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Unravelling the protracted U-Pb zircon geochronological record of high to ultrahigh temperature metamorphic rocks:Implications for provenance investigations

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Geoscience Frontiers 2023年第2期14卷 116-132页

作者： Mahyra Tedeschi pedro leonardo rossi vieira Matheus Kuchenbecker Bruno VRibeiro Vitor Barrote Humberto Reis Laura Stutenbecker Cristiano Lana Antonio pedrosa-Soares Ivo Dussin Programa de Pós-graduação em Geologia da Universidade Federal de Minerais Centro de Pesquisas Manoel Teixeira da CostaInstitute of GeosciencesFederal University of Minas GeraisAv.Antônio Carlos6627Belo Horizonte 31270-901Brazil Institute of Geological Sciences University of Bern3012 BernSwitzerland Laboratório de Estudos Tectônicos Universidade Federal dos Vales do Jequitinhonha e MucuriRodovia MGT 367Km 583-Diamantina 39100-000Brazil School of Earth Atmosphere and EnvironmentMonash UniversityClaytonVictoria 3800Australia Timescales of Mineral Systems Group School of Earth and Planetary SciencesCurtin UniversityPerthWA 6845Australia Freie Universität Berlin Institut für Geologische WissenschaftenGeochemieMalteserstr.1074-10012249 BerlinGermany Departamento de Geologia-Escola de Minas Universidade Federal de Ouro Preto 35400-000Brazil Department of Materials and Earth Sciences Institute of Applied GeosciencesTU DarmstadtSchnittspahnstr.964287 DarmstadtGermany TEKTOS Geotectonic Research Group Geology InstituteRio de Janeiro State UniversitySão Francisco Xavier Street524/4030-AMaracanãRio de Janeiro 20550-900Brazil

The assessment of detrital zircon age records is a key method in basin analysis,but it is prone to several biases that may compromise accurate sedimentary provenance *** to ultrahigh temperature(HT-UHT)metamorphism(especially if T>850℃)is herein presented as a natural cause of bias in provenance studies based on U-Pb detrital zircon ages,since zircon from rocks submitted to these extreme and often prolonged conditions frequently yield protracted,apparently concordant,geochronological *** age spreading can result from disturbance of the primary U-Pb zircon system,likewise from(re)crystallization processes during multiple and/or prolonged metamorphic *** this contribution,available geochronological data on Archean,Neoproterozoic and Palaeozoic HT-UHT metamorphic rocks,acquired by different techniques(SIMS and LA-ICP-MS)and showing distinct compositions,are reassessed to demonstrate HT-UHT metamorphism may result in modes and age distributions of unclear geological *** a consequence,it may induce misinterpretations on UPb detrital zircon provenance analyses,particularly in sedimentary rocks metamorphosed under such extreme temperature *** evaluate the presence of HT-UHT metamorphism-related bias in the detrital zircon record,we suggest a workflow for data acquisition and interpretation,combining a multi-proxy approach with:(i)in situ U-Pb dating coupled with Hf analyses to retrieve the isotopic composition of the sources,and(ii)the integration of a petrochronological investigation to typify fingerprints of the HT-UHT metamorphic *** proposed workflow is validated in the investigation of one theoretical and one natural example allowing a better characterization of the sedimentary sources,maximum depositional ages,and the tectonic setting of the *** workflow allows to the appraisal of biases imposed by HT-UHT metamorphism and resulting disturbances in the U-Pb detrital zircon record,particularly for sedimentary

关键词： Detrital zircon Protracted zircon record Sedimentary basins UHT metamorphism Prolonged metamorphism Bias in detrital zircon

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Cooling performance of earth-to-air heat exchangers applied to a poultry barn in semi-desert areas of south Iraq

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International Journal of Agricultural and Biological Engineering 2018年第3期11卷 47-53页

作者： Wasseem Morshed Lorenzo Leso leonardo Conti Giuseppe rossi Stefano Simonini Matteo Barbari Department of Agricultural Food and Forestry SystemsUniversity of FirenzeVia San Bonaventura13.50145 FirenzeItaly

