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Unveiling the Optimal Interfacial Synergy of Plasma-Modulated Trimetallic Mn-Ni-Co Phosphides:Tailoring Deposition Ratio for Complementary Water Splitting

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Energy & Environmental Materials 2023年第2期6卷 129-141页

作者： kholoud E.Salem Amina A.Saleh Ghada E.khedr Basamat S.Shaheen nageh k.allam Energy Materials Laboratory(EML) School of Sciences and EngineeringThe American University in CairoNew Cairo 11835Egypt

Designing highly active,durable,and nonprecious metal-based bifunctional electrocatalysts for overall water electrolysis is of urgent scientific importance to realize the sustainable hydrogen production,which remains a grand ***,an innovative approach is demonstrated to synthesize flower-like 3D homogenous trimetallic Mn,Ni,Co phosphide catalysts directly on nickel foam via electrodeposition followed by plasma *** electrochemical activity of the catalysts with varying Mn:Ni:Co ratios is assessed to identify the optimal composition,demonstrating that the equimolar trimetallic phosphide yields an outstanding HER catalytic performance with a current density of 10 mA cm^(-2) at an ultra-low overpotential of~14 mV,outperforming the best reported *** is asserted by the DFT calculations,revealing strong interaction of the metals and the P atom,resulting in enhanced water activation and optimized G_(H)^(*)values for the HER ***,this optimal composition appreciably catalyzes the OER by exposing more intrinsic active species in-situ formed on the catalyst surface during the ***,the Mn_(1)-Ni_(1)-Co_(1)-P-(O)/NF catalyst exhibits a decreased overpotential of~289 mV at 10 mA cm^(-2).More importantly,the electrocatalyst sustains perfect durability up to 48 h at a current density of 10 mA cm^(-2) and continued 5000 cycling stability for both HER and ***,the assembled MNC-P/NF||MNC-P/NF full water electrolyzer system attains an extremely low cell voltage of 1.48 V at 10 mA cm^(-2).Significantly,the robust stability of the overall system results in a remarkable current retention of~96%after a continuous 50-h ***,this study provides a facile design and a scalable construction of superb bifunctional ternary MNC-phosphide electrocatalysts for efficient electrochemical energy production systems.

关键词： DFT overall water splitting oxygen evolution reaction(OER)/hydrogen evolution reaction(HER) plasma ternary metallic phosphides(MnNiCo)

Prediction of permanent pacemaker implantation after transcatheter aortic valve replacement:The role of machine learning

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World Journal of Cardiology 2023年第3期15卷 95-105页

作者： Pradyumna Agasthi Hasan Ashraf Sai Harika Pujari Marlene Girardo Andrew Tseng Farouk Mookadam Nithin Venepally Matthew R Buras Bishoy Abraham Banveet k khetarpal Mohamed allam Siva k Mulpuru MD Mackram F Eleid kevin L Greason Nirat Beohar John Sweeney David Fortuin David R Jr Holmes Reza Arsanjani Department of Cardiology Mayo ClinicPhoenixAZ 85054United States Department of Internal Medicine The Brooklyn Hospital CenterBrooklynNY 11201United States Department of Biostatistics Mayo ClinicPhoenixAZ 85054United States Department of Cardiovascular Diseases Mayo ClinicRochesterMN 55905United States Department of Statistics Mayo ClinicPhoenixAZ 85054United States Department of Cardiovascular Surgery Mayo ClinicRochesterMN 55905United States Mount Sinai Medical Center Columbia UniversityMiami BeachFL 33138United States

BACkGROUND Atrioventricular block requiring permanent pacemaker(PPM)implantation is an important complication of transcatheter aortic valve replacement(TAVR).Application of machine learning could potentially be used to predict preprocedural risk for *** To apply machine learning to be used to predict pre-procedural risk for *** A retrospective study of 1200 patients who underwent TAVR(January 2014-December 2017)was performed.964 patients without prior PPM were included for a 30-d analysis and 657 patients without PPM requirement through 30 d were included for a 1-year *** the exclusion of variables with near-zero variance or≥50%missing data,167 variables were included in the random forest gradient boosting algorithm(GBM)optimized using 5-fold cross-validations repeated 10 *** receiver operator curve(ROC)for the GBM model and PPM risk score models were calculated to predict the risk of PPM at 30 d and 1 *** Of 964 patients included in the 30-d analysis without prior PPM,19.6%required PPM *** mean age of patients was 80.9±8.7 years.42.1%were *** 657 patients included in the 1-year analysis,the mean age of the patients was 80.7±*** those,42.6%of patients were female and 26.7%required PPM at 1-year *** area under ROC to predict 30-d and 1-year risk of PPM for the GBM model(0.66 and 0.72)was superior to that of the PPM risk score(0.55 and 0.54)with a P valuek of PPM post-TAVR.

