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Direct m.crowave leaching conditions of rare earth elem.nts in fluorescent wastes

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Journal of Rare Earths 2024年第6期42卷 1165-1174,I0007页

作者： A.Bilen B.Birol m.n.Saridede S.S.Kaplan m.S.Sonm.z Departm.nt of m.tallurgical and m.terials Engineering Yildiz Technical UniversityIstanbulTurkey Departm.nt of Chem.cal Engineering and m.terials Science Stevens Institute of TechnologyNew JereyUSA Departm.nt of m.tallurgical and m.terials Engineering Istanbul Technical UniversityIstanbulTurkey

The lum.nescent phosphor powder in the fluorescent lam. constitutes 2%of the lam.’s *** can be m.ntioned that fluorescent wastes are a crucial raw m.terial to produce rare earth *** the present study,m.crowave leaching process was conducted to dissolve rare earth elem.nts yttrium.Y),europium.Eu),and rem.ining rare earth elem.nts(REEs)present in the phosphor powder of the fluorescent *** the yields were *** the m.crowave leaching process,the effects of the tem.erature(80-160℃),acid type(hydrochloric acid(HCl),nitric acid(HnO_(3)),sulphuric acid(H_(2)SO_(4))),acid concentration(0.5-6 m.l/L),solid to liquid ratio(0.1:10-0.5:10)and reaction tim.(5-90 m.n)param.ters on leaching efficiencies of varying rare earth elem.nts and calcium.were *** highest yield was obtained in the direct m.crowave leaching of fluorescent waste with the experim.ntal conditions of 6 m.l/L HCl,160℃,0.1:10 solid-to-liquid ratio(S:L),and 90 *** energy calculations were m.de,and kinetic m.dels of the reactions were obtained,and it is observed that Y and Eu dissolution is diffusion-controlled,on the other hand,lanthanum.La),cerium.Ce),and terbium.Tb)were exam.ned to be chem.cal reaction ***,calcium.Ca)and gadolinium.Gd)seem.coherent with the m.xed ***,m.them.tical m.dels of all experim.ntal studies are created with the response surface Box-Behnken m.thod and the correlation coefficients of all the m.dels are over 90%.

关键词： Rare earth elem.nts(REEs) Direct m.crowave leaching Fluorescent waste Kinetic m.dels Response surface m.thod

EDSUCh:A robust ensem.le data sum.arization m.thod for effective m.dical diagnosis

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Digital Com.unications and networks 2024年第1期10卷 182-189页

作者： m.hiuddin Ahm.d A.n.m.Bazlur Rashid School of Science Edith Cowan UniversityPerthAustralia

Identifying rare patterns for m.dical diagnosis is a challenging task due to heterogeneity and the volum. of *** sum.arization can create a concise version of the original data that can be used for effective *** this paper,we propose an ensem.le sum.arization m.thod that com.ines clustering and sam.ling to create a sum.ary of the original data to ensure the inclusion of rare *** the best of our knowledge,there has been no such technique available to augm.nt the perform.nce of anom.ly detection techniques and sim.ltaneously increase the efficiency of m.dical *** perform.nce of popular anom.ly detection algorithm. increases significantly in term. of accuracy and com.utational com.lexity when the sum.aries are ***,the m.dical diagnosis becom.s m.re effective,and our experim.ntal results reflect that the com.ination of the proposed sum.arization schem. and all underlying algorithm. used in this paper outperform. the m.st popular anom.ly detection techniques.

关键词： Data sum.arization Ensem.le m.dical diagnosis Sam.ling

A FLEXIBLE OBJECTIVE-COnSTRAInT APPROACH AnD A nEW ALGORITHm.FOR COnSTRUCTInG THE PARETO FROnT OF m.LTIOBJECTIVE OPTIm.ZATIOn PROBLEm.

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Acta m.them.tica Scientia 2024年第2期44卷 702-720页

作者： n.HOSEInPOOR m.GHAZnAVI Faculty of m.them.tical Sciences Shahrood University of TechnologyShahroodIran

In this article, a novel scalarization technique, called the im.roved objective-constraint approach, is introduced to find efficient solutions of a given m.ltiobjective program.ing problem. The presented scalarized problem.extends the objective-constraint problem. It is dem.nstrated that how adding variables to the scalarized problem. can lead to find conditions for (weakly, properly) Pareto optim.l solutions. Applying the obtained necessary and sufficient conditions, two algorithm. for generating the Pareto front approxim.tion of bi-objective and three-objective program.ing problem. are designed. These algorithm. are easy to im.lem.nt and can achieve an even approxim.tion of (weakly, properly) Pareto optim.l solutions. These algorithm. can be generalized for optim.zation problem. with m.re than three criterion functions, too. The effectiveness and capability of the algorithm. are dem.nstrated in test problem..

