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福建紫金山矿田悦洋银多金属矿床银的赋存状态和沉淀机制

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岩石学报 2024年第3期40卷 987-1002页

作者：刘兰海陈静周涛发孙艺 WHITE noel c 合肥工业大学资源与环境工程学院合肥工业大学矿床成因与勘查技术研究中心(ODEC)合肥230009 安徽省矿产资源与矿山环境工程技术研究中心合肥230009 centre of Excellence in Ore Deposits(cODES) University of TasmaniaHobart 7001

浅成低温热液矿床是世界上银矿的重要矿床类型,伴生有金铜铅锌等多种金属。银的赋存状态研究可以为矿床资源禀赋、选冶成本以及经济价值的综合评价提供重要的依据。近年来,矿物自动定量分析系统越来越多地应用到贵金属的赋存状态研究中... 详细信息

浅成低温热液矿床是世界上银矿的重要矿床类型,伴生有金铜铅锌等多种金属。银的赋存状态研究可以为矿床资源禀赋、选冶成本以及经济价值的综合评价提供重要的依据。近年来,矿物自动定量分析系统越来越多地应用到贵金属的赋存状态研究中,相比传统方法而言其能提供精确定量的矿物学信息。悦洋银多金属矿床位于福建省紫金山矿田,是典型的浅成低温热液矿床,是研究银赋存状态的理想选区。通过野外地质调查研究发现,矿体主要受控于岩性边界和断裂构造,主要矿石类型为热液角砾岩型和石英脉型。成矿作用可以分为石英-黄铁矿、石英-黄铁矿-黄铜矿、石英-银多金属、石英-碳酸盐等四个阶段,其中银在石英-银多金属阶段沉淀,可以进一步划分为石英伊利石硫化物亚阶段和石英冰长石硫化物亚阶段。本文在野外地质调查的基础上,针对不同的矿石类型使用TIMA(TEScAN Integrated Mineral Analyzer)自动矿物分析系统,结合显微镜下观察、扫描电镜和电子探针分析手段,对银的赋存形式和分布情况进行了定量化研究,根据矿物共生组合对银沉淀机制及成矿过程进行了探讨。研究结果显示,悦洋矿床中的银90%以上以独立矿物的形式存在,主要是硫化银和自然银,且粒径大多在10~50μm之间;少部分银以次显微包裹体形式存在于黄铜矿中,或以显微包裹体和类质同相形式存在于黄铁矿和闪锌矿中。成矿热液中银主要以硫氢络合物形式运移,主成矿期大量的冰长石与银矿物共生表明沸腾作用是主要的沉淀机制。

关键词：银的赋存状态矿物定量分析银的沉淀机制浅成低温热液矿床紫金山矿田

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Overview on signal transduction cascades regulation roles of garlic and its bioactive constituents

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Food Science and Human Wellness 2024年第5期13卷 2353-2362页

作者： Ammad Ahmad Farooqi Iqra Mobeen Rukset Attar Khalida I.noel Baojun Xu William c.cho Institute of Biomedical and Genetic Engineering(IBGE) Islamabad 44000Pakistan Khursheed Rasheed Hospital Lahore Lahore 53720Pakistan Department of Obstetrics and Gynecology Yeditepe UniversityAtaşehir 34755Turkey Human Anatomy Department College of MedicineAl-Mustansiriyah UniversityBaghdad 10036Iraq Food Science and Technology Program Department of Life SciencesBNU-HKBU United International CollegeZhuhai 519087China Department of clinical Oncology Queen Elizabeth HospitalHong Kong G514TFChina

High-throughput technologies in combination with modern exciting advancements in mass spectrometry-based proteomics and data analysis pipelines have empowered comprehensive characterization of disease phenotypes and their mechanistic regulation by dietary agents and bioactive molecules at unprecedented dimensionality and ***-ordinary breakthroughs in the field of nutrigenomics have leveraged our understanding altogether to a new level of *** researchers have extensively analyzed health promoting and pharmacologically significant properties of garlic(Allium sativum).Importantly,garlic and its biologically active chemicals targeted oncogenic signaling *** this mini-review we have attempted to summarize how garlic and its bioactive constituents regulated signal transduction cascades in cell culture studies and tumor-bearing mice.