关键词： Transcatheter aortic valve replacement Permanent pacemaker implantation Machine learning

Optimal Allocation of a Hybrid Wind Energy-Fuel Cell System Using Different Optimization Techniques in the Egyptian Distribution Network

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Energy and Power Engineering 2021年第1期13卷 17-40页

作者： Adel A. Abou El-Ela Sohir M. allam Nermine k. Shehata Department of Electrical Engineering Faculty of Engineering Menoufia University Shebin El-Kom Egypt

This paper presents an optimal proposed allocating procedure for hybrid wind energy combined with proton exchange membrane fuel cell (WE/PEMFC) system to improve the operation performance of the electrical distribution system (EDS). Egypt has an excellent wind regime with wind speeds of about 10 m/s at many areas. The disadvantage of wind energy is its seasonal variations. So, if wind power is to supply a significant portion of the demand, either backup power or electrical energy storage (EES) system is needed to ensure that loads will be supplied in reliable way. So, the hybrid WE/PEMFC system is designed to completely supply a part of the Egyptian distribution system, in attempt to isolate it from the grid. However, the optimal allocation of the hybrid units is obtained, in order to enhance their benefits in the distribution networks. The critical buses that are necessary to install the hybrid WE/ PEMFC system, are chosen using sensitivity analysis. Then, the binary Crow search algorithm (BCSA), discrete Jaya algorithm (DJA) and binary particle swarm optimization (BPSO) techniques are proposed to determine the optimal operation of power systems using single and multi-objective functions (SOF/MOF). Then, the results of the three optimization techniques are compared with each other. Three sensitivity factors are employed in this paper, which are voltage sensitivity factor (VSF), active losses sensitivity factor (ALSF) and reactive losses sensitivity factor (RLSF). The effects of the sensitivity factors (SFs) on the SOF/MOF are studied. The improvement of voltage profile and minimizing active and reactive power losses of the EDS are considered as objective functions. Backward/forward sweep (BFS) method is used for the load flow calculations. The system load demand is predicted up to year 2022 for Mersi-Matrouh City as a part of Egyptian distribution network, and the design of the hybrid WE/PEMFC system is applied. The PEMFC system is designed considering simplified m

关键词： Wind Energy System Proton Exchange Membrane Fuel Cell Binary Crow Search Algorithm Discrete Jaya Algorithm Binary Particle Swarm Optimization Technique

Normal liver stiffness: a study in living donors with normal liver histology

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World Journal of Hepatology 2015年第8期7卷 1149-1153页

作者： Ayman Alsebaey Naglaa allam khalid Alswat Imam Waked Hepatology Department National Liver Institute Menoufeya University Liver center King Saud University

AIM: To define the normal range of liver stiffness(LS) values using transient elastography in living-related liver transplantation candidate donors with normal liver histology. METHODS: LS was measured using Fibroscan in 50(16 women, 34 men) healthy potential donors(mean age 28.4 ± 5.9 years) who were being evaluated for liver donation for their relatives at the National Liver Institute, Menoufeya University, Egypt. All potential donors had normal liver tests and were negative for hepatitis B or C virus infection. Abdominal ultrasounds showed normal findings. None of the subjects had diabetes, hypertension, renal impairment, heart disease, or body mass index > 30 kg/m2. All subjects had normal liver histology upon liver biopsy. They all donated the right lobe of their liver with successful ***: The mean LS was 4.3 ± 1.2 k Pa(range: 1.8-7.1 k Pa). The 5th and 95 th percentiles of normal LS were 2.6 k Pa and 6.8 k Pa, respectively, with a median of 4 k Pa; the interquartile range was 0.6 ± 0.4. LS measurements were not significantly different between men and women(4.4 ± 1.1 k Pa vs 3.9 ± 1.3 k Pa) and did not correlate with age. However, stiffness values were significantly lower in subjects with a body mass index kg/m2 compared to those with an index ≥ 26 kg/m2(4.0 ± 1.1 k Pa vs 4.6 ± 1.2 k Pa; P k Pa and those with stiffness > 4 k Pa. CONCLUSION: Healthy donors with normal liver histology have a median LS of 4 k Pa. Stiffness values are elevated relative to increase in body mass index.

关键词： Fibroscan Liver stiffness Living donors Normal liver histology Transient elastography

Electrical Parameters Investigation and Zero Flow Rate Effect of Nitrogen Atmospheric Nonthermal Plasma Jet

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Energy and Power Engineering 2014年第12期6卷 437-448页

作者： T. M. allam S. A. Ward H. A. El-sayed E. M. Saied H. M. Soliman k. M. Ahmed Plasma and Nuclear Fusion Department Egyptian Atomic Energy Authority Cairo Egypt Electrical Engineering Department Faculty of Engineering at Shoubra Benha University Cairo Egypt

The construction and operation of atmospheric nonthermal plasma jet, ANPJ, are presented in this work as well as the experimental investigations of its electrical parameters, the configuration of plasma jet column and its temperature. The device is energized by a low-cost Neon power supply of (10 kV, 30 mA, and 20 kHz) and the discharge takes place by using N2 gas with different flow rates from 3 to 25 L/min and input voltage of 6 kV. Diagnostic techniques such as voltage divider, Lissajous figure, image processing and thermometer are used. The electrical characteristics of discharge at different flow rates of N2 gas such as discharge voltage, current, mean power, power efficiency, and mean energy have been studied. The experimental results show that the maximum plasma jet length of 14 mm is detected at flow rate of 12 L/min. The results of plasma jet (heavy particles) temperature along the jet length show that jet plasma has approximately a room temperature at the jet column end. The results of zero flow rate effect on the ANPJ operation show damage in the Teflon insulator and a corrosion in the Aluminum electrodes.

关键词： Plasma Jet Lissajous Figure Gas Temperature Zero Flow Rate