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Progress in electrocatalytic nitrate reduction for green energy:Catalyst engineering,mechanisms,and techno-economic feasibility

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Journal of Energy Chemistry 2024年第8期95卷 380-406,I0009页

作者： Hafiz muhammad Adeel Sharif Hafiz muhammad Farooq Khan Sadeeq Ullah Yuwei Wang muhammad Ahmad Bo Yang Changping Li muhammad Bilal Asif Research Center for Eco-Environmental Engineering Dongguan University of TechnologyDongguan 523808GuangdongChina College of Chemistry and Engineering Shenzhen UniversityShenzhen 518060GuangdongChina FMH College of Medicine and Dentistry LahorePakistan School of Environment and Civil Engineering Research Center for Eco-Environment EngineeringDongguan University of TechnologyDongguan 523106GuangdongChina Advanced Membranes and Porous Materials Center(AMPMC) Physical Sciences and Engineering(PSE)King Abdullah University of Science and Technology(KAUST)Thuwal 23955Saudi Arabia

Ammonia(NH_(3))is an irreplaceable chemical that has been widely demanded to keep the sustainable development of modern ***,its industrial production consumes a huge amount of energy and releases extraordinary greenhouse gases(GHGs),leading to various environmental *** the green production of ammonia is a great challenge,which has been extensively pursued in the last *** this review,the most promising strategy,electrochemical nitrate reduction reaction(e-NO_(3)RR),is comprehensively investigated to give a complete understanding of its development and mechanism and provide guidance for future ***,owing to the complex reactions and limited selectivity,a comprehensive understanding of the mechanisms is crucial to further development and ***,NO_(3)^(-)RR is a promising strategy for simultaneous water treatment and NH_(3)production.A detailed overview of the recent progress in NO_(3)^(-)RR for NH_(3)production with nontransition and transition metal based electrocatalysts is *** addition,critical advanced techniques,future challenges,and prospects are discussed to guide future research on transition metal-based catalysts for commercial NH_(3)synthesis by NO_(3)^(-)reduction.

关键词： Nitrate reduction Electrolysis Pollution to solution Transition metal catalysts Ammonia synthesis Green energy

Physiological characteristics,geochemical properties and hydrological variables influencing pathogen migration in subsurface system:What we know or not?

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Geoscience Frontiers 2022年第6期13卷 315-330页

作者： Wenjing Zhang Juanfen Chai Shuxin Li Xinzi Wang Shengyu Wu Zhentian Liang muhammad yousuf Jat Baloch Luis F.O.Silva Dayi Zhang Key Laboratory of Groundwater Resources and Environment(Jilin University) Ministry of EducationChangchun 130021China College of New Energy and Environment Jilin UniversityChangchun 130021China School of Environment Tsinghua UniversityBeijing 100084China Departamento de Ingeniería Civil y Arquitectura Universidad de LimaAvenida Javier Prado Este 4600Santiago de Surco 1503Peru Department of Civil and Environmental Universidad de la CostaCalle 58#55-66080002 BarranquillaAtlánticoColombia

The global outbreak of coronavirus infectious disease-2019(COVID-19)draws attentions in the transport and spread of Severe Acute Respiratory Syndrome Coronavirus 2(SARS-CoV-2)in aerosols,wastewater,surface water and solid *** pathogens eventually enter the subsurface system,e.g.,soils in the vadose zone and groundwater in the aquifers,they might survive for a prolonged period of time owing to the uniqueness of subsurface *** addition,pathogens can transport in groundwater and contaminate surrounding drinking water sources,possessing long-term and concealed risks to human *** work critically reviews the influential factors of pathogen migration,unravelling the impacts of pathogenic characteristics,vadose zone physiochemical properties and hydrological variables on the migration of typical pathogens in subsurface *** assessment algorithm and two rating/weighting schemes are proposed to evaluate the migration abilities and risks of pathogens in subsurface *** there is still no evidence about the presence and distribution of SARS-CoV-2 in the vadose zones and aquifers,this study also discusses the migration potential and behavior of SARS-CoV-2 viruses in subsurface environment,offering prospective clues and suggestions for its potential risks in drinking water and effective prevention and control from hydrogeological points of view.

