute Xi’an710077China

To address the incompatibility between high environmental adaptability and deep subwavelength characteristics in conventional local resonance metamaterials,and overcome the deficiencies in the stability of existing active control techniques for band gaps,this paper proposes a design method of pure metal vibration damping metamaterial with continuously tunable stiffness for wideband elastic wave *** design a dual-helix narrow-slit pure metal metamaterial unit,which possesses the triple advantage of high spatial compactness,low stiffness characteristics,and high structural stability,enabling the opening of elastic flexural band gaps in the low-frequency *** to the principle of a sliding rheostat,the introduction of continuously sliding plug-ins into the helical slits enables the continuous variation of the stiffness of the metamaterial unit,achieving a continuously tunable band gap *** successfully extends the effective band gap by more than ten *** experimental results indicate that this metamaterial unit can be used as an additional vibration absorber to absorb the low-frequency vibration energy ***,it advances the metamaterial absorbers from a purely passive narrowband design to a wideband tunable *** pure metal double-helix metamaterials retain the subwavelength properties of metamaterials and are suitable for deployment in harsh ***,by adjusting its stiffness,it substantially broadens the effective band gap range,presenting promising potential applications in various mechanical equipment operating under adverse conditions.

关键词： elastic metamaterial absorber continuously tunable stiffness low-frequency vibration damping variable stiffness design pure metal structure

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Deep neural network-enabled battery open-circuit voltage estimation based on partial charging data

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Journal of Energy Chemistry 2024年第3期90卷 120-132,I0005页

作者： Ziyou Zhou Yonggang Liu Chengming Zhang Weixiang Shen rui Xiong State Key Laboratory of Mechanical Transmission for Advanced Equipment&College of Mechanical and Vehicle Engineering Chongqing UniversityChongqing 400000China Department of Vehicle Engineering School of Mechanical EngineeringBeijing Institute of TechnologyBeijing 100081China Department of Electrical Engineering Harbin Institute of TechnologyHarbin 150000HeilongjiangChina School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyHawthornVictoria 3122Australia

Battery management systems(BMSs) play a vital role in ensuring efficient and reliable operations of lithium-ion *** main function of the BMSs is to estimate battery states and diagnose battery health using battery open-circuit voltage(OCV).However,acquiring the complete OCV data online can be a challenging endeavor due to the time-consuming measurement process or the need for specific operating conditions required by OCV estimation *** addressing these concerns,this study introduces a deep neural network-combined framework for accurate and robust OCV estimation,utilizing partial daily charging *** incorporate a generative deep learning model to extract aging-related features from data and generate high-fidelity OCV *** analysis is employed to identify the optimal partial charging data,optimizing the OCV estimation precision while preserving exceptional *** validation results,using data from nickel-cobalt-magnesium(NCM) batteries,illustrate the accurate estimation of the complete OCV-capacity curve,with an average root mean square errors(RMSE) of less than 3 *** this level of precision for OCV estimation requires only around 50 s collection of partial charging *** validations on diverse battery types operating under various conditions confirm the effectiveness of our proposed *** cases of precise health diagnosis based on OCV highlight the significance of conducting online OCV *** method provides a flexible approach to achieve complete OCV estimation and holds promise for generalization to other tasks in BMSs.

关键词： Lithium-ion battery Open-circuit voltage Health diagnosis Deep learning

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Design and Experimental Verification of a Roll Control Strategy for Large Wingspan Flapping-Wing Aerial Vehicle

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Journal of Bionic Engineering 2024年第4期21卷 1644-1661页

作者： rui Meng Bifeng Song Jianlin Xuan Xiaojun Yang Dong Xue School of Aeronautics Northwestern Polytechnical UniversityXi’an710072China Research and Development Institute of Northwestern Polytechnical University in Shenzhen Shenzhen518057China Yangtze River Delta Research Institute of Northwestern Polytechnical University Taicang215400China

