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Journal of Rare Earths 2024年第1期42卷 1-15,I0001页

作者： Julio Corredoira-Vázquez Cristina González-Barreira Paula Oreiro-Martínez Ana M.García-Deibe Jesús Sanmartín-Matalobos Matilde Fondo Departamento de Química Inorganica Facultade de QuímicaUniversidade de Santiago de CompostelaCampus Vida15782Santiago de CompostelaSpain Phantom-g CICECO-Aveiro Institute of MaterialsDepartment of PhysicsUniversity of Aveiro3810-193AveiroPortugal Institute of Materials(iMATUS) Universidade de Santiago de Compostela15782Santiago de CompostelaSpain

In this paper,the lanthanoid complexes of n_(5) and n_(6) macrocycle ligands,without pendant arms or additional heteroatoms,are *** review covers the period from 2015 to the current date,since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety,and their complexes,were revised,and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also *** and phthalocyanine ligands are not included in this review,which primarily focuses on complexes with Schiff bases and amines without pendant arms or any additional donor other than *** synthetic methods,structural characterization,based on single X-ray crystal data,and properties of the lanthanoid complexes,with special attention to magneto-structural correlations,are presented herein.

关键词： Lanthanoid n_(5),n_(6)macrocycle Coordination chemistry Chirality Biological activity Molecule magnet

Efficient Real-Time Devices Based on Accelerometer UsingMachine Learning for HAR on Low-PerformanceMicrocontrollers

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Computers, Materials and Continua 2024年第1期81卷 1729-1756页

作者： Vi M.-T. Tran D.-n. Thuong V.T. Linh n.n. Tran D.-T. Faculty of Electrical and Electronic Engineering Phenikaa University Hanoi City 100000 Viet Nam Institute of Information Technology Vietnam Academy of Science and Technology Hanoi City 100000 Viet Nam Faculty of Information Technology and Communication Phuong Dong University Hanoi City 100000 Viet Nam Graduate University of Sciences and Technology Vietnam Academy of Science and Technology Hanoi City 100000 Viet Nam International School-Vietnam national University Hanoi City 100000 Viet Nam

Analyzing physical activities through wearable devices is a promising research area for improving health assessment. This research focuses on the development of an affordable and real-time Human Activity Recognition (HAR) system designed to operate on low-performance microcontrollers. The system utilizes data from a bodyworn accelerometer to recognize and classify human activities, providing a cost-effective, easy-to-use, and highly accurate solution. A key challenge addressed in this study is the execution of efficient motion recognition within a resource-constrained environment. The system employs a Random Forest (RF) classifier, which outperforms Gradient Boosting Decision Trees (GBDT), Support VectorMachines (SVM), and K-nearest neighbors (Knn) in terms of accuracy and computational efficiency. The proposed featuresAverage absolute deviation (AAD), Standard deviation (STD), Interquartile range (IQR), Range, and Root mean square (RMS). The research has conducted numerous experiments and comparisons to establish optimal parameters for ensuring system effectiveness, including setting a sampling frequency of 50 Hz and selecting an 8-s window size with a 40% overlap between *** conducted on both theWISDMpublic dataset and a self-collected dataset, focusing on five fundamental daily activities: Standing, Sitting, Jogging,Walking, andWalking the stairs. The results demonstrated high recognition accuracy, with the system achieving 96.7% on the WISDM dataset and 97.13% on the collected dataset. This research confirms the feasibility of deployingHAR systems on low-performance microcontrollers and highlights the system's potential applications in patient support, rehabilitation, and elderly care. © 2024 The Authors. Published by Tech Science Press.

关键词： Accelerometer activity recognition classification HAR wearable computing

Insider Attack Prevention:LAPUP—Lightweight Authentication Protocol Using PUF

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Journal of Communications and Information networks 2024年第2期9卷 192-206页

作者： Siranjeevi Rajamanickam Satyanarayana Vollala n.Ramasubramanian Department of Computer Engineering Government Polytechnic CollegeTiruchirappalli 620022India Department of Computer Science and Engineering Dr.Shyama Prasad Mukherjee International Institute of Information Technology-Naya RaipurChhattisgarh 493661India Department of Computer Science and Engineering National Institute of TechnologyTiruchirappalli 620015India

The incredible progress in technologies has drastically increased the usage of Web *** share their credentials like userid and password or use their smart cards to get authenticated by the application *** cards are handy to use,but they are susceptible to stolen smart card attacks and few other notable security *** prefer to use Web applications that guarantee for security against several security attacks,especially insider attacks,which is *** of several existing schemes prove the security pitfalls of the protocols from preventing security attacks,specifically insider *** paper introduces LAPUP:a novel lightweight authentication protocol using physically unclonable function(PUF)to prevent security attacks,principally insider *** PUFs are used to generate the security keys,challenge-response pair(CRP)and hardware signature for designing the *** transmitted messages are shared as hash values and encrypted by the keys generated by *** messages are devoid of all possible attacks executed by any attacker,including insider *** is also free from stolen verifier attacks,as the databases are secured by using the hardware signature generated by *** analysis of the protocol exhibits the strength of LAPUP in preventing insider attacks and its resistance against several other security *** evaluation results of the communication and computation costs of LAPUP clearly shows that it achieves better performance than existing protocols,despite providing enhanced security.