关键词： cancer Nutrigenomics Signaling Apoptosis Allium sativum

江南造山带东段地区三堡铅锌矿床花岗闪长斑岩的形成年代、地球化学特征及成矿指示

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大地构造与成矿学 2024年第4期48卷 879-898页

作者：侯舒雅张达玉张飞雷行行胡梦祥翁望飞 noel c White 合肥工业大学资源与环境工程学院安徽合肥230009 安徽省地质矿产勘查局332地质队安徽黄山245000

三堡铅锌矿床位于江南古陆北部,其成矿作用与花岗闪长斑岩密切相关。本文在地质特征和岩相学认识基础上,对与三堡铅锌矿床相关的花岗闪长斑岩开展了锆石LA-IcP-MS U-Pb同位素年代学、全岩地球化学和Sr-Nd同位素分析。结果显示,三堡花岗... 详细信息

三堡铅锌矿床位于江南古陆北部,其成矿作用与花岗闪长斑岩密切相关。本文在地质特征和岩相学认识基础上,对与三堡铅锌矿床相关的花岗闪长斑岩开展了锆石LA-IcP-MS U-Pb同位素年代学、全岩地球化学和Sr-Nd同位素分析。结果显示,三堡花岗闪长斑岩锆石U-Pb年龄为154.8±1.8 Ma,为晚侏罗世。三堡花岗闪长斑岩SiO_(2)含量为63.75%~67.47%,Na_(2)O+K_(2)O为3.92%~7.34%,为高钾钙碱性、准铝质‒弱过铝质的I型花岗岩;且样品富集轻稀土元素(LREE/HREE=10.50~11.29)、显示弱负Eu异常(δEu=0.68~0.77),富集Rb、Th、U、K等大离子亲石元素,亏损P、Ti、Yb等高场强元素。花岗闪长斑岩(^(87)Sr/^(86)Sr)i值为0.71028~0.71320,ε_(Nd)(t)值在-6.57~-5.55之间。岩石地球化学特征显示,三堡花岗闪长斑岩熔体来自壳幔混合源区,上升过程中经历了显著的结晶分异作用。结合区域资料对比显示,三堡铅锌矿床为江南造山带东段地区燕山期早阶段(177~153 Ma)铜铅锌成矿作用的重要组成部分,该花岗闪长斑岩所呈现的中低结晶温度、较低分异程度、较高氧逸度与水含量是该区中酸性岩浆岩的成矿专属性指标。

关键词：花岗闪长斑岩成岩年代岩石成因成矿专属性江南造山带东段地区

cD4^(+)T cells produce IFN-I to license cDc1s for induction of cytotoxic T-cell activity in human tumors

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cellular & Molecular Immunology 2024年第4期21卷 374-392页

作者： Xin Lei Daniël c.de Groot Marij J.P.Welters Tom de Wit Ellen Schrama Hans van Eenennaam Saskia J.Santegoets Timo Oosenbrug Annemarthe van der Veen Joris L.Vos charlotte L.Zuur noel F.c.c.de Miranda Heinz Jacobs Sjoerd H.van der Burg Jannie Borst Yanling Xiao Department of Immunology Leiden University Medical CenterLeidenThe Netherlands Oncode Institute Leiden University Medical CenterLeidenThe Netherlands Department of Tumor Biology and Immunology The Netherlands Cancer InstituteAmsterdamThe Netherlands Department of Medical Oncology Oncode InstituteLeiden University Medical CenterLeidenThe Netherlands IMMIOS B.V. OssThe Netherlands Division of Medical Oncology The Netherlands Cancer InstituteAmsterdamThe Netherlands Department of Otorhinolaryngology Leiden University Medical center LeidenThe Netherlands Department of Pathology Leiden University Medical CenterLeidenThe Netherlands