Most flapping-wing aircraft wings use a single degree of freedom to generate lift and thrust by flapping up and down,while relying on the tail control surfaces to manage ***,these aircraft have certain limitations,such as poor accuracy in attitude control and inadequate roll control *** paper presents a design for an active torsional mechanism at the wing's trailing edge,which enables differential variations in the pitch angle of the left and right wings during *** simple mechanical form significantly enhances the aircraft's roll control *** experimental verification of this mechanism was conducted in a wind tunnel using the RoboEagle flapping-wing aerial vehicle that we *** study investigated the effects of the control strategy on lift,thrust,and roll moment during flapping ***,the impact of roll control on roll moment was examined under various wind speeds,flapping frequencies,angles of attack,and wing ***,several rolling maneuver flight tests were performed to evaluate the agility of RoboEagle,utilizing both the elevon control strategy and the new roll control *** results demonstrated that the new roll control strategy effectively enhances the roll control capability,thereby improving the attitude control capabilities of the flapping-wing aircraft in complex wind field *** conclusion is supported by a comparison of the control time,maximum roll angle,average roll angular velocity,and other relevant parameters between the two control strategies under identical roll control input.

关键词： Roll control Bio-inspired Roll moment Flapping wing aerial vehicle

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Feature-aided pose estimation approach based on variational auto-encoder structure for spacecrafts

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Chinese Journal of Aeronautics 2024年第8期37卷 329-341页

作者： Yanfang LIU rui ZHOU Desong DU Shuqing CAO Naiming QI Department of Aerospace Engineering Harbin Institute of TechnologyHarbin 150001China Suzhou Research Institute of HIT Suzhou 215104China Shanghai Institute of Spaceflight Control Technology Shanghai 201109China Shanghai Key Laboratory of Aerospace Intelligent Control Technology Shanghai 201109China

Real-time 6 Degree-of-Freedom(DoF)pose estimation is of paramount importance for various on-orbit *** from the development of deep learning,Convolutional Neural Networks(CNNs)in feature extraction has yielded impressive achievements for spacecraft pose *** improve the robustness and interpretability of CNNs,this paper proposes a Pose Estimation approach based on Variational Auto-Encoder structure(PE-VAE)and a Feature-Aided pose estimation approach based on Variational Auto-Encoder structure(FA-VAE),which aim to accurately estimate the 6 DoF pose of a target *** methods treat the pose vector as latent variables,employing an encoder-decoder network with a Variational Auto-Encoder(VAE)*** enhance the precision of pose estimation,PE-VAE uses the VAE structure to introduce reconstruction mechanism with the whole ***,FA-VAE enforces feature shape constraints by exclusively reconstructing the segment of the target spacecraft with the desired *** evaluation against leading methods on public datasets reveals similar accuracy with a threefold improvement in processing speed,showcasing the significant contribution of VAE structures to accuracy enhancement,and the additional benefit of incorporating global shape prior features.

关键词： Pose estimation Variational auto-encoder Feature-aided Pose Estimation Approach On-orbit measurement tasks Simulated and experimental dataset

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Starlet:Network defense resource allocation with multi-armed bandits for cloud-edge crowd sensing in IoT

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Digital Communications and Networks 2024年第3期10卷 586-596页

作者： Hui Xia Ning Huang Xuecai Feng rui Zhang Chao Liu College of Computer Science and Technology Ocean University of ChinaQingdao266100China

The cloud platform has limited defense resources to fully protect the edge servers used to process crowd sensing data in Internet of *** guarantee the network's overall security,we present a network defense resource allocation with multi-armed bandits to maximize the network's overall ***,we propose the method for dynamic setting of node defense resource thresholds to obtain the defender(attacker)benefit function of edge servers(nodes)and ***,we design a defense resource sharing mechanism for neighboring nodes to obtain the defense capability of ***,we use the decomposability and Lipschitz conti-nuity of the defender's total expected utility to reduce the difference between the utility's discrete and continuous arms and analyze the difference ***,experimental results show that the method maximizes the defender's total expected utility and reduces the difference between the discrete and continuous arms of the utility.