Earth-to-air heat exchangers(EAHE)can reduce the energy consumption required for heating and cooling of *** composition and the thermal characteristics of the soil influence the heat exchange capacity,and the soil moisture can furthermore affect thermal performance of *** aim of this study was to compare the thermal performance of EAHE in dry and artificially wetted *** were carried out in the Basra Province(Iraq),in a semi-desert *** experimental EAHE were built in a poultry barn and tested from June 2013 to September *** pipe exchangers were buried at 2 m *** heat exchanger operated in dry soil(DE),while the other one operated in artificially wetted soil(WE).In the WE system,a drip tubing placed 10 cm above the air pipe wetted the soil around the *** temperatures at the inlet and at the outlet of both the exchangers as well as soil temperature at 2 m deep were continuously *** experimental results confirmed that wetting the soil around EAHE improves the general heat exchange *** coefficient of cooling performance(COP)of the earth-to-air heat exchangers system was evaluated on the basis of the ratio between the heat removed from the air or added to the air and the energy *** the day,with an average COP of 6.41,the WE system cooled the air more than the DE system,which reported a value of *** average,in the hottest hours of the day,the outlet temperature of the WE was 37.35℃ while in the DE it was 38.91℃.Moreover,during the nighttime,the WE system warmed the air more than the DE system.

关键词： Earth-to-air heat exchangers thermal performance cooling artificially wetted soil poultry barn heat stress

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Forest fire risk indices and zoning of hazardous areas in Sorocaba,Sao Paulo state,Brazil

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Journal of Forestry Research 2020年第2期31卷 581-590页

作者： leonardo Guimaraes Ziccardi Claudio Roberto Thiersch Aurora Miho Yanai Philip Martin Fearnside pedro Jose Ferreira-Filho Department of Environmental Dynamics National Institute for Research in Amazonia(INPA)Av.Andre AraujoNo.2936ManausAmazonasCEP 69067-375Brazil Department of Environmental Sciences Federal University of Sao Carlos(UFSCar)SorocabaSao PauloCEP 18052-780Brazil

This study compares the performance of three fire risk indices for accuracy in predicting fires in semideciduous forest fragments,creates a fire risk map by integrating historical fire occurrences in a probabilistic density surface using the Kernel density estimator(KDE)in the municipality of Sorocaba,Sao Paulo state,*** logarithmic Telicyn index,Monte Alegre formula(MAF)and enhanced Monte Alegre formula(MAF+)were employed using data for the period 1 January 2005 to 31 December *** data and numbers of fire occurrences were obtained from the National Institute of Meteorology(INMET)and the Institute for Space Research(INPE),*** performance measures were calculated:Heidke skill score(SS)and success rate(SR).The MAF+index was the most accurate,with values of SS and SR of 0.611%and 62.8%,*** fire risk map revealed two most susceptible areas with high(63 km^2)and very high(47 km^2)risk of fires in the *** of the best risk index and the generation of fire risk maps can contribute to better planning and cost reduction in preventing and fighting forest fires.

关键词： Forest fire risk maps Forest fire protection Monitoring Monte Alegre formula

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Boosting energy-storage capability in carbon-based supercapacitors using low-temperature water-in-salt electrolytes

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Journal of Energy Chemistry 2022年第7期31卷 521-530,I0013页

作者： Joao pedro A.Santos Manuel J.Pinzón érick A.Santos Rafael Vicentini Cesar J.B.Pagan leonardo M.Da Silva Hudson Zanin Brazilian Renewable Energies Center for Innovation on New EnergiesSchool of Electrical and Computer EngineeringUniversity of CampinasSao Paulo 13083-852Brazil Department of Semiconductors Instruments and PhotonicsSchool of Electrical and Computer EngineeringUniversity of CampinasSao Paulo 13083-852Brazil Laboratory of Fundamental and Applied Electrochemistry Department of ChemistryFederal University of Jequitinhonha e Mucuri’s ValleyMinas Gerais 39100-000Brazil

Supercapacitors(SCs) are high-power energy storage devices with ultra-fast charge/discharge *** using concentrated aqueous-based electrolytes can work at low temperatures due to their intrinsic properties, such as higher freezing point depression(FPD) and robustness. Besides the traditional organic-and aqueous-based(salt-in-water) electrolytes used in SCs, water-in-salt(WISE) sodium perchlorate electrolytes offer high FPD, non-flammability, and low-toxicity conditions, allowing the fabrication of safer, environmentally friendly, and more robust devices. For the first time, this work reports a comprehensive study regarding WISE system’s charge-storage capabilities and physicochemical properties under low-temperature conditions(T < 0 ℃) using mesoporous carbon-based electrodes. The effect of temperature reduction on the electrolyte viscosity and electrical properties was investigated using different techniques and the in-situ(or operando) Raman spectroscopy under dynamic polarization *** cell voltage, equivalent series resistance, and specific capacitance were investigated as a function of the temperature. The cell voltage(U) increased ~ 50%, while the specific capacitance decreased ~20%when the temperature was reduced from 25 ℃ to -10 ℃. As a result, the maximum specific energy(E = CU^(2)/2) increased ~ 100%. Therefore, low-temperature WISEs are promising candidates to improve the energy-storage characteristics in SCs.