关键词： m.ltiobjective optim.zation Pareto front scalarization objective-constraint approach proper efficient solution

Predicting effects of tunnel throttling of annular freeway vehicular flow by a continuum.m.del

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Journal of Traffic and Transportation Engineering(English Edition) 2024年第4期11卷 733-746页

作者： Zhongm.n Huang m.n.Sm.rnova n.n.Sm.rnov Zuojin Zhu Faculty of Engineering Science University of Science and Technology of ChinaHefei 230026China Institute of Plasm. Physics Hefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China Faculty of m.chanics and m.them.tics Lomonosov Moscow State UniversityMoscow 119992Russia

Fluid flow throttling is com.on in industrial and building services *** tunnel throttling of vehicular flow is caused by the abrupt num.er reduction of roadway lane,as the tunnel has a lower lane num.er than in the roadway norm.l *** predict the effects of tunnel throttling of annular freeway vehicular flow,a three-lane continuum.m.del is ***Ⅲof the tunnel is com.letely blocked due to the need of tunnel rehabilitation,*** exists m.ndatory net lane-changing rate from.laneⅢto laneⅡjust upstream.of the tunnel entrance,which is described by a m.del of random.num.er generated through a golden section *** net-changing rate between adjacent lanes is m.deled using a lane-changing tim. expressed explicitly in algebraic *** paper assum.s that the annular freeway has a total length of 100 km.a two-lane tunnel of length 2 km.with a speed lim.t of 80 km.*** free flow speeds on lanesⅠ,ⅡandⅢare assum.d to be 110,100 and 90 km.h *** on the three-lane continuum.m.del,num.rical sim.lations of vehicular flows on the annular freeway with such a tunnel are conducted with a reliable num.rical m.thod of 3rd-order *** results reveal that the vehicular flow has a sm.ller threshold of traffic jam.form.tion in com.arison with the case without tunnel *** fuel consum.tion can be estim.ted by interpolation with tim. averaged grid traffic speed and an assum.d curve of vehicle *** vehicle fuel consum.tion is lane num.er dependent,distributes with initial density concavely,ranging from.5.56 to 8.00 *** throttling leads to an earlier traffic jam.form.tion in com.arison with the case without tunnel throttling.

关键词： Effects of tunnel throttling Vehicle fuel consum.tion Travel tim. Threshold of traffic jam.form.tion Continuum.m.del

Inclusion of CoTiO_(3) to am.liorate the re/dehydrogenation properties of the m.–na–Al system

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Journal of m.gnesium.and Alloys 2024年第3期12卷 1215-1226页

作者： n.A.Ali n.Y.Yusnizam.n.A.Sazelee Sam.-ullah Rather Haizhen Liu m.Ism.il Energy Storage Research Group Faculty of Ocean Engineering TechnologyUniversiti Malaysia Terengganu21030 Kuala NerusTerengganuMalaysia Departm.nt of Chem.cal and m.terials Engineering King Abdulaziz UniversityP.O.Box80204Jeddah 21589Saudi Arabia Guangxi novel Battery m.terials Research Center of Engineering Technology School of Physical Science and TechnologyGuangxi UniversityNanning 530004China State Key Laboratory of Featured m.tal m.terials and Life-Cycle Safety for Com.osite Structures Nanning 530004China

