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Enhanced lithium storage of mesoporous vanadium dioxide(B) nanorods by reduced graphene oxide support

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Journal of Energy Chemistry 2018年第1期27卷 183-189页

作者： Thummala Jayalakshmi Kottam nagaraju Ganganagappa nagaraju Dept.of Chemistry Siddaganga Institute of Technology(Affiliated to Visvesvaraya Technological UniversityBelgaum) Dept.of Chemistry M.S.Ramaiah Institute of Technology(Affiliated to Visvesvaraya Technological UniversityBelgaum)

A facile synthesis of vanadium oxide with reduced graphene oxide（rGO） is developed and used as cathode material for lithium ion batteries. VO_2（B） nanorods and VO_2（B）-rGO composite were prepared by a hydrothermal method using NaVO_3 precursor and sodium oxalate as a reducing agent. The monoclinic phase and nanorod like morphology of synthesized materials were confirmed by XRD, SEM, and TEM respectively. The electrochemical properties of samples were investigated at 1.5–4.0 V, and 0.1 C rate,and the VO_2（B） nanorods exhibit reversible capacity of about 159 mAh g^（-1）, whereas VO_2（B）-rGO exhibits 274 mAh g^（-1）. The reasonable discharge capacities were obtained at high rates. The enhanced performance in electrical energy storage system reveals the effectiveness of rGO in the composite, as it enhances the conductive electron pathway to overcome the intrinsic limits of single phase VO_2（B）.

关键词： VO2(B) and VO2(B)-rGO compositeNanorodsMesoporousLithium-ion battery

Unlocking hypoglycemia–associated brain microvascular dysfunction:critical insights from proteomic analysis

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Neural Regeneration Research 2025年第6期20卷 1707-1708页

作者： Siva S.V.p.Sakamuri Anil Sakamuri Department of Chemistry Auburn University at MontgomeryMontgomeryALUSA Vascular Biology Center and Department of Medicine Medical College of Georgia at Augusta UniversityAugustaGAUSA

Hypoglycemia-a critical complication linked to worsened brain function in diabetic subjects:Hypoglycemia is characterized by a decline in circulatory glucose levels below sta nda rd physiological *** hypoglycemia,classified as level 1 hypoglycemia,is defined by blood glucose levels below 70 mg/dL and can be effectively addressed through carbohydrate *** hypoglycemia,denoted by blood glucose levels less than 54 mg/dL,poses a life-threatening risk if left *** with type 1 and type 2 diabetes undergoing insulin treatment are particularly susceptible to hypoglycemia due to impaired counterregulatory mechanisms.

关键词： impaired intake critical

Surfactant Assisted Hydrothermal Synthesis of CdSe Nanostructural Materials

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Journal of Materials Science & Technology 2012年第6期28卷 495-499页

作者： Ganganagappa nagaraju Gujjarahalli Thimmanna Chandrappa Department of Chemistry Central College CampusBangalore UniversityBangalore-560001India Laboratory of Molecular Catalysis Institute of ChemistryUFRGSPorto AlegreBrazil

CdSe/CTAB composite nanostructural materials were successfully synthesized at 160-200℃ for 2 days through a facile surfactant （cetyl trimethyl ammonium bromide-CTAB） assisted hydrothermal method us- ing cadmium acetate and sodium selenate as precursor. The obtained products were characterized by X-ray diffraction, energy dispersive X-ray analysis, Fourier transform infrared spectroscopy and thermo gravimetric analysis. Optical properties were studied by photoluminescence and UV-visible spectroscopy and morphology was investigated by scanning electron microscopy.

关键词： Hydrothermal Surfactant Nanostructure CdSe/CTAB composite

Small molecule inhibitor DDQ-treated hippocampal neuronal cells show improved neurite outgrowth and synaptic branching

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Neural Regeneration Research 2025年第9期20卷 2624-2632页

作者： Jangampalli Adi pradeepkiran priyanka Rawat Arubala p.Reddy Erika Orlov pHemachandra Reddy Department of Internal Medicine Texas Tech University Health Sciences CenterLubbockTXUSA Department of Nutritional Sciences College of Human SciencesTexas Tech UniversityLubbockTXUSA Department of pharmacology&Neuroscience Texas Tech University Health Sciences CenterLubbockTXUSA Department of Neurology Texas Tech University Health Sciences CenterLubbockTXUSA Department of Speech Language and Hearing SciencesTexas Tech University Health Sciences CenterLubbockTXUSA Department of public Health Texas Tech University Health Sciences CenterLubbockTXUSA