关键词： Carbon supercapacitors Water-in-salt electrolytes Low-temperature charge-storage Specific energy improvement at low temperatures

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Best practices for electrochemical characterization of supercapacitors

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Journal of Energy Chemistry 2023年第5期80卷 265-283,I0007页

作者： João pedro Aguiar dos Santos Fernando Cesar Rufino Joǎo IYutaka Ota Rodolfo CFernandes Rafael Vicentini Cesar JBPagan leonardo Morais Da Silva Hudson Zanin Brazilian Renewable Energies Center for Innovation on New EnergiesSchool of Electrical and Computer EngineeringUniversity of CampinasSP 13083-852Brazil School of Electrical and Computer Engineering University of CampinasSP 13083-852Brazil Department of Chemistry Laboratory of Fundamental and Applied ElectrochemistryFederal University of Jequitinhonha e Mucuri's ValleyRodovia MGT 367km 5835000Alto da Jacuba39100-000 DiamantinaMGBrazil

We discuss here essential aspects of the experimental supercapacitors characterization by a series of well-known electrochemical *** are motivated by a considerable number of publications that misreport procedures and *** often conceal or neglect essential information about the electrochemical analytical apparatus used and its *** lack of such information may lead researchers,especially inexperienced ones,to misunderstand the procedures and ***,the misled electrochemical equipment configuration favors misinterpretation of data and low reproducibility *** paper aims to highlight these issues and clarify *** explain fundamental concepts of some electrochemical analytical methods,such as cyclic voltammetry,galvanostatic charge-discharge,single potential step chronoamperometry,and electrochemical impedance spectroscopy,focusing on the supercapacitor *** configurations of electrical parameters are presented and discussed to highlight the effects of incorrect setup and uncover misleading *** discuss how the electrochemical setup and data analyses matter in reliable data results for the supercapacitor.

关键词： Supercapacitor Electrochemical instrumentation Electrochemical methods Electrochemistry

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Ion dynamics into different pore size distributions in supercapacitors under compression

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Journal of Energy Chemistry 2023年第5期80卷 110-119,I0004页

作者： João pedro Aguiar dos Santos Cesar J.B.Pagan Rafael Vicentini Reinaldo F.Teófilo Renato Beraldo leonardo M.Da Silva Hudson Zanin Brazilian Renewable Energies Center for Innovation on New EnergiesSchool of Electrical and Computer EngineeringUniversity of CampinasAv.Albert Einstein 40CampinasSP13083-852Brazil School of Electrical and Computer Engineering University of CampinasSP 13083-852Brazil Multivariate Chemical Data Analysis Laboratory Department of ChemistryUniversidade Federal de Viçosa36570-900 ViçosaMGBrazil Department of Chemistry Laboratory of Fundamental and Applied ElectrochemistryFederal University of Jequitinhonha and Mucuri's ValleyRodovia MGT 367km 5835000 Alto da Jacuba39100-000DiamantinaMGBrazil

Compressing supercapacitor(SCs)electrode is essential for improving the energy storage characteristics and minimizing ions’distance travel,faradaic reactions,and overall ohmic *** comprising the ion dynamics in SC electrodes under compression are still ***,the ionic dynamics of five aqueous electrolytes in electrodes under compression were studied in this work for tracking electrochemical and structural changes under mechanical stress.A superionic state is formed when the electrode is compressed until the micropores match the dimensions with the electrolyte’s hydrated ion sizes,which increases the *** excessive compression is applied,the accessible pore regions decrease,and the capacitance ***,as the studied hydrated ions have different dimensions,the match between ion/pore sizes *** the LiOH and NaClO4electrolytes,increasing the pressure from 60 to 120 and 100 PSI raised the capacitance from 13.5 to 35.2 F g^(-1)and 30.9 to 39.0 F g^(-1),***,the KOH electrolyte with the lowest and LiCl with the biggest combination of hydrated ion size have their point of maximum capacitance(39.5 and 36.7F g^(-1))achieved at 140 and 80 PSI,*** LiCl and KCl electrolytes,overcompression causes a drop in capacitance higher than 23%.

