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Tailoring Electrode-Electrolyte Interface Using an Electron-Deficient Borate-Based Additive in MgTFSI2-MgCl2/DME Electrolyte for Rechargeable Magnesium Batteries

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ENERGY & ENVIRONMENTAL MATERIALS 2024年第6期7卷 167-175页

作者： Fan, Haiyan Zhang, Xinxin Xiao, Jianhua Chen, Wenjie Lin, Qiyuan Ng, Zi Shyun Lin, Yitao Su, Yi pan, ludi Su, Yipeng Ren, Shuaiyang Liu, Haowen Li, Xuanzhang Zhang, Yuegang Tsinghua Univ State Key Lab Low Dimens Quantum Phys Beijing 100084 Peoples R China Tsinghua Univ Dept Phys Beijing 100084 Peoples R China Frontier Sci Ctr Quantum Informat Beijing 100084 Peoples R China

Rechargeable magnesium metal batteries need an electrolyte that forms a stable and ionically conductive solid electrolyte interphase (SEI) on the anodes. Here, we used molecular dynamic simulation, density functional theory calculation, and X-ray photoelectron spectroscopy analysis to investigate the solvation structures and SEI compositions in electrolytes consisting of dual-salts, magnesium bis(trifluoromethanesulfonyl)imide (MgTFSI2), and MgCl2, with different additives in 1,2-dimethoxyethane (DME) solvent. We found that the formed [Mg-3(mu-Cl)(4)(DME)(m)TFSI2] (m = 3, 5) inner-shell solvation clusters in MgTFSI2-MgCl2/DME electrolyte could easily decompose and form a MgO- and MgF2-rich SEI. Such electron-rich inorganic species in the SEI, especially MgF2, turned out to be detrimental for Mg plating/stripping. To reduce the MgF2 and MgO contents in SEI, we introduce an electron-deficient tri(2,2,2-trifluoroethyl) borate (TFEB) additive in the electrolyte. Mg//Mg cells using the MgTFSI2-MgCl2/DME-TFEB electrolyte could cycle stably for over 400 h with a small polarization voltage of similar to 150 mV. Even with the presence of 800 ppm H2O, the electrolyte with TFEB additive could still preserve its good electrochemical performance. The optimized electrolyte also enabled stable cycling and high-rate capability for Mg//Mo6S8 and Mg//CuS full cells, showing great potential for future applications.

关键词： electrolyte additives interfacial chemistry magnesium metal batteries solvation structure

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Tailoring Mg^(2+)Solvation Structure in a Facile All-Inorganic[Mg_(x)Li_(y)Cl2_(x+y)·nTHF]Complex Electrolyte for High Rate and Long Cycle-Life Mg Battery

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Energy & Environmental Materials 2023年第2期6卷 152-158页

作者： Haiyan Fan Xinxin Zhang Yuxing Zhao Jianhua Xiao Hua Yuan Guang Wang Yitao Lin Jifang Zhang ludi pan Ting pan Yang Liu Yuegang Zhang State Key Laboratory of Low-Dimensional Quantum Physics Department of PhysicsTsinghua UniversityBeijing 100084China

A high-performance all-inorganic magnesium-lithium chloride complex(MLCC)electrolyte is synthesized by a simple room-temperature reaction of LiCl with MgCl_(2) in tetrahydrofuran(THF)*** dynamics simulation,density functional theory calculation,Raman spectroscopy,and nuclear magnetic resonance spectroscopy reveal that the formation of[Mg_(x)Li_(y)Cl_(2x+y)·nTHF]complex solvation structure significantly lowers the coordination number of THF in the first solvation sheath of Mg^(2+),which significantly enhances its de-solvation *** MLCC electrolyte presents a stable electrochemical window up to 3.1 V(vs Mg/Mg^(2+))and enables reversible cycling of Mg metal deposition/stripping with an outstanding Coulombic efficiency up to 99%at current densities as high as 10 mA cm^(-2).Utilizing the MLCC electrolyte,a Mg/Mo_(6)S_(8) full cell can be cycled for over 10000 cycles with a superior capacity retention of 85 mA h g^(-1) under an ultrahigh rate of 50 C(1 C=128.8 mA g^(-1)).The facile synthesis of highperformance MLCC electrolyte provides a promising solution for future practical magnesium batteries.