关键词： Pathogens Viruses SARS-CoV-2 Subsurface system Migration

Consequences of Rényi entropy on the thermal geometries and Hawking evaporation of topological dyonic dilaton black hole

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Communications in Theoretical Physics 2024年第2期76卷 102-110页

作者： muhammad Yasir Xia Tiecheng muhammad Usman Shahid Chaudhary Department of Mathematics Shanghai University and Newtouch Center for Mathematics of Shanghai UniversityShanghai200444China Department of Natural Sciences and Humanities University of Engineering and Technology LahoreNew CampusPakistan

The thermodynamics of black holes(BHs)has had a profound impact on theoretical physics,providing insight into the nature of gravity,the quantum structure of spacetime and the fundamental laws governing the *** this study,we investigate thermal geometries and Hawking evaporation of the recently proposed topological dyonic dilaton BH in anti-de Sitter(Ad S)*** consider Rényi entropy and obtain the relations for pressure,heat capacity and Gibbs free energy and observe that the Rényi parameter and dilaton field play a vital role in the phase transition and stability of the ***,we use Weinhold,Ruppeiner and Hendi Panahiyah Eslam Momennia models to evaluate the scalar curvature of the BH and find out that the divergence points of the scalar curvature coincides with the zero of specific ***,using Stefan–Boltzmann law,we determine that the BH without a dilaton field evaporates far more quickly compared to the dilaton BH in Ad S space.

关键词： topological dyonic dilaton black hole phase transition thermal geometry Hawking evaporation

Underground communication:Long non-coding RNA signaling in the plant rhizosphere

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Plant Communications 2024年第7期5卷 28-51页

作者： muhammad Fahad Leeza Tariq Sajid muhammad Liang Wu Hainan Institute Zhejiang UniversitySanyaHainan 572000China Zhejiang Provincial Key Laboratory of Crop Genetic Resources College of Agriculture and BiotechnologyZhejiang UniversityHangzhouZhejiang 310058China National Key Laboratory for Rice Biology Institute of BiotechnologyZhejiang UniversityHangzhou 310058China

Long non-coding RNAs(lncRNAs)have emerged as integral gene-expression regulators underlying plant growth,development,and *** adapt to the heterogeneous and dynamic rhizosphere,plants use interconnected regulatory mechanisms to optimally fine-tune gene-expression-governing interactions with soil biota,as well as nutrient acquisition and heavy metal ***,high-throughput sequencing has enabled the identification of plant lncRNAs responsive to rhizosphere biotic and abiotic ***,we examine lncRNA biogenesis,classification,and mode of action,highlighting the functions of lncRNAs in mediating plant adaptation to diverse rhizosphere *** then discuss studies that reveal the significance and target genes of lncRNAs during developmental plasticity and stress responses at the rhizobium interface.A comprehensive understanding of specific lncRNAs,their regulatory targets,and the intricacies of their functional interaction networks will provide crucial insights into how these transcriptomic switches fine-tune responses to shifting rhizosphere *** ahead,we foresee that single-cell dissection of cell-type-specific lncRNA regulatory dynamics will enhance our understanding of the precise developmental modulation mechanisms that enable plant rhizosphere *** future challenges through multi-omics and genetic approaches will more fully reveal the integral roles of lncRNAs in governing plant adaptation to the belowground environment.

关键词： biotic and abiotic cues heavy metals long non-coding RNAs nutrients phytoremediation rhizosphere microbiome

Photochemical reactions as synthetic tool for pharmaceutical industries

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Chinese Chemical Letters 2024年第9期35卷 9-31页

作者： Shehla Khalid muhammad Bilal Nasir Rasool muhammad Imran Department of Chemistry Government College UniversityFaisalabad 38000Pakistan School of Chemistry and Chemical Engineering Shandong UniversityJi’nan 250100China Department of Chemistry Faculty of ScienceKing Khalid UniversityAbha 61413Saudi Arabia

In the quest for new agrochemicals and pharmaceuticals,chemists seek access to reliable and mild synthetic techniques to allow for the systematic modification of chemical structures,exploration of unexplored chemical space,and facilitation of practical synthesis in their search for novel agrochemicals and *** this regard,photocatalytic reactions enabled the synthesis of intricate and more functionalized *** review overviews the developed synthetic methodologies and their utility in the chemical synthesis of *** review also offers in-depth insights into contemporary photoredox reactions such as allylic additions,cyclization,reductive cross-coupling,C–H activation,ring opening,oxidative cross-coupling,dehydrogenation,desulphonation,and *** provides a positive outlook for the promising future of this field.

