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Construction of robust and durable Cu_(2)Se-V_(2)O_(5) nanosheet electrocatalyst for alkaline oxygen evolution reaction

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Frontiers of Chemical Science and Engineering 2024年第6期18卷 71-83页

作者： Tauseef Munawar Ambreen Bashir Khalid Mujasam Batoo Saman Fatima Faisal Mukhtar Sajjad Hussain Sumaira Manzoor muhammad naeem ashiq Shoukat Alim Khan Muammer Koc Faisal Iqbal Institute of Physics The Islamia University of BahawalpurBahawalpur 63100Pakistan King Abdullah Institute for Nanotechnology King Saud UniversityRiyadh 11451Saudi Arabia Hybrid Materials Center(HMC) Sejong UniversitySeoul 05006Republic of Korea Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Institute of Chemical Sciences Bahauddin Zakariya UniversityMultan 60800Pakistan Division of Sustainable Development College of Science and EngineeringHamad Bin Khalifa UniversityQatar FoundationDoha 34110Qatar

Reducing the production costs of clean energy carriers such as hydrogen through scalable water electrolysis is a potential solution for advancing the hydrogen *** the various material candidates,our group demonstrated transition-metal-based materials with tunable electronic characteristics,various phases,and ***,electrochemical water oxidation using Cu_(2)Se-V_(2)O_(5) as a non-precious metallic electrocatalyst via a hydrothermal approach is *** water-splitting performance of all the fabricated electrocatalysts was evaluated after direct growth on a stainless-steel *** electrochemically tuned Cu_(2)Se-V_(2)O_(5) catalyst exhibited a reduced overpotential of 128 mV and provided a reduced Tafel slope of 57 mV·dec^(−1) to meet the maximum current density of 250 mA·cm^(−2).The optimized strategy for interfacial coupling of the fabricated Cu_(2)Se-V_(2)O_(5) catalyst resulted in a porous structure with accessible active sites,which enabled adsorption of the intermediates and afforded an effective charge transfer rate for promoting the oxygen evolution ***,the combined effect of the catalyst components provided long-term stability for over 110 h in an alkaline solution,which makes the catalyst promising for large-scale practical *** aforementioned advantages of the composite catalyst overcome the limitations of low conductivity,agglomeration,and poor stability of the pure catalysts(Cu2Se and V2O5).

关键词： oxygen evolution reaction Cu_(2)Se-V_(2)O_(5)composite nanosheets metal-diffused ions accessible adsorption sites

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Structural,electrical,dielectric and magnetic properties of Mn-Nd substituted CoFeO3 nano sized multiferroics

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Progress in Natural Science:Materials International 2016年第4期26卷 325-333页

作者： Abdul Aziz E.Ahmed muhammad naeem ashiq muhammad Azhar Khan Nazia Karamat Irshad Ali Department of Physics Bahauddin Zakariya University Institute of Chemical Sciences Bahauddin Zakariya University Department of Physics The Islamia University of Bahawalpur Institute of Chemical Sciences Bahauddin Zakariya University

A series of Mn x Co1-xFe1-yNdyO3(where x=0.0–1.0 & y=0.0–0.1) multiferroic nanocrystals was synthesized via sol-gel auto-combustion technique. The structure was confirmed by X-ray diffraction(XRD)while morphology was investigated by scanning electron microscopy(SEM). The electrical resistivity was observed to increase from 2.14 * 107to 8.77 * 109Ω-cm and activation energy was found to increase from 0.64 to 0.75 e V, while the drift mobility decreased from 4.75 * 10-13to 1.27 * 10-15cm2V-1S-1by the substitution of Mn and Nd contents. The dielectric constant, dielectric loss and dielectric loss factor decrease with frequency and Mn-Nd contents. The saturation magnetization was increased from 34 to 70 emu g-1while the coercivity decreased from 705 to 262 Oe with the increase of *** increase in electrical resistivity and saturation magnetization while decrease in dielectric parameters and coercivity make these nanomaterials suitable for applications in microwave devices and longitudinal magnetic recording media.