关键词： cycle life electrolyte Mg battery solvation structure

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A flexible artificial solid-electrolyte interlayer supported by compactness-tailored carbon nanotube network for dendrite-free lithium metal anode

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Journal of Energy Chemistry 2022年第6期31卷 421-427,I0012页

作者： Haowen Liu Jifang Zhang Yang Liu Yang Wei Shuaiyang Ren ludi pan Yi Su Jianhua Xiao Haiyan Fan Yitao Lin Yipeng Su Yuegang Zhang State Key Laboratory of Low-Dimensional Quantum Physics and Department of Physics Tsinghua UniversityBeijing 100084China

A dendrite-free lithium metal anode requires a stable interface designed for efficient and reversible lithium plating and stripping. In this work, we have devised a mechanically flexible artificial Li_(3)N solid-electrolyte interlayer supported by a dual-layer compactness-tailored carbon nanotube fiber network. The more compact side of the network ensures a full coverage of Li_(3)N, which prevents the reaction between electrolyte and lithium. The other side, with sparsely distributed nanotube fibers, provides mechanical flexibility for the film, and induces three-dimensional lithium deposition along its structure without any dendrite formation. The resulting full cell with NCM811 cathode has a high capacity retention of 95.1% for 160 cycles compared with less than 80% for the control.

关键词： Lithium metal anode Artificial SEI CNT network 3D deposition

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Unraveling Shuttle Effect and Suppression Strategy in Lithium/Sulfur Cells by In Situ/Operando X-ray Absorption Spectroscopic Characterization

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Energy & Environmental Materials 2021年第2期4卷 222-228页

作者： Lujie Jia Jian Wang Shuaiyang Ren Guoxi Ren Xiang Jin Licheng Kao Xuefei Feng Feipeng Yang Qi Wang ludi pan Qingtian Li Yi-sheng Liu Yang Wu Gao Liu Jun Feng Shoushan Fan Yifan Ye Jinghua Guo Yuegang Zhang State Key Laboratory of Low-Dimensional Quantum Physics and Department of Physics Tsinghua UniversityBeijing 100084China Advanced Light Source and Energy Storage and Distributed Resources DivisionLawrence Berkeley National LaboratoryBerkeley CA 94720USA i-Lab Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China CAS Center for Excellence in Superconducting Electronics State Key Laboratory of Functional Materials for InformaticsShanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghai 200050China 不详

The polysulfides shuttle effect represents a great challenge in achieving high capacity and long lifespan of lithium/sulfur(Li/S)cells.A comprehensive understanding of the shuttle-related sulfur speciation and diffusion process is vital for addressing this ***,we employed in situ/operando X-ray absorption spectroscopy(XAS)to trace the migration of polysulfides across the Li/S cells by precisely monitoring the sulfur chemical speciation at the cathodic electrolyte-separator and electrolyte-anode interfaces,respectively,in a real-time *** we adopted a shuttle-suppressing strategy by introducing an electrocatalytic layer of twinborn bismuth sulfide/bismuth oxide nanoclusters in a carbon matrix(BSOC),we found the Li/S cell showed greatly improved sulfur utilization and longer life *** operando S Kedge XAS results revealed that the BSOC modification was bi-functional:trapping polysulfides and catalyzing conversion of sulfur species *** elucidated that the polysulfide trapping-and-catalyzing effect of the BSOC electrocatalytic layer resulted in an effective lithium anode *** results could offer potential stratagem for designing more advanced Li/S cells.