关键词： physically unclonable function(PUF) insiderattacks authenticationkeymanagementserver(AKMS) security

Aberrant adult neurogenesis in intractable epilepsy:can GABAergic progenitor transplantation normalize this process?

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neural Regeneration Research 2024年第7期19卷 1419-1420页

作者： Muhammad n.Arshad Janice R.naegele Department of Biology Wesleyan UniversityMiddletownCTUSA Department of neuroscience Tufts University School of MedicineBostonMAUSA

Temporal lobe epilepsy(TLE) is a common type of focal epilepsy characterized by seizure foci within the temporal *** surgical resection of the foci is an established and effective approach for controlling seizures,both temporal lobes cannot be removed,due to their prominent roles in learning and ***,seizures induce changes to the temporal lobes that contribute to hyperexcitability,including mossy fiber sprouting,astrogliosis.

关键词： epilepsy progenitor seizures

Reconstructive surgery for phantom and residual limb pain in post-conflict settings

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Chinese Journal of Plastic and Reconstructive Surgery 2024年第1期6卷 54-55页

作者： Damián Palafox Plastic and Reconstructive Surgery Department Hospital Angeles PueblaPuebla 72190Mexico

Traumatic amputations remain one of the most frequent and disturbing wounds of armed *** this scenario,most amputees develop residual and phantom limb pain,impacting their quality of *** are several elective surgical procedures available for both conditions,such as neuroma excision followed by nerve reconstruction,nerve relocation,e.g.,surgically implanting a transected nerve into a muscle,nerve transfers in cases of associated paralysis,and most recently,regenerative peripheral nerve interface *** possible in the post-conflict phase,a coordinated effort between traveling humanitarian surgeons specializing in reconstructive microsurgery and local healthcare providers is essential for successfully treating phantom and chronic residual limb pain in post-conflict *** providing a detailed logistical framework for global humanitarian missions is beyond the scope of this article,we provide a brief perspective on a topic of utmost importance for reconstructive surgeons worldwide:the high-quality care and treatment of refugees and those whose lives have been impacted by conflict,disaster,or displacement.

关键词： Residual limb pain Phantom limb pain Refugees Reconstructive surgery Microsurgery Amputees

In vivo astrocyte reprogramming following spinal cord injury

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neural Regeneration Research 2024年第3期19卷 487-488页

作者： Yannick n.Gerber Florence E.Perrin MMDn University of MontpellierEPHEINSERMMontpellierFrance Institut Universitaire de France(IUF) ParisFrance

Harmful and helpful roles of astrocytes in spinal cord injury(SCI):SCI induce gradable sensory,motor and autonomic impairments that correlate with the lesion severity and the rostro-caudal location of the injury *** absence of spontaneous axonal regeneration after injury results from neuron-intrinsic and neuron-extrinsic ***,not only adult neurons display limited capability to regrow axons but also the injury environment contains inhibitors to axonal regeneration and a lack of growth-promoting *** other cell populations that respond to the lesion,reactive astrocytes were first considered as only detrimental to spontaneous axonal ***,astrocytes.

关键词： injury impairment programming

Recovering noble metals from waste streams using porous organic frameworks for heterogeneous catalysis

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Science China Chemistry 2024年第11期67卷 3578-3587页

作者： Yu Pan Michelle ?hlén Maria Str?mme Chao Xu Division of nanotechnology and Functional Materials Department of Materials Science and Engineering ?ngstr?m LaboratoryUppsala University State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences

Recovering noble metals from waste resources and incorporating them into catalysts stands out as a promising strategy for advancing sustainability within the catalysis field. This review provides a comprehensive overview of recent investigations into noble metal recovery from waste streams, specifically employing porous organic frameworks(POFs). Additionally, the study delves into the utilization of the resultant composites, enriched with noble metals, in heterogeneous catalysis. Moreover, we offer insights into the challenges faced and outline prospects for the practical implementation of extracting noble metal catalysts from waste streams using POFs, aiming to develop cost-effective, sustainable, and efficient heterogeneous catalysts.