关键词： Nanostructured materials XRD Dielectric properties Electrical properties Magnetic properties

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Preparation and characterization of doubly substituted microwave absorbing material by sol-gel technique for super high frequency applications

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Progress in Natural Science:Materials International 2018年第4期28卷 478-482页

作者： Imran Sadiq Shahzad Naseem Saira Riaz S.Sajjad Hussain muhammad naeem ashiq Mazhar Rana Centre of Excellence in Solid State Physics University of the Punjab Institute of Chemical sciences Bahauddin Zakariya University

Rare earth Dy;and divalent Mn;elements substituting W-type hexagonal ferrites Ba;Dy;Zn;Fe;Mn;O;（x=0,0.02,0.06,0.1 and y=0,0.1,0.3,0.5）were prepared by sol-gel *** thermo-gravimetric analysis（TGA）and differential scanning calorimetry（DSC）was carried out to find the temperature at which single phase can be *** patterns indicate the presence of the single phase for all the synthesized samples with the absence of any extra peak due to unreacted material and secondary *** occurrence of absorption bands at low wave numbers(563 and 446 cm;),can be assigned to the stretching vibration of metal and oxygen ions in FTIR spectra,which also confirms the single hexagonal phase for prepared *** grains are of platelet like structure,which enhances the microwave absorption properties of hexagonal *** synthesized material exhibits the minimum reflection loss of-20.9 dB at 11.8 GHz frequency,which reflects the applications of this material in super high frequency *** microwave conductivity of the material increases with frequency.

关键词： Sol-Gel synthesis XRD Microwave absorption properties Microwave conductivity

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The Spherical q-Linear Diophantine Fuzzy Multiple-Criteria Group Decision-Making Based on Differential Measure

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Computer Modeling in Engineering & Sciences 2024年第2期138卷 1925-1950页

作者： Huzaira Razzaque Shahzaib Ashraf muhammad naeem Yu-Ming Chu Institute of Mathematics Khwaja Fareed University of Engineering&Information TechnologyRahim Yar Khan64200Pakistan Department of Mathematics Deanship of Applied SciencesUmm Al-Qura UniversityMeccaSaudi Arabia Department of Mathematics Huzhou UniversityHuzhou313000China

Spherical q-linearDiophantine fuzzy sets(Sq-LDFSs)provedmore effective for handling uncertainty and vagueness in multi-criteria decision-making(MADM).It does not only cover the data in two variable parameters but is also beneficial for three parametric *** Pythagorean fuzzy sets,the difference is calculated only between two parameters(membership and non-membership).According to human thoughts,fuzzy data can be found in three parameters(membership uncertainty,and non-membership).So,to make a compromise decision,comparing Sq-LDFSs is *** measures of different fuzzy sets do,however,can have several flaws that can lead to counterintuitive *** instance,they treat any increase or decrease in the membership degree as the same as the non-membership degree because the uncertainty does not change,even though each parameter has a different *** the Sq-LDFSs comparison,this research develops the differentialmeasure(DFM).Themain goal of the DFM is to cover the unfair arguments that come from treating different types of FSs opposing criteria *** to their relative positions in the attribute space and the similarity of their membership and non-membership degrees,two Sq-LDFSs formthis preference connectionwhen the uncertainty remains same in both *** to the degree of superiority or inferiority,two Sq-LDFSs are shown as identical,equivalent,superior,or inferior over one *** suggested DFM’s fundamental characteristics are *** on the newly developed DFM,a unique approach tomultiple criterion group decision-making is *** suggestedmethod verifies the novel way of calculating the expert weights for Sq-LDFSS as in *** proposed technique in three parameters is applied to evaluate solid-state drives and choose the optimum photovoltaic cell in two applications by taking uncertainty parameter *** method’s applicability and validity shown by the findings are contrasted with those obtained using various