cD4^(+)T cells can"help"or"license" conventional type 1 dendritic cells(cDc1s)to induce cD8^(+)cytotoxic T lymphocyte(cTL)anticancer responses,as proven in mouse *** recently identified cDc1s with a transcriptomic imprint of cD4^(+)T-cell help,specifically in T-cell-infiltrated human cancers,and these cells were associated with a good prognosis and response to PD-1-targeting ***,we delineate the mechanism of cDc1 licensing by cD4^(+)T cells in *** cD4^(+)T cells produce IFNβvia the STING pathway,which promotes MHc-I antigen(cross-)presentation by cDc1s and thereby improves their ability to induce cTL anticancer *** cooperation with cD40 ligand(L),IFNβalso optimizes the costimulatory and other functions of cDc1s required for cTL response ***-I-producing cD4^(+)T cells are present in diverse T-cell-infiltrated cancers and likely deliver“help”signals to cTLs locally,according to their transcriptomic profile and colocalization with“helped/licensed”cDcs and tumor-reactive cD8^(+)T *** agreement with this scenario,the presence of IFN-I-producing cD4^(+)T cells in the TME is associated with overall survival and the response to PD-1 checkpoint blockade in cancer patients.

关键词： cD4^(+)T-cell help cDc1 licensing IFN-I signaling cD40 costimulation (cross-)presentation cTL priming Tumor control

Statin, aspirin and metformin use and risk of hepatocellular carcinoma related outcomes following liver transplantation: A retrospective study

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World Journal of Transplantation 2024年第3期14卷 120-131页

作者： William chung Kevin Wong noel Ravindranayagam Lauren Tang Josephine Grace Darren Wong Danny con Marie Sinclair Avik Majumdar Numan Kutaiba Samuel Hui Paul Gow Vijayaragavan Muralidharan Alexander Dobrovic Adam Testro Department of Gastroenterology Austin HealthHeidelberg 3084VictoriaAustralia Victorian Liver Transplant Unit Austin HealthHeidelberg 3084VictoriaAustralia Department of Radiology Austin HealthHeidelberg 3084VictoriaAustralia Department of Gastroenterology Monash HealthClayton 3168VictoriaAustralia Department of Surgery University of MelbourneAustin HealthHeidelberg 3048VictoriaAustralia Department of Surgery Beacon LaboratoryAustin PrecinctThe University of MelbourneAustin HospitalHeidelberg 3048VictoriaAustralia

BAcKGROUND Liver transplantation(LT)is a potentially curative therapy for patients with hepatocellular carcinoma(Hcc).Hcc-recurrence following LT is associated with reduced *** is increasing interest in chemoprophylaxis to improve Hcc-related outcomes *** To investigate whether there is any benefit for the use of drugs with proposed chemoprophylactic properties against Hcc,and patient outcomes following *** This was a retrospective study of adult patients who received Deceased Donor LT for Hcc from 2005-2022,from a single Australian *** use was defined as statin,aspirin or metformin therapy for≥29 days,within 24 months post-LT.A cox proportional-hazards model with time-dependent covariates was used for survival *** measures were the composite-endpoint of Hcc-recurrence and all-cause mortality,Hcc-recurrence and Hcc-related *** analysis was performed to account for immortality time bias and statin *** Three hundred and five patients were included in this study,with 253(82.95%)males with a median age of 58.90 *** of liver disease were 150(49.18%)hepatitis c,73(23.93%)hepatitis B(HBV)and 33(10.82%)non-alcoholic fatty liver disease(NAFLD).56(18.36%)took statins,51(16.72%)aspirin and 50(16.39%)*** a median follow-up time of 59.90 months,34(11.15%)developed Hcc-recurrence,48(15.74%)died,17(5.57%)from Hcc-related ***,aspirin or metformin use was not associated with statistically significant differences in the composite endpoint of Hcc-recurrence or all-cause mortality[hazard ratio(HR):1.16,95%cI:0.58-2.30;HR:1.21,95%cI:0.28-5.27;HR:0.61,95%cI:0.27-1.36],Hcc-recurrence(HR:0.52,95%cI:0.20-1.35;HR:0.51,95%cI:0.14-1.93;HR 1.00,95%cI:0.37-2.72),or Hcc-related mortality(HR:0.32,95%cI:0.033-3.09;HR:0.71,95%cI:0.14-3.73;HR:1.57,95%cI:0.61-4.04)*** dosing was not associated with statist-ically significant differences in Hcc-related ***