关键词： Photocatalyst Photochemical reactions Drugs Natural products Late-stage functionalization

Depositional and Bio-Sequence Stratigraphic Framework of Late Cretaceous Kawagarh Formation,Kala-Chitta Range,Pakistan:Equivalent of Gurpi Formation(Iran)

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Journal of Earth Science 2024年第2期35卷 332-348页

作者： muhammad Awais Bilal Wadood muhammad Ishaq muhammad Bilal Zeeshan Zafar Nasar Khan Aminullah Khan Department of Geology University of SwabiAnbar-SwabiKhyber PakhtunkhwaSwabi23561Pakistan Department of Earth Environmental and Resources SciencesUniversity of Naples FedericoⅡNaples80126Italy State Key Laboratory of Continental Dynamics Department of GeologyNorthwest UniversityXi’an710069China National Centre of Excellence in Geology University of PeshawarPeshawarKhyber Pakhtunkhwa25130Pakistan Department of Geological Engineering School of Earth Sciences and EngineeringXi’an Shiyou UniversityXi’an610500China Department of Petroleum Geology and Engineering School of Earth ResourcesChina University of GeosciencesWuhan430074China Department of Geology University of MalakandDir Lower18800ChakdaraPakistan Department of Earth and Environmental Sciences KU LeuvenLeuven3001Belgium

The present study is focused on evaluation of deep marine pelagic sediments of Late Cretaceous Kawagarh Formation of Kala-Chitta Range in the context of microfacies analysis,paleoenvironmental interpretation,planktonic foraminiferal biostratigraphy,sequence stratigraphy and diversification of species.A total of thirty three rock samples were collected from the measured *** microfacies are interpreted,namely planktonic foraminifera wackestone,planktonic foraminifera mudstone and sandy mudstone indicating low energy depositional environment i.e.,outer *** biostratigraphic studies show plentiful planktonic foraminifera species of Globotruncana,Heterohelix and ***,no association of benthic or siliceous organisms was *** the basis of available species assemblage,a single local planktonic foraminifera biozone i.e.,Globotruncana-Heterohelix-Globotruncanita Assemblage Biozone is *** biozone information is combined with published literature and Lower Santonian to Middle Maastrichtian age has been assigned to the Kawagarh *** trend of species occurrences evinces that species number decreases over time with pulsated rise in the Kawagarh *** Kawagarh Formation carbonates show an overall Transgressive Systems Tract(TST).The Kawagarh Formation of Pakistan evinces analogous characteristics to that of the Late Cretaceous Gurpi Formation of Iran based on the geologic age,outcrop lithology,microfacies,planktonic foraminiferal assemblages,depositional setting and sequence stratigraphy.

关键词： depositional fabric biostratigraphy sequence stratigraphy Late Cretaceous Kawagarh Formation Pakistan Gurpi Formation Iran

Cold plasma-induced effects on electromagnetic wave scattering in waveguides:a mode-matching analysis

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Communications in Theoretical Physics 2024年第3期76卷 144-156页

作者： Shahana Rizvi muhammad Afzal Department of Mathematics Capital University of Science and TechnologyIslamabadPakistan

This article presents advancements in an analytical mode-matching technique for studying electromagnetic wave propagation in a parallel-plate metallic rectangular *** technique involves projecting the solution onto basis functions and solving linear algebraic systems to determine scattering *** accuracy of this method is validated via numerical assessments,which involve the reconstruction of matching conditions and conservation *** study highlights the impact of geometric and material variations on reflection and transmission phenomena in the waveguide.