关键词： Multi-criteria group decision-making spherical q-linear Diophantine fuzzy sets differencemeasures photovoltaic cells medical diagnosis

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锆酸锶纳米颗粒光催化还原二氧化碳的研究（英文）

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Science China Materials 2015年第8期58卷 634-639,593页

作者： muhammad naeem ashiq 王艳杰 muhammad Fahad Ehsan 贺涛 CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology Institute of Chemical Sciences Bahauddin Zakariya University

全球变暖和能源危机使得人们开始同时关注二氧化碳和太阳能的利用.在本工作中,我们制备了Sr Zr O3纳米颗粒,并将其作为催化剂使二氧化碳转化为高能量附加值产品.我们利用超声化学法成功制备了Sr Zr O3纳米材料,并通过X射线衍射(XRD)、... 详细信息

全球变暖和能源危机使得人们开始同时关注二氧化碳和太阳能的利用.在本工作中,我们制备了Sr Zr O3纳米颗粒,并将其作为催化剂使二氧化碳转化为高能量附加值产品.我们利用超声化学法成功制备了Sr Zr O3纳米材料,并通过X射线衍射(XRD)、拉曼光谱、扫描电子显微镜(SEM)、BET比表面积分析、X射线光电子能谱(XPS)以及紫外-可见吸收光谱(UV/vis)等对样品进行了相应表征.将Sr Zr O3作为催化剂,在300W氙灯光源照射下进行光催化还原二氧化碳实验,结果表明乙醇、甲烷和一氧化碳是主要的光催化产物,反应进行4小时后,三种产物相应的产量分别为41、2.57和1.6μmol g-1.论文分析了三种产物生成的原因.本研究工作表明,Sr Zr O3纳米材料可以作为一种有效的催化剂应用于光催化还原二氧化碳.

关键词：光催化还原 Zr 二氧化碳 CO2 工业气体 XPS 催化剂 XRD 纳米颗粒

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Variable range hopping transport and dielectric relaxation mechanism in GdCrO_(3) rare-earth orthochromite perovskite

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Journal of Rare Earths 2024年第7期42卷 1304-1316,I0004页

作者： muhammad Javed Ayaz Arif Khan Jamal Kazmi naeem Akbar Said Nasir Khisro Amanullah Dar Aleem Dad Khan Tareen Mohd Ambri Mohamed Department of Physics The University of Azad Jammu and KashmirMuzaffarabad13100Pakistan Department of Physics University of Kotli Azad Jammu and KashmirKotli11100Pakistan Institute of Microengineering and Nanoelectronics Universiti Kebangsaan Malaysia43600BangiSelangorMalaysia Department of Mathematics University of Kotli Azad Jammu and KashmirKotli11100Pakistan

The polycrystalline GdCrO_(3)(GCO)perovskite orthochromite was synthesized by the sol-gel auto-combustion *** Rietveld refined X-ray diffraction(XRD)profile of GCO confirms that the orthorhombic phase crystallizes in perovskite crystal structure with space group *** transmission electron microscopy and selected area electron diffraction divulge the polycrystalline nature of the perovskite *** field emission scanning electron microscopy(FESEM)images reveal the microstructural polyhedral growth of grains separated by sharp grain *** chemical states of the ions present in the compound were investigated by X-ray photoelectron spectroscopy(XPS)studies,and the electrical pathways were *** impedance studies were carried out in the experimental frequency and temperature ranges of 40 Hz-4 MHz and 178-408 K,*** equivalent circuit model(RGQG)(RGBQGB)resolves the impedance response into two contributions originating from the intra-grain and inter-granular micro-constituents of the *** electrical conduction mechanism is based on the Mott variable range hopping *** complex electric modulus studies demonstrate the short-and long-range mobility of the charge carriers and rule out the presence of electrode effects on the dielectric relaxation mechanism of the *** decreasing pattern of dielectric permittivity with frequency is explained by the Maxwell-Wagner type of *** frequency dependence of the loss factor exhibits the presence of thermally activated relaxation time distribution in the material.

