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An ecofriendly approach for corrosion control of 6061 Al-15%(v)SiC(P)composite and its base alloy

Chinese Journal of Chemical Engineering 2017年第3期25卷 363-372页

作者： Charitha B.P. padmalatha rao Department of chemistry Manipal Institute of TechnologyManipalUdupiKamatakaIndia

Corrosion inhibition characteristics of bio polymer dextran was studied for the corrosion control of 6061 Al-15%_((v)) SiC_((P)) composite and its base alloy in 1 mol·L^(-1) HCl. Standard electrochemical techniques such as potentiodynamic polarization(PDP) measurements and electrochemical impedance spectroscopy(EIS) method were adopted for corrosion rate measurement. Surface morphology was studied by scanning electron microscopy(SEM) and elemental mapping was done by energy dispersive X-ray(EDX) analysis. Suitable mechanism was proposed for corrosion and inhibition process. Results indicated that dextran acts as an excellent anticorrosive agent for the corrosion control of 6061 Al-15%_((v)) SiC_((P)) composite, with maximum inhibition efficiency of 91% for the concentration of 0.4 g·L^(-1) at 303 K. Dextran acted as a mixed type of inhibitor, and got physically adsorbed both on composite and base alloy by obeying Langmuir adsorption isotherm. Dextran is proved to be a green inhibitor with environmental and economic benefits.

关键词： 6061 Al-15%(v) SiC(p) composite Green inhibitor Biopolymer Electrochemical studies SEM–EDX

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Erosion corrosion control of 6061 aluminum alloy in multi-phase jet impingement conditions with eco-friendly green inhibitor

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Chinese Journal of Chemical Engineering 2020年第2期28卷 340-347页

作者： M.Lavanya V.Ramachandra Murthy padmalatha rao Department of Biotechnology Manipal Institute of TechnologyManipal Academy of Higher EducationManipalKarnatakaIndia Department of Chemistry Manipal Institute of TechnologyManipal Academy of Higher EducationManipalKarnatakaIndia

Erosion corrosion performance of 6061 aluminum alloy in simulated sea water slurry was investigated under multi-phase jet impingement conditions. The main objective of the work is to study erosion–corrosion of a material with engineering application and mitigate it using eco-friendly green inhibitor. Experiments were performed with the sand concentration of 0.3% and 0.3 μm size. The effect of temperature and flow rate on the performance of inhibitor was explored. Electrochemical methods were adopted for erosion-corrosion measurements. Experiments revealed that starch could mitigate erosion-corrosion with a maximum reduction efficiency of 58% at temperature of 303 K and flow rate of 4 L·min–1. Inhibition efficiency decreased with increase in flowrate and temperature. EIS spectrum demonstrated that the corrosion process in the presence on inhibitor was both charge transfer and mass transfer controlled. A key role of hydrodynamics in the performance of corrosion inhibitor was confirmed by the present study.

关键词： Erosion-corrosion Green-inhibitor Electrochemical studies Aluminum alloy Simulated sea water

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