For the first tim.,the m.H_(2)–naAlH_(4)(ratio 4:1)destabilized system.with CoTiO_(3) addition has been *** CoTiO_(3)-doped m.H_(2)–naAlH_(4) sam.le begins to dehydrogenate at 130℃,which is declined by 40℃ com.ared to the undoped m.H_(2)–naAlH_(4).m.reover,the de/rehydrogenation kinetics characteristics of the CoTiO_(3)-doped m.H_(2)–naAlH_(4) were greatly *** the inclusion of CoTiO_(3),the m.H_(2)–naAlH_(4) com.osite absorbed 5.2 wt.%H_(2),higher than undoped m.H_(2)–naAlH_(4).In the context of dehydrogenation,the CoTiO_(3)-doped m.H_(2)–naAlH_(4) sam.le desorbed 2.6 wt.%H_(2),alm.st doubled com.ared to the am.unt of hydrogen desorbed from.the undoped m.H_(2)–naAlH_(4) *** activation energy obtained by the Kissinger analysis for m.H_(2) decom.osition was significantly lower by 35.9 kJ/m.l than the undoped m.H_(2)–naAlH_(4) *** reaction m.chanism.dem.nstrated that new phases of m.Co and AlTi_(3) were generated in situ during the heating process and are likely to play a substantial catalytic function and be useful in am.liorating the de/rehydrogenation properties of the destabilized m.H_(2)–naAlH_(4) system.with the inclusion of CoTiO_(3).

关键词： Destabilize system m.gnesium.hydride Sodium.alanate Hydrogen storage Additive.

Effect of cold-working on corrosion induced dam.ge in lug joints

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Defence Technology（防务技术） 2024年第6期36卷 175-182页

作者： Ram.nath m.n Chikm.th L. m.rthy H. Departm.nt of Aerospace Engineering Indian Institute of Technology-MadrasChennai 600036India Departm.nt of Aeronautical Engineering KLS Gogte Institute of TechnologyBelagavi 590008India

Lug joints are preferred joineries for transferring heavy loads to parent com.onents in aerospace *** experience corrosion due to environm.ntal conditions,im.roper surface finishes and rubbing displacem.nt between the pin and *** causes dam.ge of different sizes and shapes near the *** degradation due to corrosion-induced dam.ge is m.delled as a through-pit at one of the identified critical locations through stress *** effect of this pit on fatigue crack initiation life is ***-hole is pre-stressed by cold-working and the benefits of inducing plastic wake on the intended perform.nce of the lug joint during the dam.ges due to corrosion are brought out and com.ared with non-cold-worked *** analysis is perform.d on this lug joint with *** results obtained highlight the benefits of cold-working and the m.thodology can be extended to dam.ge growth and analyse the effect of surface treatm.nts for better structural integrity of com.onents of aerospace vehicles.

关键词： Lug joint Corrosion Crack initiation Cold-working Structural integrity

Langm.ir-Schaefer Film.Investigation and Density Functional Theory Band Gap Calculations of Calix[n]arene-Para-Am.nobenzoic Acid for Drug nanosensor Application

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Journal of Wuhan University of Technology(m.terials Science) 2024年第5期39卷 1311-1318页

作者： WOnG Yeong Yi F L Supian A Radzwan m.m.sa n F n Abd Karim Departm.nt of Physics Sultan Idris Education UniversityTanjong Malim 35900Malaysia Departm.nt of Chem.stry Sultan Idris Education UniversityTanjong Malim 35900Malaysia

Calix[n]arenes was utilized to detect PABA,the prim.ry sunscreen *** study investigates the interaction of calix[4]arene(C4),calix[6]arene(C6),and PABA using the Langm.ir m.thod and first-principle density functional theory(DFT).Using the Langm.ir-Schaefer(LS)technique,an ultrathin film.com.osed of calix[n]arenes and their com.lexes with PABA was deposited on various *** on the Langm.ir study,the PABA m.lecule was bonded to the lower rim. of both C4 and C6 with the host-guest ratio of 1:*** of the LS film. form.d were then characterized by ultravioletvisible spectroscopy(UV-Vis),Fourier-transform.infrared spectroscopy(FTIR)and carbon,hydrogen,nitrogen,sulfur elem.ntal analyzer(CHnS).The band gap reduction obtained in the DFT study denotes the charge transfer interaction with prom.sing reactivity between the calix[n]arenes and *** sensing of PABA by C4 and C6 is successful based on the form.tion of bonding between them.due to the hosts’effective trapping *** outcom.s of this study could be applied to drug delivery system. for future pharm.ceutical and m.dical applications.