关键词： Auto-combustion Perovskite Electro-ceramic Dielectric Electrical transport Impedance

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Analysis of Genetic Alterations in TP53 Gene in Breast Cancer - A Secondary Publication

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Proceedings of Anticancer Research 2024年第3期8卷 25-35页

作者： Baqaur Rehman muhammad Abubakar muhammad naeem Kiani Rooma Ayyoub Department of Biosciences COMSATS University IslamabadPark RdIslamabad Capital Territory 45550Pakistan Guangdong Key Laboratory of Biomedical Measurements and Ultrasound Imaging School of Biomedical EngineeringShenzhen University Medical SchoolShenzhen UniversityShenzhen 518060China

Tumor protein p53 (TP53) mediates DNA repair and cell proliferation in growing cells. The TP53 gene is a tumor suppressor that regulates the expression of target genes in response to multiple cellular stress factors. Key target genes are involved in crucial cellular events such as DNA repair, cell cycle regulation, apoptosis, metabolism, and senescence. TP53 genetic variants and the activity of the wild-type p53 protein (WT-p53) have been linked to a wide range of tumorigenesis. Various genetic and epigenetic alterations, including germline and somatic mutations, loss of heterozygosity, and DNA methylation, can alter TP53 activity, potentially resulting in cancer initiation and progression. This study was designed to screen three reported mutations in the DNA-binding domain of the p53 protein in breast cancer, to evaluate the relative susceptibility and risk associated with breast cancer in the local population. Genomic DNA was isolated from 30 breast tumor tissues along with controls. Tetra and Tri ARMS PCR were performed to detect mutations in the TP53 coding region. For SNPs c.637C>T and c.733C>T, all analyzed cases were homozygous for the wild-type allele ‘C,’ while for SNP c.745A>G, all cases were homozygous for the wild-type allele ‘A.’ These results indicate no relevance of these three SNPs to cancer progression in our study cohort. Additionally, the findings from whole exon sequencing will help to predict more precise outcomes and assess the importance of TP53 gene mutations in breast cancer patients.

关键词： Breast cancer p53 Gene expression Mutation SNPs

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融合乌尔都语词性序列预测的汉乌神经机器翻译

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计算机工程与科学 2024年第3期46卷 518-524页

作者：陈欢欢王剑 muhammad naeem Ul Hassan 昆明理工大学信息工程与自动化学院云南昆明650500 昆明理工大学云南省人工智能重点实验室云南昆明650500

面向南亚和东南亚的小语种机器翻译,目前已有不少研究团队开展了深入研究,但作为巴基斯坦官方语言的乌尔都语,由于稀缺的数据资源和与汉语之间的巨大差距,有针对性的汉乌机器翻译方法研究非常稀少。针对这种情况,提出了基于Transformer... 详细信息

面向南亚和东南亚的小语种机器翻译,目前已有不少研究团队开展了深入研究,但作为巴基斯坦官方语言的乌尔都语,由于稀缺的数据资源和与汉语之间的巨大差距,有针对性的汉乌机器翻译方法研究非常稀少。针对这种情况,提出了基于Transformer的融合乌尔都语词性序列的汉乌神经机器翻译模型。首先利用Transformer对目标语言乌尔都语的词性序列进行预测,然后将翻译模型的预测结果和词性序列模型的预测结果相结合进行联合预测,从而实现语言知识到翻译模型的融入。在现有小规模汉乌数据集上的实验表明,所提方法在数据集上的BLEU值相较于基准模型提升了0.13,取得了较为明显的效果。

关键词： Transformer 神经机器翻译乌尔都语词性序列

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A Double-Branch Xception Architecture for Acute Hemorrhage Detection and Subtype Classification

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Computers, Materials & Continua 2023年第9期76卷 3727-3744页