关键词： in situ/operando lithium/sulfur cell shuttle effect sulfur speciation X-ray absorption spectroscopy

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A module based modeling framework for estimating lunar dust deposition due to human activities

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Chinese Journal of Aeronautics 2024年第2期37卷 501-510页

作者： Chunjian pan College of Automation Engineering Shanghai University of Electric PowerShanghai 200090China

Lunar dust is considered to be one of the top challenges for enabling humans to have extended stays on the *** activities such as module landings and launches,walking,rover operation and construction activities will inevitably produce a significant amount of ***,it is important to estimate the potential range and intensity of dust deposition caused by these activities to minimize dust accumulation over time and for maintenance planning and execution.A modular model that correlates the dust deposition distribution with initial mean dust particle velocity,its mean ejected angle and the total amount of ejected mass is developed for an elementary mechanical *** modular model is further employed to form a modeling framework to estimate dust deposition of a trajectory based activity of similar repeated movements such as the landing process of a lander,walking and rover *** model forms a unified modeling framework for different trajectory-based activities and is shown to predict consistent and physically meaningful ranges and intensities of dust deposition provided reliable data to calibrate the model parameters.

关键词： Lunar dust Dust deposition Lunar lander Lunar construction Model calibration

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Analytical Solutions for an Isotropic Elastic Half-Plane with Complete Surface Effects Subjected to a Concentrated/Uniform Surface Load

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Acta Mechanica Solida Sinica 2024年第3期37卷 371-384页

作者： Xia-Hui pan School of Civil Engineering Henan Polytechnic UniversityJiaozuo454003China

Within the context of Gurtin-Murdoch surface elasticity theory,closed-form analytical solutions are derived for an isotropic elastic half-plane subjected to a concentrated/uniform surface *** the effects of residual surface stress and surface elasticity are *** stress function method and Fourier integral transform technique are *** solutions are provided in a compact manner that can easily reduce to special situations that take into account either one surface effect or none at *** results indicate that surface effects generally lower the stress levels and smooth the deformation profiles in the *** elasticity plays a dominant role in the in-plane elastic fields for a tangentially loaded half-plane,while the effect of residual surface stress is fundamentally crucial for the out-of-plane stress and displacement when the half-plane is normally *** the remaining situations,combined effects of surface elasticity and residual surface stress should be *** results for a concentrated surface force serve essentially as fundamental solutions of the Flamant and the half-plane Cerruti problems with surface *** solutions presented in this work may be helpful for understanding the contact behaviors between solids at the nanoscale.

关键词： Surface effects Residual surface stress Surface elasticity Half-plane Analytical solutions

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Aeroengine thrust estimation and embedded verification based on improved temporal convolutional network

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Chinese Journal of Aeronautics 2024年第1期37卷 106-117页

作者： Wanzhi MENG Zhuorui pan Sixin WEN pan QIN Ximing SUN Key Laboratory of Intelligent Control and Optimization for Industrial Equipment of Ministry of Education Dalian University of TechnologyDalian 116024China School of Control Science and Engineering Dalian University of TechnologyDalian 116024China

Thrust estimation is a significant part of aeroengine thrust control *** traditional estimation methods are either low in accuracy or large in *** further improve the estimation effect,a thrust estimator based on Multi-layer Residual Temporal Convolutional Network(M-RTCN)is *** solve the problem of dead Rectified Linear Unit(ReLU),the proposed method uses the Gaussian Error Linear Unit(GELU)activation function instead of ReLU in residual *** the overall architecture of the multi-layer convolutional network is adjusted by using residual connections,so that the network thrust estimation effect and memory consumption are further ***,the comparison with seven other methods shows that the proposed method has the advantages of higher estimation accuracy and faster convergence ***,six neural network models are deployed in the embedded controller of the micro-turbojet *** Hardware-in-the-Loop(HIL)testing results demonstrate the superiority of M-RTCN in terms of estimation accuracy,memory occupation and running ***,an ignition verification is conducted to confirm the expected thrust estimation and real-time performance.