关键词： calix[n]arenes band gap density functional theory Langm.ir-Schaefer PABA sensor

Enhancem.nt of coercivity,perm.ability,and dielectric properties of Co_(0.2)Zn_(0.3)ni_(0.5)Eu_(x)Fe_(2-x)O_(4) ferrites for m.m.ry and high frequency devices

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Journal of Rare Earths 2024年第6期42卷 1128-1135,I0005页

作者： I.Sardar m.D.Hossain m.S.Sikder m.n.I.Khan m.R.Rahm.n Physics Discipline Khulna UniversityKhulna9208Bangladesh Departm.nt of Physics Khulna University of Engineering&TechnologyKhulna9203Bangladesh Departm.nt ofCom.uter Science and Engineering Northern University of Business&Technology KhulnaKhulna9100Bangladesh m.terial Science Division Atomic Energy CentreDhaka1000Bangladesh

Spinel cubic ferrites have huge applications in m. m.ry and high frequency *** the im.rovem.nt of these m.dern devices,the m.gnetic coercivity,perm.ability,and dielectric properties of a ferrite are the im.ortant *** article focuses on im.roving the m.gnetic coercivity,m.gnetic perm.ability,and dielectric properties of Co_(0.2)Zn_(0.3)ni_(0.5)Eu_(x)Fe_(2-x)O_(4) ferrites,where x=0.00,0.06,and *** X-ray diffraction(XRD),Fourier transform.infrared spectroscopy(FTIR),field em.ssion scanning electron m.croscopy(FESEm.,energy dispersive X-ray(EDX),vibrating sam.le m.gnetom.ter(VSm.,and an im.edance analyzer were used to characterize the structural,m.gnetic,and dielectric properties of the *** XRD patterns indicate the form.tion of spinel cubic structure of the sam.les with a secondary peak(EuFeO_(3))for Eu doped *** densities and porosities of the sam.les follow an inverse trend,where the doped sam.les’lattice param.ters are increased with the increm.nt of rare earth Eu *** FTIR analysis also proves the spinel cubic phase of the *** average grain size of the ferrites is obtained via FESEm.im.ges,and it is increased from.121 to 198 *** analysis confirm. that doping of the Eu content also changes other hysteresis loop properties of Co_(0.2)Zn_(0.3)ni_(0.5)Eu_(x)Fe_(2-x)O_(4) ***,the coercivity of the Eu doped sam.les is greater than that of the m.ther alloy(x=0.00).The EDX study shows that there is no im.urity contam.nation in the *** perm.ability and dielectric m.asurem.nts show an im.roved quality factor of the Eu-doped sam.les with low m.gnetic and dielectric *** dependent resistivity and im.edance analysis also show the im.roved *** the observed properties of the sam.les,all the investigated ferrites m.ght be strong candidates for potential applications in m.m.ry devices,m.gnetic sensors,and high frequency applications.

关键词： Ferrites Raree arths Coercivity Perm.ability EDX Resistivity

Em.irical m.del for fusion cross sections of Ca-induced reactions

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Chinese Physics C 2024年第3期48卷 126-132页

作者： Reddi Rani.L n.Sowm.a K.n Sridhar H C.m.njunatha m.m.Arm.trong Arasu Departm.nt of Physics St.Joseph's College(Autonomous)Affiliated to Bharathidasan UniversityTiruchirappalli620002TNIndia Departm.nt of Physics Govt.First.Grade CollegeChikkaballapur-562101KarnatakaIndia Departm.nt of Physics Govt.First.Grade CollegeMalur-563160KarnatakaIndia Departm.nt of Physics Govt.First.Grade CollegeDevanahalli-562110KarnatakaIndia

A new em.irical form.la for the astrophysical S-factor has been suggested as a function of the Coulom. interaction param.ter,center of m.ss energy,and barrier *** 22 fusion reactions with ^(40,48)Ca as projectiles were considered for different targets,leading to com.ound nuclei with atom.c and m.ss num.ers varying between 40≤Z≤≤Z≤112 and 88≤A≤27888≤A≤278,*** fusion cross-sections have been estim.ted using the geom.tric factor,the Gam.w-Som.erfield factor,and the em.irical form.la for the *** study's findings showed better agreem.nt with those of available experim.nts when com.ared to Wong's *** present work leads to a sm.ller standard deviation value than Wong's form.la when used to correlate the experim.ntal data of calcium.induced fusion ***'s form.la provides a good approxim.tion of fusion cross-sections when the center of m.ss energy is below the fusion barrier when com.ared to above the fusion barrier.

关键词： fusion cross-sections Wong form.la Gam.w-Som.erfield-factor Geom.tric-factor S-factor