关键词： Liver transplantation Hepatocellular carcinoma Transplant oncology Statins HMG-co-A reductase Aspirin Metformin Mammalian target of rapamycin

Synthesis of Ag and cd nanoparticles by nanosecond-pulsed discharge in liquid nitrogen

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Frontiers of chemical Science and Engineering 2019年第2期13卷 360-368页

作者： Mahmoud Trad Alexandre Nominé Natalie Tarasenka Jaafar Ghanbaja cédric noel Malek Tabbal Thierry Belmonte Universite de Lorraine CNRSIJLF-54000 NancyFrance B.I. Stepanov Institute of Physics National Academy of Sciences of BelarusMinskBelarus Department of Physics American University of BeirutBeirutLebanon

The synthesis of cdO, Ag2O (5nm) and Ag (~20~30 nm) nano-objects is achieved simultaneously by nanosecond-pulsed discharges in liquid nitrogen between one cadmium electrode and one silver electrode. Oxidation occurs when liquid nitrogen is fully evaporated and nanoparticles are in contact with the air. No alloy is formed, whatever the conditions, even though both elements are present simultaneously, as showed by timeresolved optical emission spectroscopy. This lack of reactivity between elements is attributed to the high pressure within the discharge that keeps each metallic vapor around the electrode it comes from. Each element exhibits a specific behavior. cubic cd particles, formed at 4 kV, get elongated with filamentary tips when the applied voltage reaches 7 and 10 kV. cd wires are formed by assembly in liquid nitrogen of cd nanoparticles driven by dipole assembly, and not by dielectrophoresis. On the contrary, silver spherical particles get assembled into 2D dendritic structures. The anisotropic growth of these structures is assumed to be due to the existence of pressure gradients.

关键词： spark discharges submerged discharges timeresolved optical emission spectroscopy liquid nitrogen

A quantum cascade laser infrared spectrometer for cO_2 stable isotope analysis：Field implementation at a hydrocarbon contaminated site under bio-remediation

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Journal of Environmental Sciences 2016年第2期28卷 60-74页

作者： christophe Guimbaud cécile noel Michel chartier Valéry catoire Michaela Blessing Jean christophe Gourry claude Robert Laboratoire de Physique et de chimie de l'Environnement et de l'Espace (LPc2E) CNRS et Universite d'Orleans (UMR 7328)45071 Orleans cedex 2 France Bureau de Recherches Geologiques et Minieres (BRGM) 45060 Orleans cedex 2 France

Real-time methods to monitor stable isotope ratios of cO_2 are needed to identify biogeochemical origins of cO_2 emissions from the soil–air interface. An isotope ratio infra-red spectrometer（IRIS） has been developed to measure cO_2 mixing ratio with δ~13c isotopic signature, in addition to mixing ratios of other greenhouse gases（cH_4, N2_O）. The original aspects of the instrument as well as its precision and accuracy for the determination of the isotopic signature δ~13c of cO_2 are discussed. A first application to biodegradation of hydrocarbons is presented, tested on a hydrocarbon contaminated site under aerobic bio-treatment. cO_2 flux measurements using closed chamber method is combined with the determination of the isotopic signature δ~13c of the cO_2 emission to propose a non-intrusive method to monitor in situ biodegradation of hydrocarbons. In the contaminated area, high cO_2 emissions have been measured with an isotopic signature δ~13c suggesting that cO_2 comes from petroleum hydrocarbon *** first field implementation shows that rapid and accurate measurement of isotopic signature of cO_2 emissions is particularly useful in assessing the contribution of contaminant degradation to the measured cO_2 efflux and is promising as a monitoring tool for aerobic bio-treatment.