关键词： Mechanic compression Pore size distribution lon dynamics Activated carbon Supercapacitors

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Big data in healthcare:Conceptual network structure,key challenges and opportunities

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Digital Communications and Networks 2023年第4期9卷 856-868页

作者： leonardo B.Furstenaua pedro Leivas Michele Kremer Sott Michael S.Dohan Jose Ricardo Lopez-Robles Manuel J.Cobo Nicola Luigi Bragazzi Kim-Kwang Raymond Choo Post-Graduate Program in Industrial Engineering Federal University of Rio Grande Do SulPorto Alegre90035-190Brazil University of Santa Cruz Do Sul Av.Independencia 2293Santa Cruz Do SulRSBrazil Business School Unisinos UniversityAv.Dr.Nilo Peçanha 160091330-002Porto AlegreBrazil Faculty of Business Administration Lakehead UniversityThunder BayOntarioCanada Autonomous University of Zacatecas Av.Ramon Lopez Velarde Col.CentroZacatecas98000Mexico Department of Computer Science and Artificial Intelligence Andalusian Research Institute in Data Science and Computational Intelligence(DaSCI)University of GranadaGranada 18071Spain York University ON M3J 1P3Canada Department of Information Systems and Cyber Security University of Texas at San AntonioSan AntonioTX78249USA

Big data is a concept that deals with large or complex data sets by using data analysis tools(e.g.,data mining,machine learning)to analyze information extracted from several sources *** data has attracted wide attention from academia,for example,in supporting patients and health professionals by improving the accuracy of decision-making,diagnosis and disease *** research aimed to perform a Bibliometric Performance and Network Analysis(BPNA)supported by a Scoping Review(SR)to depict the strategic themes,thematic evolution structure,main challenges and opportunities related to the concept of big data applied in the healthcare *** this goal in mind,4857 documents from the Web of Science covering the period between 2009 to June 2020 were analyzed with the support of SciMAT *** bibliometric performance showed the number of publications and citations over time,scientific productivity and the geographic distribution of publications and research *** strategic diagram yielded 20 clusters and their relative importance in terms of centrality and *** thematic evolution structure presented the most important themes and how it changes over ***,we presented the main challenges and future opportunities of big data in healthcare.

关键词： Big data Healthcare digitalization Bibliometric Strategic intelligence Co-word analysis SciMAT

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Postgraduate education among family and community physicians in Brazil:the Trajetórias MFC project

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Family Medicine and Community Health 2020年第3期8卷 1-10页

作者： leonardo Ferreira Fontenelle Stephani Vogt rossi Miguel Henrique Moraes de Oliveira Diego JoséBrandão Thiago Dias Sarti Medical School Universidade Vila VelhaVila VelhaBrazil Commission of Medical Residency Universidade Vila VelhaVila VelhaBrazil Department of Social Medicine Universidade Federal do Espirito SantoVitoriaBrazil

Objective Our objective was to describe the postgraduate education trajectories of family and community physicians in Brazil,where neither primary healthcare nor family and community medicine is recognised as a knowledge area for the purpose of research and postgraduate education(master’s and PhD degrees).Design An observational,exploratory study,using administrative data.A nationwide list of family and community physicians as of late November 2018 was compiled from multiple *** on the mode of specialisation was obtained from the same sources and were correlated with data on master’s and PhD degrees,obtained from the curricula vitae on the Lattes *** This study was set in *** 6238 family and community physicians(58.3%female),of whom 2795 had earned a specialist certificate(identified from the list of physicians certified by Sociedade Brasileira de Medicina de Família e Comunidade)and 3957 had completed medical residency(identified from SisCNRM,the national information system for medical residency).Results A master’s degree was held by 747(12.0%)family and community physicians,and a PhD by 170(2.7%);most degrees were in collective health(47.0%and 42%,respectively).Men were more likely than women to hold a master’s degree(adjusted odds ratio(aOR)1.24,95%uncertainty interval(UI)1.07-1.45)and even more likely to a hold PhD(aOR 1.86,95%UI 1.35-2.59).Family and community physicians were also less likely to hold a PhD degree if their master’s degree was professional(oriented towards jobs outside academia)instead of academic(aOR 0.15,95%UI 0.05-0.39)or in some area other than collective health or medicine(aOR 0.41,95%UI 0.21-0.78,compared with a master’s degree in collective health).The postgraduate degree was more likely to precede specialisation for family and community physicians specialising through certification(master’s degree 39.9%,PhD 33%)than through medical residency(master’s degree 9.1%,PhD 6%).Conclusion Family and community