关键词： electromagnetic waves scattering cold plasma metallic conducting mode-matching technique

Predicting Age and Gender in Author Profiling: A Multi-Feature Exploration

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Computers, Materials & Continua 2024年第5期79卷 3333-3353页

作者： Aiman muhammad Arshad Bilal Khan Sadique Ahmad muhammad Asim Department of Computer Science City University of Science and Information TechnologyPeshawar25000Pakistan EIAS:Data Science and Blockchain Laboratory College of Computer and Information SciencesPrince Sultan UniversityRiyadh11586Saudi Arabia School of Computer Science and Technology Guangdong University of TechnologyGuangzhou510006China

Author Profiling (AP) is a subsection of digital forensics that focuses on the detection of the author’s personalinformation, such as age, gender, occupation, and education, based on various linguistic features, e.g., stylistic,semantic, and syntactic. The importance of AP lies in various fields, including forensics, security, medicine, andmarketing. In previous studies, many works have been done using different languages, e.g., English, Arabic, French,***, the research on RomanUrdu is not up to the ***, this study focuses on detecting the author’sage and gender based on Roman Urdu text messages. The dataset used in this study is Fire’18-MaponSMS. Thisstudy proposed an ensemble model based on AdaBoostM1 and Random Forest (AMBRF) for AP using multiplelinguistic features that are stylistic, character-based, word-based, and sentence-based. The proposed model iscontrasted with several of the well-known models fromthe literature, including J48-Decision Tree (J48),Na飗e Bays(NB), K Nearest Neighbor (KNN), and Composite Hypercube on Random Projection (CHIRP), NB-Updatable,RF, and AdaboostM1. The overall outcome shows the better performance of the proposed AdaboostM1 withRandom Forest (ABMRF) with an accuracy of 54.2857% for age prediction and 71.1429% for gender predictioncalculated on stylistic features. Regarding word-based features, age and gender were considered in 50.5714% and60%, respectively. On the other hand, KNN and CHIRP show the weakest performance using all the linguisticfeatures for age and gender prediction.

关键词： Digital forensics author profiling for security AdaBoostM1 random forest ensemble learning

Federated Machine Learning Based Fetal Health Prediction Empowered with Bio-Signal Cardiotocography

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Computers, Materials & Continua 2024年第3期78卷 3303-3321页

作者： muhammad Umar Nasir Omar Kassem Khalil Karamath Ateeq Bassam SaleemAllah Almogadwy muhammad Adnan Khan muhammad Hasnain Azam Khan muhammad Adnan Department of Computer Sciences Bahria University Lahore CampusLahore54000Pakistan Faculty of Information Technology Liwa CollegeAbu Dhabi00000United Arab Emirates Department of Computing Skyline University CollegeSharjah1797United Arab Emirates Department of Computer Science Taibah UniversityMedina42353Saudi Arabia Riphah School of Computing and Innovation Faculty of ComputingRiphah International UniversityLahore CampusLahore54000Pakistan Department of Engineering and Development Dubizzle LabsLahore54000Pakistan Department of Software Faculty of Artificial Intelligence and SoftwareGachon UniversitySeongnam-si13120Korea

Cardiotocography measures the fetal heart rate in the fetus during pregnancy to ensure physical health because cardiotocography gives data about fetal heart rate and uterine shrinkages which is very beneficial to detect whether the fetus is normal or suspect or *** cardiotocography measures infer wrongly and give wrong predictions because of human *** traditional way of reading the cardiotocography measures is the time taken and belongs to numerous human errors as *** condition is very important to measure at numerous stages and give proper medications to the fetus for its *** the current period Machine learning(ML)is a well-known classification strategy used in the biomedical field on various issues because ML is very fast and gives appropriate results that are better than traditional *** techniques play a pivotal role in detecting fetal disease in its early *** research article uses Federated machine learning(FML)and ML techniques to classify the condition of the *** study proposed a model for the detection of bio-signal cardiotocography that uses FML and ML techniques to train and test the ***,the proposed model of FML used numerous data preprocessing techniques to overcome data deficiency and achieves 99.06%and 0.94%of prediction accuracy and misprediction rate,respectively,and parallel the proposed model applying K-nearest neighbor(KNN)and achieves 82.93%and 17.07%of prediction accuracy and misprediction accuracy,***,by comparing both models FML outperformed the KNN technique and achieved the best and most appropriate prediction results as compared with previous studies the proposed study achieves the best and most accurate results.

关键词： Cardiotocography ML FML fetal disease bio-signal