关键词： Isotope ratio infrared spectrometry Isotopic signature δ^(13)c of cO_2 Biodegradation monitoring Hydrocarbons BTEX

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长江中下游成矿带成矿规律和成矿模式

岩石学报 2017年第11期33卷 3353-3372页

作者：周涛发范裕王世伟 noel c WHITE 合肥工业大学资源与环境工程学院合肥230009 合肥工业大学矿床成因与勘查技术研究中心合肥230009

长江中下游成矿带作为中国东部重要的成矿带之一,成矿地质条件、成矿规律和成矿模式的相关研究已经十分深入,形成了一系列公认的理论研究成果,本文重点论述了成矿带成矿地质条件和成矿规律方面研究的新进展,并在此基础上构筑了成矿带的... 详细信息

长江中下游成矿带作为中国东部重要的成矿带之一,成矿地质条件、成矿规律和成矿模式的相关研究已经十分深入,形成了一系列公认的理论研究成果,本文重点论述了成矿带成矿地质条件和成矿规律方面研究的新进展,并在此基础上构筑了成矿带的成矿模式。本文主要开展了以下总结工作:(1)将成矿带的构造要素突破以往按构造单元分解的做法,确立跨构造单元的"复合构造系统",结合成矿带成岩成矿作用特点,重新确定了长江中下游成矿带的范围,并对成矿亚带进行了重新划分;(2)收集汇总了长江中下游成矿带近年来国内外学者最新的成岩成矿年龄数据,总结了矿床时空分布规律;(3)从地质,地球物理和地球化学等方面,总结归纳了沿基底结合带复活的网状断裂系统,阐明了成矿带的控矿构造格架,分析了长江中下游成矿带的成因规律;(4)补充和完善了断隆区和断凹区的成矿模式,并初步构筑了长江中下游成矿带综合成矿模式。提出长江中下游成矿带内主体成岩成矿作用总体上分为走滑挤压阶段(146~135Ma)、走滑引张阶段(135~126Ma)和拉张伸展阶段(126~123Ma)等三个阶段,古太平洋板块作用导致的壳幔过程,引发含元古代弧岩浆岩源区活化和中生代的构造活化("双活化")是长江中下游成矿带形成的主要机制。

关键词：长江中下游成矿带成矿规律成矿模式成矿背景

Genesis of Mafic Microgranular Enclaves in the Shaocunwu Granodiorite,Southern china,and their Implications:Evidence from Zircon and Whole-rock Geochemistry

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Acta Geologica Sinica(English Edition) 2021年第3期95卷 761-779页

作者： JIANG Hua ZHANG Dayu WANG Shiwei FU Xiang YE Longxiang noel c.WHITE ZHOU Taofa School of Resources and Environmental Engineering Hefei University of TechnologyHefei 230009China Ore Deposit and Exploration centre Hefei University of TechnologyHefei 230009China Anhui Province Engineering Research center for Mineral Resources and Mine Environments Hefei 230009China

Magmatic microgranular enclaves(MMEs)are widely developed in the Shaocunwu granodiorite at the northeast margin of the eastern Jiangnan orogenic *** geology showed that the MMEs occur as irregular ellipsoids near the edge of the intrusion,and consist of diorite,dominantly composed of amphibole,biotite,and plagioclase grains,with minor acicular *** U-Pb dating showed the ages of the host granodiorites and MMEs are 145.9±1.1 Ma and 145.6±2.5 Ma,respectively,indicating both originated during coeval late Jurassic ***-rock geochemical results show that the host granodiorite and MMEs have similar rare earth and trace element partition curves in spider grams,and similar 87Sr/86Sr,and 147Nd/144Nd isotope ratios,and their zircon 177Hf/176Hf isotopic ratios are *** studies indicate that both the host granodiorite and MMEs formed by mixing of coeval *** Ti thermometers and oxygen fugacity of the host granodiorite and the MMEs show high oxygen fugacity,similar to that of W-cu(Mo)mineralized granitoids in the eastern Jiangnan orogenic belt.A similar magma mixing process was probably one of the mechanisms that generated the W-cu(Mo)fertile melts.

关键词： MME zircon U-Pb dating Sr-Nd-Hf isotope magma mixing Shaocunwu granodiorite South Anhui