关键词： MFC collective education

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Molecular profiling and patient selection for the multimodal approaches for patients with resectable colorectal liver metastases

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Hepatobiliary Surgery and Nutrition 2024年第2期13卷 273-292页

作者： Raphael L.C.Araujo leonardo G.Fonseca Raphael Oliveira Silva Marcelo Moura Linhares pedro L.S.Uson Junior Department of Surgery Universidade Federal de São PauloSão PauloSPBrazil Hospital e Maternidade Brasil-Rede D’Or São Luiz Santo AndréSPBrazil Department of Oncology Hospital Israelita Albert EinsteinSão PauloSPBrazil Department of Oncology Instituto do Cancer do Estado de São PauloUniversity of Sao PauloSão PauloSPBrazil Department of Oncology Hospital Ministro Costa CavalcantiFoz do IguaçuPRBrazil Center for Personalized Medicine Hospital Israelita Albert EinsteinSão PauloSPBrazil

Colorectal cancer represents the third most common cancer and about 20%are diagnosed with synchronous metastatic *** a historical point of view,surgery remains the mainstream treatment for resectable colorectal liver metastases(CRLM).Furthermore,disease outcomes are improving due significant advances in systemic treatments and diagnostic ***,the optimal timing for neoadjuvant chemotherapy or upfront surgery for CRLM has not yet been established and remains an open ***,patient selection combining image workouts,time of recurrence,positive lymph nodes,and molecular biomarkers can improve the decision-making ***,molecular profiling is rising as a promising field to be incorporated in the multimodal approach and guide patient selection and sequencing of *** biomakers,genetic profiling,and circulating tumor DNA have been used to offer as much personalized treatment as possible,based on the precision oncology concept of tailored care rather than a guideline-based *** review article discusses the role of molecular pathology and biomarkers as prognostic and predictor factors in the diagnosis and treatment of resectable CRLM.

关键词： Colorectal liver metastases(CRLM) surgery chemotherapy molecular pathology circulating tumor DNA tumor markers

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Internet of things:Conceptual network structure,main challenges and future directions

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Digital Communications and Networks 2023年第3期9卷 677-687页

作者： leonardo B.Furstenau Yan Pablo Reckziegel Rodrigues Michele Kremer Sott pedro Leivas Michael S.Dohan José Ricardo López-Robles Manuel J.Cobo Nicola Luigi Bragazzi Kim-Kwang Raymond Choo Department of Industrial Engineering Federal University of Rio Grande do SulPorto Alegre 90035-190Brazil University of Santa Cruz do Sul Av.Independencia2293Santa Cruz do SulRSBrazil Business School Unisinos UniversityAv.Dr.Nilo Peçanha 160091330-002Porto AlegreBrazil Lakehead University Thunder BayONP7B 5E1Canada Academic Unit of Accounting and Management Autonomous University of ZacatecasCalle Comercio y Administracion S/NFracc.ProgresoC.P.98066ZacatecasZacatecasMexico Department of Computer Science and Artificial Intelligence University of Granada18071 GranadaSpain York University ONM3J 1P3Canada Department of Information Systems and Cyber Security University of Texas at San AntonioSan AntonioTX78249USA

Internet of Things(IoT)is a key technology trend that supports our digitalized society in applications such as smart countries and smart *** this study,we investigate the existing strategic themes,thematic evolution structure,key challenges,and potential research opportunities associated with the *** this study,we conduct a Bibliometric Performance and Network Analysis(BPNA),supplemented by an exhaustive Systematic Literature Review(SLR).Specifically,in BPNA,the software SciMAT is used to analyze 14,385 documents and 30,381 keywords in the Web of Science(WoS)database,which was released between 2002 and *** results reveal that 31 clusters are classified according to their importance and development,and the conceptual structures of key clusters are presented,along with their performance analysis and the relationship with other *** thematic evolution structure describes the important cluster(s)over *** the SLR,23 documents are *** SLR reveals key challenges and limitations associated with the *** expect the results will form the basis of future research and guide decision-making in the IoT and other supporting industries.

关键词： Internet of things Strategic intelligence Industry 4.0 SciMAT Bibliometric analysis Science mapping

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