关键词： Thrust estimation Temporal convolutional network Embedded deployment Hardware-in-the-loop testing Ignition verification

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Shape optimisation of basin insulator for DC gas insulated switchgear/gas insulated transmission lines based on artificial bee colony algorithm

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High Voltage 2024年第2期9卷 275-286页

作者： Yi Luo Shiyi Mao Ju Tang Zijun pan Cheng pan State Key Laboratory of Power Grid Environmental Protection School of Electrical Engineering and AutomationWuhan UniversityWuhanChina

The surface charge accumulation on the basin insulator is a particular problem in high-voltage direct current(HVDC)gas insulated switchgears(GIS)and gas insulated trans-mission lines(GIL),which restricts the development and application of extra/ultra high-voltage(EHV/UHV)*** surface charge distribution and anti-flashover performance are closely related to the insulator *** obtain the optimal basin insulator,a shape optimisation model based on artificial bee colony algorithm was established,and the minimisation objective functions based on capacitive(initial)electric field distribution and resistive(steady-state)electric field distribution were respectively *** optimisation results of the two objective functions were calculated,and the electric field and charge distribution on the surface of the insulator before and after optimisation were evaluated and compared using the simulation *** results indicated that the optimisation based on the capacitive electric field can significantly inhibit the surface charge accumulation,and the optimised insulator can significantly reduce the surface normal electric field and make the distribution of the tangential electric field more uniform,and the maximum tangential electric field can be reduced by 10%;the optimisation based on resistive electric field can achieve similar results,but requires more computational *** on the results,the‘anti-charge’basin insulator structure suitable for the DC field was given.

关键词： insulator artificial charge

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New opportunities for ferroelectric deep-UV nonlinear optical crystals

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Science China Materials 2024年第3期67卷 1004-1005页

作者： Miriding Mutailipu Shilie pan Research Center for Crystal Materials Xinjiang Technical Institute of Physics and ChemistryChinese Academy of SciencesUrumqi 830011China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Deep-ultraviolet(deep-UV)light with the wavelength below200 nm is one of the most crucial elements of both laser-driven industrial and scientific applications in recent years[1].DeepUV light has been produced using a variety of techniques,such as gas discharge lamps,synchrotron radiation,excimer lasers,free electron lasers,and nonlinear frequency conversion.

关键词： nonlinear optical ferroelectric

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Time-domain Differential Protection Based on Operating and Restraining Trajectory Indices for Lines Connecting Battery Storage Energy Stations

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Journal of Modern Power Systems and Clean Energy 2024年第4期12卷 1074-1086页

作者： Yingyu Liang Cunyue pan School of Mechanical and Electrical Engineering China University of Mining and Technology(Beijing)BeijingChina

Battery energy storage stations(BESSs)pose sever-al challenges for both phasor-based differential protection and the newly-proposed time-domain differential *** challenges include low sensitivity and even ***,the negative impact of various nonideal conditions,including current transformer(CT)saturation,errors,and outliers,on the security of differential protection remains an important *** by the aforementioned issues,this study ac-counts for the trajectory distribution discrepancy on Cartesian plane under various conditions and proposes a time-domain dif-ferential protection *** this paper,the trajectory formed by operating and restraining current samples is ***,after considering different operating states,the fault severity levels,and nonideal conditions,the variances in trajectory distribution between internal and external faults are extensively *** this basis,the Cartesian plane is divided into operating,uncertainty,and restraining ***-ther,the operating and restraining trajectory indices are meticu-lously designed and a protection criterion based on these indi-ces is formed to accurately separate internal faults from other events,unaffected by CT saturation,errors,and *** exceptional performance of the proposed protection method is extensively validated through PSCAD simulations and a hard-ware-in-the-loop testing *** the dependability,sensitivity,and security,the proposed protection method outper-forms three state-of-the-art differential protection methods.

关键词： Battery energy storage station time-domain differential protection operating trajectory index(OTI) restraining trajectory index(RTI)

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