The process of neurite outgrowth and branching is a crucial aspect of neuronal development and *** and dendrites,sometimes referred to as neurites,are extensions of a neuron's cellular body that are used to start *** we explored the effects of diethyl(3,4-dihydroxyphenethylamino)(quinolin-4-yl)methylphosphonate(DDQ)on neurite developmental features in HT22 neuronal *** this work,we examined the protective effects of DDQ on neuronal processes and synaptic outgrowth in differentiated HT22cells expressing mutant Tau(mTau)*** investigate DDQ chara cteristics,cell viability,biochemical,molecular,western blotting,and immunocytochemistry were *** outgrowth is evaluated through the segmentation and measurement of neural *** neural processes can be seen and measured with a fluorescence microscope by manually tracing and measuring the length of the neurite *** neuronal processes can be observed and quantified with a fluorescent microscope by manually tracing and measuring the length of the neuronal ***-treated mTau-HT22 cells(HT22 cells transfected with cDNA mutant Tau)were seen to display increased levels of synaptophysin,MAp-2,andβ-***,we confirmed and noted reduced levels of both total and p-Tau,as well as elevated levels of microtubule-associated protein 2,β-tubulin,synaptophysin,vesicular acetylcholine transporter,and the mitochondrial biogenesis protein-pe roxisome prolife rator-activated receptor-gamma coactivator-1α.In mTa u-expressed HT22 neurons,we observed DDQ enhanced the neurite characteristics and improved neurite development through increased synaptic *** findings conclude that mTa u-HT22(Alzheimer's disease)cells treated with DDQ have functional neurite developmental chara *** key finding is that,in mTa u-HT22 cells,DDQ preserves neuronal structure and may even enhance nerve development function with mTa u inhibition.

关键词： diethyl(3 4-dihydroxyphenethylamino)(quinolin-4-yl)methylphosphonate(DDQ) hippocampal neuronal cells HT22 neurite outgrowth neuronal development small molecule

Dynamic Behavior-Based Churn Forecasts in the Insurance Sector

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Computers, Materials & Continua 2023年第4期75卷 977-997页

作者： nagaraju Jajam Nagendra panini Challa School of Computer Science and Engineering(SCOpE) VIT-AP UniversityAmaravati522237India

In the insurance sector, a massive volume of data is being generatedon a daily basis due to a vast client base. Decision makers and businessanalysts emphasized that attaining new customers is costlier than retainingexisting ones. The success of retention initiatives is determined not only bythe accuracy of forecasting churners but also by the timing of the *** works on churn forecast presented models for anticipating churnquarterly or monthly with an emphasis on customers’ static behavior. Thispaper’s objective is to calculate daily churn based on dynamic variations inclient behavior. Training excellent models to further identify potential churningcustomers helps insurance companies make decisions to retain customerswhile also identifying areas for improvement. Thus, it is possible to identifyand analyse clients who are likely to churn, allowing for a reduction in thecost of support and maintenance. Binary Golden Eagle Optimizer (BGEO)is used to select optimal features from the datasets in a preprocessing *** a result, this research characterized the customer’s daily behavior usingvarious models such as RFM (Recency, Frequency, Monetary), MultivariateTime Series (MTS), Statistics-based Model (SM), Survival analysis (SA),Deep learning (DL) based methodologies such as Recurrent Neural Network(RNN), Long Short-Term Memory (LSTM), Gated Recurrent Unit (GRU),and Customized Extreme Learning Machine (CELM) are framed the problemof daily forecasting using this description. It can be concluded that all modelsproduced better overall outcomes with only slight variations in performancemeasures. The proposed CELM outperforms all other models in terms ofaccuracy (96.4).

关键词： Customer churn customized extreme learning machine deep learning survival analysis RFM MTS SM BGEO

AMS studies on a 450 km long 2216 Ma dyke from Dharwar craton, India:Implications to magma flow

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Geoscience Frontiers 2019年第5期10卷 1931-1939页

作者： E. nagaraju V. parashuramulu paleomagnetism Division CSIR-National Geophysical Research InstituteUppal RoadHyderabad-500007India TSMS Jr. College BaswapurPulkalSangareddy DistrictTelanganaIndia

Anisotropy of magnetic susceptibility (AMS) studies were carried out on a precisely dated (2216.0 ± 0.9 Ma),450 km long NeS striking dyke in the Dharwar Craton,to determine the magma flow direction along the dyke *** order to use the imbrication of the magnetic foliation,forty eight samples were collected from 13 locations along the length of the *** studies show that AMS fabric is dominated by medium grained interstitial Ti-poor multidomain *** corrected anisotropy degree (pj) of the samples was found to be low to moderate,between 1.007 and 1.072,which indicates primary magnetic *** magnetic ellipsoid is either triaxial,prolate or oblate and clearly defines normal,intermediate and inverse magnetic fabrics related to magma flow during the dyke *** maximum susceptibility axes (Kmax) of the AMS tensor of the dyke is predominantly inclined at low angles (pth along the NeS profile,indicating sub-horizontal flow even at mid crustal levels which could probably be governed by location of the focal region of the magma source (mantle plume?),flow dynamics together with the compressive stresses exerted by the overlying crust.