关键词： porous organic frameworks noble metal recovery heterogeneous catalysis sustainability

Evaluation of slope stability through rock mass classification and kinematic analysis of some major slopes along nH-1A from Ramban to Banihal, north Western Himalayas

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第1期16卷 167-182页

作者： Amit Jaiswal A.K.Verma T.n.Singh Department of Civil and Environmental Engineering Indian Institute of Technology PatnaPatna801106India

The network of Himalayan roadways and highways connects some remote regions of valleys or hill slopes,which is vital for India’s socio-economic *** to natural and artificial factors,frequency of slope instabilities along the networks has been increasing over last few *** of stability of natural and artificial slopes due to construction of these connecting road networks is significant in safely executing these roads throughout the *** rock mass classification methods are generally used to assess the strength and deformability of rock *** study assesses slope stability along the nH-1A of Ramban district of north Western *** structurally and non-structurally controlled rock mass classification systems have been applied to assess the stability conditions of 14 *** evaluating the stability of these slopes,kinematic analysis was performed along with geological strength index(GSI),rock mass rating(RMR),continuous slope mass rating(CoSMR),slope mass rating(SMR),and Q-slope in the present *** SMR gives three slopes as completely unstable while CoSMR suggests four slopes as completely *** stability of all slopes was also analyzed using a design chart under dynamic and static conditions by slope stability rating(SSR)for the factor of safety(FoS)of 1.2 and 1 respectively.Q-slope with probability of failure(PoF)1%gives two slopes as stable *** slope angle has been determined based on the Q-slope safe angle equation and SSR design chart based on the *** value ranges given by different empirical classifications were RMR(37-74),GSI(27.3-58.5),SMR(11-59),and CoSMR(3.39-74.56).Good relationship was found among RMR&SSR and RMR&GSI with correlation coefficient(R 2)value of 0.815 and 0.6866,***,a comparative stability of all these slopes based on the above classification has been performed to identify the most critical slope along this road.

关键词： Rock mass classification Kinematic analysis Slope stability Himalayan road Static and dynamic conditions

Comprehensive analysis of uncertainty quantification for the^(58)ni(n,p)^(58)Co reaction cross section

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Chinese Physics C 2024年第9期48卷 170-175页

作者： Mahesh Choudhary Aman Sharma namrata Singh Mahima Upadhyay Punit Dubey A.Gandhi Akash Hingu G Mishra Sukanya De L.S.Danu Ajay Kumar R.G.Thomas Saurav Sood Sajin Prasad S.Mukherjee I.n.Ruskov Yu.n.Kopatch A.Kumar Department of Physics Banaras Hindu UniversityVaranasi 221005India Horia Hulubei national Institute of Physics and nuclear Engineering-IFIn-HH Bucharest 077125Romania Department of Physics The Maharaja Sayajirao University of BarodaVadodara 390002India nuclear Physics Division Bhabha Atomic Research CentreMumbai 400085India Health Physics Division Bhabha Atomic Research CentreMumbai 400085India Department of Electrical Power Engineering Brno University of TechnologyBrno 61600Czech Republic Institute for nuclear Research and nuclear Energy Bulgarian Academy of SciencesSofia 1784Bulgaria Joint Institute for nuclear Research(JInR) Dubna 141980Russia

In this study,we measured the^(58)ni(n,p)^(58)Co reaction cross section with neutron energies of 1.06,1.86,and 2.85 *** cross section was measured using neutron activation techniques andγ-ray spectroscopy,and it was compared with cross section data available in the ***,we calculated the covariance matrix of the measured cross section for the aforementioned nuclear *** uncertainties of the theoretical calculation for^(58)ni(n,p)^(58)Co reaction cross section were calculated via Monte Carlo *** this study,we used uncertainties in the optical model and level density parameters to calculate uncertainties in the theoretical cross *** theoretical calculations were performed by using *** this study,we aim to analyze the effect of uncertainties of the nuclear model input as well as different experimental variables used to obtain the values of reaction cross section.

关键词： ^(58)ni(n p)^(58)Co reaction γ-ray spectroscopy uncertainty quantification of cross section covariance analysis

Calibration of the DEM sliding friction and rolling friction parameters of a cohesionless bulk material

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Particuology 2024年第9期92卷 126-139页

作者： Jonatan Marín Pérez Tugrul Comlekci Yevgen Gorash Donald MacKenzie University of Strathclyde 75 Montrose StreetG11XJGlasgowUnited Kingdom

The discrete element method(DEM)has become a valuable tool for understanding the mechanical behaviour of granular assemblies,however,the accuracy of the DEM simulations depends on several interaction parameters such as the sliding friction and rolling friction ***,these parameters are estimated using bulk calibration approach(BCA)where the draw down test has been suggested as an effective way to approach these *** test provides up to four bulk criteria,the angle of repose,shear angle,mass flow rate and the mass loss which are used to narrow down the possible ***,there is still more research needed around it to fully understand how this methodology *** experimental and numerical study was carried out using the draw down test to assess the influence of different mass flow rates and particle shapes on DEM parameters for a cohesionless bulk *** is concluded that use of multi-sphere particles and three aperture sizes in the draw down test to calibrate the sliding and rolling friction parameters of a cohesionless bulk material can converge to a small feasible region in which a single combination of the friction coefficients can be *** calibrated sliding and rolling friction coefficients were validated using multi-sphere particles,where the maximum deviation was 5.9%from the experimental values.

关键词： Discrete element method Calibration Draw down Sliding friction Rolling friction Particle shape