关键词： Internet of things Defense resource sharing Multi-armed bandits Defense resource allocation

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ON MONOTONE TRAVELING WAVES FOR NICHOLSON'S BLOWFLIES EQUATION WITH DEGENERATE p-LAPLACIAN DIFFUSION

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Acta Mathematica Scientia 2024年第4期44卷 1550-1571页

作者： rui HUANG Yong WANG Zhuo YIN School of Mathematical Sciences South China Normal UniversityGuangzhou 510631China

We study the existence and stability of monotone traveling wave solutions of Nicholson's blowflies equation with degenerate p-Laplacian *** prove the existence and nonexistence of non-decreasing smooth traveling wave solutions by phase plane analysis ***,we show the existence and regularity of an original solution via a compactness ***,we prove the stability and exponential convergence rate of traveling waves by an approximated weighted energy method.

关键词： degenerate diffusion p-Laplacian traveling waves stability

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A discussion about the limitations of the Eurocode’s high-speed load model for railway bridges

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Railway Engineering Science 2024年第2期32卷 211-228页

作者： Gonçalo Ferreira Pedro Montenegro Josérui Pinto António Abel Henriques rui Calçada CONSTRUCT-LESE Faculty of EngineeringUniversity of PortoRua Dr.Roberto Frias4200-465 PortoPortugal CONSTRUCT-LABEST Faculty of EngineeringUniversity of PortoRua Dr.Roberto Frias4200-465 PortoPortugal

High-speed railway bridges are subjected to normative limitations concerning maximum permissible deck *** the design of these structures,the European norm EN 1991-2 introduces the high-speed load model(HSLM)—a set of point loads intended to include the effects of existing high-speed ***,the evolution of current trains and the recent development of new load models motivate a discussion regarding the limits of validity of the *** this study,a large number of randomly generated load models of articulated,conventional,and regular trains are tested and compared with the envelope of HSLM *** each type of train,two sets of 100,000 load models are considered:one abiding by the limits of the EN 1991-2 and another considering wider *** comparison is achieved using both a bridge-independent metric(train signatures)and dynamic analyses on a case study bridge(the Canelas bridge of the Portuguese Railway Network).For the latter,a methodology to decrease the computational cost of moving loads analysis is *** show that some theoretical load models constructed within the stipulated limits of the norm can lead to effects not covered by the *** is especially noted in conventional trains,where there is a relation with larger distances between centres of adjacent vehicle bogies.

关键词： High-speed load model Dynamic analysis High-speed railways Train signature Railway bridges Deck acceleration

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MCDM technique using single-valued neutrosophic trigonometric weighted aggregation operators

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Journal of Management Analytics 2024年第1期11卷 45-61页

作者： Jun Ye Shigui Du rui Yong School of Civil and Environmental Engineering Ningbo UniversityNingboPeople’s Republic of China

Motivated based on the trigonometric t-norm and t-conorm,the aims of this article are to present the trigonometric t-norm and t-conorm operational laws of SvNNs and then to propose the SvNN trigonometric weighted average and geometric aggregation operators for the modelling of a multiple criteria decision making(MCDM)technique in an inconsistent and indeterminate *** realize the aims,this paper first proposes the trigonometric t-norm and t-conorm operational laws of SvNNs,which contain the hybrid operations of the tangent and arctangent functions and the cotangent and inverse cotangent functions,and presents the SvNN trigonometric weighted average and geometric operators and their ***,an MCDM technique is proposed in view of the presented two aggregation operators in the circumstance of *** the end,an actual case of the choice issue of slope treatment schemes is provided to indicate the practicability and effectivity of the proposed MCDM technique.

关键词： Single-valued neutrosophic number trigonometric t-norm and t-conorm trigonometric weighted aggregation operator decision making

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