关键词： Anisotropy of magnetic susceptibility Dharwar craton Dyke swarms

Trusted Certified Auditor Using Cryptography for Secure Data Outsourcing and privacy preservation in Fog-Enabled VANETs

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Computers, Materials & Continua 2024年第5期79卷 3089-3110页

作者： nagaraju pacharla K.Srinivasa Reddy School of Computer Science and Engineering VIT-AP UniversityAmaravatiAndhra Pradesh522237India

With the recent technological developments,massive vehicular ad hoc networks(VANETs)have been established,enabling numerous vehicles and their respective Road Side Unit(RSU)components to communicate with *** best way to enhance traffic flow for vehicles and traffic management departments is to share thedata they *** needs to be more protection for the VANET *** effective and safe methodof outsourcing is suggested,which reduces computation costs by achieving data security using a homomorphicmapping based on the conjugate operation of *** research proposes a VANET-based data outsourcingsystem to fix the *** keep data outsourcing secure,the suggested model takes cryptography models *** will keep the generated keys for the purpose of vehicle *** controlling and overseeingthe outsourced data while preserving privacy,the suggested approach considers the Trusted Certified Auditor(TCA).Using the secret key,TCA can identify the genuine identity of VANETs when harmful messages *** proposed model develops a TCA-based unique static vehicle labeling system using cryptography(TCA-USVLC)for secure data outsourcing and privacy preservation in *** proposed model calculatesthe trust of vehicles in 16 ms for an average of 180 vehicles and achieves 98.6%accuracy for data encryption toprovide *** proposedmodel achieved 98.5%accuracy in data outsourcing and 98.6%accuracy in privacypreservation in fog-enabled *** curve cryptography models can be applied in the future for betterencryption and decryption rates with lightweight cryptography operations.

关键词： Vehicular ad-hoc networks data outsourcing privacy preservation cryptography keys trusted certified auditors data security

Adding new dimension to non-directed C（sp3）–H functionalizations

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Science China Chemistry 2025年

作者： Konstantin p.Bryliakov Laboratory of Selective Oxidation Catalysis N.D.Zelinsky Institute of Organic Chemistry RAS

Aliphatic C–H groups are among the most abundant yet least reactive functional groups in organic molecules. Nature has evolved metalloenzymes such as those of the cytochrome p450 superfamily that efficiently activate individual tertiary（3） and secondary （2） C（sp3）–H bonds in complex molecules with the highest level of regio-and stereoselectivity [1], thus encouraging studies aimed at engineering artificial metalloenzymes for synthetic applications [2].

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Catalytic activity of manganese oxide supported on alumina in the synthesis of quinoxalines

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Frontiers of Chemical Science and Engineering 2013年第4期7卷 415-421页

作者： Rekha M. Kathyayini H nagaraju N Catalysis Research Laboratory St Joseph's College Post Graduate and Research Centre Bangalore 560027 India Centre for Emerging Technologies Global Campus Jain University Bangalore 562112 India

Two catalysts, alumina and manganese oxide supported on alumina, have been prepared by calcination and precipitation-impregnation methods, respectively. The catalysts are characterised by the following techniques： Brunner-Emmett-Teller-N2 adsorption-desorption for sur- face area, temperature programmed desorption of NH3 and n-butyl amine back titration methods for surface acidity, powder X-ray diffraction for textural properties, and Fourier transform infrared spectroscopy for the anionic radicals. The catalytic activity has been determined under heterogeneous conditions in the condensation reaction between o-phenylenediamine and benzil. The product purity is checked by thin-layer chromatography and melting point. The products are also analysed by LC-MS and 1H-NMR techniques. The yields of the products have been found to be good and catalysts exhibited excellent recyclability. The effect of changing the reaction para- meters such as temperature, reaction time, amount of the catalyst, nature of solvent and molar ratio of reactants on the yield of the product has been studied. The surface acidity of the catalysts plays an important role in activating the reaction.

关键词： alumina manganese oxide deposited onalumina quinoxaline synthesis