作者： muhammad naeem Akram muhammad Usman Yaseen muhammad Waqar muhammad Imran Aftab Hussain Department of Computer Science COMSATS University IslamabadIslamabad45550Pakistan Department of Software Engineering Capital University of Science&TechnologyIslamabad44000Pakistan

This study presents a deep learning model for efficient intracranial hemorrhage(ICH)detection and subtype classification on non-contrast head computed tomography(CT)*** refers to bleeding in the skull,leading to the most critical life-threatening health condition requiring rapid and accurate *** is classified as intra-axial hemorrhage(intraventricular,intraparenchymal)and extra-axial hemorrhage(subdural,epidural,subarachnoid)based on the bleeding location inside the *** computer-aided diagnoses(CAD)-based schemes have been proposed for ICH detection and classification at both slice and scan ***,these approaches performonly binary classification and suffer from a large number of parameters,which increase storage ***,the accuracy of brain hemorrhage detection in existing models is significantly low for medically critical *** overcome these problems,a fast and efficient system for the automatic detection of ICH is *** designed a double-branch model based on xception architecture that extracts spatial and instant features,concatenates them,and creates the 3D spatial context(common feature vectors)fed to a decision tree classifier for final *** data employed for the experimentation was gathered during the 2019 Radiologist Society of North America(RSNA)brain hemorrhage detection *** model outperformed benchmark models and achieved better accuracy in intraventricular(99.49%),subarachnoid(99.49%),intraparenchymal(99.10%),and subdural(98.09%)categories,thereby justifying the performance of the proposed double-branch xception architecture for ICH detection and classification.

关键词： Computed tomography convolutional neural networks intracranial hemorrhage xception architecture

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Numerical Simulation of Reiner–Rivlin Nanofluid Flow under the Influence of Thermal Radiation and Activation Energy over a Rotating Disk

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Computer Modeling in Engineering & Sciences 2022年第6期131卷 1669-1692页

作者： Arfan Shahzad muhammad Imran muhammad Nawaz naeem Mohsan Raza Department of Mathematics Government College University FaisalabadFaisalabad38000Pakistan Department of Sciences&Humanities National University of Computer and Emerging SciencesChiniot-Faisalabad CampusFaisalabad38000Pakistan

In current study,the numerical computations of Reiner–Rivlin nanofluid flow through a rotational disk under the influence of thermal radiation and Arrhenius activation energy is *** innovative physical situations,the motile microorganisms are incorporated *** multiple slip effects are considered in the boundary *** bioconvection of motile microorganism is utilized alongside nanofluids to provide stability to enhanced thermal *** Bioconvection pattern in various nanoparticles accredits novel applications of biotechnology like the synthesis of biological polymers,biosensors,fuel cells,petroleum engineering,and the natural *** deploying some suitable similarity transformation functions,the governing partial differential equations(PDEs)of the flow problem are rehabilitated into dimensionless *** accomplished ordinary differential equations(ODEs)are solved numerically through the bvp4c scheme via a built-in function in computational MATLAB *** upshots of some prominent physical and bioconvection parameters including wall slip parameters,thermophoresis parameter,Brownian motion parameter,Reiner–Revlin nanofluid parameter,Prandtl number,Peclet number,Lewis number,bioconvection Lewis number,and the mixed convection parameter against velocity,temperature,nanoparticles concentration,and density of motile microorganism profiles are dichotomized and pondered through graphs and *** presented computations show that the velocity profiles are de-escalated by the wall slip parameters while the thermal and solutal fields are upgraded with augmentation in thermophoresis number and wall slip *** presence of thermal radiation enhances the temperature profile of *** concentration profile of nanoparticles is boosted by intensification in activation ***,the increasing values of bioconvection Lewis number and Peclet number decay the motile microorganisms’field.

关键词： Reiner-Rivlin nanofluid bioconvection motile swimming microorganisms rotational disk multiple slip conditions bvp4c

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